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1. 发明申请

US20220315847A1 SYSTEM AND METHOD FOR PRODUCING UN-HYDROGENATED AND HYDROGENATED C9+ COMPOUNDS 有权
公开(公告)号：US20220315847A1
公开(公告)日：2022-10-06
申请号：US17626229
申请日：2020-07-13
申请人： SABIC Global Technologies B.V.
发明人： Shehzada Khurram , Ernesto Uehara
IPC分类号： C10G69/06 , C10G9/36 , C10G45/48 , C10G45/52 , C10G7/00
摘要： A system and method for processing pyrolysis gasoline is disclosed. The system and method involves separating a pyrolysis gasoline stream to produce a first stream comprising primarily un-hydrogenated C9+ compounds. The separating of the pyrolysis e gasoline occurs without hydrogenation being carried out on the pyrolysis gasoline before the separating.

2. 发明授权

US10982157B2 Two-step hydrocracking process for the production of naphtha comprising a hydrogenation step carried out upstream of the second hydrocracking step 有权
公开(公告)号：US10982157B2
公开(公告)日：2021-04-20
申请号：US16737415
申请日：2020-01-08
申请人： IFP Energies nouvelles
发明人： Emmanuelle Guillon , Anne-Claire Dubreuil , Antoine Daudin
IPC分类号： C10G65/12 , C10G45/48 , C10G45/52
摘要： The present invention is based on the use of a two-step hydrocracking process for the production of naphtha, comprising a step of hydrogenation placed upstream of the second hydrocracking step, the hydrogenation step treating the unconverted liquid fraction separated in the distillation step in the presence of a specific hydrogenation catalyst. Furthermore, the hydrogenation step and a second hydrocracking step are carried out under specific operating conditions and in particular under temperature conditions that are very specific with respect to one another.

3. 发明授权

US10829695B2 Conversion of biomass into a liquid hydrocarbon material 有权
公开(公告)号：US10829695B2
公开(公告)日：2020-11-10
申请号：US15777856
申请日：2016-11-21
申请人： SHELL OIL COMPANY
发明人： Laxmi Narasimhan Chilkoor Soundararajan , Alan Anthony Del Paggio , Dhairya Dilip Mehta , Vikrant Nanasaheb Urade
IPC分类号： C10G3/00 , C10G45/52 , C10G1/08 , C10G1/06 , C10G45/10 , C10G45/48 , C10G45/06 , C10G1/00 , C10G45/08 , C10G45/50
摘要： A process for producing liquid hydrocarbon products from a biomass-containing feedstock and/or a biomass-derived feedstock is provided. The process comprises: a) contacting the feedstock with a hydropyrolysis catalyst composition and molecular hydrogen in a hydropyrolysis reactor vessel to produce a product stream comprising a deoxygenated hydrocarbon product, H2O, H2, CO2, CO, C1-C3 gases, char and catalyst fines; b) removing char and catalyst fines from said product stream; c) cooling the remaining product stream to a temperature of no more than 300° C.; and d) hydroconverting all or a portion of said deoxygenated hydrocarbon product in a hydroconversion reactor in the presence of one or more catalyst compositions suitable for the aromatic saturation of the deoxygenated hydrocarbon product and of the H2O, CO2, CO, H2, and C1-C3 gas generated in step a), to produce a product comprising C4+ hydrocarbon product, H2O, CO, CO2, and C1-C3 gases.

4. 发明授权

US10294440B2 Catalytic system for preparation of high branched alkane from olefins 有权
公开(公告)号：US10294440B2
公开(公告)日：2019-05-21
申请号：US15078830
申请日：2016-03-23
申请人： Shanghai Chemrun Co., Ltd.
发明人： Yong Tang , Wenjie Tao , Xiuli Sun , Junfang Li , Zheng Wang
IPC分类号： C10M105/04 , B01J31/18 , C07C323/45 , C07C251/08 , C07C251/20 , C10G45/48 , C10G45/52 , C10G50/00 , C10G69/12 , C08F10/00 , C07F15/04 , B01J31/22 , C07C251/24 , C08F8/04 , C10M177/00 , C10M107/10 , C08F110/02 , C08F110/08 , C10G50/02
摘要： The present invention discloses a catalytic system for preparing highly branched alkane from olefin, which contains novel nickel or palladium complexes. In the presence of the catalytic system, highly branched oily alkane mixture can be efficiently obtained from olefins (such as ethylene) under mild conditions. The alkane mixture has a low bromine number, and can be used as a processing aid(s) and lubricant base oil with high-performance. Provides also was a method for preparing the catalyst and a method for preparing an oily olefin polymer.

