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    • 1. 发明授权
    • Electrolytic cell for producing periodates
    • 电解池生产高碘酸盐
    • US4687565A
    • 1987-08-18
    • US843981
    • 1986-03-25
    • Kaoru HirakataMasaaki MochizukiHideo KanaiReiichi Itai
    • Kaoru HirakataMasaaki MochizukiHideo KanaiReiichi Itai
    • C25B1/28C25B9/00C25B9/08C25B11/02
    • C25B9/08C25B1/28
    • An improved electrolytic cell of simple construction capable of satisfactorily producing periodates comprises a plurality of cathodes mounted vertically in parallel to the long sides of a cell body and spaced at equal intervals from each other, a plurality of open anodic compartment boxes with plate separators adapted to maintain the equal intervals, one or more anodes inserted in the compartment boxes, a plurality of PVC diaphragms mounted on both sides of the anodic compartment boxes in parallel to the cathodes, an anolyte inlet mounted in the lower part of the anodic compartment boxes and an anolyte outlet mounted in the upper part of the opposite side of the anodic compartment boxes, a cell cover provided with air intake holes and cell gas exhaust pipes, and perforated PVC lids for the cathodic compartments positioned between the cell cover and the upper level of the catholyte.
    • 具有能够令人满意地生产高碘酸盐的简单结构的改进的电解池包括垂直于电池体的长边并排安装的多个阴极,并且彼此间隔相等的间隔开的多个阳极隔室箱, 保持相等的间隔,一个或多个阳极插入隔室箱中,多个PVC隔板安装在阴极平行的阳极隔间箱的两侧,安装在阳极室箱的下部的阳极电解液入口和 阳极电解液出口安装在阳极室箱的相对侧的上部,设置有进气孔和电池排气管的电池盖,以及用于阴极室的穿孔PVC盖,其位于电池盖和电池盖的上层之间 阴极电解液
    • 7. 发明授权
    • Anode coated with .beta.-lead dioxide and method of producing same
    • 用β-二氧化碳涂覆的阳极及其制备方法
    • US4415411A
    • 1983-11-15
    • US236908
    • 1981-02-23
    • Hideo KanaiAkihiro ShinagawaTakahiro YamazakiReiichi Itai
    • Hideo KanaiAkihiro ShinagawaTakahiro YamazakiReiichi Itai
    • C25B11/02C25B11/16C25C7/02C25D17/12
    • C25B11/16C25B11/02C25C7/02
    • An anode coated with .beta.-lead dioxide which comprises a titanium substrate, titanium expanded metal welded on at least one side of the titanium substrate, titanium reinforcing bars welded on the peripheries of said expanded metal to both said expanded metal and said substrate, at least one intermediate layer being applied on said substrate and said expanded metal, said intermediate layer consisting either of an alloy or an oxide of platinum group metals; and a .beta.-lead dioxide coating layer on said intermediate layer.The anode of this invention has particularly good dimensional stability and provides excellent adhesion of the .beta.-lead dioxide coating layer to the substrate, and hence is highly suitable for the electrolytic production of chlorates, perchlorates, and periodates, and furthermore it is also useful as an insoluble anode in electroplating and in electrolytic treatment of waste water.
    • 涂覆有β-二氧化碳的阳极,其包括钛基底,焊接在钛基底的至少一侧上的钛膨胀金属,至少焊接在所述多孔金属和所述基底两者上的钛钢筋,至少 一个中间层施加在所述基材和所述多孔金属上,所述中间层由铂族金属的合金或氧化物组成; 和所述中间层上的β-二氧化碳涂层。 本发明的阳极具有特别好的尺寸稳定性,并且提供了β-二氧化铅涂层对基材的极好的粘合性,因此非常适用于氯酸盐,高氯酸盐和高碘酸盐的电解生产,此外它也可用作 在电镀和电解处理废水中的不溶性阳极。