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1. 发明授权

US5998562A Permanent organosilicon compounds, their preparation and use 失效
标题翻译：永久性有机硅化合物，其制备和用途
公开(公告)号：US5998562A
公开(公告)日：1999-12-07
申请号：US888934
申请日：1997-07-07
申请人： Guenter Mahr , Jochen Dauth , Bernward Deubzer , Monika Ott , Petra Gratzl , Hans Lautenschlager
发明人： Guenter Mahr , Jochen Dauth , Bernward Deubzer , Monika Ott , Petra Gratzl , Hans Lautenschlager
IPC分类号： C14C11/00 , C07F7/10 , C07F7/18 , C08G77/10 , C08G77/26 , C08G77/388 , C08G77/54 , D06M15/643 , C08G77/08
CPC分类号： C08G77/388 , C08G77/54 , Y10S8/01
摘要： The present invention relates to triazine-containing organosilicon compounds having units of the formulaA.sub.a R.sub.b X.sub.c SiO.sub.(4-a-b-c)/2 (I),whereR is identical or different and denotes a hydrogen atom or a monovalent substituted or unsubstituted hydrocarbon radical, having 1 to 26 carbon atoms, preferably 1 to 18 per radical,X is identical or different and is a halogen atom, a chlorine atom or a radical of the formula --OR.sup.1, where R.sup.1 denotes an alkyl radical, having 1 to 18 carbon atoms, preferably 1 to 8 per radical and which may be substituted by an ether oxygen atom,a is 0 or 1, preferably 0.01-0.5b is 0, 1, 2 or 3, preferably 0.5-3.0c is 0, 1, 2 or 3, preferably 0.0-2.0 and the sum a+b+c.ltoreq.4, preferably 0.1-3.5, andA is a radical of the formula ##STR1## where R.sup.2 is an unbranched or branched, optionally substituted alkylene radical, having 1 to 18, preferably 1 to 12, carbon atoms,Y is identical or different and denotes a hydrogen atom or an unbranched or branched alkyl radical, having 1 to 12, preferably 1 to 8, carbon atoms or denotes a radical of the formula --OR.sup.1, where R.sup.1 has the meaning given above, andZ is identical or different and denotes X, --NR.sub.2, --(O)CR or --SR, where X and R have the meanings given above with the proviso that at least one radical A containing at least one halogen atom, preferably a chlorine atom, is present per polymer molecule.
摘要翻译：本发明涉及具有式AaRbXcSiO（4-abc）/ 2（I）单元的含三嗪的有机硅化合物，其中R相同或不同，表示氢原子或一价取代或未取代的烃基，其具有1至 26个碳原子，优选1至18个基团，X相同或不同，为卤素原子，氯原子或式-OR1基团，其中R1表示具有1至18个碳原子的烷基，优选1 至8个，并且可被醚氧原子取代，a为0或1，优选为0.01-0.5b为0,1,2或3，优选0.5-3.0c为0,1,2或3，优选为总和a + b + c 4，优选0.1-3.5，A是下式的基团，其中R 2是无支链或支链的任选取代的亚烷基，其具有1至18，优选1至 12，碳原子，Y相同或不同，表示氢原子或无支链或支链烷基，具有1至12个，优选为1〜8个碳原子，或表示式-OR1的基团，其中R1具有上述含义，Z相同或不同，表示X，-NR2， - （O）CR或-SR，其中X和 R具有上述含义，条件是每个聚合物分子存在至少一个含有至少一个卤素原子，优选氯原子的基团A.

