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1. 发明授权

US07009081B2 N-methylated amines from selective vapor phase amination of amino ether alcohols 失效
标题翻译：来自氨基醚醇的选择性气相胺化的N-甲基化胺
公开(公告)号：US07009081B2
公开(公告)日：2006-03-07
申请号：US10634516
申请日：2003-08-04
申请人： John William Mitchell , Richard Paul Underwood , Michael Edward Ford , Gamini Ananda Vedage , Hong-Xin Li
发明人： John William Mitchell , Richard Paul Underwood , Michael Edward Ford , Gamini Ananda Vedage , Hong-Xin Li
IPC分类号： C07C209/16
CPC分类号： C07C213/02 , C07C217/08
摘要： A method for converting amino ether alcohols to amino ether amines by amination in the vapor phase with a catalyst comprising copper and zinc. The catalyst may also comprise an alkali, alkaline earth, or lanthanide element as a promoter.
摘要翻译：通过在含有铜和锌的催化剂的气相中胺化将氨基醚醇转化为氨基醚胺的方法。催化剂还可以包含作为助催化剂的碱金属，碱土金属或镧系元素。

2. 发明授权

US5639916A Amination of allylic alcohols 失效
标题翻译：烯丙醇的胺化
公开(公告)号：US5639916A
公开(公告)日：1997-06-17
申请号：US564666
申请日：1995-11-29
申请人： John William Mitchell , Gamini Ananda Vedage
发明人： John William Mitchell , Gamini Ananda Vedage
IPC分类号： C07C209/16 , C07C211/21
CPC分类号： C07C211/21 , C07C209/16
摘要： This invention relates to an improvement in a process for the catalytic amination of an allylic alcohol of the formula:CH.sub.2 .dbd.CR--CH.sub.2 OHwhere R is hydrogen or methyl with ammonia or an amine of the formula R.sub.1 R.sub.2 NH where R.sub.1 and R.sub.2 represent hydrogen or a C.sub.1-5 hydrocarbyl group in the presence of an effective amount of a phosphorous containing catalyst to effect reaction between the allylic alcohol and the ammonia or amine to produce an allylic amine. The improvement in the process resides in utilizing a neutral group IIA metal phosphate as a catalyst component. Calcium phosphate is preferred and the catalyst.
摘要翻译：本发明涉及用于下式的烯丙醇催化胺化的方法：CH 2 = CR-CH 2 OH，其中R是氢或甲基与氨或式R 1 R 2 NH的胺，其中R 1和R 2表示氢或C1 -5烃基，在有效量的含磷催化剂存在下进行烯丙醇与氨或胺之间的反应以产生烯丙基胺。该方法的改进在于利用中性IIA族金属磷酸盐作为催化剂组分。优选的是磷酸钙和催化剂。

3. 发明授权

US08143321B2 N,N,N,′-trimethyl-bis-(aminoethyl) ether and its derivatives as catalysts for polyurethanes 有权
标题翻译： N，N，N，'三甲基 - 双 - （氨基乙基）醚及其衍生物作为聚氨酯的催化剂
公开(公告)号：US08143321B2
公开(公告)日：2012-03-27
申请号：US11485724
申请日：2006-07-13
申请人： Juan Jesus Burdeniuc , Stephan Herman Wendel , John William Mitchell
发明人： Juan Jesus Burdeniuc , Stephan Herman Wendel , John William Mitchell
IPC分类号： C08G18/18 , C08G18/28 , C08J9/06 , C08J9/12 , C08J9/14
CPC分类号： B01J31/0209 , B01J31/0204 , B01J31/0237 , B01J31/0271 , B01J2231/14 , C08G18/1833 , C08G18/1841 , C08G18/7621 , C08G18/7657 , C08G2101/0008 , C08G2101/005 , C08G2101/0058 , C08J9/14 , C08J2375/04
摘要： The present invention provides compounds produced by the reaction of glycidyl ethers and glycidyl esters with ether compounds including N,N,N′-trimethyl-bis-(aminoethyl) ether. N,N,N′-trimethyl-bis-(aminoethyl) ether and its derivatives can be used as polyurethane catalysts.
摘要翻译：本发明提供通过缩水甘油醚和缩水甘油酯与包括N，N，N'-三（三甲基 - 双 - （氨基乙基）醚的醚化合物的反应制备的化合物。 N，N，N'-三甲基 - 双 - （氨基乙基）醚及其衍生物可用作聚氨酯催化剂。

