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    • 7. 发明授权
    • Process for stabilizing silica-rich geothermal brine to prevent silica
scaling
    • 用于稳定富二氧化硅的地热盐水以防止二氧化硅结垢的方法
    • US4405463A
    • 1983-09-20
    • US318127
    • 1981-11-04
    • John W. JostWilliam C. LieffersOlin D. Whitescarver
    • John W. JostWilliam C. LieffersOlin D. Whitescarver
    • C02F1/60C02F1/72C02F1/52C02F1/74
    • C02F1/72C02F1/60
    • A process for stabilizing silica-rich geothermal brine to prevent silica scaling comprises selectively providing a supply of ferric ions, allowing the silica-rich brine to combine with the ferric ions to form insoluble, iron-rich siliceous material and separating the insoluble siliceous material from the brine to form a brine having a silica content which is reduced below the saturation level required for substantially scale-free handling of the brine. In one embodiment of the process in which the brine contains sufficient dissolved ferrous ions, the process comprises selectively contacting the brine with an oxidizing agent, preferably by aerating the brine, to oxidize a selected portion of the ferrous ions to ferric ions, which then combine with silica to form the insoluble iron-rich siliceous material. The ferric ion content of an iron-deficient brine may be augmented by adding ferric and/or ferrous ions to the brine. Steam released by flashing the untreated brine may be used to heat the stabilized brine before disposal thereof, so as to increase the silica solubility and reduce the amount of silica required to be removed to prevent scaling.
    • 用于稳定富二氧化硅的地热盐水以防止二氧化硅结垢的方法包括选择性地提供铁离子供应,允许富含二氧化硅的盐水与三价铁离子结合以形成不溶性富铁硅质材料,并将不溶性硅质材料从 盐水形成盐水,其二氧化硅含量降低到基本无水处理盐水所需的饱和水平以下。 在其中盐水含有足够溶解的亚铁离子的方法的一个实施方案中,该方法包括选择性地使盐水与氧化剂接触,优选通过使盐水充气,将亚铁离子的选定部分氧化成铁离子,然后将铁离子 用二氧化硅形成不溶性富铁硅质材料。 通过向盐水中加入铁和/或亚铁离子可以增加缺铁盐水的铁离子含量。 通过闪蒸未经处理的盐水释放的蒸汽可用于在处理之前加热稳定的盐水,以便增加二氧化硅溶解度并减少被除去的二氧化硅的量以防止结垢。
    • 8. 发明授权
    • Preventing scale deposition from geothermal fluids
    • 防止地热液体沉积
    • US4224151A
    • 1980-09-23
    • US968480
    • 1978-12-11
    • John W. Jost
    • John W. Jost
    • C02F1/72C02B5/02
    • C02F1/72
    • A method for preventing the deposition of sulfide and/or sulfate scale during the production of a hot two-phase geothermal fluid which contains hydrogen sulfide, barium heavy and/or transition metals, and at least a critical minimum amount of calcium in solution. Gaseous oxygen is injected into the geothermal fluid at a critical rate to selectively oxidize the hydrogen sulfide to intermediate sulfide oxidation products, such as thiosulfates. Thereafter the geothermal fluid is separated into gaseous and liquid phases. Where iron is present in the geothermal fluid, the degree of turbulence induced during the oxidation step is selectively controlled in order to prevent the deposition of iron pyrites.
    • 一种用于在生产含有硫化氢,钡重和/或过渡金属的热的两相地热流体和至少在溶液中至少临界的最小量的钙的过程中防止硫化物和/或硫酸盐垢沉积的方法。 将气态氧以临界速率注入地热流体中,以选择性地将硫化氢氧化成中间硫化物氧化产物,例如硫代硫酸盐。 此后,将地热液分离成气相和液相。 在地热流体中存在铁的情况下,选择性地控制在氧化步骤期间引起的湍流程度,以防止铁黄铁矿的沉积。