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1. 发明授权

US6040383A Organosilicon compounds containing oligoisobutylene or polyisobutylene groups 失效
标题翻译：含有低聚异丁烯或聚异丁烯基团的有机硅化合物
公开(公告)号：US6040383A
公开(公告)日：2000-03-21
申请号：US52508
申请日：1998-03-31
申请人： Jochen Dauth , Thomas Hierstetter , Bernward Deubzer , Petra Gratzl
发明人： Jochen Dauth , Thomas Hierstetter , Bernward Deubzer , Petra Gratzl
IPC分类号： C08G81/02 , C07F7/18 , C08F8/42 , C08F10/10 , C08G77/382 , C08G77/388 , C08G77/442 , C08G77/46 , C09D183/10 , C09G1/16 , C08F8/00 , C08L43/00
CPC分类号： C09G1/16 , C08G77/382 , C08G77/388 , C08G77/442 , C08G77/46
摘要： The invention describes novel organosilicon compounds containing oligoisobutylene or polyisobutylene groups and comprising at least one unit of the formulaA.sub.a R.sub.b SiX.sub.c O.sub.4-(a+b+c)/2, (I)where R are identical or different and are each a monovalent, divalent or trivalent unsubstituted or substituted hydrocarbon radical, X are identical or different and are each a chlorine atom or a radical of the formula --OR.sup.1, where R.sup.1 is a hydrogen atom or an alkyl radical which may be substituted by an ether oxygen atom, or a radical of the formula--R.sup.2 ([OCH(CH.sub.3)CH.sub.2 ].sub.e [OCH.sub.2 CH.sub.2 ].sub.f [O(CH.sub.2).sub.4 ].sub.g OR.sup.3).sub.y (II)where R.sup.2 is a divalent or trivalent, unsubstituted or substituted hydrocarbon radical which is substituted by one or more groups of the formulae--(C.dbd.O)--O--, --(C.dbd.O)--NR.sup.3 --, --NR.sup.3 --, --O--, --S--,R.sup.3 is a hydrogen atom or R.sup.1 or a radical of the formula--(C.dbd.O)--R.sup.1,e, f and g are each an integer of 0-200, with the proviso that the sum e+f+g.gtoreq.1 and y is 1 or 2,a is 0, 1 or 2,b is 0, 1, 2 or 3,c is 0, 1, 2 or 3 and the sum a+b+c.ltoreq.4, andA is a radical which contains an oligoisobutylene or polyisobutylene group, with the proviso that at least one radical of the formula A is present per molecule.
摘要翻译：本发明描述了含有低聚异丁烯或聚异丁烯基团的新型有机硅化合物，并且包含至少一个式A a R b Si X c O 4 - （a + b + c）/ 2，（I）的单元，其中R相同或不同，并且各自是一价，二价或三价未取代的或取代的烃基，X相同或不同，并且各自为氯原子或式-OR1的基团，其中R 1为氢原子或可被醚氧原子取代的烷基，或其中R 2是被一个或多个基团取代的二价或三价，未取代或取代的烃基，其中R 2是（C 1 -C 4 式（C = O）-O - ， - （C = O）-NR 3 - ， - NR 3 - ， - O-，-S-，R 3是氢原子或R 1或式 - （ C = O）-R1，e，f和g各自为0-200的整数，条件是和e + f + g> / = 1和y为1或2，a为0,1或2 ，b为0,1,2或3，c为0,1,2或3，并且和a + b + c为4，并且A是含有低聚异丁烯或聚异丁烯基团的基团，条件是每个分子存在至少一个式A的基团。

