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1. 发明申请

US20070249484A1 Process for the Photoactivation and use of a Catalyst by an Inverted Two-Stage Procedure 审中-公开
标题翻译：通过反相两阶段过程激活和使用催化剂的方法
公开(公告)号：US20070249484A1
公开(公告)日：2007-10-25
申请号：US11631994
申请日：2005-07-11
申请人： Johannes Benkhoff , Tunja Jung , Andreas Valet , Kurt Dietliker , Eugene Sitzmann
发明人： Johannes Benkhoff , Tunja Jung , Andreas Valet , Kurt Dietliker , Eugene Sitzmann
IPC分类号： B01J37/34 , B01J31/02 , C07D311/00 , C07D487/00 , B01J35/00
CPC分类号： B01J31/0239 , B01J31/0205 , B01J31/0217 , B01J31/0234 , B01J31/0268 , B01J31/06 , C08G18/10 , C08G18/2018 , C08G18/2063 , C08G18/4812 , C08G18/62 , C08G18/792 , C08G59/4064 , C08G59/686 , C08G2101/0008 , C08G2101/0083 , C09D11/101 , C09D163/00 , C09D175/04 , C09J163/00 , C09J175/04 , G03F7/0045 , C08G18/48
摘要： The invention pertains to a process for the application of a specific photolatent catalyst (a) wherein a composition of matter, comprising said catalyst, is subjected to irradiation before being further processed.
摘要翻译：本发明涉及应用特定光催化剂催化剂（a）的方法，其中包含所述催化剂的物质组合物在进一步加工之前经受照射。

2. 发明申请

US20100022676A1 PHOTOCURABLE COMPOSITIONS COMPRISING A PHOTOINITIATOR OF THE PHENYLGLYOXYLATE TYPE 审中-公开
标题翻译：含有苯甲酸酯类型的光敏剂的可光性组合物
公开(公告)号：US20100022676A1
公开(公告)日：2010-01-28
申请号：US12442779
申请日：2007-09-24
申请人： Jonathan Rogers , Johannes Benkhoff , Karin Powell , Tunja Jung , Kurt Dietliker , Pascal Hayoz , Jean-Luc Birbaum , Thomas Vogel , Rinaldo Hüsler
发明人： Jonathan Rogers , Johannes Benkhoff , Karin Powell , Tunja Jung , Kurt Dietliker , Pascal Hayoz , Jean-Luc Birbaum , Thomas Vogel , Rinaldo Hüsler
IPC分类号： C08F2/46 , C08J7/18 , C07C69/67
CPC分类号： G03F7/031 , C07C59/90 , C07C69/738 , C07C2601/10 , C07C2601/14 , C08F2/50 , G03F7/0045 , G03F7/038
摘要： The invention provides a uv-curable colored composition, comprising (a) at least one selected ethylenically unsaturated photopolymerizable compound; (b) at least one selected curing agent; and (c) at least one selected colorant.
摘要翻译：本发明提供了一种紫外线固化着色组合物，其包含（a）至少一种选择的烯属不饱和光聚合化合物; （b）至少一种选择的固化剂; 和（c）至少一种选择的着色剂。

