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1. 发明申请

US20080004406A1 DIIMINES AND SECONDARY DIAMINES 审中-公开
公开(公告)号：US20080004406A1
公开(公告)日：2008-01-03
申请号：US11855803
申请日：2007-09-14
申请人： John Lee , Paul Wiggins , Judith Orgad , Mahmood Sabahi , Vernon Brandt
发明人： John Lee , Paul Wiggins , Judith Orgad , Mahmood Sabahi , Vernon Brandt
IPC分类号： C08F291/12 , C07C211/50
CPC分类号： C07C211/12 , C07C211/51 , C08G18/10 , C08G18/3234 , C08G18/324 , C08G18/325 , C08G18/5024 , C08G18/6685 , C08G18/7671 , Y02P20/582
摘要： This invention provides aromatic diimines which have imino hydrocarbylidene groups with at least two carbon atoms, and aromatic secondary diamines which have amino hydrocarbyl groups with at least two carbon atoms. Both the aromatic diimines and the aromatic secondary diamines either are in the form of one phenyl ring, or are in the form of two phenyl rings connected by an alkylene bridge; each position ortho to an imino group or an amino group bears a hydrocarbyl group. When in the form of one phenyl ring, there are two imino groups on the ring or two amino groups on the ring; the imino groups or amino groups are meta or para relative to each other. When in the form of two phenyl rings connected by an alkylene bridge, there is either one imino group or one amino group on each phenyl ring. Also provided are processes for forming diimines and secondary diamines.

2. 发明申请

US20080033210A1 DIIMINES AND SECONDARY DIAMINES 失效
标题翻译： DIIMINES和次级DIAMINES
公开(公告)号：US20080033210A1
公开(公告)日：2008-02-07
申请号：US11855839
申请日：2007-09-14
申请人： John Lee , Paul Wiggins , Judith Orgad , Mahmood Sabahi
发明人： John Lee , Paul Wiggins , Judith Orgad , Mahmood Sabahi
IPC分类号： C07C211/51 , C07C211/35
CPC分类号： C07C211/12 , C07C211/51 , C08G18/10 , C08G18/3234 , C08G18/324 , C08G18/325 , C08G18/5024 , C08G18/6685 , C08G18/7671 , Y02P20/582
摘要： This invention provides aromatic diimines which have imino hydrocarbylidene groups with at least two carbon atoms, and aromatic secondary diamines which have amino hydrocarbyl groups with at least two carbon atoms. Both the aromatic diimines and the aromatic secondary diamines either are in the form of one phenyl ring, or are in the form of two phenyl rings connected by an alkylene bridge; each position ortho to an imino group or an amino group bears a hydrocarbyl group. When in the form of one phenyl ring, there are two imino groups on the ring or two amino groups on the ring; the imino groups or amino groups are meta or para relative to each other. When in the form of two phenyl rings connected by an alkylene bridge, there is either one imino group or one amino group on each phenyl ring. Also provided are processes for forming diimines and secondary diamines.
摘要翻译：本发明提供具有至少两个碳原子的亚氨基亚烃基的芳族二亚胺和具有至少两个碳原子的氨基烃基的芳族仲二胺。芳族二亚胺和芳族仲胺都是一个苯环的形式，或者是由亚烷基桥连接的两个苯环的形式; 亚氨基或氨基的邻位各为一个烃基。当以一个苯环的形式，环上有两个亚氨基或环上两个氨基; 亚氨基或氨基相对于彼此是间位或对位的。当以亚烷基桥连接的两个苯环的形式，每个苯环上有一个亚氨基或一个氨基。还提供了形成二亚胺和仲二胺的方法。

