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    • 9. 发明授权
    • Hollow molded articles and process for manufacturing them
    • 中空成型制品及其制造方法
    • US5858491A
    • 1999-01-12
    • US917055
    • 1997-08-22
    • Theo L. V. GeussensHerbert BongartzJozef J. I. Van Dun
    • Theo L. V. GeussensHerbert BongartzJozef J. I. Van Dun
    • C08L23/06C08L23/08B29D22/00B29D23/00
    • C08L23/06C08L2205/02C08L23/0815C08L2314/02C08L2314/06Y10T428/139Y10T428/1397
    • Hollow molded articles prepared from a molding composition comprising:(A) from 95 to 60 percent by weight, based on the weight of (A) and (B), of an ethylene polymer having a density of 0.955 g/cm.sup.3 or higher, a melt index from 0.3 to 10 g/10 min, a melt index ratio I.sub.21 /I.sub.2 of from 40 to 80, and a polydispersity of from 1.8 to 10, the ethylene polymer being selected from the group consisting of i) high density ethylene homopolymers and ii) high density ethylene copolymers prepared by slurry or gas phase polymerization in the presence of a Ziegler or Phillips catalyst or prepared by polymerization in the presence of a transition metal compound catalyst containing a cyclopentadienyl or cyclopentadienyl derivative moiety; and(B) from 5 to 40 percent by weight, based on the weight of (A) and (B), of a homogeneous linear or substantially linear ethylene interpolymer having a density from 0.85 to 0.93 g/cm.sup.3, a melt index from 0.5 to 5 g/10 min, and a polydispersity of from 1.8 to 2.5 , the ethylene interpolymer being an interpolymer of at least ethylene and an .alpha.-olefin;wherein the composition has a density from 0.94 to 0.962 g/cm.sup.3 ;and a process of manufacturing hollow molded articles by molding such composition are claimed.
    • 由模塑组合物制备的中空成型制品,其包含:(A)基于(A)和(B)的重量,95至60重量%的密度为0.955g / cm 3或更高的乙烯聚合物, 熔融指数为0.3至10g / 10min,熔体指数比I21 / I2为40至80,多分散性为1.8至10,乙烯聚合物选自i)高密度乙烯均聚物和 ii)通过浆料或气相聚合在齐格勒或菲利普斯催化剂存在下制备的高密度乙烯共聚物或通过在含有环戊二烯基或环戊二烯基衍生物部分的过渡金属化合物催化剂存在下聚合制备的; 和(B)5-40重量%,基于(A)和(B)的重量,具有0.85至0.93g / cm 3密度的均匀直链或基本线性的乙烯互聚物,熔体指数为0.5 至5g / 10min,多分散性为1.8至2.5,乙烯互聚物为至少为乙烯和α-烯烃的互聚物; 其中所述组合物的密度为0.94至0.962g / cm 3; 要求保护通过模制这种组合物制造中空成型制品的方法。