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1. 发明授权

US08652709B2 Method of sealing a bipolar plate supported solid oxide fuel cell with a sealed anode compartment 有权
标题翻译：用密封阳极室密封双极板支撑的固体氧化物燃料电池的方法
公开(公告)号：US08652709B2
公开(公告)日：2014-02-18
申请号：US12616186
申请日：2009-11-11
申请人： John David Carter , Joong-Myeon Bae , Terry Alan Cruse , James Michael Ralph , Deborah J. Myers
发明人： John David Carter , Joong-Myeon Bae , Terry Alan Cruse , James Michael Ralph , Deborah J. Myers
IPC分类号： H01M8/00 , H01M2/14 , H01M8/04 , H01M4/82
CPC分类号： H01M8/1226 , H01M8/0208 , H01M8/021 , H01M8/0232 , H01M8/0247 , H01M8/0258 , H01M8/0273 , H01M8/0282 , H01M8/0286 , H01M8/0297 , H01M8/2432 , H01M8/2435 , H01M8/2485 , Y10T29/4911
摘要： Methods of sealing a bipolar plate supported solid oxide fuel cell with a sealed anode compartment are provided. The solid oxide fuel cell includes a cathode, an electrolyte, and an anode, which are supported on a metallic bipolar plate assembly including gas flow fields and the gas impermeable bipolar plate. The electrolyte and anode are sealed into an anode compartment with a metal perimeter seal. An improved method of sealing is provided by extending the metal seal around the entire perimeter of the cell between an electrolyte and the bipolar plate to form the anode compartment. During a single-step high temperature sintering process the metal seal bonds to the edges of the electrolyte and anode layers, the metal foam flow field and the bipolar plate to form a gastight containment.
摘要翻译：提供了用密封阳极室密封双极板支撑的固体氧化物燃料电池的方法。固体氧化物燃料电池包括阴极，电解质和阳极，其被支撑在包括气体流场的金属双极板组件和不透气的双极板上。将电解质和阳极密封在具有金属周边密封件的阳极室中。通过将金属密封件围绕电解质和双极板之间的电池的整个周边延伸以形成阳极室来提供改进的密封方法。在单步高温烧结过程中，金属密封结合到电解质和阳极层的边缘，金属泡沫流场和双极板以形成密封容器。

2. 发明授权

US07632593B2 Bipolar plate supported solid oxide fuel cell with a sealed anode compartment 有权
标题翻译：双极板支撑固体氧化物燃料电池与密封的阳极室
公开(公告)号：US07632593B2
公开(公告)日：2009-12-15
申请号：US11406097
申请日：2006-04-18
申请人： John David Carter , Joong-Myeon Bae , Terry Alan Cruse , James Michael Ralph , Deborah J. Myers
发明人： John David Carter , Joong-Myeon Bae , Terry Alan Cruse , James Michael Ralph , Deborah J. Myers
IPC分类号： H01M2/08
CPC分类号： H01M8/1226 , H01M8/0208 , H01M8/021 , H01M8/0232 , H01M8/0247 , H01M8/0258 , H01M8/0273 , H01M8/0282 , H01M8/0286 , H01M8/0297 , H01M8/2432 , H01M8/2435 , H01M8/2485 , Y10T29/4911
摘要： A bipolar plate supported solid oxide fuel cell with a sealed anode compartment is provided. The solid oxide fuel cell includes a cathode, an electrolyte, and an anode, which are supported on a metallic bipolar plate assembly including gas flow fields and the gas impermeable bipolar plate. The electrolyte and anode are sealed into an anode compartment with a metal perimeter seal. An improved method of sealing is provided by extending the metal seal around the entire perimeter of the cell between an electrolyte and the bipolar plate to form the anode compartment. During a single-step high temperature sintering process the metal seal bonds to the edges of the electrolyte and anode layers, the metal foam flow field and the bipolar plate to form a gastight containment.
摘要翻译：提供了具有密封阳极室的双极板支撑的固体氧化物燃料电池。固体氧化物燃料电池包括阴极，电解质和阳极，其被支撑在包括气体流场的金属双极板组件和不透气的双极板上。将电解质和阳极密封在具有金属周边密封件的阳极室中。通过将金属密封件围绕电解质和双极板之间的电池的整个周边延伸以形成阳极室来提供改进的密封方法。在单步高温烧结过程中，金属密封结合到电解质和阳极层的边缘，金属泡沫流场和双极板以形成密封容器。

