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1. 发明授权

US07473728B2 Dual phase rubber composition and tire with nanocomposite-containing sidewall thereof 失效
标题翻译：双相橡胶组合物和具有纳米复合材料侧壁的轮胎
公开(公告)号：US07473728B2
公开(公告)日：2009-01-06
申请号：US11014017
申请日：2004-12-16
申请人： Junling Zhao , Michael Julian Crawford , Aaron Scott Puhala , Martin Paul Cohen
发明人： Junling Zhao , Michael Julian Crawford , Aaron Scott Puhala , Martin Paul Cohen
IPC分类号： C08K9/04
CPC分类号： C08L7/00 , C08K3/346 , C08K3/36 , C08L23/16 , C08L23/22 , C08L23/283 , C08L2666/02 , C08L2666/08
摘要： This invention relates to a dual phase rubber composition and pneumatic tire with a rubber sidewall thereof, namely a dual phased non-black colored rubber composition composed of a first pre-formed elastomer phase comprised of butyl-type rubber and EPDM rubber containing a dispersion therein of reinforcing filler comprised of a particulate amorphous precipitated silica and a second pre-formed elastomer phase comprised of a nanocomposite of natural rubber containing a dispersion therein of exfoliated clay platelets. Said exfoliated clay platelets may be substantially oriented within the tire sidewall in a parallel direction to each and may also be substantially oriented in an annular direction about the axis of the tire. The tire sidewall rubber composition may contain at least one additional elastomer which may be included in either or both of said elastomer phases. Such tire sidewall rubber composition may contain a non-black colorant pigment, such as for example a white colored titanium dioxide pigment. The dual phased tire sidewall rubber composition is prepared by a phase mixing process comprised of pre-blending said butyl-type rubber and EPDM rubber together with said precipitated silica reinforcing filler to form a pre-mix thereof, and thereafter mixing therewith said nanocomposite as a pre-formed blend of natural rubber and exfoliated clay platelets.
摘要翻译：本发明涉及一种双相橡胶组合物和具有橡胶侧壁的充气轮胎，即双相非黑色橡胶组合物，其由包含丁基橡胶的第一预成型弹性体相和含有分散体的EPDM橡胶组成的由无定形沉淀二氧化硅颗粒构成的增强填料和由纳米复合材料组成的第二预成形弹性体相，其中所述天然橡胶含有分散在其中的剥离粘土片晶。所述剥离的粘土小片可以在轮胎侧壁内基本上在与每个平行的方向上定向并且也可以基本上围绕轮胎的轴线在环形方向上取向。轮胎侧壁橡胶组合物可以含有至少一种另外的弹性体，其可以包括在所述弹性体相中的一个或两个中。这种轮胎侧壁橡胶组合物可以含有非黑色着色剂颜料，例如白色二氧化钛颜料。双相轮胎侧壁橡胶组合物通过相混合方法制备，该相混合方法包括将所述丁基橡胶和EPDM橡胶与所述沉淀二氧化硅增强填料一起预混合以形成其预混物，然后与所述纳米复合材料混合，预先形成的天然橡胶和剥离粘土血小板的混合物。

2. 发明授权

US08662123B2 Tire with rubber tread of circumferential zones with graduated physical properties 有权
标题翻译：轮胎具有橡胶胎面圆周区域，具有分级物理性能
公开(公告)号：US08662123B2
公开(公告)日：2014-03-04
申请号：US12479884
申请日：2009-06-08
申请人： Aaron Scott Puhala , Michael Julian Crawford , Leonard James Reiter , Jeremy Elton Miracle , Martin Paul Cohen , Samuel Patrick Landers , David Charles Poling , Robert Allen Losey , Bernard Matthew Bezilla, Jr. , Donald Allan Abbott
发明人： Aaron Scott Puhala , Michael Julian Crawford , Leonard James Reiter , Jeremy Elton Miracle , Martin Paul Cohen , Samuel Patrick Landers , David Charles Poling , Robert Allen Losey , Bernard Matthew Bezilla, Jr. , Donald Allan Abbott
IPC分类号： B60C1/00 , B60C11/00
CPC分类号： B60C11/00 , B60C11/005 , B60C11/0058 , B60C2011/0025
摘要： The invention relates to a tire having a rubber tread comprised of cap/base construction where the tread cap layer provides the running surface of the tread and the tread base layer underlies the tread cap layer and thereby provides a transition between the tread cap layer and the tire carcass. For this invention, the tread cap layer is comprised of a plurality of individual circumferential load-bearing zones of rubber compositions, which exhibit graduated physical properties, and which extend from the outer running surface of the tread cap layer radially inward to said tread base layer. In one aspect, the zoned rubber tread cap layer and rubber tread base layer are co-extruded together to form a unit as an integral tread rubber composite.
摘要翻译：本发明涉及一种具有橡胶胎面的轮胎，该橡胶胎面由帽/底座结构组成，其中胎面覆盖层提供胎面的跑道表面，而胎面基底层位于胎冠盖层的下面，从而提供胎面覆盖层和轮胎胎体对于本发明，胎面覆盖层由橡胶组合物的多个独立的圆周承载区域组成，其具有分级的物理性能，并且从胎面盖层的外部行进表面径向向内延伸到所述胎面基底层。在一个方面，将分区的橡胶胎冠层和橡胶胎面基层共同挤压在一起以形成作为整体胎面橡胶复合材料的单元。

