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    • 1. 发明授权
    • Preparation of oxidation-stable and low-temperature-stable base oils and
middle distillates
    • 氧化稳定和低温稳定的基础油和中间馏分的制备
    • US5143595A
    • 1992-09-01
    • US654883
    • 1991-02-01
    • Juergen ThomasRoland SpahlThomas AnstockAnsgar EisenbeisWolfgang Schmid
    • Juergen ThomasRoland SpahlThomas AnstockAnsgar EisenbeisWolfgang Schmid
    • B01J27/18B01J29/04C10G45/12C10G65/12C10M101/02C10N20/00C10N20/02C10N30/02C10N30/08C10N30/10C10N40/25
    • C10G65/12
    • A process for the preparation of a base oil and middle distillate which is stable to oxidation and low temperature from a mineral oil fraction having a boiling range above 350.degree. C., by, in a first step, converting the mineral oil fraction on a hydrocracking catalyst under hydrocracking conditions to an extent of from 20 to 80% by weight into fractions which boil below 360.degree. C., separating the reactor effluent, if necessary, into liquid and gas phases in a high-pressure separator, treating the entire reactor effluent or only the liquid phase, directly or after removal of the fractions boiling below 360.degree. C. by distillation, in a second step with hydrogen at from 200.degree. to 450.degree. C. and at from 20 to 150 bar in the presence of a catalyst which contains a crystalline pentasil-type borosilicate zeolite, alumina and/or amorphous alumosilicate as the carrier material and one or more metals from Group VIb and/or Group VIII of the Periodic Table and phosphorus, and, after distillation of the hydrogenation product, obtaining a middle distillate in the boiling range from 180.degree. to 360.degree. C. having a pour point of below -30.degree. C. and an oxidation-stable residue having a boiling point >360.degree. C., a viscosity index of from 110 to 135 and a pour point of below -12.degree. C.
    • 一种制备基础油和中间馏分的方法,该方法由沸点范围高于350℃的矿物油馏分对氧化和低温稳定,在第一步中,将矿物油馏分转化为加氢裂化 催化剂在加氢裂化条件下的范围为20至80重量%,沸点低于360℃,如果需要,将反应器流出物分离成高压分离器中的液相和气相,处理整个反应器流出物 或直接或通过蒸馏除去沸点低于360℃的馏分,在第二步中,在200至450℃的氢气和20至150巴的催化剂存在下,仅进行液相 其包含结晶pentasil型硼硅酸盐沸石,氧化铝和/或无定形铝硅酸盐作为载体材料和来自元素周期表VIb和/或VIII族的一种或多种金属和磷,并且在蒸馏之后 的氢化产物,得到沸点低于-30℃的沸点范围为180至360℃的中间馏分和沸点> 360℃的氧化稳定残余物,粘度 指数为110至135,倾点低于-12℃