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1. 发明申请

US20060241330A1 Method for separating hydrocarbons and use of a zeolite therefor 失效
标题翻译：烃的分离方法和沸石的使用
公开(公告)号：US20060241330A1
公开(公告)日：2006-10-26
申请号：US10568723
申请日：2004-08-17
申请人： Joeri Denayer , Refik Ocakoglu , Gino Baron
发明人： Joeri Denayer , Refik Ocakoglu , Gino Baron
IPC分类号： C07C7/12
CPC分类号： B01D15/00 , B01D15/08 , B01D15/1821 , B01J20/18 , B01J29/70 , C07C7/12 , C10G25/003 , C10G25/12 , C07C9/00
摘要： A method for separating a mixture of hydrocarbons into fractions enriched in linear, mono-branched, or multi-branched hydrocarbons is disclosed. In particular, mono-branched alkanes are separated from a mixture of alkanes containing multi-branched, mono-branched and linear alkanes, by selectively adsorbing the mono-branched alkanes on a zeolitic adsorbent. The zeolitic adsorbent MCM-22 is particularly suitable for carrying out the method.
摘要翻译：公开了将烃混合物分离成富含线性，单支链或多支链烃的馏分的方法。特别地，通过在沸石吸附剂上选择性吸附单支链烷烃，单链烷烃与含有多支链，单支链和直链烷烃的烷烃的混合物分离。沸石吸附剂MCM-22特别适用于实施该方法。

2. 发明授权

US07435865B2 Method for separating hydrocarbons and use of a zeolite therefor 失效
标题翻译：烃的分离方法和沸石的使用
公开(公告)号：US07435865B2
公开(公告)日：2008-10-14
申请号：US10568723
申请日：2004-08-17
申请人： Joeri Denayer , Refik Ocakoglu , Gino Baron
发明人： Joeri Denayer , Refik Ocakoglu , Gino Baron
IPC分类号： C07C7/12 , C07C7/13 , C07C7/00 , C07C5/13 , B01D53/02 , B01D15/00 , B01D15/08
CPC分类号： B01D15/00 , B01D15/08 , B01D15/1821 , B01J20/18 , B01J29/70 , C07C7/12 , C10G25/003 , C10G25/12 , C07C9/00
摘要： A method for separating a mixture of hydrocarbons into fractions enriched in linear, mono-branched, or multi-branched hydrocarbons is disclosed. In particular, mono-branched alkanes are separated from a mixture of alkanes containing multi-branched, mono-branched and linear alkanes, by selectively adsorbing the mono-branched alkanes on a zeolitic adsorbent. The zeolitic adsorbent MCM-22 is particularly suitable for carrying out the method.
摘要翻译：公开了将烃混合物分离成富含线性，单支链或多支链烃的馏分的方法。特别地，通过在沸石吸附剂上选择性吸附单支链烷烃，单链烷烃与含有多支链，单支链和直链烷烃的烷烃的混合物分离。沸石吸附剂MCM-22特别适用于实施该方法。

3. 发明授权

US06679986B1 Catalytic support with an oxide base from a metal belonging to the SVI group of the periodic table, its preparation and its uses 失效
标题翻译：具有氧化物基的催化支持物，属于周期表SVI组的金属，其制备及其用途
公开(公告)号：US06679986B1
公开(公告)日：2004-01-20
申请号：US09571894
申请日：2000-05-16
申请人： Pedro Da Silva , Marc Bisson , Alain Milan , Sebastien Decker , Joeri Denayer
发明人： Pedro Da Silva , Marc Bisson , Alain Milan , Sebastien Decker , Joeri Denayer
IPC分类号： B01J2106
CPC分类号： C10G49/02 , B01J21/063 , B01J21/066 , B01J27/053 , B01J37/031 , C07C5/2772 , C07C2521/06 , C07C2521/08 , Y10S585/94 , C07C9/16
摘要： A catalytic support includes a substantial quantity of at least one SVI group Periodic Table metal oxide in which is incorporated silica. The mass ratio between the quantity of SVI group metal oxide and the quantity of silica it contains ranges between 5 and 70, the SVI group metal oxide is in crystalline form, and the specific surface of the support is greater than or equal to 160 m2/g.
摘要翻译：催化载体包括大量的至少一种SVI基团周期表金属氧化物，其中掺入二氧化硅。 SVI族金属氧化物的量与其含有的二氧化硅的量之间的质量比范围在5至70之间，SVI族金属氧化物是结晶形式，并且载体的比表面积大于或等于160μm， 2> / g。

4. 发明授权

US06448198B1 Acid catalyst with a sulfated zirconia base and its uses 失效
标题翻译：具有硫酸化氧化锆基体的酸催化剂及其用途
公开(公告)号：US06448198B1
公开(公告)日：2002-09-10
申请号：US09613585
申请日：2000-07-10
申请人： Georges Szabo , Pedro Nascimento , Alain Milan , Sebastien Decker , Joeri Denayer , Jean-Pierre Dath
发明人： Georges Szabo , Pedro Nascimento , Alain Milan , Sebastien Decker , Joeri Denayer , Jean-Pierre Dath
IPC分类号： B01J27053
CPC分类号： B01J21/066 , B01J27/053 , B01J37/0009
摘要： The invention relates to an acid catalyst containing a substantial quantity of supported or mass sulfated zirconia and at least one hydrogenating transition metal. This catalyst is characterized by the fact that the sulfated zirconia is in crystallized form and that it shows a specific surface area greater than or equal to 135 m2/g, a pore volume greater than or equal to 0.16 cm3/g and an average pore diameter greater than or equal to 20 Angstroms (20×10−10 m). The invention also relates to methods of making this catalyst and to the uses of this catalyst in hydrocarbon transformation chemical reactions requiring the use of an acid type catalyst, such as for example, isomerization, alkylation, oligomerization reactions or even light hydrocarbon dehydration reactions, and also heavier hydrocarbon hydrocracking and hydroisomerization reactions. In a preferred embodiment of the method of the present invention, a hydrated zirconia gel is washed with a soluble polar organic solvent (other than water). In accordance with the method including this washing step, a solid acid catalyst containing pure mass sulfated zirconia in a crystallized form has a surface area greater than or equal to 150 m2/g, a pore volume greater than or equal to 0.2 cm3/g, and more preferably greater than or equal to 0.25 cm3/g, and an average pore diameter greater than or equal to 20 Angstroms (20×10−10 m) and preferably greater than or equal to 30 Angstroms (30×10−10 m).
摘要翻译：本发明涉及含有大量负载或大量硫酸化氧化锆和至少一种氢化过渡金属的酸催化剂。该催化剂的特征在于硫酸化氧化锆是结晶形式，并且其表现出大于或等于135m 2 / g的比表面积，大于或等于0.16cm 3 / g的孔体积和平均孔径大于或等于20埃（20x10-10米）。本发明还涉及制备该催化剂的方法以及该催化剂在需要使用酸型催化剂的烃转化化学反应中的用途，例如异构化，烷基化，低聚反应或甚至轻质烃脱水反应，以及还有较重的烃加氢裂化和加氢异构化反应。在本发明方法的优选实施方案中，用可溶性极性有机溶剂（水除外）洗涤水合氧化锆凝胶。根据包括该洗涤步骤的方法，含有结晶形式的纯质量硫酸化氧化锆的固体酸催化剂具有大于或等于150m 2 / g的表面积，大于或等于0.2cm 3 / g的孔体积，更优选大于或等于0.25cm 3 / g，平均孔径大于或等于20埃（20×10 -10 m），优选大于或等于30埃（30×10 -10 m）。

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