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1. 发明授权

US06758046B1 Slush hydrogen production method and apparatus 失效
标题翻译：冷凝氢生产方法和装置
公开(公告)号：US06758046B1
公开(公告)日：2004-07-06
申请号：US07237952
申请日：1988-08-22
申请人： John A. Barclay , Steven R. Jaeger , Peter J. Claybaker , Carl B. Zimm , Steven F. Kral
发明人： John A. Barclay , Steven R. Jaeger , Peter J. Claybaker , Carl B. Zimm , Steven F. Kral
IPC分类号： F25B2100
CPC分类号： C01B3/00 , F25B21/00 , F25B2321/0021 , F25C1/142 , Y02B30/66 , Y02P20/124 , Y10S62/914
摘要： A slush hydrogen production device (10) utilizes a hydrogen slushifier magnetic refrigerator (30) having a wheel (50) of material exhibiting the magnetocaloric effect. The wheel is rotated through a magnetic field of varying intensity around the circumference of a wheel housing (36) created by the windings of superconductive magnets (56). The material of the wheel (50) follows a magnetic Carnot cycle as the wheel rotates (36) through regions of low temperature heat transfer and high temperature heat transfer. Liquid hydrogen is supplied to the regions of low and high temperature heat transfer through inlet pipes (39 and 42). Gaseous hydrogen is produced in the high temperature heat transfer region and vented away by an outlet pipe (48). Solid hydrogen is produced in the low temperature heat transfer region by direct solidification upon the magnetic wheel (50); and is removed by scrapers (76) and deposited in a compartment (26) where it mixes with liquid hydrogen to form slush hydrogen. A second magnetic refrigerator (108) may be used to keep its magnets and the magnets of the hydrogen slushifier magnetic refrigerator (30) at a temperature region suitable to maintain superconductivity. The slush hydrogen production device (10) may be part of a larger operating system that includes a liquid hydrogen storage tank (146), a slush hydrogen storage tank (136), a slush conditioner (148) and appropriate connective plumbing.
摘要翻译：冷凝氢制造装置（10）利用具有表现出磁热效应的材料的轮（50）的氢冷却剂磁性制冷机（30）。车轮通过由超导磁体（56）的绕组产生的轮壳体（36）的圆周周围的不同强度的磁场旋转。车轮（50）的材料随着车轮通过低温传热和高温热传递区域旋转（36）而跟随磁卡诺循环。液体氢气通过入口管道（39和42）供应到低温和高温热传递区域。在高温传热区域产生气态氢气，并通过出口管（48）排出。通过在磁轮（50）上直接凝固，在低温传热区域产生固体氢。并通过刮板（76）除去并沉积在隔室（26）中，在该隔室（26）中与液态氢混合形成冷凝氢。可以使用第二磁性制冷器（108）将其磁性体和氢冷却剂磁性制冷器（30）的磁体保持在适于保持超导性的温度区域。冷冻氢气生产装置（10）可以是更大的操作系统的一部分，其包括液体储氢罐（146），汲取氢气储存箱（136），冷却器（148）和适当的连接管道。

2. 发明授权

US4702090A Magnetic refrigeration apparatus with conductive heat transfer 失效
标题翻译：具有导电传热的磁性制冷装置
公开(公告)号：US4702090A
公开(公告)日：1987-10-27
申请号：US922746
申请日：1986-10-24
申请人： John A. Barclay , Walter F. Stewart , F. Coyne Prenger , Carl B. Zimm , John P. Parsons
发明人： John A. Barclay , Walter F. Stewart , F. Coyne Prenger , Carl B. Zimm , John P. Parsons
IPC分类号： F25B21/00 , F25B21/02
CPC分类号： F25B21/00 , F25B2321/0021 , Y02B30/66
摘要： A magnetic refrigerator has a rotating magnetic wheel which includes a stack of spaced rings of magnetic material. Heat transfer plates of a high temperature heat extractor are interleaved with the magnetic rings and extend to a solid heat transfer conduit which leads to a high temperature terminal. Superconducting magnet coils are mounted to provide a magnetic field through the magnetic wheel at the position of the high temperature heat transfer plates. Low temperature extractor heat transfer plates are positioned outside of the magnetic field and interleave with the rings of the magnetic wheel to transfer heat thereto which is conducted from a low temperature terminal through a solid conduit. As the magnetic wheel is rotated, heat is drawn from a load and conducted through the solid material of the low temperature heat extractor to the magnetic wheel, is released when the material of the wheel is subjected to the magnetic field and transferred to the high temperature heat transfer plates, and is then conducted through the solid material of the heat transfer conduit to the high temperature terminal. Helium gas is sealed in the space surrounding the rotating magnetic wheel to transfer heat between the rings of the wheel and the heat transfer plates. Substantially all heat transfer in the magnetic refrigerator is thus provided by conduction through a solid, allowing start-up of the refrigerator without an initial charge of liquid helium to cool the refrigerator to cryogenic operating temperatures.
摘要翻译：磁性冰箱具有旋转的磁轮，其包括一叠间隔开的磁性材料环。高温取出器的传热板与磁环交错并延伸到固体传热管道，导热管导致高温端子。安装超导磁体线圈以在高温传热板的位置处通过磁轮提供磁场。低温提取器传热板位于磁场外部并与磁轮的环交错，以将热量从低温端子传导通过固体导管传递到其上。当磁轮旋转时，热量从负载中抽出，并通过低温散热器的固体材料传导到磁轮，当车轮的材料经受磁场并转移到高温时释放传热板，然后通过传热导管的固体材料传导到高温端子。氦气密封在旋转的磁轮周围的空间中，以在轮的环和传热板之间传递热量。因此，磁性冰箱中的所有传热基本上都是通过固体传导而提供的，允许启动冰箱，而不用初始充入液氦，将冰箱冷却至低温操作温度。

