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    • 7. 发明授权
    • Melt-processible semicrystalline block copolyimides
    • 熔融加工半结晶嵌段共聚酰亚胺
    • US06444783B1
    • 2002-09-03
    • US09741941
    • 2000-12-21
    • John R. DoddJohn A. KreuzBrian C. Auman
    • John R. DoddJohn A. KreuzBrian C. Auman
    • C08L7908
    • C08G73/14C08G73/1014C08G73/1017C08G73/1042
    • Segmented, melt-processible, semicrystalline copolyimides are disclosed herein. These polymers are comprised of an amorphous or semicrystalline A segment (soft segment) and a semicrystalline B segment (hard segment), wherein the level of semicrystallinity in the A segment is less than that in the B segment. These copolyimides are semicrystalline and exhibit melting points in the range from about 330-395° C. In preferred embodiments, these copolyimides are end-capped and are crystallizable from their melts (i.e., they exhibit recoverable semicrystallinity). These copolyimides either inherently have suitably low melt visocosities to be melt-processible or can be made to have suitably low melt viscosities to be melt-processible by addition of certain additives. Tailoring of the melting points and glass transition temperatures of these copolyimides can be effected by changing their molecular architecture.
    • 本文公开了分段的,可熔融加工的半结晶共聚酰亚胺。 这些聚合物由无定形或半结晶的A段(软链段)和半结晶B区段(硬链段)组成,其中A区段的半结晶度小于B区段的半结晶度。 这些共聚酰亚胺是半结晶的,并且在约330-395℃的范围内显示出熔点。在优选的实施方案中,这些共聚酰亚胺被封端并且可以从它们的熔体中结晶(即它们表现出可回收的半结晶性)。 这些共聚酰亚胺本质上具有适当的低熔融粘稠性以使其可熔融加工,或者可以制成具有合适的低熔融粘度,以通过加入某些添加剂而可熔融加工。 这些共聚酰亚胺的熔点和玻璃化转变温度的调整可以通过改变它们的分子结构来实现。