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1. 发明授权

US08133469B2 Processes for conjointly producing bromine and calcium chloride 失效
标题翻译：共同生产溴和氯化钙的方法
公开(公告)号：US08133469B2
公开(公告)日：2012-03-13
申请号：US12594881
申请日：2008-02-05
申请人： Joe D. Sauer , George W. Cook, Jr. , Tyson J. Hall
发明人： Joe D. Sauer , George W. Cook, Jr. , Tyson J. Hall
IPC分类号： C01B7/09 , C01F11/24
CPC分类号： C01B7/09 , C01B7/096 , C01F11/28
摘要： Processes are provided for conjointly producing Br2 and a concentrated aqueous solution containing at least about 5 wt % CaCI2, based on the weight of the concentrated aqueous solution, from an HBr-rich recycle stream and a feed brine dilute in CaCI2. wherein the aqueous HBr-rich stream is produced from an HBr-rich recycle stream and a portion of the feed brine. Such processes can comprise feeding the HBr-rich recycle stream and a liquid comprising a portion of the feed brine, either together or separately to an HBr absorption tower; producing an aqueous HBr-rich stream in the HBr absorption tower; feeding the aqueous HBr-rich stream and, optionally, a portion of the feed brine to a bromine tower, oxidizing bromide moieties within the bromine tower with CI2 to produce Br2; recovering Br2 from the bromine tower, removing a bromide-depleted bottoms from the bromine tower, such bottoms containing HCI; adding a Ca++ source to the bromide-depleted bottoms to convert substantially all of the HCI in the bottoms to CaCI2, and, as necessary, removing water from the treated bottoms to produce the concentrated aqueous solution.
摘要翻译：提供用于从富含HBr的循环流和在CaCl 2中稀释的进料盐水中共同生产Br2和基于浓缩水溶液的重量至少约5重量％CaCl 2的浓缩水溶液的方法。其中富含HBr的水溶液由富含HBr的循环流和一部分进料盐水制成。这种方法可以包括将富含HBr的循环物流和包含一部分进料盐水的液体一起或分开地供应到HBr吸收塔; 在HBr吸收塔中产生富含HBr的水溶液; 将富含HBr的水流和任选的一部分进料盐水加入到溴塔中，用Cl 2氧化溴塔内的溴化物部分以产生Br 2; 从溴塔中回收Br2，从溴塔中除去溴化物贫乏的塔底物，这些含HCl的塔底物; 向溴化物贫乏的塔底物中加入Ca ++源，以将塔底中的基本上所有的HCl转化为CaCl 2，并根据需要从经处理的塔底产物中除去水以产生浓缩的水溶液。

2. 发明授权

US08133467B2 Processes for conjointly producing bromine and calcium chloride 失效
标题翻译：共同生产溴和氯化钙的方法
公开(公告)号：US08133467B2
公开(公告)日：2012-03-13
申请号：US12523785
申请日：2008-02-05
申请人： Joe D. Sauer , George W. Cook, Jr. , Tyson J. Hall , George A. Newbill
发明人： Joe D. Sauer , George W. Cook, Jr. , Tyson J. Hall , George A. Newbill
IPC分类号： C01B7/09 , C01F11/24
CPC分类号： C01B7/09 , C01B7/096 , C01F11/28
摘要： Processes are provided for conjointly producing Br2 and a concentrated aqueous solution containing at least about 5 wt % CaCI2, based on the weight of the concentrated aqueous solution, from an aqueous HBr rich stream and, optionally, a feed brine dilute in CaCI2. Such processes can comprise feeding the aqueous HBr-rich stream and the feed brine to a tower, oxidizing bromide moieties within the tower with Cl2 to produce Br2, recovering Br2 from the tower, removing a bromide-depleted bottoms from the tower, such bottoms containing HCI, adding a Ca++ source to the bromide-depleted bottoms to convert substantially all of the HCI in the bottoms to CaCI2, and, as necessary, removing water from the treated bottoms to produce the concentrated aqueous solution.
摘要翻译：提供了用于从富含HBr水溶液和任选的在CaCl 2中稀释的进料盐水中共同生产Br2和含有至少约5重量％CaCl 2的浓缩水溶液（基于浓缩水溶液的重量）的方法。这样的方法可以包括将富含HBr的水流和进料盐水加入到塔中，用Cl 2氧化塔内的溴化物部分以产生Br 2，从塔中回收Br 2，从塔中除去溴化物贫化的塔底物， HCl，向溴化物贫乏的塔底物中加入Ca ++源，以将塔底中的基本上所有的HCl转化为CaCl 2，并根据需要从经处理的塔底产物中除去水以产生浓缩的水溶液。

