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1. 发明授权

US5904990A Amino functional poly (para-phenylene vinylene)s as protective coatings 失效
标题翻译：氨基官能聚（对亚苯基亚乙烯基）作为保护涂层
公开(公告)号：US5904990A
公开(公告)日：1999-05-18
申请号：US46848
申请日：1998-03-13
申请人： John D. Stenger-Smith , Melvin H. Miles , William P. Norris , John Nelson , Peter Zarras , John W. Fischer , Andrew P. Chafin
发明人： John D. Stenger-Smith , Melvin H. Miles , William P. Norris , John Nelson , Peter Zarras , John W. Fischer , Andrew P. Chafin
IPC分类号： C09D165/00 , B32B15/04 , B32B15/08 , B32B27/00
CPC分类号： C09D165/00 , Y10T428/31504 , Y10T428/31678 , Y10T428/31692 , Y10T428/31855
摘要： Until recently, conducting polymers have been used as protective coatings.lthough these types of polymers appear to be effective in most cases, problems have resulted when attempting to bind these polymers to an aluminum surface. The polymers of this invention adhere extremely well to aluminum and aluminum alloys and thus, provide a very effective form of corrosion protection.
摘要翻译：直到最近，导电聚合物已被用作保护涂层。尽管这些类型的聚合物在大多数情况下似乎是有效的，但是当试图将这些聚合物结合到铝表面时，会产生问题。本发明的聚合物非常适合于铝和铝合金，从而提供非常有效的防腐蚀形式。

2. 发明授权

US5882785A Nonlinear optical films from pair-wise-deposited semi-ionomeric syndioregic polymers 失效
标题翻译：来自成对沉积的半离聚单体聚合物的非线性光学膜
公开(公告)号：US5882785A
公开(公告)日：1999-03-16
申请号：US800943
申请日：1997-01-23
申请人： Richard A. Hollins , Geoffrey A. Lindsay , Marion J. Roberts , Peter Zarras , John D. Stenger-Smith , Kenneth J. Wynne , Andrew P. Chafin
发明人： Richard A. Hollins , Geoffrey A. Lindsay , Marion J. Roberts , Peter Zarras , John D. Stenger-Smith , Kenneth J. Wynne , Andrew P. Chafin
IPC分类号： B05D1/20 , G02F1/361 , C09K19/02 , C09K19/48
CPC分类号： B82Y30/00 , B05D1/202 , B82Y20/00 , B82Y40/00 , G02F1/3616 , G02F1/3618 , Y10T428/261 , Y10T428/31504 , Y10T428/31728
摘要： This invention is comprised of new nonlinear optic polymers and a new Lanir-Blodgett (LB) film deposition scheme for which these polymers were designed. The invention is unique because it produces an electro-optic film which has never undergone electric-field poling nor high temperature treatment. It eliminates the dilution effect of the long hydrophobic alkyl groups, and creates stronger ionic bonds between the polymer chains. Finally, the invention reduces the time to make a film of a given thickness by at least half by virtue of depositing two polymer layers per stroke. The new polymers are comprised of asymmetric chromophores linked head-to-head by alternating two different kinds of bridging groups. One of the bridging groups contains one or more ionic groups, and the other bridging group contains one or more non-ionic, hydrophilic groups.
摘要翻译：本发明由新型非线性光学聚合物和这些聚合物设计的新型Langmuir-Blodgett（LB）薄膜沉积方案组成。本发明是独特的，因为它产生从未经过电场极化或高温处理的电光膜。它消除了长疏水烷基的稀释效应，并在聚合物链之间产生更强的离子键。最后，本发明通过每冲程沉积两个聚合物层，减少了将给定厚度的膜制成至少一半的时间。新的聚合物由不对称的发色团组成，通过交替两种不同种类的桥连基团与头对头连接。桥连基团之一含有一个或多个离子基团，另一个桥连基团含有一个或多个非离子的亲水基团。