2. 发明授权

US6043362A Hydrophilic permanent organosilicon compounds 失效
标题翻译：亲水性永久性有机硅化合物
公开(公告)号：US6043362A
公开(公告)日：2000-03-28
申请号：US888557
申请日：1997-07-07
申请人： Jochen Dauth , Guenter Mahr , Bernward Deubzer , Petra Gratzl , Hans-Juergen Lautenschlager
发明人： Jochen Dauth , Guenter Mahr , Bernward Deubzer , Petra Gratzl , Hans-Juergen Lautenschlager
IPC分类号： C07F7/10 , C07F7/18 , C08G77/10 , C08G77/26 , C08G77/388 , C08G77/46 , D06M13/02 , D06M13/148 , D06M13/322 , D06M13/35 , D06M13/355 , D06M13/358 , D06M13/364 , D06M13/50 , D06M13/51 , D06M13/513 , C07D47/00
CPC分类号： C08G77/388 , C08G77/26 , C08G77/46
摘要： The invention relates to oxyalkylene-group-containing organosilicon compounds having units of the formula ##STR1## where R is identical or different, and denotes a monovalent halogenated or nonhalogenated hydrocarbon radical, X is identical or different and is a chlorine atom or a radical of the formula --OR.sup.1, where R.sup.1 denotes an alkyl radical which can be substituted by an ether oxygen atom,a is 0 or 1,b is 0, 1, 2 or 3,c is 0, 1, 2 or 3 and the total a+b+c.ltoreq.4 andA is a radical of the formula ##STR2## where R.sup.2 signifies an unbranched or branched substituted or unsubstituted divalent hydrocarbon radical, which may or may not contain ether, amine, sulfide, ester, amide, carbonate, urea and urethane groups, B is identical or different, and denotes X, --NR.sub.2.sup.1, --O--C(.dbd.O)--R.sup.1, --SR.sup.1 or a radical of the formula--NR.sup.3 R.sup.2 [O--CH(CH.sub.3)--CH.sub.2 ].sub.d [OCH.sub.2 CH.sub.2 ].sub.e [O(CH.sub.2).sub.4 ].sub.f OR.sup.4 (III),where X, R.sup.1 and R.sup.2 have the meanings given for these above, R.sup.3 is identical or different and is a hydrogen atom or has the meaning of R, R.sup.4 has the meaning of R.sup.3 or signifies a radical of the formula--C(.dbd.O)--R, --R.sup.2 NR.sub.2.sup.3, --NR.sup.3 R.sup.2 --, --R.sup.2 NR.sub.2.sup.3 H.sup.+ X.sup.-,d, e and f are an integer from 0 to 200, with the proviso that the sum d+e+f.gtoreq.1 and B contains at least one radical of the formula (III) per polymer molecule.
摘要翻译：本发明涉及具有下式的单元的含氧化烯基的有机硅化合物，其中R相同或不同，表示一价卤代或非卤代烃基，X相同或不同，为氯原子或式 - OR1，其中R1表示可被醚氧原子取代的烷基，a为0或1，b为0,1,2或3，c为0,1,2或3，总计a + b + C 4和A是下式的基团，其中R 2表示无支链或支链的取代或未取代的二价烃基，其可以含有或不含有醚，胺，硫醚，酯，酰胺，碳酸酯，脲和氨基甲酸酯基团， B表示相同或不同的表示X，-NR 21，-OC（= O）-R 1，-SR 1或-NR 3 R 2基团的基团[O-CH（CH 3）-CH 2] d [OCH 2 CH 2] CH 2）4] fOR 4（III），其中X，R 1和R 2具有上述含义，R 3相同或不同，为氢原子或具有R的含义，R 4具有平均或表示式-C（= O）-R，-R2NR23，-NR3R2-，-R2NR23H + X，D，e和f的基团为0至200的整数，条件是总和d + e + f> / = 1，B包含每个聚合物分子中至少一个式（III）的基团。

3. 发明授权

US5869726A Process for preparing organosilicon compounds containing (meth)acryloxy groups 失效
标题翻译：制备含有（甲基）丙烯酰氧基的有机硅化合物的方法
公开(公告)号：US5869726A
公开(公告)日：1999-02-09
申请号：US931723
申请日：1997-09-16
申请人： Jochen Dauth , Bernward Deubzer , Petra Gratzl , Josef Wolferseder
发明人： Jochen Dauth , Bernward Deubzer , Petra Gratzl , Josef Wolferseder
IPC分类号： C08G77/12 , C08G77/20 , C08G77/38 , C09D183/06 , C09D183/07 , C07F7/08
CPC分类号： C09D183/06 , C08G77/38
摘要： A novel process for preparing organosilicon compounds containing (meth)acxyloxy groups is described, in which alkoxylated alk-2-yne 1,4-di(meth)acrylates (1) of the formula ##STR1## where R.sup.2 is a hydrogen atom or a methyl radical,R.sup.3 is a linear or branched alkylene radical having from 1 to 6 carbon atoms per radical andR.sub.4 is a linear or branched alkylene radical having from 1 to 6 carbon atoms per radical, andz is an integer from 1 to 12,are reacted with organosilicon compounds (2) comprising units of the formula ##STR2## where R is an identical or different monovalent, optionally halogenated hydrocarbon radical having from 1 to 18 carbon atoms per radical, ande is 0 or 1, on average from 0.01 to 1.0,f is 0, 1, 2 or 3, on average from 0.0 to 3.0, andhaving at least one Si-bonded hydrogen atom per molecule in the presence of catalysts (3) which promote the addition Si-bonded hydrogen onto aliphatic multiple bonds and also in the presence of polymerization inhibitors (4), where alkoxylated alk-2-yne 1,4-di(meth)acrylates (1) are used in amounts of from 1.01 to 1.5 mole per gram atom of Si-bonded hydrogen in organosilicon compound (2).
摘要翻译：描述了制备含有（甲基）丙氧基的有机硅化合物的新方法，其中式（II）的烷氧基化烷基-2-炔基1,4-二（甲基）丙烯酸酯（1）其中R2是氢原子或甲基，R3是每个基团具有1至6个碳原子的直链或支链亚烷基，R4是每个基团具有1至6个碳原子的直链或支链亚烷基，z是1至 12与包含式（III）的单元的有机硅化合物（2）反应，其中R是相对或不同的每个基团具有1至18个碳原子的单价，任选卤代烃基，e是0或1 平均为0.01〜1.0，f为0,1,2或3，平均为0.0〜3.0，在催化剂（3）的存在下，每分子具有至少一个Si键合的氢原子，促进Si的添加键合的氢键到脂族多重键上，并且在聚合抑制剂的存在下（4），其中烷氧基化的烷基-2-炔1,4-二（甲基）丙烯酸酯（1）的用量为有机硅化合物（2）中每克原子的Si键合氢的1.01至1.5摩尔。