3. 发明授权

US07723399B2 N-substituted imides as polymerization initiators 有权
标题翻译： N-取代酰亚胺作为聚合引发剂
公开(公告)号：US07723399B2
公开(公告)日：2010-05-25
申请号：US11666887
申请日：2005-10-31
申请人： Peter Nesvadba , Johannes Benkhoff , Lucienne Bugnon , Karin Powell , Tunja Jung
发明人： Peter Nesvadba , Johannes Benkhoff , Lucienne Bugnon , Karin Powell , Tunja Jung
IPC分类号： C08F299/00 , C07D221/04 , C07D209/56 , C07D209/48
CPC分类号： C07D207/404 , B33Y70/00 , C07D207/46 , C07D209/48 , C07D221/14 , C08F4/00
摘要： The invention relates to novel N-substituted imides and polymerizable compositions comprising these N-substituted imides. The invention further relates to the use of N-substituted imides as polymerization initiators. The imides are compounds of the formula (I) and (II) wherein n is 1 or 2; m is 1 or 2; R1 and R2 are each, independently of one another, hydrogen, C1-C18alkyl, C1-C-18alkenyl C6-C14aryl, aralkyl, C5-C12cycloalkyl, each of which may be substituted by halogen, C1-C4-alkyl, hydroxy, C1-C6alkoxy, carbonyl, C1-C6alkoxycarbonyl; or R1 and R2 together with the adjacent —CO—N—CO— group may form a monocyclic, bicyclic or polycyclic ring, said ring having up to 50 non hydrogen atoms and wherein said ring may contain the structural element (formula III) more than once; R3 if n is 1, is C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, OR10 or SR11, NR12R13; wherein R3 if n is 2, is C2-C12alkylene, C6-C14arylene, xylylene R4 and R5, correspond to R1 and R2; R6 if n is 1, is hydrogen, C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, NR14R15; wherein R6 if n is 2, is C2-C12alkylene, C6-C14arylene, xylylene; R7 is hydrogen, C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, each of which may be substituted by halogen, C1-C4-alkyl, hydroxy, C1-C6alkoxy, carbonyl, C1-C6alkoxy-carbonyl; or R7 and R14 or R7 and R15 form together with the N-atom attached to R7 a 5-6 membered ring, optionally interrupted by —NH—, —N(C1-C8alkyl)-, —O— and/or S-atoms.
摘要翻译：本发明涉及新型的N-取代的酰亚胺和包含这些N-取代的酰亚胺的可聚合组合物。本发明还涉及N-取代的酰亚胺作为聚合引发剂的用途。酰亚胺是式（I）和（II）的化合物，其中n为1或2; m为1或2; R 1和R 2各自独立地为氢，C 1 -C 18烷基，C 1 -C 18烯基C 6 -C 14芳基，芳烷基，C 5 -C 12环烷基，其各自可被卤素，C 1 -C 4 - 烷基，羟基，C 1 -C 1-6烷氧基，羰基，C 1 -C 6烷氧基羰基; 或R 1和R 2与相邻的-CO-N-CO-基团一起可以形成单环，双环或多环，所述环具有至多50个非氢原子，并且其中所述环可含有结构单元（式III）一旦; 如果n为1，R 3为C 1 -C 18烷基，C 6 -C 14芳基，芳烷基，C 5 -C 12环烷基，OR 10或SR 11，NR 12 R 13; 其中如果n为2，R 3为C 2 -C 12亚烷基，C 6 -C 14亚芳基，亚二甲苯基R4和R 5对应于R 1和R 2; 如果n为1，R 6为氢，C 1 -C 18烷基，C 6 -C 14芳基，芳烷基，C 5 -C 12环烷基，NR 14 R 15; 其中如果n为2，R 6为C 2 -C 12亚烷基，C 6 -C 14亚芳基，亚二甲苯基; R 7是氢，C 1 -C 18烷基，C 6 -C 14芳基，芳烷基，C 5 -C 12环烷基，其各自可被卤素，C 1 -C 4 - 烷基，羟基，C 1 -C 6烷氧基，羰基，C 1 -C 6烷氧基 - 羰基取代; 或R 7和R 14或R 7和R 15与连接至R 7的N-原子一起形成5-6元环，任选被-NH-，-N（C 1 -C 8烷基） - ， - 和 - 或S-原子。