3. 发明授权

US08133468B2 Processes for conjointly producing bromine, calcium chloride, and chlorine 失效
标题翻译：共同生产溴，氯化钙和氯的方法
公开(公告)号：US08133468B2
公开(公告)日：2012-03-13
申请号：US12594877
申请日：2008-02-05
申请人： Joe D. Sauer , George W. Cook, Jr. , Tyson J. Hall , George A. Newbill
发明人： Joe D. Sauer , George W. Cook, Jr. , Tyson J. Hall , George A. Newbill
IPC分类号： C01B7/09 , C01B7/03 , C01F11/24
CPC分类号： C01B7/09 , C01B7/03 , C01B7/096 , C01F11/28 , C25B1/24
摘要： Processes are provided for conjointly producing Br2, a concentrated aqueous solution containing CaCI2, and Cl2 from an aqueous HBr-rich stream and a feed brine dilute in CaCI2 that comprises NaCI. Such processes can comprise feeding the aqueous HBr-rich stream and the feed brine to a tower, oxidizing bromide moieties within the tower with Cl2 from a Cl2 source, at least a portion of which is produced according to this invention, to produce Br2, recovering Br2 from the tower, removing a bromide-depleted bottoms from the tower, such bottoms containing HCI, adding a Ca++ source to the bromide-depleted bottoms to convert substantially all of the HCI in the bottoms to CaCI2, as necessary, removing water from the treated bottoms to produce the concentrated aqueous solution, producing Cl2 and caustics from residual chlorides such as NaCI, and using at least a portion of the thus produced Cl2 in the Cl2 source.
摘要翻译：提供了从富含HBr水溶液的水中共同生成Br2，含有CaCl 2和Cl 2的浓缩水溶液和在包含NaCl的CaCl 2中稀释的进料盐水的方法。这样的方法可以包括将富含HBr的水流和进料盐水加入到塔中，用来自Cl 2源的Cl 2氧化塔内的溴化物部分，其至少一部分根据本发明生产以产生Br2，回收 Br2，从塔中除去溴化物贫乏的塔底物，这样的含有HCl的塔底物，向溴化物贫乏的塔底物中加入Ca ++源，根据需要将底部的基本上所有的HCl转化为CaCl 2，从而从处理的底部产物以产生浓缩的水溶液，从残余氯化物如NaCl中产生Cl 2和苛性碱，并使用Cl2源中由此产生的Cl 2的至少一部分。

4. 发明申请

US20090155385A1 METHODS OF REDUCING OR ELIMINATING SALMONELLA IN REPTILES AND/OR THEIR EGGS 审中-公开
标题翻译：减少或消除鱼类在复制品和/或其蛋鸡中的方法
公开(公告)号：US20090155385A1
公开(公告)日：2009-06-18
申请号：US12297296
申请日：2007-06-15
申请人： Joe D. Sauer , George W. Cook, Jr. , Christopher J. Nalepa
发明人： Joe D. Sauer , George W. Cook, Jr. , Christopher J. Nalepa
IPC分类号： A01N59/08 , A01N43/50 , A01N59/00
CPC分类号： A61K31/4166 , Y02A50/481
摘要： A method for reducing or eliminating Salmonella in reptiles and/or reptile eggs through the use of at least one N,N-dihalo-5,5-dialkylhydantoin in which each of the alkyl groups is independently selected from those containing in the range of from 1 to about 6 carbon atoms.
摘要翻译：一种通过使用至少一种N，N-二卤代-5,5-二烷基乙内酰脲来减少或消除爬行动物和/或爬行动物中的沙门氏菌的方法，其中每个烷基独立地选自 1至约6个碳原子。