3. 发明申请

US20100064508A1 METHOD OF SEALING A BIPOLAR PLATE SUPPORTED SOLID OXIDE FUEL CELL WITH A SEALED ANODE COMPARTMENT 有权
标题翻译：用密封阳极室密封支撑板支撑的固体氧化物燃料电池的方法
公开(公告)号：US20100064508A1
公开(公告)日：2010-03-18
申请号：US12616186
申请日：2009-11-11
申请人： John David Carter , Joong-Myeon Bae , Terry Alan Cruse , James Michael Ralph , Deborah J. Myers
发明人： John David Carter , Joong-Myeon Bae , Terry Alan Cruse , James Michael Ralph , Deborah J. Myers
IPC分类号： H01M8/10
CPC分类号： H01M8/1226 , H01M8/0208 , H01M8/021 , H01M8/0232 , H01M8/0247 , H01M8/0258 , H01M8/0273 , H01M8/0282 , H01M8/0286 , H01M8/0297 , H01M8/2432 , H01M8/2435 , H01M8/2485 , Y10T29/4911
摘要： Methods of sealing a bipolar plate supported solid oxide fuel cell with a sealed anode compartment are provided. The solid oxide fuel cell includes a cathode, an electrolyte, and an anode, which are supported on a metallic bipolar plate assembly including gas flow fields and the gas impermeable bipolar plate. The electrolyte and anode are sealed into an anode compartment with a metal perimeter seal. An improved method of sealing is provided by extending the metal seal around the entire perimeter of the cell between an electrolyte and the bipolar plate to form the anode compartment. During a single-step high temperature sintering process the metal seal bonds to the edges of the electrolyte and anode layers, the metal foam flow field and the bipolar plate to form a gastight containment.
摘要翻译：提供了用密封阳极室密封双极板支撑的固体氧化物燃料电池的方法。固体氧化物燃料电池包括阴极，电解质和阳极，其被支撑在包括气体流场的金属双极板组件和不透气的双极板上。将电解质和阳极密封在具有金属周边密封件的阳极室中。通过将金属密封件围绕电解质和双极板之间的电池的整个周边延伸以形成阳极室来提供改进的密封方法。在单步高温烧结过程中，金属密封结合到电解质和阳极层的边缘，金属泡沫流场和双极板以形成密封容器。