3. 依法登记的发明

USH2046H1 Process for mass producing uniform multi-layer non-linear optical polymer thin polar films 失效
公开(公告)号：USH2046H1
公开(公告)日：2002-09-03
申请号：US08956017
申请日：1997-10-22
申请人： M. Joe Roberts , Geoff A. Lindsay , Kenneth J. Wynne , Andrew P. Chafin , John D. Stenger-Smith , Peter Zarras , Rena Y. Yee , Richard A. Holloins
发明人： M. Joe Roberts , Geoff A. Lindsay , Kenneth J. Wynne , Andrew P. Chafin , John D. Stenger-Smith , Peter Zarras , Rena Y. Yee , Richard A. Holloins
IPC分类号： B05D506
摘要： A process that lends itself to automation for producing multi-layer second-order nonlinear optical polymer (NLOP) thin films by the forming of a polycation layer containing an NLO-active cationic polymer, having non-centrosymmetric chromophores, on a substrate followed by the forming of a polyanion layer, also having non-centrosymmetric chromophores, on the polycation layer. A predetermind number of the polycation and the polyanion layers may be alternated upon the surface as well as one or more buffer layers. An added benefit is the formation of an ultra-smooth surface of the same order of roughness as the substrate upon which the layers are formed.

4. 发明授权

US6114031A Polarized films from pairwise-deposited semi-ionomeric syndioregic polymers 失效
标题翻译：成对沉积的半离聚物共聚聚合物的极化膜
公开(公告)号：US6114031A
公开(公告)日：2000-09-05
申请号：US246197
申请日：1999-01-11
申请人： Marion J. Roberts , John D. Stenger-Smith , Kenneth J. Wynne , Peter Zarras , Andrew P. Chafin , Richard A. Hollins , Geoffrey A. Lindsay
发明人： Marion J. Roberts , John D. Stenger-Smith , Kenneth J. Wynne , Peter Zarras , Andrew P. Chafin , Richard A. Hollins , Geoffrey A. Lindsay
IPC分类号： B05D1/20 , G02F1/361
CPC分类号： B82Y30/00 , B05D1/202 , B82Y20/00 , B82Y40/00 , G02F1/3616 , G02F1/3618 , Y10T428/261
摘要： This invention is comprised of new nonlinear optic polymers and a new Lanir-Blodgett (LB) film deposition scheme for which these polymers were designed. The invention is unique because it produces an electro-optic film which has never undergone electric-field poling nor high temperature treatment. It eliminates the dilution effect of the long hydrophobic alkyl groups, and creates stronger ionic bonds between the polymer chains. Finally, the invention reduces the time to make a film of a given thickness by at least half by virtue of depositing two polymer layers per stroke. The new polymers are comprised of asymmetric chromophores linked head-to-head by alternating two different kinds of bridging groups. One of the bridging groups contains one or more ionic groups, and the other bridging group contains one or more non-ionic, hydrophilic groups.
摘要翻译：本发明由新型非线性光学聚合物和这些聚合物设计的新型Langmuir-Blodgett（LB）薄膜沉积方案组成。本发明是独特的，因为它产生从未经过电场极化或高温处理的电光膜。它消除了长疏水烷基的稀释效应，并在聚合物链之间产生更强的离子键。最后，本发明通过每冲程沉积两个聚合物层，减少了将给定厚度的膜制成至少一半的时间。新的聚合物由不对称的发色团组成，通过交替两种不同种类的桥连基团与头对头连接。桥连基团之一含有一个或多个离子基团，另一个桥连基团含有一个或多个非离子的亲水基团。