5. 发明授权

US08349380B2 Bromine-based biocides suitable for food processing 失效
标题翻译：适用于食品加工的溴基杀生物剂
公开(公告)号：US08349380B2
公开(公告)日：2013-01-08
申请号：US12520443
申请日：2008-01-11
申请人： Joe D. Sauer , George W. Cook, Jr. , William S. Pickrell
发明人： Joe D. Sauer , George W. Cook, Jr. , William S. Pickrell
IPC分类号： A23L1/304
CPC分类号： A23B4/20 , A23B4/24 , A23L3/3526 , A23V2002/00 , A23V2200/10 , A23V2250/1574
摘要： Ultraviolet light stabilized antimicrobial compositions are formed from (A) and (B). (A) is (I) a solid-state microbiocidal compound having at least one bromine atom in the molecule; (II) an aqueous solution or slurry of (I); (III) is a concentrated aqueous antimicrobial composition having a dissolved active bromine content derived from (i) BrCl or BrCl and Br2 and (ii) overbased alkali metal sulfamate and/or sulfamic acid, alkali metal base, and water, (IV) solids made by dewatering a composition of (III). (B) is a ultraviolet light degradation-inhibiting amount of up to one part by weight of ascorbic acid, dehydroascorbic acid and/or an edible water-soluble salt/ester thereof per part by weight of bromine in the selected antimicrobial composition. Preparation and uses of such compositions are described. Methods of controlling contamination of seafood and seafood products by pathogens are also described.
摘要翻译：（A）和（B）形成紫外光稳定的抗微生物组合物。（A）是（I）分子中具有至少一个溴原子的固态杀微生物化合物; （II）（I）的水溶液或浆液; （III）是具有衍生自（i）BrCl或BrCl和Br2的溶解的活性溴含量的浓缩水性抗微生物组合物和（ii）高碱性碱金属氨基磺酸盐和/或氨基磺酸，碱金属碱和水，（IV）固体通过脱水（III）的组合物制成。（B）是所选抗微生物组合物中每重量份溴至多1重量份的抗坏血酸，脱氢抗坏血酸和/或其食用水溶性盐/酯的紫外光降解抑制量。描述了这种组合物的制备和用途。还描述了通过病原体控制海鲜和海产品污染的方法。

6. 发明授权

US08992882B2 Ultra-high purity zinc bromides and quaternary ammonium bromides for use in zinc-bromine batteries 有权
标题翻译：用于锌 - 溴电池的超高纯度溴化锌和溴化季铵
公开(公告)号：US08992882B2
公开(公告)日：2015-03-31
申请号：US12528738
申请日：2008-02-13
申请人： Joe D. Sauer , George W. Cook, Jr.
发明人： Joe D. Sauer , George W. Cook, Jr.
IPC分类号： C01B9/00 , H01M6/04 , C01G9/04 , C07C209/12 , H01M12/08
CPC分类号： C01G9/04 , C01P2006/40 , C01P2006/80 , C07C209/12 , H01M12/085 , Y02E60/128 , C07C211/63
摘要： Ultra-high purity zinc bromide and quaternary ammonium bromides suitable for use in zinc-bromine batteries, and methods for making same, are provided.
摘要翻译：提供了适用于锌 - 溴电池的超高纯度溴化锌和溴化季铵及其制备方法。