3. 发明申请

US20060217567A1 Diimines and secondary diamines 失效
标题翻译：二亚胺和仲胺
公开(公告)号：US20060217567A1
公开(公告)日：2006-09-28
申请号：US11390777
申请日：2006-03-27
申请人： John Lee , Paul Wiggins , Judith Orgad , Mahmood Sabahi , Vernon Brandt
发明人： John Lee , Paul Wiggins , Judith Orgad , Mahmood Sabahi , Vernon Brandt
IPC分类号： C07D249/02
CPC分类号： C07C211/12 , C07C211/51 , C08G18/10 , C08G18/3234 , C08G18/324 , C08G18/325 , C08G18/5024 , C08G18/6685 , C08G18/7671 , Y02P20/582
摘要： This invention provides aromatic diimines which have imino hydrocarbylidene groups with at least two carbon atoms, and aromatic secondary diamines which have amino hydrocarbyl groups with at least two carbon atoms. Both the aromatic diimines and the aromatic secondary diamines either are in the form of one phenyl ring, or are in the form of two phenyl rings connected by an alkylene bridge; each position ortho to an imino group or an amino group bears a hydrocarbyl group. When in the form of one phenyl ring, there are two imino groups on the ring or two amino groups on the ring; the imino groups or amino groups are meta or para relative to each other. When in the form of two phenyl rings connected by an alkylene bridge, there is either one imino group or one amino group on each phenyl ring. Also provided are processes for forming diimines and secondary diamines.
摘要翻译：本发明提供具有至少两个碳原子的亚氨基亚烃基的芳族二亚胺和具有至少两个碳原子的氨基烃基的芳族仲二胺。芳族二亚胺和芳族仲胺都是一个苯环的形式，或者是由亚烷基桥连接的两个苯环的形式; 亚氨基或氨基的邻位各为一个烃基。当以一个苯环的形式，环上有两个亚氨基或环上两个氨基; 亚氨基或氨基相对于彼此是间位或对位的。当以亚烷基桥连接的两个苯环的形式，每个苯环上有一个亚氨基或一个氨基。还提供了形成二亚胺和仲二胺的方法。

4. 发明申请

US20070270566A1 Chain Extenders 失效
标题翻译：扩链器
公开(公告)号：US20070270566A1
公开(公告)日：2007-11-22
申请号：US11534968
申请日：2006-09-25
申请人： John Lee , Paul Wiggins , Judit Orgad , Mahmood Sabahi , Vernon Brandt
发明人： John Lee , Paul Wiggins , Judit Orgad , Mahmood Sabahi , Vernon Brandt
IPC分类号： C08G18/00 , C07D249/02
CPC分类号： C08G18/7671 , C07C211/09 , C07C211/12 , C07C211/49 , C07C211/51 , C07C251/08 , C08G18/12 , C08G18/3228 , C08G18/3234 , C08G18/324 , C08G18/325 , C08G18/5024 , C08G18/6685
摘要： This invention provides chain extender compositions. These compositions comprise (i) an aromatic primary diamine, and (ii) a component selected from the group consisting of: (a) an aliphatic secondary diamine; (b) an aliphatic primary diamine; (c) an aliphatic secondary diamine and an aliphatic primary diamine; (d) a diimine; and (e) a combination of any two or more of (a) through (d). When (ii) is (a), (a) has amino hydrocarbyl groups which are secondary or tertiary hydrocarbyl groups; when (ii) is (d), and (d) is an aromatic diimine, each imino hydrocarbylidene group has at least two carbon atoms. Processes for producing polyurethanes, polyureas, and polyurea-urethanes are also provided.
摘要翻译：本发明提供扩链剂组合物。这些组合物包含（i）芳族伯二胺，和（ii）选自以下的组分：（a）脂族仲胺; （b）脂族伯胺; （c）脂族二胺和脂族伯二胺; （d）二亚胺; 和（e）（a）至（d）中任意两个或多个的组合。当（ii）是（a）时，（a）具有二级或三级烃基的氨基烃基; 当（ii）是（d）和（d）是芳族二亚胺时，每个亚氨基亚烃基具有至少两个碳原子。还提供了生产聚氨酯，聚脲和聚脲 - 聚氨酯的方法。

5. 发明授权

US07709545B2 Benzophenone/thioxanthone derivatives and their use in photopolymerizable compositions 失效
标题翻译：二苯甲酮/噻吨酮衍生物及其在光聚合组合物中的用途
公开(公告)号：US07709545B2
公开(公告)日：2010-05-04
申请号：US11950764
申请日：2007-12-05
申请人： Charles E. Hoyle , Sukhendu B. Hait , Mahmood Sabahi
发明人： Charles E. Hoyle , Sukhendu B. Hait , Mahmood Sabahi
IPC分类号： C08F2/50 , C07D335/16 , C07C319/00 , C07C49/786
CPC分类号： C08F2/50 , Y10S522/904 , Y10S522/905
摘要： Benzophenone/thioxanthone derivatives useful as photoinitiators are provided as well as photopolymerizable compositions comprising the benzophenone/thioxanthone derivatives.
摘要翻译：提供可用作光引发剂的二苯甲酮/噻吨酮衍生物以及包含二苯甲酮/噻吨酮衍生物的光聚合组合物。

