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    • 1. 发明授权
    • Photographic recording material
    • 摄影记录材料
    • US5674668A
    • 1997-10-07
    • US704461
    • 1996-08-26
    • Jorg HagemannGunter HellingBeate Weber
    • Jorg HagemannGunter HellingBeate Weber
    • G03C7/00G03C1/005G03C1/815G03C7/388
    • G03C7/3885G03C1/005G03C1/8155Y10S430/132
    • A color photographic recording material having at least one silver halide emulsion layer, which material contains in at least one of its layers a combination of at least one UV absorber of the formula I and at least one low molecular weight or polymeric oil formula containing acid groups, for example of the formula T--�R.sup.21 --(Q.sup.1).sub.p !.sub.q --X.sup.21 --OH (II), exhibits improved absorption for UV light. ##STR1## In the formula I: R.sup.1 and R.sup.3 mean H, halogen, hydroxy, mercapto, alkyl, aryl, alkoxy, aryloxy, acyloxy, alkylthio, arylthio, --NR.sup.5 --R.sup.6, alkoxycarbonyl, carbamoyl or sulphamoyl; R.sup.2 means H, hydroxy, halogen or alkyl; R.sup.4 means alkyl, alkoxy, alkylthio, aryloxy, arylthio or a residue of the formula ##STR2## R.sup.5 means H, alkyl or aryl; R.sup.6 means H, alkyl, aryl, acyl, alkoxycarbonyl, carbamoyl, sulphamoyl or sulphonyl; m, n and o mean 1, 2, 3 or 4, wherein two or more residues R.sup.1, R.sup.2 and R.sup.3 are identical or different; in the formula II: X.sup.21 means ##STR3## T means H or a segment of a polymer skeleton; Q.sup.1 and Q.sup.2 mean --O-- or --NR.sup.22 --; R.sup.21 means alkylene or arylene; R.sup.22 means H, alkyl or aryl; p, q and r mean 0 or 1.
    • 一种具有至少一个卤化银乳剂层的彩色照相记录材料,该材料在其至少一层中含有至少一种式I的UV吸收剂与至少一种含有酸基团的低分子量或聚合物油配方的组合 ,例如式T- [R21-(Q1)p] q-X21-OH(Ⅱ)表现出改进的UV光吸收。 (I)在式I中,R 1和R 3表示H,卤素,羟基,巯基,烷基,芳基,烷氧基,芳氧基,酰氧基,烷硫基,芳硫基,-NR5-R6,烷氧基羰基,氨基甲酰基或氨磺酰基。 R2表示H,羟基,卤素或烷基; R 4表示烷基,烷氧基,烷硫基,芳氧基,芳硫基或式烷基,芳基,酰基,烷氧基羰基,氨基甲酰基,氨磺酰基或磺酰基的残基; m,n和o表示1,2,3或4,其中两个或多个残基R1,R2和R3相同或不同; 在公式II中:X21表示骨架; Q1和Q2表示-O-或-NR22-; R21表示亚烷基或亚芳基; R22表示H,烷基或芳基; p,q和r表示0或1。
    • 3. 发明授权
    • Color photographic recording material containing combination of phenolic
light stabilizers with novel polycyclic phenols as color stabilizers
for the magenta pyrazoloazol type azomethine dyes
    • 包含酚类光稳定剂与新型多环酚的组合的彩色照相记录材料作为品红色吡唑并唑型偶氮甲碱染料的颜色稳定剂
    • US5436125A
    • 1995-07-25
    • US281623
    • 1994-07-28
    • Jorg HagemannBeate Weber
    • Jorg HagemannBeate Weber
    • G03C7/30G03C7/392
    • G03C7/3008
    • In a color photographic recording material, the light stability of a dye image produced from a magenta coupler and stabilized with a compound of the formula I may be further improved by additionally using a compound of one of the formulae II and III. ##STR1## In the formulae I, II and III, R.sup.1, R.sup.21, R.sup.25, R.sup.31, R.sup.34 mean H, alkyl, aryl, acyl;R.sup.2, R.sup.22, R.sup.32 mean --OR.sup.1 alkyl, aryl, dialkylamino, acylamino, sulphonamido, acyl, sulphonyl;R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.23, R.sup.24, R.sup.33 mean H, halogen or a residue as R.sup.2 ;m, n, q mean 0, 1, 2 or 3;o means 0, 1 or 2;p means a positive integer;A means alkylene, --O--, --S--, --NR.sup.25 --, --SO.sub.2 ;B means alkylene, --O--, --S--, --NR.sup.34 --, --SO.sub.2 --;wherein two adjacent residues --OR.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6 may together complete a 5- to 8-membered ring, two adjacent residues --OR.sup.21, R.sup.23, R.sup.22 or --OR.sup.21, R.sup.24, R.sup.22, or --OR.sup.31, R.sup.33 or R.sup.32, R.sup.33 may together complete a 5- or 6-membered ring, wherein R.sup.22 or R.sup.32 are not identical to --OR.sup.21 or --OR.sup.31 respectively, if R.sup.21 or R.sup.31 is H, and wherein two residues R.sup.31 are not simultaneously H.