3. 发明申请

US20090242091A1 TIRE WITH RUBBER TREAD OF CIRCUMFERENTIAL ZONES WITH GRADUATED PHYSICAL PROPERTIES 有权
标题翻译：轮胎与带有分级物理特性的圆形区域的橡胶条
公开(公告)号：US20090242091A1
公开(公告)日：2009-10-01
申请号：US12479884
申请日：2009-06-08
申请人： Aaron Scott Puhala , Michael Julian Crawford , Leonard James Reiter , Jeremy Elton Miracle , Martin Paul Cohen , Samuel Patrick Landers , David Charles Poling , Robert Allen Losey , Bernard Matthew Bezilla, JR. , Donald Allan Abbott
发明人： Aaron Scott Puhala , Michael Julian Crawford , Leonard James Reiter , Jeremy Elton Miracle , Martin Paul Cohen , Samuel Patrick Landers , David Charles Poling , Robert Allen Losey , Bernard Matthew Bezilla, JR. , Donald Allan Abbott
IPC分类号： B60C11/00
CPC分类号： B60C11/00 , B60C11/005 , B60C11/0058 , B60C2011/0025
摘要： The invention relates to a tire having a rubber tread comprised of cap/base construction where the tread cap layer provides the running surface of the tread and the tread base layer underlies the tread cap layer and thereby provides a transition between the tread cap layer and the tire carcass. For this invention, the tread cap layer is comprised of a plurality of individual circumferential load-bearing zones of rubber compositions, which exhibit graduated physical properties, and which extend from the outer running surface of the tread cap layer radially inward to said tread base layer. In one aspect, the zoned rubber tread cap layer and rubber tread base layer are co-extruded together to form a unit as an integral tread rubber composite.
摘要翻译：本发明涉及一种具有橡胶胎面的轮胎，该橡胶胎面由帽/底座结构组成，其中胎面覆盖层提供胎面的跑道表面，而胎面基底层位于胎冠盖层的下面，从而提供胎面覆盖层和轮胎胎体对于本发明，胎面覆盖层由橡胶组合物的多个独立的圆周承载区域组成，其具有分级的物理性能，并且从胎面盖层的外部行进表面径向向内延伸到所述胎面基底层。在一个方面，将分区的橡胶胎冠层和橡胶胎面基层共同挤压在一起以形成作为整体胎面橡胶复合材料的单元。

4. 发明授权

US07559348B2 Tire with rubber tread of circumferential zones with graduated physical properties 有权
标题翻译：轮胎具有橡胶胎面圆周区域，具有分级物理性能
公开(公告)号：US07559348B2
公开(公告)日：2009-07-14
申请号：US11043495
申请日：2005-01-26
申请人： Aaron Scott Puhala , Michael Julian Crawford , Leonard James Reiter , Jeremy Elton Miracle , Martin Paul Cohen , Samuel Patrick Landers , David Charles Poling , Robert Allen Losey , Bernard Matthew Bezilla, Jr. , Donald Allan Abbott
发明人： Aaron Scott Puhala , Michael Julian Crawford , Leonard James Reiter , Jeremy Elton Miracle , Martin Paul Cohen , Samuel Patrick Landers , David Charles Poling , Robert Allen Losey , Bernard Matthew Bezilla, Jr. , Donald Allan Abbott
IPC分类号： B60C1/00 , B60C11/00
CPC分类号： B60C11/00 , B60C11/005 , B60C11/0058 , B60C2011/0025
摘要： The invention relates to a tire having a rubber tread comprised of cap/base construction where the tread cap layer provides the running surface of the tread and the tread base layer underlies the tread cap layer and thereby provides a transition between the tread cap layer and the tire carcass. For this invention, the tread cap layer is comprised of a plurality of individual circumferential load-bearing zones of rubber compositions, which exhibit graduated physical properties, and which extend from the outer running surface of the tread cap layer radially inward to said tread base layer. In one aspect, the zoned rubber tread cap layer and rubber tread base layer are co-extruded together to form a unit as an integral tread rubber composite.
摘要翻译：本发明涉及一种具有橡胶胎面的轮胎，该橡胶胎面由帽/底座结构组成，其中胎面覆盖层提供胎面的跑道表面，而胎面基底层位于胎冠盖层的下面，从而提供胎面覆盖层和轮胎胎体对于本发明，胎面覆盖层由橡胶组合物的多个独立的圆周承载区域组成，其具有分级的物理性能，并且从胎面盖层的外部行进表面径向向内延伸到所述胎面基底层。在一个方面，将分区的橡胶胎冠层和橡胶胎面基层共同挤压在一起以形成作为整体胎面橡胶复合材料的单元。