6. 发明授权

US07015367B2 Stabilization and use of propargyl bromide 有权
公开(公告)号：US07015367B2
公开(公告)日：2006-03-21
申请号：US10756672
申请日：2004-01-12
申请人： Robert C. Herndon, Jr. , Robert H. Allen , Noel H. Brantley , Ronny W. Lin , Ralph W. Magin , Mahmood Sabahi
发明人： Robert C. Herndon, Jr. , Robert H. Allen , Noel H. Brantley , Ronny W. Lin , Ralph W. Magin , Mahmood Sabahi
IPC分类号： C07C33/042 , A01N29/08 , A01N31/02
CPC分类号： C07C21/22 , A01N29/02 , C07C17/16 , C07C17/42 , A01N2300/00
摘要： Propargyl bromide is effectively stabilized against shock or thermal decomposition by use therewith of an environmentally acceptable inert liquid solvent that forms an azeotrope with propargyl bromide.

7. 发明授权

US5350875A Michael reaction 失效
标题翻译：迈克尔反应
公开(公告)号：US5350875A
公开(公告)日：1994-09-27
申请号：US156755
申请日：1993-11-23
申请人： Govindarajulu Kumar , Mahmood Sabahi
发明人： Govindarajulu Kumar , Mahmood Sabahi
IPC分类号： C07C67/347 , C07C69/34
CPC分类号： C07C67/347
摘要： Compounds varying from liquids to solids can be prepared via a reaction in which at least one Michael donor is reacted with one or more Michael acceptors in the presence of an undissolved basic compound as the catalyst.
摘要翻译：从液体到固体的化合物可以通过其中至少一种迈克尔供体在未溶解的碱性化合物作为催化剂的存在下与一种或多种迈克尔受体反应的反应来制备。

8. 发明授权

US5347043A Process for preparing Michael addition products 失效
标题翻译：迈克尔加成产物的制备方法
公开(公告)号：US5347043A
公开(公告)日：1994-09-13
申请号：US169261
申请日：1993-12-20
申请人： Mahmood Sabahi , Robert G. Irwin
发明人： Mahmood Sabahi , Robert G. Irwin
IPC分类号： C07C67/343 , C07C69/34 , C07C67/00 , C07C67/465 , C07C69/38
CPC分类号： C07C67/343
摘要： Dialkyl malonate/alkyl acrylate Michael addition product mixtures having at least three acceptor moieties in a substantial number of the molecules can be consistently prepared without the need for long reaction times or the use of a large excess of the acceptor when the reaction is effected by gradually adding one molar proportion of a dialkyl malonate to at least three molar proportions of an alkyl acrylate which has been preheated to 60.degree.-80.degree. C. in admixture with an initiator and a phase transfer catalyst. In a preferred embodiment, the preheated mixture is maintained at 60.degree.-80.degree. C. for at least one hour before the dialkyl malonate is added in order to increase the percentage of product composed of the heavier components.
摘要翻译：丙二酸二烷基酯/丙烯酸烷基酯在相当数量的分子中具有至少三个受体部分的迈克尔加成产物混合物可以一致地制备，而不需要长的反应时间或当反应通过逐渐地进行反应时使用大量过量的受体将1摩尔比例的丙二酸二烷基酯加入到至少三摩尔比例的丙烯酸烷基酯中，该丙烯酸烷基酯与引发剂和相转移催化剂混合预热至60-80℃。在优选的实施方案中，将预热的混合物在加入丙二酸二烷基酯之前保持在60-80℃至少1小时以增加由较重组分组成的产物的百分比。