3. 发明授权

US5182914A Rotary dipole active magnetic regenerative refrigerator 失效
标题翻译：旋转偶极有源磁再生式冰箱
公开(公告)号：US5182914A
公开(公告)日：1993-02-02
申请号：US493339
申请日：1990-03-14
申请人： John A. Barclay , Joseph A. Waynert , Anthony J. DeGregoria , Joseph W. Johnson , Peter J. Claybaker
发明人： John A. Barclay , Joseph A. Waynert , Anthony J. DeGregoria , Joseph W. Johnson , Peter J. Claybaker
IPC分类号： F25B21/00 , H01F1/01
CPC分类号： F25B21/00 , F25B2321/0021 , H01F1/015 , Y02B30/66 , Y10S505/889 , Y10S505/891 , Y10S505/892 , Y10S505/894 , Y10S505/895 , Y10S505/896 , Y10S505/897 , Y10S505/898 , Y10S505/899
摘要： The rotary dipole active magnetic regenerative refrigerator (10) of the present invention comprises a stationary first regenerative magnetic bed (12) positioned within a stationary first inner dipole magnet (14), a stationary second regenerative magnetic material bed (16) positioned within a stationary second inner dipole magnet (18), an outer dipole magnet (20) that rotates on a longitudinal axis and encloses the inner dipole magnets (14, 18), a cold heat exchanger (22), hot heat exchangers (24, 26), a fluid displacer (28), and connective plumbing through which a heat transfer fluid is conveyed. The first and second regenerative magnetic beds (12, 16) are magnetized and demagnetized as the vector sums of the magnetic fields of the inner dipoles magnets (14, 18) and the outer dipole magnet (20) are added together upon rotation of the outer dipole magnet (20), such magnetization and demagnetization causing a correlative increase and decrease in the temperature of the magnetic material beds (12, 16) by the magnetocaloric effect. Upon magnetization of any particular magnetic material bed (12 or 16), fluid flow is forced therethrough in the connective plumbing by the fluid displacer (28) in the direction from the cold heat exchanger (22) to one of the hot heat exchangers (24,26). Upon demagnetization of any particular magnetic material bed (12 or 16), fluid flow is reversed by the fluid displacer (28) and is forced in the direction from one of the hot heat exchangers (24, 26) to the cold heat exchanger (22).
摘要翻译：本发明的旋转偶极子活性磁再生式制冷机（10）包括位于固定的第一内部偶极子磁体（14）内的固定的第一再生磁性床（12），固定的第二再生磁性材料床（16）第二内部偶极子磁体（18），在纵向轴线上旋转并包围内部偶极子磁体（14,18）的外部偶极子磁体（20），冷热交换器（22），热交换器（24,26）流体置换器（28），以及输送传热流体的连接管道。当外部偶极子磁体（14,18）和外部偶极子磁体（20）的旋转之后，第一和第二再生磁性层（12,16）被磁化和去磁，偶极磁体（20），这种磁化和退磁通过磁热效应引起磁性材料床（12,16）的温度的相关增加和降低。在任何特定的磁性材料床（12或16）的磁化时，流体排出器（28）沿着从冷热交换器（22）到热交换器（24）的热交换器，26）。在任何特定的磁性材料床（12或16）退磁时，流体流动由流体置换器（28）反向，并且被迫从热热交换器（24,26）之一到冷热交换器（22）的方向）。