4. 发明授权

US06670305B2 Free-standing monolithic catalyst with micro-scale channel dimensions 失效
标题翻译：独立式整体式催化剂，具有微尺度通道尺寸
公开(公告)号：US06670305B2
公开(公告)日：2003-12-30
申请号：US09851843
申请日：2001-05-09
申请人： Joong-Myeon Bae , John David Carter , Michael Krumpelt , Shabbir Ahmed
发明人： Joong-Myeon Bae , John David Carter , Michael Krumpelt , Shabbir Ahmed
IPC分类号： B01J2104
CPC分类号： B01J37/0244 , B01J23/42 , B01J23/63 , B01J35/04 , B01J37/0018 , B01J37/0219 , C01B3/382 , Y02P20/52
摘要： A monolithic catalyst with micro-scale flow channels and methods of making such a monolithic catalyst are provided. The monolithic catalyst includes a plurality of thin catalyst walls. The walls have a set thickness in a range from 1 to 150 &mgr;m. The thin catalyst walls define a plurality of flow channels. A fugitive material is used to form the flow channels. The flow channels have a set width in a range from 1 to 200 &mgr;m. The flow channels are formed by an organic fugitive material, which burns off during processing. By using the thin catalyst walls and flow channels having a set width in a range from 1 to 200 &mgr;m, a reduced diffusion path length that molecules travel between the bulk gas and the active site is provided. Accelerating the mass transport thus improves the overall reaction rate, which allows processing of more reactants. Thus, the volume of the required catalyst is reduced, allowing more compact reactors. Fabrication methods involve simple, low-cost and scaleable procedures, allowing the flow channel and catalyst dimensions to be easily scaled to a requisite size for a given application. One fabrication method involves tape casting successive layers of fugitive and catalyst materials, and then firing to remove the organic binders and partially sinter the catalyst particles. The slurries can also be cast into thin layers using various processes, including screen printing, wet spraying and spin casting. Another fabrication method for fabricating a supported catalyst involves dipping a pre-shaped metal foil into a slurry containing an active catalyst powder, allowing the catalyst slurry to coat the foil evenly and allowing the catalyst slurry coated foil to dry. The catalyst slurry coated foil is dipped into a solution to form a fugitive coating layer, next the coated metal foil is cut into strips and formed into a selected shape.
摘要翻译：提供了具有微尺度流动通道的整体式催化剂和制造这种整体式催化剂的方法。整体式催化剂包括多个薄的催化剂壁。墙壁的厚度范围为1至150 mum。薄催化剂壁限定多个流动通道。使用逃逸材料形成流动通道。流道的设定宽度范围为1〜200μm。流动通道由加工过程中燃烧的有机短暂物质形成。通过使用具有1至200μm范围内的设定宽度的薄催化剂壁和流动通道，提供分子在大气体和活性位点之间行进的减小的扩散路径长度。因此，加速质量传递提高了整体反应速率，这允许加工更多的反应物。因此，所需催化剂的体积减小，允许更紧凑的反应器。制造方法涉及简单，低成本和可扩展的程序，允许流动通道和催化剂尺寸容易地缩放到给定应用的必要尺寸。一种制造方法包括将连续的挥发性和催化剂材料层进行带铸，然后焙烧以除去有机粘合剂并部分烧结催化剂颗粒。浆料也可以使用各种方法浇铸成薄层，包括丝网印刷，湿式喷涂和旋转浇铸。用于制造负载型催化剂的另一种制造方法包括将预形金属箔浸入含有活性催化剂粉末的浆料中，使催化剂浆料均匀地涂覆箔片，并使涂覆有催化剂浆料的箔片干燥。将催化剂浆料涂覆的箔浸入溶液中以形成短暂的涂层，接下来将涂覆的金属箔切成条并形成选定的形状。

5. 发明授权

US06843960B2 Compositionally graded metallic plates for planar solid oxide fuel cells 失效
标题翻译：用于平面固体氧化物燃料电池的组成分级金属板
公开(公告)号：US06843960B2
公开(公告)日：2005-01-18
申请号：US10167832
申请日：2002-06-12
申请人： Michael Krumpelt , Terry Alan Cruse , John David Carter , Jules L. Routbort , Romesh Kumar
发明人： Michael Krumpelt , Terry Alan Cruse , John David Carter , Jules L. Routbort , Romesh Kumar
IPC分类号： B22F3/11 , B22F5/00 , B22F7/00 , H01M8/02 , B22F3/00
CPC分类号： H01M8/0208 , B22F3/1137 , B22F5/006 , B22F7/002 , B22F2003/145 , B22F2999/00 , H01M8/021 , H01M8/0228 , H01M8/0232 , Y10T428/12458 , B22F3/22
摘要： A method for preparing compositionally graded metallic plates and compositionally graded metallic plates suitable for use as interconnects for solid oxide fuel cells are provided. The method of the invention, utilizing powder metallurgy, enables making metallic plates of generally any desired composition to meet the corrosion requirements of fuel cells and other applications, and enables making metallic plates of graded composition from one surface of the plate to the other. A powder of the desired alloy composition is obtained, then solvents, dispersants, a plasticizer and an organic binder are added to form a slip. The slip is then formed into a layer on a desired substrate that can be flat or textured. Once dried, the layer is removed from the substrate and the binder is burned out. The layer is sintered in a reducing atmosphere at a set temperature for a predefined duration specific to the materials used and the desired final properties.
摘要翻译：提供了一种制备适合用作固体氧化物燃料电池互连件的组成分级金属板和组成分级金属板的方法。利用粉末冶金技术的本发明的方法使得能够使金属板通常具有任何所需的组成以满足燃料电池和其它应用的腐蚀要求，并且使得能够从板的一个表面到另一个表面制备分级成分的金属板。得到所需合金组成的粉末，然后加入溶剂，分散剂，增塑剂和有机粘合剂以形成滑移。然后将滑移物形成为可以是平坦的或纹理化的期望的基底上的层。一旦干燥，将层从基材上除去，并将粘合剂烧掉。该层在还原气氛中在设定温度下烧结预定的持续时间，其特定于所使用的材料和期望的最终性能。