5. 发明授权

US5604292A Polymers with electrical and non-linear optical properties 失效
标题翻译：具有电气和非线性光学性质的聚合物
公开(公告)号：US5604292A
公开(公告)日：1997-02-18
申请号：US252701
申请日：1994-05-31
申请人： John D. Stenger-Smith , William P. Norris , Andrew P. Chafin , Scott T. Sackinger
发明人： John D. Stenger-Smith , William P. Norris , Andrew P. Chafin , Scott T. Sackinger
IPC分类号： C08G61/02 , C08F112/00
CPC分类号： C08G61/02
摘要： Novel conjugated amino substituted phenylene polymers are disclosed havingon-linear optical properties, and which can be converted to electrically conductive polymers. Such polymers are produced by reacting a novel bis-cycloalkylene sulfonium salt of 2,5,N,N-tetramethylaniline hydrochloride, such as 2,5-(N,N-dimethyl)aniline hydrochloride dimethylene bis-(tetramethylene sulfonium chloride) with alkali metal hydroxide to form a cycloalkylene sulfonium salt precursor polymer, and then heating the precursor polymer under conditions to produce the amino substituted phenylene vinylene polymer, such as poly(2-(N,N-dimethylamino) phenylene vinylene). The polymers can also be made directly by treatment of the bis chlormethyl dimethyl aniline hydrochloride derivative with alkali metal alkoxide.
摘要翻译：公开了具有非线性光学性质的新型共轭氨基取代的亚苯基聚合物，并且其可以转化为导电聚合物。这种聚合物通过使2,5，N，N-四甲基苯胺盐酸盐如2,5-（N，N-二甲基）苯胺盐酸盐二亚甲基双 - （四亚甲基锍氯化物）与碱的碱的双 - 亚环烷基锍盐金属氢氧化物以形成亚环烷基锍盐前体聚合物，然后在产生氨基取代的亚苯基亚乙烯基聚合物如聚（2-（N，N-二甲基氨基）亚苯基亚乙烯基）的条件下加热前体聚合物。聚合物也可以通过用碱金属醇盐处理双氯甲基二甲基苯胺盐酸盐衍生物直接制备。

6. 发明授权

US5587488A Bis-sulfonium salts of amino substituted bis(halomethyl) benzene 失效
标题翻译：氨基取代的双（卤代甲基）苯的双锍盐
公开(公告)号：US5587488A
公开(公告)日：1996-12-24
申请号：US441178
申请日：1995-05-10
申请人： John D. Stenger-Smith , William P. Norris , Andrew P. Chafin
发明人： John D. Stenger-Smith , William P. Norris , Andrew P. Chafin
IPC分类号： C08G61/02 , C07D409/10
CPC分类号： C08G61/02
摘要： Novel bis-sulfonium salts of amino substituted bis(halomethyl)benzene are disclosed. The sulfonium salts are prepared by reaction of an amino substituted bis(halo methyl)benzene with an aliphatic sulfide. These sulfonium salts can be made into polymer having non-linear optical properties, and polymers which can be converted to electrically conductive polymers. Such polymers are produced by reacting a novel bis-cycloalkylene sulfonium salt of 2,5,N,N-tetramethylaniline hydrochloride, such as 2,5-(N,N-dimethyl)aniline hydrochloride dimethylene bis-(tetramethylene sulfonium chloride) with alkali metal hydroxide to form a cycloalkylene sulfonium salt precursor polymer, and then heating the precursor polymer under conditions to produce the amino substituted phenylene vinylene polymer, such as poly(2-(N,N-dimethylamino) phenylene vinylene).
摘要翻译：公开了氨基取代的双（卤代甲基）苯的新型双锍盐。锍盐通过氨基取代的双（卤代甲基）苯与脂族硫醚的反应来制备。这些锍盐可以制成具有非线性光学性质的聚合物和可以转化成导电聚合物的聚合物。这种聚合物通过使2,5，N，N-四甲基苯胺盐酸盐如2,5-（N，N-二甲基）苯胺盐酸盐二亚甲基双 - （四亚甲基锍氯化物）与碱的碱的双 - 亚环烷基锍盐金属氢氧化物以形成亚环烷基锍盐前体聚合物，然后在产生氨基取代的亚苯基亚乙烯基聚合物如聚（2-（N，N-二甲基氨基）亚苯基亚乙烯基）的条件下加热前体聚合物。