4. 发明授权

US4956976A Magnetic refrigeration apparatus for He II production 失效
标题翻译： He II制作用磁制冷装置
公开(公告)号：US4956976A
公开(公告)日：1990-09-18
申请号：US469186
申请日：1990-01-24
申请人： Stephen F. Kral , John A. Barclay , Peter Claybaker , Steven R. Jaeger
发明人： Stephen F. Kral , John A. Barclay , Peter Claybaker , Steven R. Jaeger
IPC分类号： F25B21/00
CPC分类号： F25B21/00 , F25B2321/0021 , Y02B30/66
摘要： A magnetic refrigeration apparatus (10) is modular in design, so that housing modules (14) are alternately stacked with superconducting magnet pairs (24). Each module (14) has a wheel (16) that is rotated through the module (14), the wheel (16) having cutout regions (18) into which elements (20) of magnetic material are inserted. Each cutout region has two elements (20) separated by a wave spring, the wave spring biasing the elements (20) against the housing module (14) so that the elements (14) are in slidable contact with the module (14) upon rotation. In operation, the wheel (16) carries the elements (20) cyclically between high and low magnetic field zones. In low field regions the elements (20) are cooled by the magnetocaloric effect and heat exchangers absorb heat from either a stagnant subcooled superfluid helium bath or a forced-flow subcooled superfluid helium stream. In high field regions the elements (20) are heated by the magnetocaloric effect and a force-flow stream of liquid helium passes through the high temperature heat exchangers absorbing heat from the magnetic refrigeration apparatus (10).
摘要翻译：磁性制冷装置（10）在设计中是模块化的，使得壳体模块（14）交替地堆叠有超导磁体对（24）。每个模块（14）具有通过模块（14）旋转的轮（16），轮（16）具有切断区域（18），磁性材料元件（20）插入其中。每个切口区域具有由波形弹簧分开的两个元件（20），波形弹簧将元件（20）偏压抵靠壳体模块（14），使得元件（14）在旋转时可与模块（14）滑动接触。在操作中，轮（16）在高磁场区和低磁场区之间循环地承载元件（20）。在低场区域中，元件（20）被磁热效应冷却，热交换器从停滞的过冷超流体氦池或强制流过冷的超流体氦气流吸收热量。在高场区域中，元件（20）被磁热效应加热，液氦的力流通过吸收来自磁致冷装置（10）的热量的高温热交换器。

5. 发明申请

US20130183705A1 CONVERSION OF ALGAE TO LIQUID METHANE, AND ASSOCIATED SYSTEMS AND METHODS 审中-公开
标题翻译：液态甲烷的转化及相关系统及方法
公开(公告)号：US20130183705A1
公开(公告)日：2013-07-18
申请号：US13584662
申请日：2012-08-13
申请人： John A. Barclay , David Haberman
发明人： John A. Barclay , David Haberman
IPC分类号： C12P5/02
CPC分类号： C12P5/023 , A01G33/00 , C12M21/02 , C12M21/04 , C12M23/58 , C12N1/12 , Y02A40/88 , Y02E50/343
摘要： Systems and methods for converting algae to liquid methane are disclosed. The system in accordance with a particular embodiment includes an algae cultivator, an anaerobic digester operatively coupled to the algae cultivator to receive algae and produce biogas, and a biogas converter coupled to the anaerobic digester to receive the biogas and produce liquefied methane and thermal energy, at least a portion of the thermal energy resulting from a methane liquefaction process. The system can further include a thermal path between the biogas converter and at least one of the algae cultivator and the anaerobic digester. The system can still further include a controller coupled to the biogas converter and at least one of the algae cultivator and the anaerobic digester. The controller can be programmed with instructions that, when executed (e.g., based on measured variables of the system), direct the portion of thermal energy between the biogas converter and the algae cultivator and/or anaerobic digester.
摘要翻译：公开了将藻类转化为液体甲烷的系统和方法。根据特定实施例的系统包括藻类耕耘机，可操作地耦合到藻类耕耘机以接收藻类并产生生物气体的厌氧消化器，以及耦合到厌氧消化器以接收沼气并产生液化甲烷和热能的生物气体转化器，由甲烷液化过程产生的至少一部分热能。该系统还可以包括生物气体转化器和至少一个藻类培养器和厌氧消化器之间的热路径。该系统还可以包括耦合到沼气转化器和至少一个藻类培养器和厌氧消化器的控制器。控制器可以用指令进行编程，当执行时（例如，基于系统的测量变量），指导生物气体转换器和藻类培养器和/或厌氧消化器之间的热能的一部分。