4. 发明授权

US5627296A Phosphorus-containing organosilicon compounds 失效
标题翻译：含磷有机硅化合物
公开(公告)号：US5627296A
公开(公告)日：1997-05-06
申请号：US559269
申请日：1995-11-15
申请人： Jochen Dauth , Hans Mayer , Bernward Deubzer , Petra Gratzl
发明人： Jochen Dauth , Hans Mayer , Bernward Deubzer , Petra Gratzl
IPC分类号： C07F9/30 , C07F9/38 , C07F9/48 , C07F19/00 , C08G77/395 , C08G77/48 , C07F7/08
CPC分类号： C08G77/395 , C07F9/301 , C07F9/3821 , C07F9/4816 , C08G77/48
摘要： The present invention provides novel phosphorus-containing organosilicon compounds which can be prepared in a simple manner using readily obtainable starting materials, which are hydrophilic to water-soluble and whose hydrophilicity or water-solubility can be specifically controlled by modification of the phosphorus-containing organosilicon compounds.
摘要翻译：本发明提供新颖的含磷有机硅化合物，其可以使用容易获得的起始原料以简单的方式制备，其亲水性为水溶性，并且其亲水性或水溶性可以通过改性含磷有机硅化合物。

5. 发明授权

US5593787A Organosilicon compounds containing (meth) acryloxy groups, their preparation and their use 失效
标题翻译：含有（甲基）丙烯酰氧基的有机硅化合物，其制备及其应用
公开(公告)号：US5593787A
公开(公告)日：1997-01-14
申请号：US548127
申请日：1995-10-25
申请人： Jochen Dauth , Christian Herzig , Bernward Deubzer , Thomas Hierstetter , Petra Gratzl
发明人： Jochen Dauth , Christian Herzig , Bernward Deubzer , Thomas Hierstetter , Petra Gratzl
IPC分类号： B01J31/22 , C07B61/00 , C07F7/08 , C07F7/18 , C08F30/08 , C08G77/14 , C08G77/20 , C08G77/22 , C08G77/38 , C08L83/07 , C09D137/00 , C09D143/04 , C09D183/06 , C09D183/07 , B32B9/04
CPC分类号： C08G77/38 , C08G77/20 , C09D183/06 , Y10T428/31663
摘要： The present invention relates to organosilicon compounds containing (meth)acryloxy groups which can be prepared in a simple manner with high selectivity using readily accessible starting substances. The organopolysiloxanes containing (meth)acryloxy groups rapidly crosslink in the presence of a photoinitiator and light. The compounds of the present invention may be employed in the production of coatings.
摘要翻译：本发明涉及含有（甲基）丙烯酰氧基的有机硅化合物，其可以使用容易获得的起始物质以高选择性以简单的方式制备。含有（甲基）丙烯酰氧基的有机聚硅氧烷在光引发剂和光的存在下迅速交联。本发明的化合物可用于制备涂料。