2. 发明授权

US5593787A Organosilicon compounds containing (meth) acryloxy groups, their preparation and their use 失效
标题翻译：含有（甲基）丙烯酰氧基的有机硅化合物，其制备及其应用
公开(公告)号：US5593787A
公开(公告)日：1997-01-14
申请号：US548127
申请日：1995-10-25
申请人： Jochen Dauth , Christian Herzig , Bernward Deubzer , Thomas Hierstetter , Petra Gratzl
发明人： Jochen Dauth , Christian Herzig , Bernward Deubzer , Thomas Hierstetter , Petra Gratzl
IPC分类号： B01J31/22 , C07B61/00 , C07F7/08 , C07F7/18 , C08F30/08 , C08G77/14 , C08G77/20 , C08G77/22 , C08G77/38 , C08L83/07 , C09D137/00 , C09D143/04 , C09D183/06 , C09D183/07 , B32B9/04
CPC分类号： C08G77/38 , C08G77/20 , C09D183/06 , Y10T428/31663
摘要： The present invention relates to organosilicon compounds containing (meth)acryloxy groups which can be prepared in a simple manner with high selectivity using readily accessible starting substances. The organopolysiloxanes containing (meth)acryloxy groups rapidly crosslink in the presence of a photoinitiator and light. The compounds of the present invention may be employed in the production of coatings.
摘要翻译：本发明涉及含有（甲基）丙烯酰氧基的有机硅化合物，其可以使用容易获得的起始物质以高选择性以简单的方式制备。含有（甲基）丙烯酰氧基的有机聚硅氧烷在光引发剂和光的存在下迅速交联。本发明的化合物可用于制备涂料。

3. 发明授权

US5998562A Permanent organosilicon compounds, their preparation and use 失效
标题翻译：永久性有机硅化合物，其制备和用途
公开(公告)号：US5998562A
公开(公告)日：1999-12-07
申请号：US888934
申请日：1997-07-07
申请人： Guenter Mahr , Jochen Dauth , Bernward Deubzer , Monika Ott , Petra Gratzl , Hans Lautenschlager
发明人： Guenter Mahr , Jochen Dauth , Bernward Deubzer , Monika Ott , Petra Gratzl , Hans Lautenschlager
IPC分类号： C14C11/00 , C07F7/10 , C07F7/18 , C08G77/10 , C08G77/26 , C08G77/388 , C08G77/54 , D06M15/643 , C08G77/08
CPC分类号： C08G77/388 , C08G77/54 , Y10S8/01
摘要： The present invention relates to triazine-containing organosilicon compounds having units of the formulaA.sub.a R.sub.b X.sub.c SiO.sub.(4-a-b-c)/2 (I),whereR is identical or different and denotes a hydrogen atom or a monovalent substituted or unsubstituted hydrocarbon radical, having 1 to 26 carbon atoms, preferably 1 to 18 per radical,X is identical or different and is a halogen atom, a chlorine atom or a radical of the formula --OR.sup.1, where R.sup.1 denotes an alkyl radical, having 1 to 18 carbon atoms, preferably 1 to 8 per radical and which may be substituted by an ether oxygen atom,a is 0 or 1, preferably 0.01-0.5b is 0, 1, 2 or 3, preferably 0.5-3.0c is 0, 1, 2 or 3, preferably 0.0-2.0 and the sum a+b+c.ltoreq.4, preferably 0.1-3.5, andA is a radical of the formula ##STR1## where R.sup.2 is an unbranched or branched, optionally substituted alkylene radical, having 1 to 18, preferably 1 to 12, carbon atoms,Y is identical or different and denotes a hydrogen atom or an unbranched or branched alkyl radical, having 1 to 12, preferably 1 to 8, carbon atoms or denotes a radical of the formula --OR.sup.1, where R.sup.1 has the meaning given above, andZ is identical or different and denotes X, --NR.sub.2, --(O)CR or --SR, where X and R have the meanings given above with the proviso that at least one radical A containing at least one halogen atom, preferably a chlorine atom, is present per polymer molecule.
摘要翻译：本发明涉及具有式AaRbXcSiO（4-abc）/ 2（I）单元的含三嗪的有机硅化合物，其中R相同或不同，表示氢原子或一价取代或未取代的烃基，其具有1至 26个碳原子，优选1至18个基团，X相同或不同，为卤素原子，氯原子或式-OR1基团，其中R1表示具有1至18个碳原子的烷基，优选1 至8个，并且可被醚氧原子取代，a为0或1，优选为0.01-0.5b为0,1,2或3，优选0.5-3.0c为0,1,2或3，优选为总和a + b + c 4，优选0.1-3.5，A是下式的基团，其中R 2是无支链或支链的任选取代的亚烷基，其具有1至18，优选1至 12，碳原子，Y相同或不同，表示氢原子或无支链或支链烷基，具有1至12个，优选为1〜8个碳原子，或表示式-OR1的基团，其中R1具有上述含义，Z相同或不同，表示X，-NR2， - （O）CR或-SR，其中X和 R具有上述含义，条件是每个聚合物分子存在至少一个含有至少一个卤素原子，优选氯原子的基团A.