4. 发明申请

US20080132600A1 N-Substituted Imides As Polymerization Initiators 有权
公开(公告)号：US20080132600A1
公开(公告)日：2008-06-05
申请号：US11666887
申请日：2005-10-31
申请人： Peter Nesvadba , Johannes Benkhoff , Lucienne Bugnon , Karin Powell , Tunja Jung
发明人： Peter Nesvadba , Johannes Benkhoff , Lucienne Bugnon , Karin Powell , Tunja Jung
IPC分类号： C08L79/08 , C07D209/48 , C07D221/06 , C07D207/46 , C07D209/56
CPC分类号： C07D207/404 , B33Y70/00 , C07D207/46 , C07D209/48 , C07D221/14 , C08F4/00
摘要： The invention relates to novel N-substituted imides and polymerizable compositions comprising these N-substituted imides. The invention further relates to the use of N-substituted imides as polymerization initiators. The imides are compounds of the formula (I) and (II) wherein n is 1 or 2; m is 1 or 2; R1 and R2 are each, independently of one another, hydrogen, C1-C18alkyl, C1-C18alkenyl C6-C14aryl, aralkyl, C5-C12cycloalkyl, each of which may be substituted by halogen, C1-C4-alkyl, hydroxy, C1-C6alkoxy, carbonyl, C1-C6alkoxycarbonyl; or R1 and R2 together with the adjacent —CO—N—CO— group may form a monocyclic, bicyclic or polycyclic ring, said ring having up to 50 non hydrogen atoms and wherein said ring may contain the structural element (formula III) more than once; R3 if n is 1, is C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, OR10 or SR11, NR12R13; wherein R3 if n is 2, is C2-C12alkylene, C6-C14arylene, xylylene R4 and R5, correspond to R1 and R2; R6 if n is 1, is hydrogen, C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, NR14R15; wherein R6 if n is 2, is C2-C12alkylene, C6-C14arylene, xylylene; R7 is hydrogen, C1-C18alkyl, C6-C14aryl, aralkyl, C5-C12cycloalkyl, each of which may be substituted by halogen, C1-C4-alkyl, hydroxy, C1-C6alkoxy, carbonyl, C1-C6alkoxy-carbonyl; or R7 and R14 or R7 and R15 form together with the N-atom attached to R7 a 5-6 membered ring, optionally interrupted by —NH—, —N(C1-C8alkyl)-, —O- and/or S-atoms.

5. 发明授权

US07727702B2 Method of coloring a coating composition 失效
标题翻译：着色涂料组合物的方法
公开(公告)号：US07727702B2
公开(公告)日：2010-06-01
申请号：US11547153
申请日：2005-03-29
申请人： Johannes Benkhoff , Karin Powell
发明人： Johannes Benkhoff , Karin Powell
IPC分类号： G03F7/00 , G03F7/004 , G03F7/20
CPC分类号： G03F7/105 , B41M5/30 , B41M5/323 , B41M5/327 , B41M2205/04 , C09D5/032 , C09D7/41 , C09D11/50 , G03C1/732 , Y10S430/106 , Y10S430/146
摘要： A method is provided for irreversibly coloring a coating composition containing a color former comprising the steps of a) providing a coating composition that contains an UV curable resin, a thermosetting resin or an alkyd resin with the proviso that the coating composition contains no developer nor any additive which may function as developer; b) mixing the coating composition with the color former whereby no color is formed; c) applying the colorless composition obtained in step b) to a substrate; d) in case of a thermosetting resin curing the resin between 100 and 300° C., preferably between 100 and 150° C., whereby no color is formed, in case of alkyd resin drying of the resin at room temperature, whereby no color is formed; e) exposure to UV or high energy radiation below 400 nm whereby the color is formed.
摘要翻译：提供了一种用于不可逆地着色含有着色剂的涂料组合物的方法，包括以下步骤：a）提供含有UV可固化树脂，热固性树脂或醇酸树脂的涂料组合物，条件是涂料组合物不含显影剂，也不含任何可用作显影剂的添加剂; b）将涂料组合物与成色剂混合，不形成颜色; c）将步骤b）中得到的无色组合物加到基材上; d）在热固性树脂固化树脂100至300℃之间，优选在100至150℃之间的情况下，在室温下树脂的醇酸树脂干燥的情况下，不会形成颜色，因此没有颜色形成了; e）暴露于低于400nm的UV或高能量辐射，从而形成颜色。