6. 发明授权

US07744677B2 Systems and methods for processing methane and other gases 有权
标题翻译：用于处理甲烷和其他气体的系统和方法
公开(公告)号：US07744677B2
公开(公告)日：2010-06-29
申请号：US11754135
申请日：2007-05-25
申请人： John A. Barclay , Michael A. Barclay
发明人： John A. Barclay , Michael A. Barclay
IPC分类号： B01D53/04
CPC分类号： B01D53/0462 , B01D2253/102 , B01D2253/104 , B01D2253/108 , B01D2256/24 , B01D2257/504 , B01D2258/05 , B01D2259/403 , B01D2259/416 , Y02C10/04 , Y02C10/08
摘要： Systems and methods for processing methane and other gases are disclosed. A representative method in accordance with one embodiment includes directing a first portion of a gas stream through a first adsorbent while exchanging heat between a second adsorbent and a third adsorbent. The method can further include directing a second portion of the gas stream through the third adsorbent while exchanging heat between the first and second adsorbents. The method can still further include directing a third portion of the gas stream through the second adsorbent while exchanging heat between the first and third adsorbents. In further particular aspects, the adsorbent can be used to remove carbon dioxide from a flow of methane. In other particular aspects, a heat exchange fluid that is not in direct contact with the adsorbents is used to transfer heat among the adsorbents.
摘要翻译：公开了用于处理甲烷和其它气体的系统和方法。根据一个实施方案的代表性方法包括将气流的第一部分引导通过第一吸附剂，同时在第二吸附剂和第三吸附剂之间交换热量。该方法还可以包括将气流的第二部分引导通过第三吸附剂，同时在第一和第二吸附剂之间交换热量。该方法还可以包括在第一和第三吸附剂之间交换热量的同时引导气流的第三部分通过第二吸附剂。在另外的特定方面，吸附剂可用于从甲烷流中除去二氧化碳。在其它特定方面，不与吸附剂直接接触的热交换流体用于在吸附剂之间传递热量。

7. 发明申请

US20120308989A1 CONVERSION OF AQUATIC PLANTS TO LIQUID METHANE, AND ASSOCIATED SYSTEMS AND METHODS 审中-公开
标题翻译：水生植物转化为液体甲烷，以及相关系统和方法
公开(公告)号：US20120308989A1
公开(公告)日：2012-12-06
申请号：US13344154
申请日：2012-01-05
申请人： John A. Barclay , David Haberman
发明人： John A. Barclay , David Haberman
IPC分类号： C12P5/02 , C12M1/38 , C12Q3/00 , C12M1/107 , C12M1/36
CPC分类号： A01G33/00 , C12M21/04 , C12M43/08 , C12N1/12 , C12P5/023 , Y02E50/343 , Y02P20/129
摘要： Systems and methods for converting aquatic plants to liquid methane are disclosed. A representative system includes an aquatic plant cultivator, an anaerobic digester operatively coupled to the aquatic plant cultivator to receive aquatic plants and produce biogas, and a biogas converter coupled to the anaerobic digester to receive the biogas and produce liquefied methane and thermal energy, at least a portion of the thermal energy resulting from a methane liquefaction process. The system can further include a thermal path between the biogas converter and at least one of the aquatic plant cultivator and the anaerobic digester. A controller can be coupled to the biogas converter and the aquatic plant cultivator and/or the anaerobic digester. The controller can be programmed with instructions that, when executed (e.g., based on measured variables of the system), direct the portion of thermal energy between the biogas converter and the aquatic plant cultivator and/or anaerobic digester.
摘要翻译：公开了将水生植物转化为液态甲烷的系统和方法。一个代表性的系统包括一个水生植物培养器，一个可操作地连接到水生植物耕作机以接收水生植物并生产沼气的厌氧消化器，以及一个与厌氧消化器相连接以接收沼气并产生液化甲烷和热能的生物气转化器，至少由甲烷液化过程产生的热能的一部分。该系统还可以包括生物气体转化器与至少一个水生植物培养器和厌氧消化器之间的热路径。控制器可以耦合到沼气转化器和水生植物培养器和/或厌氧消化器。控制器可以用指令编程，当执行（例如，基于系统的测量变量）时，将生物气体转化器和水生植物培养器和/或厌氧消化器之间的热能的一部分引导。