7. 发明授权

US5578699A Process for making amino functional poly(para-phenylene vinylene)s 失效
标题翻译：制备氨基官能聚（对亚苯基亚乙烯基）的方法
公开(公告)号：US5578699A
公开(公告)日：1996-11-26
申请号：US457350
申请日：1995-05-18
申请人： John D. Stenger-Smith , William P. Norris , Andrew P. Chafin , Scott T. Sackinger
发明人： John D. Stenger-Smith , William P. Norris , Andrew P. Chafin , Scott T. Sackinger
IPC分类号： C08G61/02 , C08G75/00 , C08F6/00
CPC分类号： C08G61/02
摘要： A process for synthesizing novel conjugated amino substituted phenylene pmers is disclosed. The process results in polymers having non-linear optical properties, and the polymers can be converted to electrically conductive polymers. The process involves reacting a novel bis-cycloalkylene sulfonium salt of 2,5,N,N-tetramethylaniline hydrochloride, such as 2,5-(N,N-dimethyl)aniline hydrochloride dimethylene bis-(tetramethylene sulfonium chloride) with alkali metal hydroxide to form a cycloalkylene sulfonium salt precursor polymer, and then heating the precursor polymer under conditions to produce the amino substituted phenylene vinylene polymer, such as poly(2-(N,N-dimethylamino) phenylene vinylene). Another process involves treatment of the bis chlormethyl dimethyl aniline hydrochloride derivative with alkali metal alkoxide.
摘要翻译：公开了一种合成新的共轭氨基取代的亚苯基聚合物的方法。该方法导致具有非线性光学性质的聚合物，并且聚合物可以转化为导电聚合物。该方法包括使2,5，N，N-四甲基苯胺盐酸盐如2,5-（N，N-二甲基）苯胺盐酸盐二亚甲基双 - （四亚甲基氯化锍）与碱金属氢氧化物的新型双亚烷基锍盐形成亚环烷基锍盐前体聚合物，然后在产生氨基取代的亚苯基亚乙烯基聚合物如聚（2-（N，N-二甲基氨基）亚苯基亚乙烯基）的条件下加热前体聚合物。另一个方法包括用碱金属醇盐处理双氯甲基二甲基苯胺盐酸盐衍生物。

8. 发明授权

US5585522A Amino substituted bishalomethyl benzene compounds 失效
标题翻译：氨基取代的双甲基苯化合物
公开(公告)号：US5585522A
公开(公告)日：1996-12-17
申请号：US441179
申请日：1995-05-10
申请人： John D. Stenger-Smith , William P. Norris , Andrew P. Chafin
发明人： John D. Stenger-Smith , William P. Norris , Andrew P. Chafin
IPC分类号： C08G61/02 , C07C211/52
CPC分类号： C08G61/02
摘要： Novel amino substituted bishalomethyl benzene compounds, which are precurs to phenylene polymers are disclosed having non-linear optical properties, and which can be converted to electrically conductive polymers. Such polymers are produced by reacting a novel amino substituted bishalomethyl benzene compound with a dialkyl sulfide to make a bis-cycloalkylene sulfonium salt of 2,5,N,N-tetramethylaniline hydrochloride, which is 2,5-(N,N-dimethyl)aniline hydrochloride dimethylene bis-(tetramethylene sulfonium chloride) and reacting this sulfonium salt with alkali metal hydroxide to form a cycloalkylene sulfonium salt precursor polymer, and then heating the precursor polymer under conditions to produce the amino substituted phenylene vinylene polymer, such as poly(2-(N,N-dimethylamino) phenylene vinylene). The polymers can also be made directly by treatment of the bis chlormethyl dimethyl aminobenzene hydrochloride derivative with alkali metal alkoxide.
摘要翻译：公开了作为亚苯基聚合物的前体的新型氨基取代的双甲基苯化合物，其具有非线性光学性质，并且可以转化为导电聚合物。这种聚合物通过使新的氨基取代的二异丙基甲基苯化合物与二烷基硫化物反应来制备2,5-N，N-四甲基苯胺盐酸盐的双亚环烷基锍盐，其为2,5-（N，N-二甲基）苯胺盐酸盐二亚甲基双 - （四亚甲基氯化锍），并使该锍盐与碱金属氢氧化物反应形成环亚烷基锍盐前体聚合物，然后在条件下加热前体聚合物，生成氨基取代的亚苯基亚乙烯基聚合物，如聚（2 - （N，N-二甲基氨基）亚苯基亚乙烯基）。聚合物也可以通过用碱金属醇盐处理二氯甲基二甲基氨基苯盐酸盐衍生物直接制备。