6. 发明授权

US06177511B1 Amino silicone oil emulsions crosslinked by reactions similar to a Michael addition 失效
标题翻译：通过与迈克尔加成相似的反应交联的氨基硅油乳液
公开(公告)号：US06177511B1
公开(公告)日：2001-01-23
申请号：US09236809
申请日：1999-01-25
申请人： Jochen Dauth , Bernward Deubzer , Robert Schröck , Petra Gratzl
发明人： Jochen Dauth , Bernward Deubzer , Robert Schröck , Petra Gratzl
IPC分类号： C08G7720
CPC分类号： C08G77/54 , C08F283/12 , C08L83/08 , C08L2666/34
摘要： Novel organopolysiloxane compositions comprising (A) organopolysiloxanes which contain at least one SiC-bonded organic radical containing basic nitrogen, where the basic nitrogen is optionally present in part as a salt of a water-soluble organic acid, water-soluble inorganic acid, or water-insoluble organic acid, (B) anionic, cationic, nonionic or amphoteric surfactants, which are in soluble or soluble in (A) (C) substituted or unsubstituted diacrylates and/or oligoacrylates, and optionally, (C′) substituted or unsubstituted acrylates, and (D) water are described.
摘要翻译：新型有机聚硅氧烷组合物，其包含（A）含有至少一个含有碱性氮的SiC键合的有机基团的有机聚硅氧烷，其中碱性氮部分作为水溶性有机酸，水溶性无机酸或水的盐部分地部分存在（A）（C）取代或未取代的二丙烯酸酯和/或低聚丙烯酸酯，和任选的（C'）取代或未取代的丙烯酸酯（C）的可溶性或可溶性的阴离子，阳离子，非离子或两性表面活性剂，（D）水。

7. 发明授权

US6040383A Organosilicon compounds containing oligoisobutylene or polyisobutylene groups 失效
标题翻译：含有低聚异丁烯或聚异丁烯基团的有机硅化合物
公开(公告)号：US6040383A
公开(公告)日：2000-03-21
申请号：US52508
申请日：1998-03-31
申请人： Jochen Dauth , Thomas Hierstetter , Bernward Deubzer , Petra Gratzl
发明人： Jochen Dauth , Thomas Hierstetter , Bernward Deubzer , Petra Gratzl
IPC分类号： C08G81/02 , C07F7/18 , C08F8/42 , C08F10/10 , C08G77/382 , C08G77/388 , C08G77/442 , C08G77/46 , C09D183/10 , C09G1/16 , C08F8/00 , C08L43/00
CPC分类号： C09G1/16 , C08G77/382 , C08G77/388 , C08G77/442 , C08G77/46
摘要： The invention describes novel organosilicon compounds containing oligoisobutylene or polyisobutylene groups and comprising at least one unit of the formulaA.sub.a R.sub.b SiX.sub.c O.sub.4-(a+b+c)/2, (I)where R are identical or different and are each a monovalent, divalent or trivalent unsubstituted or substituted hydrocarbon radical, X are identical or different and are each a chlorine atom or a radical of the formula --OR.sup.1, where R.sup.1 is a hydrogen atom or an alkyl radical which may be substituted by an ether oxygen atom, or a radical of the formula--R.sup.2 ([OCH(CH.sub.3)CH.sub.2 ].sub.e [OCH.sub.2 CH.sub.2 ].sub.f [O(CH.sub.2).sub.4 ].sub.g OR.sup.3).sub.y (II)where R.sup.2 is a divalent or trivalent, unsubstituted or substituted hydrocarbon radical which is substituted by one or more groups of the formulae--(C.dbd.O)--O--, --(C.dbd.O)--NR.sup.3 --, --NR.sup.3 --, --O--, --S--,R.sup.3 is a hydrogen atom or R.sup.1 or a radical of the formula--(C.dbd.O)--R.sup.1,e, f and g are each an integer of 0-200, with the proviso that the sum e+f+g.gtoreq.1 and y is 1 or 2,a is 0, 1 or 2,b is 0, 1, 2 or 3,c is 0, 1, 2 or 3 and the sum a+b+c.ltoreq.4, andA is a radical which contains an oligoisobutylene or polyisobutylene group, with the proviso that at least one radical of the formula A is present per molecule.
摘要翻译：本发明描述了含有低聚异丁烯或聚异丁烯基团的新型有机硅化合物，并且包含至少一个式A a R b Si X c O 4 - （a + b + c）/ 2，（I）的单元，其中R相同或不同，并且各自是一价，二价或三价未取代的或取代的烃基，X相同或不同，并且各自为氯原子或式-OR1的基团，其中R 1为氢原子或可被醚氧原子取代的烷基，或其中R 2是被一个或多个基团取代的二价或三价，未取代或取代的烃基，其中R 2是（C 1 -C 4 式（C = O）-O - ， - （C = O）-NR 3 - ， - NR 3 - ， - O-，-S-，R 3是氢原子或R 1或式 - （ C = O）-R1，e，f和g各自为0-200的整数，条件是和e + f + g> / = 1和y为1或2，a为0,1或2 ，b为0,1,2或3，c为0,1,2或3，并且和a + b + c为4，并且A是含有低聚异丁烯或聚异丁烯基团的基团，条件是每个分子存在至少一个式A的基团。