5. 发明授权

US10258969B2 Catalyst with a mesoporous and macroporous co-mixed nickel active phase having a median macropore diameter of more than 300 nm, and its use in hydrogenation 有权
公开(公告)号：US10258969B2
公开(公告)日：2019-04-16
申请号：US15318611
申请日：2015-06-09
申请人： IFP Energies nouvelles
发明人： Malika Boualleg , Anne-Claire Dubreuil , Emily Maille , Cecile Thomazeau
IPC分类号： B01J21/04 , B01J23/755 , B01J35/10 , B01J37/00 , B01J37/02 , B01J37/03 , B01J37/04 , B01J37/08 , B01J37/16 , C07C5/03 , C07C5/10 , B01J37/20 , B01J33/00 , C07C5/05 , C10G45/36 , C10G45/48 , C10G45/40 , C10G45/52 , B01J35/00
摘要： The invention concerns a catalyst comprising a calcined oxide matrix which is mainly alumina and an active phase comprising nickel, said active phase being at least partially co-mixed within said calcined oxide matrix which is mainly alumina, the nickel content being in the range 5% to 65% by weight of said element with respect to the total mass of catalyst, said active phase not comprising metal from group VIB, the nickel particles having a diameter of less than 15 nm, said catalyst having a median mesopore diameter in the range 8 nm to 25 nm, a median macropore diameter of more than 300 nm, a mesopore volume, measured by mercury porosimetry, of 0.30 mL/g or more and a total pore volume, measured by mercury porosimetry, of 0.34 mL/g or more. The invention also concerns the process for the preparation of said catalyst, and its use in a hydrogenation process.

6. 发明申请

US20180154340A1 CATALYST WITH A MESOPOROUS AND MACROPOROUS CO-MIXED NICKEL ACTIVE PHASE HAVING A MEDIAN MACROPORE DIAMETER IN THE RANGE 50 TO 300 NM, AND ITS USE IN HYDROGENATION 审中-公开
公开(公告)号：US20180154340A1
公开(公告)日：2018-06-07
申请号：US15317839
申请日：2015-06-09
申请人： IFP Energies nouvelles
发明人： Malika BOUALLEG , Anne-Claire DUBREUIL , Emily MAILLE , Cecile THOMAZEAU
IPC分类号： B01J23/755 , C07C5/03 , C07C5/10 , C07C5/05 , C10G45/36 , C10G45/48 , B01J21/04 , B01J35/10 , B01J35/02 , B01J37/08 , B01J37/03 , B01J37/00 , B01J37/02 , B01J37/04
CPC分类号： B01J23/755 , B01J21/04 , B01J23/835 , B01J23/892 , B01J27/1853 , B01J33/00 , B01J35/006 , B01J35/023 , B01J35/026 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J35/1066 , B01J35/109 , B01J35/1095 , B01J37/0009 , B01J37/0045 , B01J37/009 , B01J37/0236 , B01J37/03 , B01J37/036 , B01J37/038 , B01J37/04 , B01J37/08 , B01J37/20 , B01J2523/00 , C07C5/03 , C07C5/05 , C07C5/10 , C07C2521/04 , C07C2523/755 , C07C2601/14 , C10G45/36 , C10G45/48 , C07C9/18 , C07C15/073 , C07C11/10 , C07C13/18 , B01J2523/31 , B01J2523/847
摘要： A catalyst comprising a calcined oxide matrix which is mainly alumina and an active phase comprising nickel, said active phase being at least partially co-mixed within said calcined oxide matrix which is mainly alumina, the nickel content being in the range 5% to 65% by weight of said element with respect to the total mass of catalyst, said active phase not comprising any metal from group VIB, the nickel particles having a diameter of less than 15 nm, said catalyst having a median mesopore diameter in the range 12 nm to 25 nm, a median macropore diameter in the range 50 to 300 nm, a mesopore volume, measured by mercury porosimetry, of 0.40 mL/g or more and a total pore volume, measured by mercury porosimetry, of 0.45 mL/g or more. The process for the preparation of said catalyst, and its use in a hydrogenation process.