4. 发明申请

US20080015273A1 N,N,N,'-trimethyl-bis-(aminoethyl) ether and its derivatives as catalysts for polyurethanes 有权
标题翻译： N，N，N，'三甲基 - 双 - （氨基乙基）醚及其衍生物作为聚氨酯的催化剂
公开(公告)号：US20080015273A1
公开(公告)日：2008-01-17
申请号：US11485724
申请日：2006-07-13
申请人： Juan Jesus Burdeniuc , Stephan Herman Wendel , John William Mitchell
发明人： Juan Jesus Burdeniuc , Stephan Herman Wendel , John William Mitchell
IPC分类号： C08G18/16 , C08G18/18
CPC分类号： B01J31/0209 , B01J31/0204 , B01J31/0237 , B01J31/0271 , B01J2231/14 , C08G18/1833 , C08G18/1841 , C08G18/7621 , C08G18/7657 , C08G2101/0008 , C08G2101/005 , C08G2101/0058 , C08J9/14 , C08J2375/04
摘要： The present invention provides compounds produced by the reaction of glycidyl ethers and glycidyl esters with ether compounds including N,N,N′-trimethyl-bis-(aminoethyl) ether. N,N,N′-trimethyl-bis-(aminoethyl) ether and its derivatives can be used as polyurethane catalysts.
摘要翻译：本发明提供通过缩水甘油醚和缩水甘油酯与包括N，N，N'-三（三甲基 - 双 - （氨基乙基）醚的醚化合物的反应制备的化合物。 N，N，N'-三甲基 - 双 - （氨基乙基）醚及其衍生物可用作聚氨酯催化剂。

5. 发明授权

US07041857B1 Hydrogenation of acetone 有权
标题翻译：丙酮氢化
公开(公告)号：US07041857B1
公开(公告)日：2006-05-09
申请号：US11221066
申请日：2005-09-07
申请人： Kathryn Sue Hayes , John William Mitchell , Anita Niak , Michael Gerard Turcotte
发明人： Kathryn Sue Hayes , John William Mitchell , Anita Niak , Michael Gerard Turcotte
IPC分类号： C07C29/145 , C07C29/136
CPC分类号： C07C29/145 , C12C11/02 , C07C31/10
摘要： This invention relates to an improvement in a liquid phase process for producing isopropanol by the hydrogenation of acetone in the presence of a hydrogenation catalyst; the improvement comprising; contacting acetone with hydrogen under continuous liquid phase conditions; and, employing a sponge metal catalyst promoted with an effective amount of chromium.
摘要翻译：本发明涉及通过在氢化催化剂存在下氢化丙酮生产异丙醇的液相方法的改进; 改进包括：在连续液相条件下使丙酮与氢气接触; 并且使用用有效量的铬促进的海绵金属催化剂。

6. 发明授权

US09878317B2 N,N,N′-trimethyl-bis-(aminoethyl) ether and its derivatives as catalysts for polyurethanes 有权
公开(公告)号：US09878317B2
公开(公告)日：2018-01-30
申请号：US13401971
申请日：2012-02-22
申请人： Juan Jesus Burdeniuc , Stephan Hermann Wendel , John William Mitchell
发明人： Juan Jesus Burdeniuc , Stephan Hermann Wendel , John William Mitchell
IPC分类号： B01J31/02 , C08G18/18 , C08J9/14 , C08G18/76 , C08G101/00
CPC分类号： B01J31/0209 , B01J31/0204 , B01J31/0237 , B01J31/0271 , B01J2231/14 , C08G18/1833 , C08G18/1841 , C08G18/7621 , C08G18/7657 , C08G2101/0008 , C08G2101/005 , C08G2101/0058 , C08J9/14 , C08J2375/04
摘要： The present invention provides compounds produced by the reaction of glycidyl ethers and glycidyl esters with ether compounds including N,N,N′-trimethyl-bis-(aminoethyl)ether. N,N,N′-trimethyl-bis-(aminoethyl)ether and its derivatives can be used as polyurethane catalysts.

7. 发明授权

US06723877B1 Dimethylformamide synthesis via reactive distillation of methyl formate and dimethylamine 失效
标题翻译：通过甲酸甲酯和二甲胺的反应蒸馏二甲基甲酰胺合成
公开(公告)号：US06723877B1
公开(公告)日：2004-04-20
申请号：US10462916
申请日：2003-06-16
申请人： Robin Joyce Maliszewskyj , Michael Gerard Turcotte , John William Mitchell
发明人： Robin Joyce Maliszewskyj , Michael Gerard Turcotte , John William Mitchell
IPC分类号： C07C23300
CPC分类号： C07C231/02 , C07C67/40 , Y02P20/127 , C07C69/07 , C07C233/03
摘要： A continuous process for the production of dimethylformamide comprising the steps: (a) reacting methyl formate and dimethylamine in a reactive distillation column under conditions to form dimethylformamide and by-product methanol; (b) vaporizing the by-product methanol and generating a liquid dimethylformamide while in said reactive distillation column; (c) removing at least a major portion of the by-product methanol as an overhead from said reactive distillation column; (d) removing a crude liquid dimethylformamide containing residual by-product methanol as a bottoms fraction from said reactive distillation column; (e) introducing said bottoms fraction containing dimethylformamide and residual by-product methanol to a purification column wherein the by-product methanol is removed from said dimethylformamide as an overhead and purified dimethylformamide is removed as a bottoms fraction; and, optionally, (f) recycling the by-product methanol removed as an overhead from the purification column to the reactive distillation column.
摘要翻译：一种用于生产二甲基甲酰胺的连续方法，包括以下步骤：（a）在反应性蒸馏塔中使甲酸甲酯和二甲基胺在形成二甲基甲酰胺和副产物甲醇的条件下反应;（b）蒸发副产物甲醇并产生液体二甲基甲酰胺同时在所述反应蒸馏塔中;（c）从所述反应蒸馏塔中除去至少大部分副产物甲醇作为塔顶馏出物;（d）除去作为底部馏分的残留副产物甲醇的粗液体二甲基甲酰胺，所述反应性蒸馏塔;（e）将含有二甲基甲酰胺和残余副产物甲醇的塔底馏分引入纯化塔，其中副产物甲醇作为塔顶馏出物从所述二甲基甲酰胺中除去，纯化的二甲基甲酰胺作为塔底馏分除去; 和（f）将从塔顶馏去的副产物甲醇从净化塔循环到反应蒸馏塔。