7. 发明授权

US07932292B2 Use of quaternary ammonium compounds in the remediation of mold, mildew, and funguses 有权
标题翻译：在霉菌，霉菌和真菌的修复中使用季铵化合物
公开(公告)号：US07932292B2
公开(公告)日：2011-04-26
申请号：US12513288
申请日：2007-11-05
申请人： Joe D. Sauer , George W. Cook, Jr. , Christopher S. Knight
发明人： Joe D. Sauer , George W. Cook, Jr. , Christopher S. Knight
IPC分类号： A01N33/12 , A01N33/00 , C09D5/18
CPC分类号： A01N33/12 , Y10T428/249953 , Y10T428/31989 , A01N2300/00
摘要： The present invention relates to the use of quaternary ammonium compounds in the remediation of microbial growth such as mold, funguses, and mildew.
摘要翻译：本发明涉及季铵化合物在微生物生长修复中的应用，如霉菌，霉菌和霉菌。

8. 发明授权

US5077444A Process for drying hexabromocyclododecane 失效
标题翻译：六溴环十二烷干燥方法
公开(公告)号：US5077444A
公开(公告)日：1991-12-31
申请号：US614379
申请日：1990-11-15
申请人： George W. Cook, Jr. , George H. Ransford
发明人： George W. Cook, Jr. , George H. Ransford
IPC分类号： C07C17/02 , C09K21/08
CPC分类号： C09K21/08 , C07C17/02 , C07C2101/20
摘要： A flame retardant product predominant in hexabromocyclododecane is prepared and dried by a process wherein gaseous ammonia is injected into the dryer system to prevent the formation of color bodies which contaminant the product.
摘要翻译：通过其中将气态氨注入干燥器系统中以防止形成污染产品的着色体的方法制备并在六溴环十二烷中主要的阻燃产物干燥。

9. 发明授权

US06432380B1 Synthesis of aluminosilicates via cofeeding an alkali metal aluminate and sodium silicate and cofeeding apparatus therefor 失效
标题翻译：通过加入碱金属铝酸盐和硅酸钠及其共进料装置合成铝硅酸盐
公开(公告)号：US06432380B1
公开(公告)日：2002-08-13
申请号：US09657830
申请日：2000-09-08
申请人： Joseph E. Coury , Wylie A. Barrow , Yongzhuo Su , George W. Cook, Jr. , Robert F. Pierpoline
发明人： Joseph E. Coury , Wylie A. Barrow , Yongzhuo Su , George W. Cook, Jr. , Robert F. Pierpoline
IPC分类号： C01B3902
CPC分类号： C01B39/02
摘要： Synthetic zeolite is produced by force feeding separate aqueous streams of sodium silicate and of an alkali metal aluminate into coaxial alignment with each other. The coaxially aligned solutions are then introduced into in an open space in coaxial fashion with one of the streams being injected from a nozzle. The open space constitutes a mixing zone in which the two streams come together and are thoroughly mixed to produce a precrystallized mixture. This mixture then passes in unimpeded fashion through an entrance port and into a crystallization reactor or vessel. The system used for conducting this operation thus serves the dual function of being a feeding system and a mixing system whereby the silicate and aluminate streams interact with each other before entering the crystallization reactor or zone. Intimate mixing is assured by virtue of the relatively small volume of the mixing zone and the higher velocity of the stream emanating from the nozzle.
摘要翻译：合成沸石通过将分离的硅酸钠和碱金属铝酸盐的水流强制供给彼此同轴对准而制备。同轴对准的溶液然后以同轴的方式引入开放空间中，其中一个流从喷嘴注入。开放空间构成混合区，其中两个物流在一起并被充分混合以产生预结晶的混合物。然后，该混合物以无阻碍的方式通过入口进入结晶反应器或容器。用于进行该操作的系统因此具有作为进料系统和混合系统的双重功能，由此硅酸盐和铝酸盐流在进入结晶反应器或区域之前相互作用。通过混合区的相对较小的体积和从喷嘴发出的流的较高速度来确保紧密混合。

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