6. 发明申请

US20100119858A1 TINTED CLEAR COATINGS FOR WOOD 审中-公开
标题翻译： TODTED CLEAR COATINGS FOR WOOD
公开(公告)号：US20100119858A1
公开(公告)日：2010-05-13
申请号：US12594348
申请日：2008-04-16
申请人： Johannes Benkhoff , Wolfgang Peter , Christian Marcus Schaller
发明人： Johannes Benkhoff , Wolfgang Peter , Christian Marcus Schaller
IPC分类号： B32B21/04 , B05D3/00
CPC分类号： C09D15/00 , B05D3/0254 , B05D7/06 , B05D7/53 , B05D7/57 , Y10T428/31989
摘要： The present invention pertains to tinted clear coating for wood comprising: a) an un-tinted clear coating layer and b) at least one tinted clear coating layer and to a process for obtaining such tinted clear coating for wood.
摘要翻译：本发明涉及用于木材的有色透明涂层，其包括：a）未着色的透明涂层和b）至少一个有色透明涂层和用于获得这种有色透明涂层的木材的方法。

7. 发明申请

US20070066724A1 Bisazoquinolone pigments, processes for their preparation and their use 审中-公开
公开(公告)号：US20070066724A1
公开(公告)日：2007-03-22
申请号：US10557224
申请日：2004-06-04
申请人： Johannes Benkhoff , Max Hugin , Thomas Eichenberger
发明人： Johannes Benkhoff , Max Hugin , Thomas Eichenberger
IPC分类号： C08K5/34 , C09D11/00 , C07D401/02
CPC分类号： C08K5/0041 , C08K5/3437 , C09B33/153
摘要： Bisazoquinolone pigments which, in one of the tautomeric forms thereof, correspond to formula (1) wherein W is the radical of an unsubstituted or substituted C6-C24aryl or the radical of an unsubstituted or substituted heteroaryl, Ar1 is unsubstituted or substituted C6-C24aryl or unsubstituted or substituted heteroaryl, Ar11 is unsubstituted or substituted C6-C24aryl or unsubstituted or substituted heteroaryl, R1 R1, R2, R10, R11, and R12 are each independently of the others hydrogen, C1-C6alkyl, halogen, cyano, CF3, nitro, NR3R4, COOR4, NR4COR3, COOX+, COR4, OR4, SR3, S02R3, S02NR3R4, S03-X+, or C6-C24aryl unsubstituted or mono- or poly-substituted by R5, R3 is C1-C6alkyl, or C6-C12aryl unsubstituted or mono- or polysubstituted by halogen, hydroxy, OR7, cyano, nitro, SR7, NR6R7, COOR7, CONR6R7, NR6COR7, NR6COOR7, COO—X+, COR4, OR4, S02R7, S02NR6R7, S03-X+ or by S03R7, R4 is hydrogen or has the same meanings as R3, R5 is hydrogen, C1-C4alkyl, halogen, nitro, NR7R8 or OR7, R6 is hydrogen or C1-C3alkyl, R7 and R8 are each independently of the other hydrogen, C1-C3alkyl, phenyl unsubstituted or mono- or poly-substituted by halogen, nitro, OR5 or by NR16R17, or benzyl unsubstituted or mono- or poly-substituted by halogen, nitro, OR5 or by NR16R17, and X+ is a cation H+, Li+, Na+, K+, Mg++1/2, Ca++1/2, Sr++1/2, Ba++1/2, Cu+, Cu++1/2, Zn++1/2, Mn++1/2, Al+++1/3 or [NR19R20R21R22]+ wherein R19, R20, R21 and R22 are each independently of the others hydrogen, C1-C6alkyl, phenyl unsubstituted or mono- or polysubstituted by C1-C6alkyl, halogen, nitro, OR5 or by NR16R17, or benzyl unsubstituted or mono- or poly-substituted by C1-C6alkyl, halogen, nitro, OR5 or by NR16R17, R16 and R17 are each independently of the other hydrogen or C1-C6alkyl, Z1, is —NH— or -0-, and Z2 is —NH or -0- are suitable for colouring high molecular weight material and are distinguished by the resulting colorations having good fastness properties.