7. 发明申请

US20170259249A1 NICKEL-BASED MESOPOROUS CATALYST AND USE THEREOF IN HYDROGENATION 审中-公开
公开(公告)号：US20170259249A1
公开(公告)日：2017-09-14
申请号：US15509873
申请日：2015-08-21
申请人： IFP Energies Nouvelles
发明人： Malika BOUALLEG , Anne-Claire DUBREUIL , Emily MAILLE , Cecile THOMAZEAU
IPC分类号： B01J23/755 , B01J35/00 , B01J35/10 , B01J35/02 , B01J37/03 , C10G45/48 , B01J37/02 , B01J37/08 , B01J37/16 , C07C7/163 , C10G45/36 , B01J21/04 , B01J37/00
CPC分类号： B01J23/755 , B01J21/04 , B01J23/835 , B01J23/892 , B01J35/0006 , B01J35/0013 , B01J35/006 , B01J35/026 , B01J35/10 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/108 , B01J37/0009 , B01J37/009 , B01J37/0201 , B01J37/0205 , B01J37/0207 , B01J37/0213 , B01J37/0236 , B01J37/031 , B01J37/035 , B01J37/036 , B01J37/08 , B01J37/16 , B01J37/18 , C01F7/141 , C01F7/34 , C01F7/441 , C01P2006/12 , C01P2006/14 , C01P2006/16 , C07C7/163 , C10G45/36 , C10G45/48 , C10G2300/705 , C07C9/15
摘要： A supported catalyst having a calcined, predominantly aluminium, oxide support and an active phase of 5 to 65% by weight nickel with respect to the total mass of the catalyst, said active phase having no group VIB metal, the nickel particles having a diameter less than or equal to 20 nm, said catalyst having a mesopore median diameter greater than or equal to 14 nm, a mesopore volume measured by mercury porosimetry greater than or equal to 0.45 mL/g, a total pore volume measured by mercury porosimetry greater than or equal to 0.45 mL/g, a macropore volume less than 5% of the total pore volume, said catalyst being in the form of grains having an average diameter comprised between 0.5 and 10 mm. The invention also relates to the process for the preparation of said catalyst and the use thereof in a hydrogenation process.

8. 发明授权

US09371495B2 Process for the production of naphthenic process oils by hydrogenation 有权
标题翻译：通过氢化生产环烷加工油的工艺
公开(公告)号：US09371495B2
公开(公告)日：2016-06-21
申请号：US13385580
申请日：2010-10-14
申请人： Nils Hansen
发明人： Nils Hansen
IPC分类号： C10G45/44 , C10G45/48 , C10G45/46
CPC分类号： C10G45/50 , B01J23/883 , C08L9/06 , C09D5/008 , C09D11/02 , C10G45/44 , C10G45/46 , C10G45/48 , C10G2300/1096 , C10G2300/30 , C10G2300/4006 , C10G2300/4012 , C10G2400/30 , C10M101/02 , C10M2203/1065 , C10N2240/40
摘要： A method for producing naphthenic process oils that have a high content of naphthenic carbon atoms of 20-60 wt % and a low content of polycyclic aromatics of less than 3 wt %, determined in accordance with IP 346, by the hydrogenation of a process oil educt that has a high content of polycyclic aromatics, are provided. The method enables secondary extracts, such as are formed in the production of label-free process oils, even in a mixture with primary extracts, to be utilized in an economically meaningful way. The resulting process oils are likewise label-free, so that the use of PCA-containing process oils can be reduced and less of these substances will get into the environment. By avoiding heating oil, CO2 emissions are also reduced. Also, through the direct hydrogenation of DAE, high value naphthenic process oils are obtained. The process oils that are obtained contain surprisingly high amounts of naphthenic hydrocarbon compounds.
摘要翻译：根据IP 346测定的具有20-60重量％的高环烷烃含量和小于3重量％的少量多环芳烃的环烷工艺油的方法，通过加工油提供了具有高含量的多环芳族化合物的离子。该方法使得二次提取物，例如在生产无标记工艺油中形成的二次提取物，即使在与初级提取物的混合物中，可以以经济上有意义的方式使用。所得到的加工油同样是无标记的，因此可以减少使用含PCA的工艺油，并减少这些物质的进入环境。通过避免采暖油，二氧化碳排放也减少。此外，通过DAE的直接氢化，获得了高价值的环烷烃加工油。获得的工艺油含有令人惊讶的高含量的环烷烃化合物。

