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    • 2. 发明授权
    • Cathodic electrocoating composition containing an epoxy resin chain
extended with a primary amine
    • 含有与伯胺延伸的环氧树脂链的阴极电涂组合物
    • US6020069A
    • 2000-02-01
    • US099541
    • 1998-06-18
    • Joseph A. AntonelliChristopher Scopazzi
    • Joseph A. AntonelliChristopher Scopazzi
    • C08G18/12C08G18/58C08G18/80C09D5/44B32B27/38
    • C09D5/4434C08G18/12C08G18/581C08G18/8064Y10T428/31511
    • An improved aqueous cathodic electrocoating composition of an aqueous carrier having dispersed therein a film forming binder of (1) an epoxy-resin amine adduct and (2) a blocked polyisocyanate crosslinking agent; wherein the improvement is an epoxy resin amine adduct which is a reaction product of an epoxy resin and a polyhydric phenol which is chain extended with a primary amine to form a chain extended epoxy resin having epoxy end groups and an equivalent amine to epoxy ratio is 1-10 to 4-10 and wherein the epoxy end groups of the resin are reacted with a ketimine and/or a diamine and the resulting chain extended epoxy resin has an epoxy equivalent weight of about 700-2,000 and is neutralized with an organic or inorganic acid; wherein the electrocoating composition has improved throw power and forms coatings that have improved corrosion resistance in comparison to conventional electrocoating compositions formed from epoxy resins extended with conventional diamines or polyols.
    • 一种水性载体的改进的水性阴极电泳涂料组合物,其中分散有(1)环氧树脂胺加合物的成膜粘合剂和(2)封端的多异氰酸酯交联剂; 其中改进是环氧树脂胺加合物,其是环氧树脂和多元酚的反应产物,其与伯胺链延长以形成具有环氧端基的链延长环氧树脂,并且等同的胺与环氧化合物的比例为1 -10至4-10,并且其中树脂的环氧端基与酮亚胺和/或二胺反应,所得的链延长环氧树脂具有约700-2,000的环氧当量,并用有机或无机 酸; 其中与由常规二胺或多元醇延伸的环氧树脂形成的常规电涂组合物相比,电涂组合物具有改进的抛光力并形成具有改善的耐腐蚀性的涂层。
    • 4. 发明授权
    • Star polymers made from macromonomers made by cobalt chain transfer
process
    • 由通过钴链转移法制备的大分子单体制成的星形聚合物
    • US5310807A
    • 1994-05-10
    • US998350
    • 1992-12-30
    • Joseph A. AntonelliChristopher Scopazzi
    • Joseph A. AntonelliChristopher Scopazzi
    • C08F293/00C08F4/80C08F290/02C08F290/04C08F299/00C08L53/00C09D153/00C09D155/00C08F265/04C08F265/06C08F265/10
    • C08F290/04
    • A polymer dispersion of a star polymer dispersed in an organic liquid; wherein the star polymer has a crosslinked core having attached thereto at least three macromonomer arms; where(1) the core is formed of monomers having at least two ethylenically unsaturated double bonds which are crosslinked with each other and the core has at least 3 free radical polymerizable sites each of which are reacted with the macromonomer; and(2) the macromonomer that forms the arms of the star polymer is formed of ethylenically unsaturated monomers that have been polymerized by free radical polymerization in the presence of a free radical polymerization initiator and a catalytic chain transfer agent containing Co.sup.+2 to provide the macromonomer with a terminal ethylenically unsaturated group that is polymerized with the free radical polymerizable site on the core to form the star polymer.The process for making the star polymer and coating compositions that utilize the star polymer are also part of this invention.
    • 分散在有机液体中的星形聚合物的聚合物分散体; 其中所述星形聚合物具有附着至少三个大分子单体臂的交联核心; 其中(1)芯由具有至少两个彼此交联的烯属不饱和双键的单体形成,并且芯具有至少3个自由基可聚合位点,每个位点与大分子单体反应; 和(2)形成星形聚合物的臂的大分子单体由在自由基聚合引发剂和含有Co + 2的催化链转移剂的存在下已经通过自由基聚合聚合的烯属不饱和单体形成,以提供 具有末端烯属不饱和基团的大分子单体,其与芯上的自由基可聚合位点聚合以形成星形聚合物。 制造使用星形聚合物的星形聚合物和涂料组合物的方法也是本发明的一部分。