4. 发明授权

US5869726A Process for preparing organosilicon compounds containing (meth)acryloxy groups 失效
标题翻译：制备含有（甲基）丙烯酰氧基的有机硅化合物的方法
公开(公告)号：US5869726A
公开(公告)日：1999-02-09
申请号：US931723
申请日：1997-09-16
申请人： Jochen Dauth , Bernward Deubzer , Petra Gratzl , Josef Wolferseder
发明人： Jochen Dauth , Bernward Deubzer , Petra Gratzl , Josef Wolferseder
IPC分类号： C08G77/12 , C08G77/20 , C08G77/38 , C09D183/06 , C09D183/07 , C07F7/08
CPC分类号： C09D183/06 , C08G77/38
摘要： A novel process for preparing organosilicon compounds containing (meth)acxyloxy groups is described, in which alkoxylated alk-2-yne 1,4-di(meth)acrylates (1) of the formula ##STR1## where R.sup.2 is a hydrogen atom or a methyl radical,R.sup.3 is a linear or branched alkylene radical having from 1 to 6 carbon atoms per radical andR.sub.4 is a linear or branched alkylene radical having from 1 to 6 carbon atoms per radical, andz is an integer from 1 to 12,are reacted with organosilicon compounds (2) comprising units of the formula ##STR2## where R is an identical or different monovalent, optionally halogenated hydrocarbon radical having from 1 to 18 carbon atoms per radical, ande is 0 or 1, on average from 0.01 to 1.0,f is 0, 1, 2 or 3, on average from 0.0 to 3.0, andhaving at least one Si-bonded hydrogen atom per molecule in the presence of catalysts (3) which promote the addition Si-bonded hydrogen onto aliphatic multiple bonds and also in the presence of polymerization inhibitors (4), where alkoxylated alk-2-yne 1,4-di(meth)acrylates (1) are used in amounts of from 1.01 to 1.5 mole per gram atom of Si-bonded hydrogen in organosilicon compound (2).
摘要翻译：描述了制备含有（甲基）丙氧基的有机硅化合物的新方法，其中式（II）的烷氧基化烷基-2-炔基1,4-二（甲基）丙烯酸酯（1）其中R2是氢原子或甲基，R3是每个基团具有1至6个碳原子的直链或支链亚烷基，R4是每个基团具有1至6个碳原子的直链或支链亚烷基，z是1至 12与包含式（III）的单元的有机硅化合物（2）反应，其中R是相对或不同的每个基团具有1至18个碳原子的单价，任选卤代烃基，e是0或1 平均为0.01〜1.0，f为0,1,2或3，平均为0.0〜3.0，在催化剂（3）的存在下，每分子具有至少一个Si键合的氢原子，促进Si的添加键合的氢键到脂族多重键上，并且在聚合抑制剂的存在下（4），其中烷氧基化的烷基-2-炔1,4-二（甲基）丙烯酸酯（1）的用量为有机硅化合物（2）中每克原子的Si键合氢的1.01至1.5摩尔。

5. 发明授权

US06177511B1 Amino silicone oil emulsions crosslinked by reactions similar to a Michael addition 失效
标题翻译：通过与迈克尔加成相似的反应交联的氨基硅油乳液
公开(公告)号：US06177511B1
公开(公告)日：2001-01-23
申请号：US09236809
申请日：1999-01-25
申请人： Jochen Dauth , Bernward Deubzer , Robert Schröck , Petra Gratzl
发明人： Jochen Dauth , Bernward Deubzer , Robert Schröck , Petra Gratzl
IPC分类号： C08G7720
CPC分类号： C08G77/54 , C08F283/12 , C08L83/08 , C08L2666/34
摘要： Novel organopolysiloxane compositions comprising (A) organopolysiloxanes which contain at least one SiC-bonded organic radical containing basic nitrogen, where the basic nitrogen is optionally present in part as a salt of a water-soluble organic acid, water-soluble inorganic acid, or water-insoluble organic acid, (B) anionic, cationic, nonionic or amphoteric surfactants, which are in soluble or soluble in (A) (C) substituted or unsubstituted diacrylates and/or oligoacrylates, and optionally, (C′) substituted or unsubstituted acrylates, and (D) water are described.
摘要翻译：新型有机聚硅氧烷组合物，其包含（A）含有至少一个含有碱性氮的SiC键合的有机基团的有机聚硅氧烷，其中碱性氮部分作为水溶性有机酸，水溶性无机酸或水的盐部分地部分存在（A）（C）取代或未取代的二丙烯酸酯和/或低聚丙烯酸酯，和任选的（C'）取代或未取代的丙烯酸酯（C）的可溶性或可溶性的阴离子，阳离子，非离子或两性表面活性剂，（D）水。

