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    • 4. 发明授权
    • Process for integrating treatment of and energy derivation from
geothermal brine
    • 将地热盐水处理和能量衍生整合的过程
    • US4244190A
    • 1981-01-13
    • US953644
    • 1978-10-23
    • William C. Lieffers
    • William C. Lieffers
    • F03G4/06F03G7/04F03G7/00
    • F03G7/04Y02E10/10
    • A process for treating and deriving useful energy from a two-phase geothermal brine containing non-condensible gases, including hydrogen sulfide, and also containing heavy and/or transition metals in solution, wherein the non-condensible gases are separated from the geothermal brine. Substantially all of the hydrogen sulfide contained in the non-condensible gas is converted to sulfur dioxide and at least a portion of the sulfur dioxide is removed from the non-condensible gas thereby rendering the same environmentally acceptable for discharge. The separated geothermal brine is flashed to a high quality steam utilized for energy derivation. The portion of sulfur dioxide removed from the non-condensible gas is added to the remaining brine for reinjection into the subterranean geothermal reservoir.
    • 一种从含有不可冷凝气体(包括硫化氢)并且还含有溶液中的重金属和/或过渡金属的两相地热卤水处理和获得有用能量的方法,其中不可冷凝的气体与地热卤水分离。 包含在不可冷凝气体中的所有硫化氢基本上都被转化为二氧化硫,并且至少一部分二氧化硫从不可冷凝气体中除去,从而使排放相同的环境是可接受的。 分离的地热盐水被闪蒸到用于能量衍生的高质量蒸汽。 将从不可冷凝气体中除去的二氧化硫部分加入到剩余的盐水中以再注入地下地热储层。
    • 5. 发明授权
    • Process for stabilizing silica-rich geothermal brine to prevent silica
scaling
    • 用于稳定富二氧化硅的地热盐水以防止二氧化硅结垢的方法
    • US4405463A
    • 1983-09-20
    • US318127
    • 1981-11-04
    • John W. JostWilliam C. LieffersOlin D. Whitescarver
    • John W. JostWilliam C. LieffersOlin D. Whitescarver
    • C02F1/60C02F1/72C02F1/52C02F1/74
    • C02F1/72C02F1/60
    • A process for stabilizing silica-rich geothermal brine to prevent silica scaling comprises selectively providing a supply of ferric ions, allowing the silica-rich brine to combine with the ferric ions to form insoluble, iron-rich siliceous material and separating the insoluble siliceous material from the brine to form a brine having a silica content which is reduced below the saturation level required for substantially scale-free handling of the brine. In one embodiment of the process in which the brine contains sufficient dissolved ferrous ions, the process comprises selectively contacting the brine with an oxidizing agent, preferably by aerating the brine, to oxidize a selected portion of the ferrous ions to ferric ions, which then combine with silica to form the insoluble iron-rich siliceous material. The ferric ion content of an iron-deficient brine may be augmented by adding ferric and/or ferrous ions to the brine. Steam released by flashing the untreated brine may be used to heat the stabilized brine before disposal thereof, so as to increase the silica solubility and reduce the amount of silica required to be removed to prevent scaling.
    • 用于稳定富二氧化硅的地热盐水以防止二氧化硅结垢的方法包括选择性地提供铁离子供应,允许富含二氧化硅的盐水与三价铁离子结合以形成不溶性富铁硅质材料,并将不溶性硅质材料从 盐水形成盐水,其二氧化硅含量降低到基本无水处理盐水所需的饱和水平以下。 在其中盐水含有足够溶解的亚铁离子的方法的一个实施方案中,该方法包括选择性地使盐水与氧化剂接触,优选通过使盐水充气,将亚铁离子的选定部分氧化成铁离子,然后将铁离子 用二氧化硅形成不溶性富铁硅质材料。 通过向盐水中加入铁和/或亚铁离子可以增加缺铁盐水的铁离子含量。 通过闪蒸未经处理的盐水释放的蒸汽可用于在处理之前加热稳定的盐水,以便增加二氧化硅溶解度并减少被除去的二氧化硅的量以防止结垢。