8. 外观设计

USD757140S1 Radial machine safety guard 有权
标题翻译：径向机安全防护
公开(公告)号：USD757140S1
公开(公告)日：2016-05-24
申请号：US29517125
申请日：2015-02-10
申请人： John William Mitchell
设计人： John William Mitchell

9. 发明申请

US20120149794A1 N,N,N'-Trimethyl-Bis-(Aminoethyl) Ether and its Derivatives as Catalysts for Polyurethanes 有权
标题翻译： N，N，N'-三甲基 - 二 - （氨基乙基）醚及其衍生物作为聚氨酯的催化剂
公开(公告)号：US20120149794A1
公开(公告)日：2012-06-14
申请号：US13401971
申请日：2012-02-22
申请人： Juan Jesus Burdeniuc , Stephan Herman Wendel , John William Mitchell
发明人： Juan Jesus Burdeniuc , Stephan Herman Wendel , John William Mitchell
IPC分类号： C07C217/28 , C07C69/02 , C08L75/00 , C08G65/00 , C08L67/00 , C08L71/00 , C07C69/767 , C08G63/00
CPC分类号： B01J31/0209 , B01J31/0204 , B01J31/0237 , B01J31/0271 , B01J2231/14 , C08G18/1833 , C08G18/1841 , C08G18/7621 , C08G18/7657 , C08G2101/0008 , C08G2101/005 , C08G2101/0058 , C08J9/14 , C08J2375/04
摘要： The present invention provides compounds produced by the reaction of glycidyl ethers and glycidyl esters with ether compounds including N,N,N′-trimethyl-bis-(aminoethyl)ether. N,N,N′-trimethyl-bis-(aminoethyl)ether and its derivatives can be used as polyurethane catalysts.
摘要翻译：本发明提供通过缩水甘油醚和缩水甘油酯与包括N，N，N'-三（三甲基 - 双 - （氨基乙基）醚的醚化合物的反应制备的化合物。 N，N，N'-三甲基 - 双 - （氨基乙基）醚及其衍生物可用作聚氨酯催化剂。

10. 发明授权

US5919979A Preparation of alkyl formamides 失效
标题翻译：烷基甲酰胺的制备
公开(公告)号：US5919979A
公开(公告)日：1999-07-06
申请号：US127854
申请日：1993-09-28
申请人： John William Mitchell , Thomas Albert Johnson
发明人： John William Mitchell , Thomas Albert Johnson
IPC分类号： B01J23/02 , B01J31/02 , C07C231/10
CPC分类号： C07C231/10 , B01J23/02 , B01J31/0212
摘要： This invention relates to an improvement in a process for the production of an alkyl formamide, wherein a gas-containing carbon monoxide is reacted at elevated temperature and pressure in reaction zone with a nitrogen-containing compound selected from the group consisting of ammonia, a primary or secondary alkylamine, in the presence of a solvent and a catalyst. The improvement comprises utilizing a solvent comprising a polyethylene glycol, polypropylene glycol, polyethylenepropylene glycol, or mixtures, and an alkali metal or alkaline earth metal alkoxide of a polyethylene glycol, polypropylene glycol, polyethylenepropylene glycol or mixtures as the catalyst.
摘要翻译：本发明涉及一种制备烷基甲酰胺的方法的改进，其中含气体的一氧化碳在与含氮化合物反应的反应区域中在升高的温度和压力下反应，所述含氮化合物选自氨，初级或仲烷基胺，在溶剂和催化剂存在下进行。该改进包括使用包含聚乙二醇，聚丙二醇，聚乙烯丙二醇或其混合物的溶剂，以及聚乙二醇，聚丙二醇，聚乙烯丙二醇或其混合物的碱金属或碱土金属醇盐作为催化剂。

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