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    • 1. 发明授权
    • Electrocodeposition of polymer blends for photoreceptor substrates
    • 用于感光体底物的聚合物共混物的电沉积
    • US5258461A
    • 1993-11-02
    • US606846
    • 1990-11-26
    • John S. FacciRonald E. JansenDavid H. PanWilliam G. HerbertDonald S. SypulaJoseph Mammino
    • John S. FacciRonald E. JansenDavid H. PanWilliam G. HerbertDonald S. SypulaJoseph Mammino
    • C08L67/02C08L69/00C08L79/08C09D5/44G03G5/05G03G5/14G03G5/147C08L27/14C08L27/16
    • G03G5/14713C08L67/02C08L69/00C08L79/08C09D5/44G03G5/0525G03G5/142
    • Polymer films are formed by electrocodeposition of solutions containing a dispersion of charged particles of a first polymer and charged particles of a second polymer. Microheterogeneous films are obtained having micro-domains of a minor component polymer dispersed in the major component polymer. Processes for preparing dispersions for electrocodeposition are also provided In a first process, two polymers are dissolved in a common solvent and then dispersed as small charged particles in another solvent which is a precipitant for both polymers. In another process, a dispersion of a first polymer is prepared by adding a solution of the first polymer to a dispersant solvent, and then a solution of a second polymer is dispersed in the dispersion of the first polymer. In another process, a solution of the second polymer is added to a dispersion of the first polymer which contains only a single non-solvent for the second polymer. In yet another process, a dispersion of the first polymer in a first solvent system is mixed directly with a dispersion of a second polymer in a second solvent system, resulting in a dispersion of the first and second polymers in a resulting solvent system of the first and second solvent systems. In yet another process, a block copolymer composed of two blocks is dissolved in a solvent, and then dispersed in a non-solvent to form the dispersion.
    • 通过电沉积包含第一聚合物的带电粒子和第二聚合物的带电粒子的溶液的溶液形成聚合物膜。 获得了微分子膜,其具有分散在主要组分聚合物中的次要组分聚合物的微畴。 还提供了制备用于电沉积的分散体的方法。在第一种方法中,将两种聚合物溶解在常用溶剂中,然后作为小的带电粒子分散在另一种溶剂中,这是两种聚合物的沉淀剂。 在另一方法中,通过将第一聚合物的溶液加入到分散剂溶剂中,然后将第二聚合物的溶液分散在第一聚合物的分散体中来制备第一聚合物的分散体。 在另一方法中,将第二聚合物的溶液加入到仅含有用于第二聚合物的单一非溶剂的第一聚合物的分散体中。 在另一个方法中,将第一聚合物在第一溶剂体系中的分散体直接与第二聚合物在第二溶剂体系中的分散体混合,导致第一和第二聚合物在所得第一溶剂系统的溶剂体系中的分散 和第二溶剂体系。 在另一方法中,将由两个嵌段组成的嵌段共聚物溶解在溶剂中,然后分散在非溶剂中以形成分散体。