6. 发明授权

US6043362A Hydrophilic permanent organosilicon compounds 失效
标题翻译：亲水性永久性有机硅化合物
公开(公告)号：US6043362A
公开(公告)日：2000-03-28
申请号：US888557
申请日：1997-07-07
申请人： Jochen Dauth , Guenter Mahr , Bernward Deubzer , Petra Gratzl , Hans-Juergen Lautenschlager
发明人： Jochen Dauth , Guenter Mahr , Bernward Deubzer , Petra Gratzl , Hans-Juergen Lautenschlager
IPC分类号： C07F7/10 , C07F7/18 , C08G77/10 , C08G77/26 , C08G77/388 , C08G77/46 , D06M13/02 , D06M13/148 , D06M13/322 , D06M13/35 , D06M13/355 , D06M13/358 , D06M13/364 , D06M13/50 , D06M13/51 , D06M13/513 , C07D47/00
CPC分类号： C08G77/388 , C08G77/26 , C08G77/46
摘要： The invention relates to oxyalkylene-group-containing organosilicon compounds having units of the formula ##STR1## where R is identical or different, and denotes a monovalent halogenated or nonhalogenated hydrocarbon radical, X is identical or different and is a chlorine atom or a radical of the formula --OR.sup.1, where R.sup.1 denotes an alkyl radical which can be substituted by an ether oxygen atom,a is 0 or 1,b is 0, 1, 2 or 3,c is 0, 1, 2 or 3 and the total a+b+c.ltoreq.4 andA is a radical of the formula ##STR2## where R.sup.2 signifies an unbranched or branched substituted or unsubstituted divalent hydrocarbon radical, which may or may not contain ether, amine, sulfide, ester, amide, carbonate, urea and urethane groups, B is identical or different, and denotes X, --NR.sub.2.sup.1, --O--C(.dbd.O)--R.sup.1, --SR.sup.1 or a radical of the formula--NR.sup.3 R.sup.2 [O--CH(CH.sub.3)--CH.sub.2 ].sub.d [OCH.sub.2 CH.sub.2 ].sub.e [O(CH.sub.2).sub.4 ].sub.f OR.sup.4 (III),where X, R.sup.1 and R.sup.2 have the meanings given for these above, R.sup.3 is identical or different and is a hydrogen atom or has the meaning of R, R.sup.4 has the meaning of R.sup.3 or signifies a radical of the formula--C(.dbd.O)--R, --R.sup.2 NR.sub.2.sup.3, --NR.sup.3 R.sup.2 --, --R.sup.2 NR.sub.2.sup.3 H.sup.+ X.sup.-,d, e and f are an integer from 0 to 200, with the proviso that the sum d+e+f.gtoreq.1 and B contains at least one radical of the formula (III) per polymer molecule.
摘要翻译：本发明涉及具有下式的单元的含氧化烯基的有机硅化合物，其中R相同或不同，表示一价卤代或非卤代烃基，X相同或不同，为氯原子或式 - OR1，其中R1表示可被醚氧原子取代的烷基，a为0或1，b为0,1,2或3，c为0,1,2或3，总计a + b + C 4和A是下式的基团，其中R 2表示无支链或支链的取代或未取代的二价烃基，其可以含有或不含有醚，胺，硫醚，酯，酰胺，碳酸酯，脲和氨基甲酸酯基团， B表示相同或不同的表示X，-NR 21，-OC（= O）-R 1，-SR 1或-NR 3 R 2基团的基团[O-CH（CH 3）-CH 2] d [OCH 2 CH 2] CH 2）4] fOR 4（III），其中X，R 1和R 2具有上述含义，R 3相同或不同，为氢原子或具有R的含义，R 4具有平均或表示式-C（= O）-R，-R2NR23，-NR3R2-，-R2NR23H + X，D，e和f的基团为0至200的整数，条件是总和d + e + f> / = 1，B包含每个聚合物分子中至少一个式（III）的基团。