8. 发明申请

US20120152116A1 ROTARY FLUID PROCESSING SYSTEMS AND ASSOCIATED METHODS 审中-公开
标题翻译：旋转流体加工系统及相关方法
公开(公告)号：US20120152116A1
公开(公告)日：2012-06-21
申请号：US12970865
申请日：2010-12-16
申请人： John A. Barclay , Tadeusz Szymanski , Lenard J. Stoltman , Kathryn Oseen-Senda , Hunter A. Chumbley
发明人： John A. Barclay , Tadeusz Szymanski , Lenard J. Stoltman , Kathryn Oseen-Senda , Hunter A. Chumbley
IPC分类号： B01D53/08
CPC分类号： B01D53/06 , B01D53/0438 , B01D2253/108 , B01D2256/245 , B01D2257/304 , B01D2257/504 , B01D2257/80 , B01D2259/40088 , B01D2259/4009 , B01D2259/65 , C07C7/12 , F28F9/26 , Y02C10/08 , Y02C20/20 , Y10T29/4935
摘要： Rotary fluid processing systems and associated methods are disclosed. A purification system in accordance with the particular embodiment includes a rotatable adsorbent-containing heat/mass transfer element that is generally symmetric about a rotation axis, and includes multiple radial flow paths oriented transverse to the rotation axis and multiple axial flow paths oriented transverse to the radial flow paths. The axial flow paths and radial flow paths are in thermal communication with each other, and are generally isolated from fluid communication with each other at the heat transfer element. Particular embodiments can further include a housing arrangement having multiple manifolds with individual manifolds having an entry port and an exit port, and with individual manifolds having different circumferential locations relative to the rotation axis. Still further embodiments can include a seal arrangement positioned between the heat transfer element and the housing arrangement to expose the radial flow paths, but not the axial flow paths, to the entry and exit ports of one of the manifolds, and expose the axial flow paths, but not the radial flow paths, to the entry and exit ports of another of the manifolds.
摘要翻译：公开了旋转流体处理系统和相关方法。根据特定实施例的净化系统包括可旋转的含吸附剂的热传质元件，其大致对称于旋转轴线，并且包括横向于旋转轴线的多个径向流动路径和横向于该旋转轴线的多个轴向流动路径径向流动路径。轴向流动路径和径向流动路径彼此热连通，并且通常与传热元件处于彼此流体连通的隔离状态。具体实施例还可以包括具有多个歧管的壳体装置，其中单个歧管具有入口和出口，并且具有相对于旋转轴线具有不同圆周位置的各个歧管。另外的实施例可以包括定位在传热元件和壳体装置之间的密封装置，以将歧管中的一个的入口和出口露出径向流动路径而不是轴向流动路径，并且暴露轴向流动路径而不是径向流动路径，而不是另一个歧管的入口和出口。

9. 发明授权

US4459811A Magnetic refrigeration apparatus and method 失效
标题翻译：磁性制冷装置及方法
公开(公告)号：US4459811A
公开(公告)日：1984-07-17
申请号：US479596
申请日：1983-03-28
申请人： John A. Barclay , William C. Overton, Jr. , Walter F. Stewart
发明人： John A. Barclay , William C. Overton, Jr. , Walter F. Stewart
IPC分类号： F25B21/00 , F25B21/02
CPC分类号： F25B21/00 , F25B2321/0021 , Y02B30/66
摘要： The disclosure relates to refrigeration through magnetizing and demagnitizing a body by rotating it within a magnetic field. Internal and external heat exchange fluids and in one embodiment, a regenerator, are used.
摘要翻译：本公开涉及通过使磁体在磁场内旋转来磁化并使身体退磁的制冷。内部和外部热交换流体，并且在一个实施例中，使用再生器。

10. 发明授权

US4332135A Active magnetic regenerator 失效
标题翻译：主动式蓄电器
公开(公告)号：US4332135A
公开(公告)日：1982-06-01
申请号：US228836
申请日：1981-01-27
申请人： John A. Barclay , William A. Steyert
发明人： John A. Barclay , William A. Steyert
IPC分类号： F25B21/00 , F25B21/02
CPC分类号： F25B21/00 , F25B2321/0021 , Y02B30/66 , Y10S505/889 , Y10S505/891 , Y10S505/894
摘要： The disclosure is directed to an active magnetic regenerator apparatus and method. Brayton, Stirling, Ericsson, and Carnot cycles and the like may be utilized in an active magnetic regenerator to provide efficient refrigeration over relatively large temperature ranges.
摘要翻译：本发明涉及一种主动式蓄热装置和方法。 Brayton，Stirling，Ericsson和Carnot循环等可用于主动式蓄电器中，以在相对较大的温度范围内提供有效的制冷。

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