    • 在彩色照相记录材料中,通过另外使用式II和III之一的化合物,可以进一步提高由品红成色剂产生并用式I化合物稳定化的染料影像的光稳定性。 (III)在式I,II和III中,R 1,R 21,R 25,R 31,R 34表示H,烷基,芳基,酰基; R2,R22,R32表示-OR1烷基,芳基,二烷基氨基,酰氨基,磺酰氨基,酰基,磺酰基; R 3,R 4,R 5,R 6,R 23,R 24,R 33表示H,卤素或残基作为R 2; m,n,q表示0,1,2或3; o表示0,1或2; p表示正整数; A表示亚烷基,-O - , - S - , - NR 25 - , - SO 2; B表示亚烷基,-O - , - S - , - NR 34 - , - SO 2 - ; 其中两个相邻的残基-OR1,R2,R3,R4,R5,R6可以一起完成5-至8-元环,两个相邻的残基-OR 21,R 23,R 22或-OR 21,R 24,R 22或-OR 31,R 33 或R32,R33可以一起完成5-或6-元环,其中如果R 21或R 31为H,R 22或R 32分别不与-OR 21或-OR 31相同,并且其中两个残基R31不同时为H.
    • 10. 发明授权
    • Color photographic recording material
    • 彩色摄影材料
    • US5466569A
    • 1995-11-14
    • US257532
    • 1994-06-09
    • Beate WeberJorg HagemannMarkus Geiger
    • Beate WeberJorg HagemannMarkus Geiger
    • G03C7/00G03C7/392G03C1/08G03C7/26G03C7/32
    • G03C7/39296G03C7/39216
    • A color photographic material, at least one layer of which contains a compound of the formula (I) ##STR1## in which X means --NH--, --NR-- or --O--,R means alkyl, cycloalkyl or aryl,R.sub.1 means a chemical bond or a divalent bridging member,R.sub.2 and R.sub.3 mean alkyl, alkoxy, alkenyl, cycloalkyl, aryl or aryloxy, or two residues R.sub.2 or R.sub.3 mean the remaining atoms of a benzene ring condensed with the phenyl residue andm and n mean 0 to 3, wherein all alkyl, alkoxy, cycloalkyl, alkenyl, aryl and aryloxy residues may be further substituted and in each of the two phenyl residues a residue R.sub.1, R.sub.2 or R.sub.3 is in para position relative to the oxygen atom, is characterized by improved dye stability after processing.
    • 一种彩色照相材料,其至少一层含有式(I)化合物,R表示烷基,环烷基或芳基,R 1表示化学键或二价桥连体,R 2和R 3表示烷基,烷氧基,烯基,环烷基 ,芳基或芳氧基,或两个残基R2或R3表示与苯基残基稠合的苯环的剩余原子,m和n表示0至3,其中所有烷基,烷氧基,环烷基,烯基,芳基和芳氧基残基可以进一步 在两个苯基残基中的每一个中,残基R 1,R 2或R 3相对于氧原子处于对位,其特征在于处理后改善的染料稳定性。