5. 发明申请

US20130065984A1 TIRE HAVING RUBBER COMPONENT CONTAINING SHORT FIBER REINFORCEMENT WITH COMPATABLIZER 有权
标题翻译：具有包含短纤维加固的橡胶组件的轮胎与配套器
公开(公告)号：US20130065984A1
公开(公告)日：2013-03-14
申请号：US13668403
申请日：2012-11-05
申请人： Junling Zhao , Martin Paul Cohen
发明人： Junling Zhao , Martin Paul Cohen
IPC分类号： C08L7/00 , C08L77/10 , C08L9/00 , C08J3/22
CPC分类号： C08L9/06 , C08K7/02 , C08L15/00 , Y10T152/10513 , C08L2666/08
摘要： The invention relates to a tire having a rubber component which contains short fiber reinforcement with a compatabilizer for the fiber reinforcement. Desirably said short fiber reinforcement is an aramid pulp. Desirably said compatabilizer is an epoxy functionalized natural rubber.
摘要翻译：本发明涉及一种具有橡胶组分的轮胎，该橡胶组分含有纤维增强剂的混合物的短纤维增强物。理想地说，短纤维增强物是芳族聚酰胺纸浆。理想地说，所述配制剂是环氧官能化天然橡胶。

6. 发明申请

US20120152423A1 TIRE HAVING RUBBER COMPONENT CONTAINING SHORT FIBER REINFORCEMENT WITH COMPATABLIZER 审中-公开
标题翻译：具有包含短纤维加固的橡胶组件的轮胎与配套器
公开(公告)号：US20120152423A1
公开(公告)日：2012-06-21
申请号：US12971326
申请日：2010-12-17
申请人： Junling Zhao , Martin Paul Cohen
发明人： Junling Zhao , Martin Paul Cohen
IPC分类号： B60C9/12 , C08K3/36 , C08K3/04 , C08J3/22
CPC分类号： C08L9/06 , C08K7/02 , C08L15/00 , Y10T152/10513 , C08L2666/08
摘要： The invention relates to a tire having a rubber component which contains short fiber reinforcement with a compatabilizer for the fiber reinforcement. Desirably said short fiber reinforcement is an aramid pulp. Desirably said compatabilizer is an epoxy functionalized natural rubber.
摘要翻译：本发明涉及一种具有橡胶组分的轮胎，该橡胶组分含有纤维增强剂的混合物的短纤维增强物。理想地说，短纤维增强物是芳族聚酰胺纸浆。理想地说，所述配制剂是环氧官能化天然橡胶。

7. 发明申请

US20130310501A1 TREATMENT OF PRE-HYDROPHOBATED SILICA IN SITU WITHIN A RUBBER COMPOSITION, THE RUBBER COMPOSITION AND TIRE WITH COMPONENT 审中-公开
标题翻译：在橡胶组合物中的预处理二氧化硅处理，橡胶组合物和轮胎与组分
公开(公告)号：US20130310501A1
公开(公告)日：2013-11-21
申请号：US13474772
申请日：2012-05-18
申请人： Junling Zhao , John Joseph Andre Verthe , Martin Paul Cohen
发明人： Junling Zhao , John Joseph Andre Verthe , Martin Paul Cohen
IPC分类号： C08K5/548
CPC分类号： C08K9/06 , C08K5/54 , C08K5/548 , C08L21/00
摘要： The invention relates to treatment of a pre-hydrophobated precipitated silica in situ within a rubber composition. The invention relates to preparation of treated precipitated silica by treatment of pre-hydrophobated precipitated silica in situ within a rubber composition with a bis(3-trialkoxysilylalkyl) polysulfide. The invention further comprises the resultant rubber composition and a tire having a component thereof.
摘要翻译：本发明涉及在橡胶组合物内原位处理预疏水化沉淀二氧化硅。本发明涉及通过用双（3-三烷氧基甲硅烷基烷基）多硫化物在橡胶组合物内原位处理预疏水化沉淀二氧化硅来制备经处理的沉淀二氧化硅。本发明还包括所得橡胶组合物和具有其组分的轮胎。