6. 发明授权

US07563292B2 Fuel processor and method for generating hydrogen for fuel cells 失效
公开(公告)号：US07563292B2
公开(公告)日：2009-07-21
申请号：US10789219
申请日：2004-02-27
申请人： Shabbir Ahmed , Sheldon H. D. Lee , John David Carter , Michael Krumpelt , Deborah J. Myers
发明人： Shabbir Ahmed , Sheldon H. D. Lee , John David Carter , Michael Krumpelt , Deborah J. Myers
IPC分类号： B01J7/00
CPC分类号： B01J8/0492 , B01J8/0465 , B01J8/0496 , B01J2208/00309 , B01J2208/00495 , B01J2208/0053 , C01B3/382 , C01B3/386 , C01B3/48 , C01B2203/0244 , C01B2203/0283 , C01B2203/0288 , C01B2203/044 , C01B2203/0455 , C01B2203/0465 , C01B2203/047 , C01B2203/0485 , C01B2203/066 , C01B2203/0844 , C01B2203/0877 , C01B2203/0883 , C01B2203/1041 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C01B2203/1205 , C01B2203/1241 , C01B2203/1247 , C01B2203/1276 , C01B2203/1282 , C01B2203/1294 , C01B2203/142 , C01B2203/143 , C01B2203/146 , C01B2203/169 , C01B2203/82
摘要： A method of producing a H2 rich gas stream includes supplying an O2 rich gas, steam, and fuel to an inner reforming zone of a fuel processor that includes a partial oxidation catalyst and a steam reforming catalyst or a combined partial oxidation and stream reforming catalyst. The method also includes contacting the O2 rich gas, steam, and fuel with the partial oxidation catalyst and the steam reforming catalyst or the combined partial oxidation and stream reforming catalyst in the inner reforming zone to generate a hot reformate stream. The method still further includes cooling the hot reformate stream in a cooling zone to produce a cooled reformate stream. Additionally, the method includes removing sulfur-containing compounds from the cooled reformate stream by contacting the cooled reformate stream with a sulfur removal agent. The method still further includes contacting the cooled reformate stream with a catalyst that converts water and carbon monoxide to carbon dioxide and H2 in a water-gas-shift zone to produce a final reformate stream in the fuel processor.

7. 发明授权

US09073758B2 Synthesis of metal borides 有权
标题翻译：金属硼化物的合成
公开(公告)号：US09073758B2
公开(公告)日：2015-07-07
申请号：US13454022
申请日：2012-04-23
申请人： Rasit Koc , Jennifer R. Mawdsley , John David Carter
发明人： Rasit Koc , Jennifer R. Mawdsley , John David Carter
IPC分类号： C01B35/04 , C01B35/00 , C01B35/02
CPC分类号： C01B35/04 , C01B35/00 , C01B35/02 , C01P2004/62 , C01P2006/12
摘要： Methods for the synthesis of metal borides. Metal boride compounds synthesized by those methods are also disclosed.
摘要翻译：金属硼化物的合成方法。还公开了通过这些方法合成的金属硼化物。