8. 发明申请

US20090162307A1 Photolatent Systems 有权
标题翻译：照相系统
公开(公告)号：US20090162307A1
公开(公告)日：2009-06-25
申请号：US12084335
申请日：2006-10-30
申请人： Katharina Fritzsche , Walter Fischer , Johannes Benkhoff , Karin Powell , Dirk Simon
发明人： Katharina Fritzsche , Walter Fischer , Johannes Benkhoff , Karin Powell , Dirk Simon
IPC分类号： A61K8/35 , C07C49/258 , C07D249/06 , A61Q5/06 , C11D1/72 , A61K8/34 , A61Q5/02 , C08K5/05 , C08K5/06 , C09K3/00 , A61Q5/12 , A61Q15/00
CPC分类号： C07C49/84 , C07C49/825 , C07C49/83 , C07D209/48 , C07D249/20 , C08K5/134
摘要： The instant invention relates to new photolatent compounds of the formula I wherein R1 and R2 are each independently of the other C1-C10alkyl or C3-C8cycloalkyl, R3 is hydrogen or C1-C4alkyl, and wherein the photochemically cleaved group R4OH is selected from the group consisting of fragrances, UV absorbers, anti-microbials, anti-fogging agents and clarifiers; with the proviso that, when R1 and R2 are tert-butyl and R3 is hydrogen, R4 is not methyl or phenyl.
摘要翻译：本发明涉及新的式I化合物，其中R 1和R 2各自独立地为C 1 -C 10烷基或C 3 -C 8环烷基，R 3为氢或C 1 -C 4烷基，并且其中光化学裂解基团R 4 OH选自由香料，紫外线吸收剂，抗微生物剂，防雾剂和澄清剂组成; 条件是当R 1和R 2是叔丁基且R 3是氢时，R 4不是甲基或苯基。

9. 发明申请

US20060219134A1 Monoazoquinolone pigments, process for their preparation and their use 审中-公开
公开(公告)号：US20060219134A1
公开(公告)日：2006-10-05
申请号：US10549525
申请日：2004-03-15
申请人： Johannes Benkhoff , Olof Wallquist
发明人： Johannes Benkhoff , Olof Wallquist
IPC分类号： C09D11/00 , C09B27/00
CPC分类号： C08K5/0041 , C08K5/3437 , C09B29/0048 , C09B29/337
摘要： Monoazoquinolone pigments which, in one of their tautomeric forms, correspond to formula (1), wherein W is unsubstituted or substituted C6-C24aryl or unsubstituted or substituted heteroaryl or is a radical of formula (1a), wherein Ar2 is unsubstituted or substituted C6-C24aryl or unsubstituted or substituted heteroaryl, Ar1 is unsubstituted or substituted C6-C24aryl or unsubstituted or substituted heteroaryl, R, R1, and R2 are each independently of the others hydrogen, C1-C6alkyl, halogen, cyano, CF3, nitro, NR3R4, COOR4, NR4COR3, COO−X+, COR4, OR4, SR3, SO2R3, SO2NR3R4, SO3−X+, or C6-C24aryl which is unsubstituted or mono- or polysubstituted by R5, R3 is C1-C6alkyl, or C6-C12aryl which is unsubstituted or mono- or poly-substituted by halogen, hydroxy, OR7, cyano, nitro, SR7, NR6R7, COOR7, CONR6R7, NR6COR7, NR6COOR7, COO−X+, COR4, OR4, SO2R7, SO2NR6R7, SO3−X+ or by SO3R7, R4 is hydrogen or has the meanings of R3, R5 is hydrogen, C1-C4alkyl, halogen, nitro, NR7R8 or OR7, R6 is hydrogen or C1-C3alkyl, R7 and R8 are each independently of the other hydrogen; C1-C3alkyl; phenyl which is unsubstituted or mono- or poly-substituted by halogen, nitro, OR5, NR16R17; or benzyl which is unsubstituted or mono- or poly-substituted by halogen, nitro, OR5, NR16R17, and X+ is a cation H+, Li+, Na+, K+, Mg++1/2, Ca++1/2, Sr++1/2, Ba++1/2, Cu+, Cu++1/2, Zn++1/2, Mn++1/2, Al+++1/3 or [NR9R10R11R12]+, wherein R9, R10, R11 and R12 are each independently of the others hydrogen; C1-C6alkyl; phenyl which is unsubstituted or mono- or poly-substituted by C1-C6alkyl, halogen, nitro, OR5, NR16R17; or benzyl which is unsubstituted or mono- or poly-substituted by C1-C6alkyl, halogen, nitro,OR5, NR16R17, and R16 and R17 are each independently of the other hydrogen or C1-C6alkyl, are suitable for the colouring of high molecular weight material and are distinguished by good fastness properties of the resulting colourations.