8. 发明授权

US06251313B1 Process for the preparation of microencapsulated products having organopolysiloxane walls 失效
标题翻译：制备具有有机聚硅氧烷壁的微囊化产品的方法
公开(公告)号：US06251313B1
公开(公告)日：2001-06-26
申请号：US09261401
申请日：1999-03-03
申请人： Bernward Deubzer , Jochen Dauth
发明人： Bernward Deubzer , Jochen Dauth
IPC分类号： B01J1302
CPC分类号： B01J13/18 , B01J13/04 , Y10T428/257 , Y10T428/2982
摘要： In the preparation of microcapsules having shell walls of organopolysiloxane and a core material, the shell walls are produced in situ by hydrolysis and polycondensation of organosilanes and/or their condensates having not more than 4 silicon atoms.
摘要翻译：在制备具有有机聚硅氧烷和核心材料的壳壁的微胶囊时，壳壁通过有机硅烷和/或其具有不超过4个硅原子的缩合物的水解和缩聚而原位制备。

9. 发明授权

US5605983A Soluble organopolysiloxane free-radical macroinitators for graft copolymerization 失效
标题翻译：用于接枝共聚的可溶性有机聚硅氧烷自由基大分子
公开(公告)号：US5605983A
公开(公告)日：1997-02-25
申请号：US360102
申请日：1994-12-20
申请人： Jochen Dauth , Catherine Oleggini , Bernward Deubzer
发明人： Jochen Dauth , Catherine Oleggini , Bernward Deubzer
IPC分类号： C08F4/00 , C08F283/12 , C08G77/48 , C08G77/392 , C08G77/388
CPC分类号： C08G77/48 , C08F283/12
摘要： The invention relates to partially crosslinked organopolysiloxanes which contain a radical forming group, a base-catalyzed process for their preparation, graft copolymers produced from these organopolysiloxanes and a process for the preparation of the graft copolymers. The present invention avoids problems related to known methods wherein a considerable portion of the organopolymer chains do not graft to the organopolysiloxane graft back-bone but remain as an unattached homopolymers.
摘要翻译：本发明涉及含有自由基形成基团的部分交联的有机聚硅氧烷，其制备的碱催化方法，由这些有机聚硅氧烷制备的接枝共聚物和制备接枝共聚物的方法。本发明避免了与已知方法相关的问题，其中相当大一部分的有机聚合物链不接枝到有机聚硅氧烷移植物背骨上，而是保留为未附着的均聚物。

10. 发明授权

US5561231A Homogeneous hydrosilylation catalysts 失效
标题翻译：均相氢化硅烷化催化剂
公开(公告)号：US5561231A
公开(公告)日：1996-10-01
申请号：US276922
申请日：1994-07-19
申请人： Jochen Dauth , Bernward Deubzer , Hans Bindl , Udo Peetz
发明人： Jochen Dauth , Bernward Deubzer , Hans Bindl , Udo Peetz
IPC分类号： B01J31/22 , C07B61/00 , C07F7/08 , C07F7/18 , C07F15/00 , C08G77/06 , C08G77/26 , C08G77/38 , C08G77/388 , C08G77/398 , C08K5/00 , C08L83/05 , C08L83/07 , C07F7/02
CPC分类号： C08G77/398 , C07F15/006 , C07F15/0066 , C07F15/0086 , C07F15/0093 , C07F7/0854 , C07F7/1876 , C08G77/26 , C08G77/388 , C08K5/0091
摘要： Transition metal-containing organosiloxanes of at least three organosiloxane units, comprising at least one transition metal complex, chemically bonded via ligands selected from among amino, phosphino or sulfido groups of Pt, Pd, Rh, Ru, Os or Ir, excluding those organosiloxanes which contain exclusively Pt(O) complexes bonded via amino ligands, are used as homogeneous hydrosilylation catalysts.
摘要翻译：至少有三个有机硅氧烷单元的过渡金属的有机硅氧烷包含至少一个过渡金属配合物，通过选自Pt，Pd，Rh，Ru，Os或Ir的氨基，膦基或硫基中的配体化学键合，不包括那些有机硅氧烷仅含有通过氨基配体键合的Pt（O）配合物，被用作均匀的氢化硅烷化催化剂。

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