8. 发明授权

US08501837B2 Tire having rubber component containing short fiber reinforcement with compatablizer 有权
标题翻译：轮胎具有含有短纤维增强材料的橡胶组分，具有可塑性
公开(公告)号：US08501837B2
公开(公告)日：2013-08-06
申请号：US13668403
申请日：2012-11-05
申请人： Junling Zhao , Martin Paul Cohen
发明人： Junling Zhao , Martin Paul Cohen
IPC分类号： C08L7/00
CPC分类号： C08L9/06 , C08K7/02 , C08L15/00 , Y10T152/10513 , C08L2666/08
摘要： The invention relates to a tire having a rubber component which contains short fiber reinforcement with a compatabilizer for the fiber reinforcement. Desirably said short fiber reinforcement is an aramid pulp. Desirably said compatabilizer is an epoxy functionalized natural rubber.
摘要翻译：本发明涉及一种具有橡胶组分的轮胎，该橡胶组分含有纤维增强剂的混合物的短纤维增强物。理想地说，短纤维增强物是芳族聚酰胺纸浆。理想地说，所述配制剂是环氧官能化天然橡胶。

9. 发明授权

US07342065B2 Preparation of nanocomposite of elastomer and exfoliated clay platelets, rubber compositions comprised of said nanocomposite and articles of manufacture, including tires 失效
标题翻译：制备弹性体和剥离粘土片晶的纳米复合材料，由所述纳米复合材料和制品制成的橡胶组合物，包括轮胎
公开(公告)号：US07342065B2
公开(公告)日：2008-03-11
申请号：US10932534
申请日：2004-09-02
申请人： Xiaoping Yang , Martin Paul Cohen , Michael Leslie Senyek , Dane Kenton Parker , Steven Wayne Cronin , Lewis Timothy Lukich , William Paul Francik , Cigdem Gurer
发明人： Xiaoping Yang , Martin Paul Cohen , Michael Leslie Senyek , Dane Kenton Parker , Steven Wayne Cronin , Lewis Timothy Lukich , William Paul Francik , Cigdem Gurer
IPC分类号： C08K3/34
CPC分类号： C08J3/215 , B60C1/00 , B60C1/0008 , B60C1/0016 , B60C1/0025 , B60C17/0009 , B60C2200/02 , C08J2321/00 , C08K3/346 , C08K9/04 , C08L21/00 , C08L2666/08
摘要： This invention relates to preparation of nanocomposites comprised of elastomer and a dispersion of an at least partially exfoliated water swellable clay and to rubber compositions containing such nanocomposite and articles of manufacture which contain at least one component thereof. The nanocomposite is prepared by addition of a water suspension of water swellable clay particles to an anionic aqueous emulsion of elastomer particles to form a mixture to which an amine having at least two amine centers is added to intercalate and at least partially exfoliate the water swelled clay particles by an ion exchange within the galleries of the multilayered clay with cation exchangeable ion(s) and to aid in coagulating the elastomer and resultant clay particles to form said nanocomposite.
摘要翻译：本发明涉及由弹性体和至少部分剥离的水可溶胀粘土的分散体组成的纳米复合材料，以及含有至少一种组分的纳米复合材料和制品。纳米复合材料通过将水溶胀性粘土颗粒的水悬浮液添加到弹性体颗粒的阴离子水性乳液中而形成混合物，其中加入具有至少两个胺中心的胺以插入并至少部分地去除水溶胀粘土颗粒通过离子交换在具有阳离子可交换离子的多层粘土的画廊内，并且有助于使弹性体和所得粘土颗粒凝结形成所述纳米复合材料。

10. 发明授权

US07368587B2 Functionalized siloxy compound, silica reinforced rubber compositions thereof and tire with component comprised thereof 有权
标题翻译：官能化甲硅烷氧基化合物，二氧化硅增强橡胶组合物和其组成的组分的轮胎
公开(公告)号：US07368587B2
公开(公告)日：2008-05-06
申请号：US11117106
申请日：2005-04-28
申请人： Martin Paul Cohen
发明人： Martin Paul Cohen
IPC分类号： C07F7/08
CPC分类号： C08K5/549 , C08K3/36 , C08L21/00
摘要： The present invention relates to a functionalized siloxy compound which is useful in silica-filled rubber compositions and the processing of a sulfur curable rubber composition containing silica. Accordingly, the invention further relates to a rubber composition containing at least one diene-based elastomer, particulate synthetic amorphous silica (e.g. precipitated silica) and said functionalized siloxy compound as a coupling agent and to an article of manufacture (e.g. tire) containing a component comprised of such rubber composition.
摘要翻译：本发明涉及一种功能化的甲硅烷氧基化合物，其可用于二氧化硅填充的橡胶组合物和加工含有二氧化硅的硫可固化橡胶组合物。因此，本发明还涉及含有至少一种二烯基弹性体，颗粒状合成无定形二氧化硅（例如沉淀二氧化硅）和所述官能化甲硅烷氧基化合物作为偶联剂的橡胶组合物和含有组分由这种橡胶组合物组成。

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