9. 发明授权

US07578859B2 Poly (3,4-alkylenedioxythiophene)-based capacitors using ionic liquids as supporting electrolytes 有权
标题翻译：使用离子液体作为支持电解质的聚（3,4-亚烷基二氧噻吩）基电容器
公开(公告)号：US07578859B2
公开(公告)日：2009-08-25
申请号：US11169255
申请日：2005-06-22
申请人： John R. Reynolds , Kyukwan Zong , John D. Stenger-Smith , Nicole Anderson , Cynthia K. Webber , Andrew P. Chafin
发明人： John R. Reynolds , Kyukwan Zong , John D. Stenger-Smith , Nicole Anderson , Cynthia K. Webber , Andrew P. Chafin
IPC分类号： H01M4/82 , H01M6/00 , H01M4/00
CPC分类号： H01M4/60 , H01G11/56 , H01M4/606 , H01M10/0568 , H01M2300/0045 , H01M2300/0085 , Y02E60/13 , Y10T29/49108 , Y10T29/49115
摘要： A supercapacitor comprising a poly(3,4-ethylendioxythiophene) (PEDOT) and poly(3,4-propylenedioxythiophene) (PProDOT) as electrode couples for the capacitor and a pair of gel electrolyte layers disposed between the electrodes. The gel electrolytes are separated by a battery paper and are selected from a group consisting of a lithium salt and an organic electrolyte.
摘要翻译：包含聚（3,4-乙二氧噻吩）（PEDOT）和聚（3,4-亚丙二氧基噻吩）（PProDOT）作为电容器的电极的超级电容器和设置在电极之间的一对凝胶电解质层。凝胶电解质由电池纸分离，并且选自锂盐和有机电解质。

10. 发明授权

US06965509B2 Poly (3,4-alkylenedioxythiophene)-based capacitors using ionic liquids as supporting electrolytes 有权
标题翻译：使用离子液体作为支持电解质的聚（3,4-亚烷基二氧噻吩）基电容器
公开(公告)号：US06965509B2
公开(公告)日：2005-11-15
申请号：US10307585
申请日：2002-12-02
申请人： John R. Reynolds , Kyukwan Zong , John D. Stenger-Smith , Nicole Anderson , Cynthia K. Webber , Andrew P. Chafin
发明人： John R. Reynolds , Kyukwan Zong , John D. Stenger-Smith , Nicole Anderson , Cynthia K. Webber , Andrew P. Chafin
IPC分类号： H01G9/02 , H01G9/028 , H01G9/04 , H01G9/042 , H01M4/60 , H01M10/04 , H01M10/0568
CPC分类号： H01M10/0568 , H01G11/48 , H01G11/56 , H01M4/60 , H01M4/606 , H01M2300/0085 , Y02E60/13
摘要： A supercapacitor comprising a poly(3,4-ethylendioxythiophene) (PEDOT) and poly(3,4-propylenedioxythiophene) (PProDOT) as electrode couples for the capacitor and a pair of gel electrolyte layers disposed between the electrodes. The gel electrolytes are separated by a battery paper and are selected from a group consisting of a lithium salt and an organic electrolyte.
摘要翻译：包含聚（3,4-乙二氧噻吩）（PEDOT）和聚（3,4-亚丙二氧基噻吩）（PProDOT）作为电容器的电极的超级电容器和设置在电极之间的一对凝胶电解质层。凝胶电解质由电池纸分离，并且选自锂盐和有机电解质。

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