9. 发明授权

US5240630A Refrigeration compositions containing diester-amides of dialkanolamines 失效
标题翻译：含有二烷醇胺二酯的制冷组合物
公开(公告)号：US5240630A
公开(公告)日：1993-08-31
申请号：US958628
申请日：1992-10-09
申请人： Mahmood Sabahi , Donald R. Bell
发明人： Mahmood Sabahi , Donald R. Bell
IPC分类号： C07C233/18 , C10M105/68 , C10M171/00
CPC分类号： C10M171/008 , C07C233/18 , C10M105/68 , C10M2211/022 , C10M2211/06 , C10M2215/08 , C10N2240/00 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66
摘要： A refrigeration lubricant suitable for use with R-134a-type refrigerants comprises at least one dialkanolamine diester-amide oil corresponding to one of the formulas: ##STR1## in which formulas R is a hydrocarbylene group containing 1-10 carbons; n represents zero or one; each R' is independently selected from alkylene groups containing 1-10 carbons; R" is hydrogen or a hydrocarbyl group containing 1-10 carbons; and each G, when not linked with another G, is independently selected from hydrocarbyl groups containing 1-10 carbons or, when linked with another G, is a hydrocarbylene group which, together with the colinked G, forms a hydrocarbylene group containing 1-10 carbons.
摘要翻译：适合与R-134a型制冷剂一起使用的制冷润滑剂包含至少一种对应于下式之一的二烷醇胺二酯 - 酰胺油：其中式R为含有1-10个碳的亚烃基; n表示0或1; 每个R'独立地选自含有1-10个碳的亚烷基; R“是氢或含有1-10个碳的烃基; 并且每个G不与另一个G连接时，独立地选自含有1-10个碳的烃基，或者当与另一个G连接时，是亚烃基，其与连接的G一起形成含有1-10个碳原子的亚烃基碳。

10. 发明授权

US08212078B2 Diimines and secondary diamines 有权
标题翻译：二亚胺和仲胺
公开(公告)号：US08212078B2
公开(公告)日：2012-07-03
申请号：US11909824
申请日：2005-12-30
申请人： John Y. Lee , Paul L. Wiggins , Judit Orgad , Mahmood Sabahi , Vernon O. Brandt , David W. Owens
发明人： John Y. Lee , Paul L. Wiggins , Judit Orgad , Mahmood Sabahi , Vernon O. Brandt , David W. Owens
IPC分类号： C07C211/00
CPC分类号： C07C211/12 , C07C211/51 , C08G18/10 , C08G18/3234 , C08G18/324 , C08G18/325 , C08G18/5024 , C08G18/6685 , C08G18/7671 , Y02P20/582
摘要： This invention provides aromatic diimines where the diimines have imino groups with at least two carbon atoms, and either are in the form of one benzene ring having two imino groups on the ring, which imino groups are meta or para relative to each other, and in which each position ortho to an imino group bears a hydrocarbyl group, or are in the form of two benzene rings connected by an alkylene bridge and having one imino group on each ring, and in which each position ortho to an imino group bears a hydrocarbyl group. This invention also provides aromatic secondary diamines where the diamines have amino hydrocarbyl groups with at least two carbon atoms, and either are in the form of one benzene ring having two amino groups on the ring, which amino groups are meta or para relative to each other, and in which each position ortho to an amino group bears a hydrocarbyl group, or are in the form of two benzene rings connected by an alkylene bridge and having one amino group on each ring, and in which each position ortho to an amino group bears a hydrocarbyl group. Also provided are processes for forming diimines and secondary diamines from primary diamines, including the aromatic diimines and aromatic secondary diamines of the invention.
摘要翻译：本发明提供芳族二亚胺，其中二亚胺具有至少两个碳原子的亚氨基，并且是环上具有两个亚氨基的一个苯环的形式，该亚氨基相对于彼此是间位或对位的，并且在其中每个位于亚氨基的邻位具有烃基，或者是由亚烷基桥连接并在每个环上具有一个亚氨基的两个苯环的形式，并且其中亚氨基的邻位各有一个烃基。本发明还提供芳族仲二胺，其中二胺具有至少两个碳原子的氨基烃基，并且是环上具有两个氨基的一个苯环的形式，该氨基相对于彼此是间位或对位的并且其中氨基的每个位置具有烃基，或者为两个苯环的形式，其通过亚烷基桥连接并且在每个环上具有一个氨基，并且其中氨基的邻位各自承载烃基。还提供了由伯二胺形成二亚胺和仲二胺的方法，包括本发明的芳族二亚胺和芳族仲二胺。

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