9. 发明申请

US20160075955A1 PROCESS FOR HYDROGENATION OF A HYDROCARBON FEEDSTOCK COMPRISING AROMATIC COMPOUNDS 有权
标题翻译：含有芳香族化合物的烃类加料工艺
公开(公告)号：US20160075955A1
公开(公告)日：2016-03-17
申请号：US14785666
申请日：2014-04-10
申请人： AXENS
发明人： Jean-Christophe CANDELON , Fabienne LE PELTIER , Annick PUCCI
IPC分类号： C10G65/08 , C10G45/48
CPC分类号： C10G65/08 , C10G45/48 , C10G45/50 , C10G45/52
摘要： Process for hydrogenation of aromatic compounds in a feedstock comprising hydrocarbons having at least five carbon atoms, comprising: a) contacting feedstock, a hydrogen gas, and a nickel or platinum hydrogenation catalyst at 100 to 400° C., 0.5 to 8 MPa, and a feedstock flow rate 0.5 to 5 h−1, as to produce a partially-hydrogenated hydrocarbon feedstock and gas; and b) contacting the partially-hydrogenated feedstock, and a nickel or platinum hydrogenation catalyst at 100 and 400° C., a pressure of between 0.5 and 8 MPa, with a flow rate of the partially-hydrogenated feedstock between 0.3 and 8 h−1, a ratio between the volume of hydrogen and the volume of the partially-hydrogenated feedstock between 0.3 and 3 Nm3/m3, and a ratio between the superficial mass flow rate of the partially-hydrogenated feedstock and the superficial mass flow rate of gas (Ul/Ug) at the inlet of the reactor between 50 and 500.
摘要翻译：在包含具有至少五个碳原子的烃的原料中芳族化合物的氢化方法，包括：a）使原料，氢气和镍或铂氢化催化剂在100-400℃，0.5-8MPa下接触，和原料流速为0.5至5h-1，以产生部分氢化的烃原料和气体; 和b）使部分氢化的原料和镍或铂氢化催化剂在100和400℃，压力为0.5-8MPa之间，部分氢化原料的流速在0.3-8小时之间， 1，氢气体积与部分氢化原料的体积之间的比例为0.3-3 Nm3 / m3，部分氢化原料的表观质量流量与气体的表面质量流量之比（ Ul / Ug）在反应器的入口处在50和500之间。

10. 发明授权

US09074144B2 Process for hydrogenation of benzene 有权
标题翻译：苯氢化方法
公开(公告)号：US09074144B2
公开(公告)日：2015-07-07
申请号：US12244208
申请日：2008-10-02
申请人： Jean Cosyns , Quentin Debuisschert , Jean-Luc Nocca , Delphine Largeteau
发明人： Jean Cosyns , Quentin Debuisschert , Jean-Luc Nocca , Delphine Largeteau
IPC分类号： C10G45/48 , C01B3/26 , C01B3/50 , C10G7/02 , C10G35/04
CPC分类号： C10G45/48 , C01B3/26 , C01B3/50 , C01B2203/0277 , C01B2203/047 , C10G7/02 , C10G35/04 , C10G2300/1096 , C10G2300/4006 , C10G2400/02 , C10G2400/04
摘要： This invention relates to a process for hydrogenation of benzene contained in a catalytic reformate, in which: The hydrogen that is present in the catalytic reformate is separated from the remainder of the reformate with separation means, A light benzene-enriched fraction is separated from the heavy reformate, The light reformate that contains the benzene is brought into contact with a nickel-based hydrogenation catalyst at a temperature of between 90° C. and 150° C., a VVH of between 0.5 and 10, and with at least one portion of hydrogen that is obtained during the separation stage of the hydrogen at the top of the separator tank and used at the output pressure of said separator.
摘要翻译：本发明涉及催化重整油中所含的苯氢化方法，其中：催化重整产物中存在的氢气与分离装置与剩余的重整产物分离，将轻的富含苯的馏分与重质量重组体，含有苯的轻质重整油在90℃〜150℃，VVH为0.5〜10℃的温度下与镍系氢化催化剂接触，并与至少一部分在分离罐顶部的氢分离阶段期间获得的氢气，并在所述分离器的输出压力下使用。

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