7. 发明授权

US5627296A Phosphorus-containing organosilicon compounds 失效
标题翻译：含磷有机硅化合物
公开(公告)号：US5627296A
公开(公告)日：1997-05-06
申请号：US559269
申请日：1995-11-15
申请人： Jochen Dauth , Hans Mayer , Bernward Deubzer , Petra Gratzl
发明人： Jochen Dauth , Hans Mayer , Bernward Deubzer , Petra Gratzl
IPC分类号： C07F9/30 , C07F9/38 , C07F9/48 , C07F19/00 , C08G77/395 , C08G77/48 , C07F7/08
CPC分类号： C08G77/395 , C07F9/301 , C07F9/3821 , C07F9/4816 , C08G77/48
摘要： The present invention provides novel phosphorus-containing organosilicon compounds which can be prepared in a simple manner using readily obtainable starting materials, which are hydrophilic to water-soluble and whose hydrophilicity or water-solubility can be specifically controlled by modification of the phosphorus-containing organosilicon compounds.
摘要翻译：本发明提供新颖的含磷有机硅化合物，其可以使用容易获得的起始原料以简单的方式制备，其亲水性为水溶性，并且其亲水性或水溶性可以通过改性含磷有机硅化合物。

8. 发明授权

US06451909B1 Multiphase formulations of organosilicon compounds 失效
标题翻译：有机硅化合物的多相配方
公开(公告)号：US06451909B1
公开(公告)日：2002-09-17
申请号：US09738026
申请日：2000-12-14
申请人： Christian Herzig , Robert Schröck , Petra Gratzl , Reinhard Stallbauer
发明人： Christian Herzig , Robert Schröck , Petra Gratzl , Reinhard Stallbauer
IPC分类号： C08L8310
CPC分类号： C08J3/03 , C08G77/442 , C08J2383/04
摘要： A process for the preparation of multiphase formulations of organosilicon compounds by (A) formation of a mixture containing organic compound(s) (1) containing at least two aliphatic double bonds and of the general formula R2(CR1═CH2)x, (1) in which R1 are a hydrogen atom or an alkyl radical having 1 to 6 carbon atoms per radical, R2 is a divalent, trivalent or tetravalent hydrocarbon radical having 1 to 25 carbon atoms per radical; and x denotes 2, 3 or 4 corresponding to the valence of R2; and an organopolysiloxane (2) having on average more than one Si-bonded hydrogen atom per molecule; a catalyst (3) promoting the addition of Si-bonded hydrogen at an aliphatic double bond; an emulsifier (4); and an agent (5) immiscible with (1) and (2); and (B) emulsification of the mixture, with the proviso that the ratio of aliphatic double bond in organic compound (1) to Si-bonded hydrogen in the organopolysiloxane (2) in (A) is such that toluene-soluble siloxane copolymers are obtained.
摘要翻译：（A）形成含有至少两个脂肪族双键的有机化合物（1）的混合物，以及一般化学式，其中R 1为氢原子或具有氢原子的烷基的通式（1）所示的制备有机硅化合物的多相配方的方法每个基团为1至6个碳原子，R 2为每个基团具有1至25个碳原子的二价，三价或四价烃基; andx表示对应于R2的化合价的2,3或4; 和每分子平均具有多于一个Si键合的氢原子的有机聚硅氧烷（2）;促进在脂肪族双键上加入Si键合的氢的催化剂（3）;乳化剂（4）; （5）与（1）和（2）不混溶; 和（B）混合物的乳化，条件是（A）中的有机化合物（1）中的有机聚硅氧烷（2）中的有机化合物（1）中的脂族双键与Si键合的氢的比例使得得到甲苯可溶的硅氧烷共聚物。

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