8. 发明授权

US08455711B2 Disposable absorbent article comprising a durable hydrophilic topsheet 有权
标题翻译：一次性吸收制品，其包含耐用的亲水性顶片
公开(公告)号：US08455711B2
公开(公告)日：2013-06-04
申请号：US11479545
申请日：2006-06-30
申请人： Ekaterina Anatolyevna Ponomarenko , John David Carter , Ronald Dean Cramer , Mattias Schmidt , Robert Henry Rohrbaugh
发明人： Ekaterina Anatolyevna Ponomarenko , John David Carter , Ronald Dean Cramer , Mattias Schmidt , Robert Henry Rohrbaugh
IPC分类号： A61F13/15 , A61F13/511
CPC分类号： A61F13/51121 , A61F13/51311 , A61F13/8405 , A61F2013/51066
摘要： A disposable absorbent article having a durable hydrophilic substantially liquid pervious topsheet. The topsheet includes a topsheet substrate and a hydrophilicity boosting composition coated on the topsheet substrate. The hydrophilicity boosting composition includes a hydrophilicity boosting amount of nanoparticles having a particle size of from about 1 nanometer to about 750 nanometers.
摘要翻译：一种一次性吸收制品，具有耐久的亲水基本上液体可透过的顶片。顶片包括顶片基材和涂覆在顶片基材上的亲水性增强组合物。亲水性增强组合物包括具有约1纳米至约750纳米的粒度的亲水性增强量的纳米颗粒。

9. 发明申请

US20120315207A1 SYNTHESIS OF METAL BORIDES 有权
标题翻译：金属合金的合成
公开(公告)号：US20120315207A1
公开(公告)日：2012-12-13
申请号：US13454022
申请日：2012-04-23
申请人： Rasit Koc , Jennifer R. Mawdsley , John David Carter
发明人： Rasit Koc , Jennifer R. Mawdsley , John David Carter
IPC分类号： C01B35/00 , B82Y30/00 , B82Y40/00
CPC分类号： C01B35/04 , C01B35/00 , C01B35/02 , C01P2004/62 , C01P2006/12
摘要： Methods for the synthesis of metal borides. Metal boride compounds synthesized by those methods are also disclosed.
摘要翻译：金属硼化物的合成方法。还公开了通过这些方法合成的金属硼化物。

10. 发明申请

US20090057619A1 Compositions and Visual Perception Changing Methods 审中-公开
标题翻译：组合和视觉感知变化方法
公开(公告)号：US20090057619A1
公开(公告)日：2009-03-05
申请号：US12198156
申请日：2008-08-26
申请人： Stephen Allen Goldman , John David Carter
发明人： Stephen Allen Goldman , John David Carter
IPC分类号： C09K3/00
CPC分类号： C11D3/40 , C11D17/0039
摘要： A composition includes at least one visual indicator dye and a surfactant. Upon dilution of the composition with a volume of water a diluted product is formed, and wherein: i) the extinction coefficient of the composition is less than the extinction coefficient of the diluted product measured at a wavelength from about 400 nm to about 700 nm; ii) a ratio of an absorbance measured between about 550-650 nm and an absorbance measured between about 395-440 nm increases upon increasing dilution of the composition; and/or iii) the pKa of the composition is greater than the pKa of the diluted product. Additionally, methods for changing the visual perception of a composition comprise diluting a composition.
摘要翻译：组合物包括至少一种视觉指示剂染料和表面活性剂。在用体积的水稀释组合物时，形成稀释的产物，并且其中：i）组合物的消光系数小于在约400nm至约700nm的波长下测量的稀释产物的消光系数; ii）在约550-650nm处测量的吸光度与在约395-440nm之间测量的吸光度的比率随着组合物的稀释增加而增加; 和/或iii）组合物的pKa大于稀释产物的pKa。另外，用于改变组合物的视觉感知的方法包括稀释组合物。

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