10. 发明申请

US20050222397A1 Process for the preparation of 4-methyl-7-aminoquinolones 失效
标题翻译：制备4-甲基-7-氨基喹诺酮的方法
公开(公告)号：US20050222397A1
公开(公告)日：2005-10-06
申请号：US10498456
申请日：2002-12-03
申请人： Johannes Benkhoff , Bernd Lamatsch
发明人： Johannes Benkhoff , Bernd Lamatsch
IPC分类号： C07B61/00 , C07C211/52 , C07C235/80 , C07D215/38 , C09B29/42 , C07D215/36
CPC分类号： C07D215/38
摘要： The present invention relates to a process for the preparation of a compound of the general formula (1), which comprises converting a compound of the general formula (II), in an aprotic organic solvent in the presence of a catalytically active amount of a strong acid (catalyst) or of an agent that liberates a strong acid or of an ammonium salt of a strong acid, it also being possible for the catalyst to be part of the starting material/product, into a compound of formula I, wherein R5, R6 and R8 are each independently of the others a hydrogen atom, a nitro group, a sulfo group, a halogen atom, a pseudohalogen, a group COOR1 or CONHR2 or a C1-8 alkyl, C1-8 alkoxy or aryloxy radical, an amide group, a thioalkyl or thioaryl radical, an alkyl- or aryl-sulfonyl radical, an alkyl- or aryl-sulfinyl radical, a trifluoromethyl group or a phosphono group, R1 and R2 being a hydrogen atom or a C1-8 alkyl radical or an aryl or aralkyl radical, R10 is a group —C(O)CH2C(O)CH3 and R11 is a hydrogen atom or an acyl radical, or R10 and R11 are a group —C(O)CH2C(O)CH3. The process according to the invention is simple to perform and results in products of high chemical purity and high isomeric purity in a high yield.
摘要翻译：本发明涉及制备通式（1）化合物的方法，该方法包括在非质子传递的有机溶剂中，在催化活性量的强力存在下，将通式（II）的化合物酸（催化剂）或释放强酸或强酸铵盐的试剂，也可以将催化剂作为原料/产物的一部分转化为式I化合物，其中R 1，其中，R 6，R 6和R 8各自独立地为氢原子，硝基，磺基，卤原子，假卤素，基团COOR 1或CONHR 2或C 1-8烷基，C 1-8烷氧基或芳氧基，酰胺基，硫代烷基或硫代芳基，烷基 - 或芳基 - 磺酰基，烷基 - 或芳基 - 亚硫酰基，三氟甲基或膦酰基，R 1和 R 2是氢原子或C 1 1-8个烷基或芳基或芳烷基，R 10是基团-C（O）CH 2 C（O）CH 3和R 11是氢原子或酰基，或R 10和R 11是基团-C（ O）CH 2 C（O）CH 3。根据本发明的方法操作简单，产生高产率的高化学纯度和高异构纯度的产品。

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