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    • 4. 发明授权
    • Polymer bound multidentate complexes
    • 聚合物结合的多齿络合物
    • US4230828A
    • 1980-10-28
    • US968123
    • 1978-12-11
    • John H. Gaul, Jr.Russell S. Drago
    • John H. Gaul, Jr.Russell S. Drago
    • C08F8/28C08F8/32C08F8/42C08F8/30C08F8/04
    • C08F8/32C08F2810/20
    • Polymer bound multidentate complexes are prepared by reacting pendant benzyl chloride and benzyl iodide groups on a variety of polymer supports, including crosslinked polystyrene, with 3,3'-iminodiproprionitrile and reducing the nitrile groups by treatment with, for example, a boron hydride-tetrahydrofuran complex to form the amine. The amine is a precursor for other ligand systems; for example, the primary amine groups formed condense with an aldehyde or ketone to yield five coordinate Schiff base ligands. The polydentate amine ligand systems are useful for synthesis of chelating agents for sequestering metal ions from solution for purification or concentration purposes. Metal complexes of these ligands with manganese, iron, cobalt, nickel, copper, and zinc can be prepared which are useful as heterogeneous oxidation catalysts.
    • 通过使各种聚合物载体(包括交联聚苯乙烯)与3,3'-亚氨基二丙腈反应,将苄基氯和苄基碘基团反应,通过用例如硼氢化物 - 四氢呋喃处理来还原腈基来制备聚合物结合的多齿络合物 复合以形成胺。 胺是其他配体体系的前体; 例如,伯胺基团与醛或酮缩合以产生五配位席夫碱配体。 多齿胺配体体系可用于合成螯合剂,用于从溶液中螯合金属离子用于纯化或浓缩。 可以制备这些配体与锰,铁,钴,镍,铜和锌的金属络合物,其可用作非均相氧化催化剂。
    • 6. 发明授权
    • Polymer bound multidentate complexes
    • 聚合物结合的多齿络合物
    • US4281086A
    • 1981-07-28
    • US148065
    • 1980-05-12
    • John H. Gaul, Jr.Russell S. Drago
    • John H. Gaul, Jr.Russell S. Drago
    • C08F8/28C08F8/32C08F8/42C08F8/18C08F8/26C08F8/30
    • C08F8/28C08F12/18C08F212/08C08F2810/20
    • Polymer bound multidentate complexes are prepared by reacting pendant benzyl chloride and benzyl iodide groups on a variety of polymer supports, including crosslinked polystyrene, with 3,3'-iminodiproprionitrile and reducing the nitrile groups by treatment with, for example, a boron hydride-tetrahydrofuran complex to form the amine. The amine is a precursor for other ligand systems; for example, the primary amine groups formed condense with an aldehyde or ketone to yield five coordinate Schiff base ligands. The polydentate amine ligand systems are useful for synthesis of chelating agents for sequestering metal ions from solution for purification or concentration purposes. Metal complexes of these ligands with manganese, iron, cobalt, nickel, copper, and zinc can be prepared which are useful as heterogeneous oxidation catalysts.
    • 通过使各种聚合物载体(包括交联聚苯乙烯)与3,3'-亚氨基二丙腈反应,将苄基氯和苄基碘基团反应,通过用例如硼氢化物 - 四氢呋喃处理来还原腈基来制备聚合物结合的多齿络合物 复合以形成胺。 胺是其他配体体系的前体; 例如,伯胺基团与醛或酮缩合以产生五配位席夫碱配体。 多齿胺配体体系可用于合成螯合剂,用于从溶液中螯合金属离子用于纯化或浓缩。 可以制备这些配体与锰,铁,钴,镍,铜和锌的金属络合物,其可用作非均相氧化催化剂。