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    • 5. 发明授权
    • Graded palladium-containing partial combustion catalyst
    • 分级含钯部分燃烧催化剂
    • US5258349A
    • 1993-11-02
    • US617973
    • 1990-11-26
    • Ralph A. Dalla BettaKazunori TsurumiToru Shoji
    • Ralph A. Dalla BettaKazunori TsurumiToru Shoji
    • B01J23/44B01J35/00F23C13/00B01J21/06B01J23/66B01J35/04
    • F23C13/00B01J23/44B01J35/0006
    • This invention is a graded catalyst comprising palladium and also a partial combustion process in which the fuel is partially combusted using that catalyst. The catalyst utilizes a catalytic support structure suitable for high flow rates of combustible gas mixtures through it. The catalyst is situated on the support so that in the flowing gas stream a leading portion of the support has a higher combustion activity, such as by a higher concentration of catalytic metal, than has the trailing portion. The combination of graded catalyst and support provides a low "light off" temperature for the combustible gas (only a low preheat temperature is needed to cause the combustion reaction to begin) and yet does not cause "hot spots" to occur because of excess activity. The combustion gas produced by the catalytic process may be at a temperature below the adiabatic combustive temperature, may be used at that temperature, or fed to other combustion stages for further use in a gas turbine, furnace, boiler, or the like.
    • 本发明是一种包含钯的分级催化剂,也是使用该催化剂将燃料部分燃烧的部分燃烧过程。 该催化剂使用适合于通过其的可燃气体混合物的高流速的催化支撑结构。 催化剂位于载体上,使得在流动的气流中,载体的引导部分具有比具有后部的更高的燃烧活性,例如通过较高浓度的催化金属。 分级催化剂和载体的组合为可燃气体提供低的“轻度关闭”温度(仅需要低预热温度才能使燃烧反应开始),并且不会由于过量的活性而引起“热点” 。 通过催化过程产生的燃烧气体可能处于低于绝热燃烧温度的温度,可以在该温度下使用,或者进料到其它燃烧阶段,以进一步用于燃气轮机,炉,锅炉等。
    • 6. 发明授权
    • Graded palladium-containing partial combustion catalyst and a process
for using it
    • 分级含钯部分燃烧催化剂及其使用方法
    • US5248251A
    • 1993-09-28
    • US856462
    • 1992-03-24
    • Ralph A. Dalla BettaKazunori TsurumiToru Shoji
    • Ralph A. Dalla BettaKazunori TsurumiToru Shoji
    • B01J23/44B01J35/00F23C13/00
    • F23C13/00B01J23/44B01J35/0006
    • This invention is a graded catalyst comprising palladium and also a partial combustion process in which the fuel is partially combusted using that catalyst. The catalyst utilizes a catalytic support structure suitable for high flow rates of combustible gas mixtures through it. The catalyst is situated on the support so that in the flowing gas stream a leading portion of the support has a higher combustion activity, such as by a higher concentration of catalytic metal, than has the trailing portion. The combination of graded catalyst and support provides a low "light off" temperature for the combustible gas (only a low preheat temperature is needed to cause the combustion reaction to begin) and yet does not cause "hot spots" to occur because of excess activity. The combustion gas produced by the catalytic process may be at a temperature below the adiabatic combustive temperature, may be used at that temperature, or fed to other combustion stages for further use in a gas turbine, furnace, boiler, or the like.
    • 本发明是一种包含钯的分级催化剂,也是使用该催化剂将燃料部分燃烧的部分燃烧过程。 该催化剂使用适合于通过其的可燃气体混合物的高流速的催化支撑结构。 催化剂位于载体上,使得在流动的气流中,载体的引导部分具有比具有后部的更高的燃烧活性,例如通过较高浓度的催化金属。 分级催化剂和载体的组合为可燃气体提供低的“轻度关闭”温度(仅需要低预热温度才能使燃烧反应开始),并且不会由于过量活性而引起“热点” 。 通过催化过程产生的燃烧气体可能处于低于绝热燃烧温度的温度,可以在该温度下使用,或者进料到其它燃烧阶段,以进一步用于燃气轮机,炉,锅炉等。
    • 10. 发明授权
    • Electrically-heated combustion catalyst structure and method for
start-up of a gas turbine using same
    • 电加热燃烧催化剂结构及使用其的燃气轮机起动方法
    • US6109018A
    • 2000-08-29
    • US688075
    • 1996-07-26
    • Thomas Rostrup-NielsenRalph A. Dalla BettaToru ShojiScott A. MagnoDavid K. Yee
    • Thomas Rostrup-NielsenRalph A. Dalla BettaToru ShojiScott A. MagnoDavid K. Yee
    • F01N3/20F01N3/28F23C13/00F23R3/40F02C7/26
    • F23R3/40F01N3/2013F01N3/2026F01N3/281F02C7/26F23C13/00F23C13/02F01N2330/323F01N2610/03F05D2220/76F05D2260/85F23D2206/10Y02T10/26
    • This invention relates to an electrically-heated catalyst (EHC) and a start-up method of a gas turbine engine for combusting a hydrocarbonaceous fuel/oxygen-containing gas mixture using this electrically-heated catalyst. The catalytic structure is electrically heated to a predetermined temperature prior to start up of the turbine so as to reduce emissions during the start-up of the system. The EHC unit is a stacked or spirally wound layering of flat and corrugated thin metal foils which forms a plurality of axially-extending, longitudinal channels. The channels are preferably coated on one surface with a catalytic material, leaving the other surface free from the reaction to act as a heat sink, making the design an IHE (integral heat exchange) catalytic unit. The preferred embodiment of the EHC has electrodes outside of the fuel/oxygen-containing mixture stream, and uses electrical power having a predetermined voltage in the range of 100 to 200 volts to heat the unit. A method for using the EHC in the start-up of a gas turbine is also disclosed wherein an electrical power is applied to heat the EHC a predetermined temperature prior to the fuel/oxygen-containing mixture being introduced and may be left on for a certain period of time after the introduction of the fuel/oxygen-containing mixture. The EHC may be maintained at the desired predetermined temperature by modulating the applied voltage. The electrical power is terminated when any one of several conditions are met including when the heat of the catalytic reaction is sufficient to maintain the catalyst at its steady-state condition or when a certain period of time has elapsed.
    • 本发明涉及使用该电加热催化剂燃烧含烃燃料/含氧气体混合物的燃气涡轮发动机的电加热催化剂(EHC)和起动方法。 催化结构在涡轮启动之前被电加热至预定温度,以便在系统启动期间减少排放。 EHC单元是形成多个沿轴向延伸的纵向通道的平坦且波浪形的薄金属箔的层叠或螺旋卷绕的层。 通道优选在一个表面上用催化材料涂布,使另一个表面没有反应作为散热器,使得设计成为IHE(整体式热交换)催化单元。 EHC的优选实施例具有位于燃料/含氧混合物流之外的电极,并且使用具有在100至200伏特范围内的预定电压的电力来加热该单元。 还公开了在燃气轮机起动中使用EHC的方法,其中在引入燃料/含氧混合物之前施加电功率以将EHC加热到预定温度,并且可以保持一定的 在引入燃料/含氧混合物之后的时间段。 可以通过调制所施加的电压将EHC保持在所需的预定温度。 当满足几个条件中的任何一个时,电力终止,包括当催化反应的热量足以使催化剂保持在其稳定状态或当经过一定时间段时。