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1. 发明申请

US20120157719A1 TUBE BUNDLE REACTOR FOR UNCATALYZED OR HOMOGENEOUSLY CATALYZED REACTIONS 有权
标题翻译：用于未加氢化或均相催化反应的管组反应器
公开(公告)号：US20120157719A1
公开(公告)日：2012-06-21
申请号：US13380207
申请日：2010-01-19
申请人： Joaquim Henrique Teles , Peter Resch , Wilhelm Ruppel , Ulrike Wegerle , Wolfgang Gerliing , Beatrice Rössler-Feigel , Anton Meier , Christian Müller
发明人： Joaquim Henrique Teles , Peter Resch , Wilhelm Ruppel , Ulrike Wegerle , Wolfgang Gerliing , Beatrice Rössler-Feigel , Anton Meier , Christian Müller
IPC分类号： C07C45/00 , B01J19/00
CPC分类号： B01J19/2425 , B01J4/001 , B01J19/006 , B01J2219/00085 , B01J2219/00166 , F28D7/16 , F28F9/0265 , F28F9/0275 , F28F9/0278 , Y02P20/582
摘要： The invention relates to a tube bundle reactor with a flat feed hood. Alternatively, the release hood may also have a flat design. The flat design reduces the heat of reaction which arises in the hood in the case of reaction types which take place not only in the tube bundle (uncatalyzed reactions and reactions with homogeneously distributed catalyst). This greatly suppresses undesired reactions which already take place in the hood owing to accumulated heat, which achieves a higher selectivity in the case of thermally sensitive reactions. In addition, the thermal distribution within the hoods can be controlled precisely.The tube bundle reactor comprises a tube bundle which has a feed end which is connected to a feed hood of the tube bundle reactor, wherein the feed hood is configured in a flat design with a cross-sectional area at the feed end and an internal volume, and the ratio of internal volume to cross-sectional area is less than 0.35 m. The invention is further implemented by means of a process for operating a tube bundle reactor, comprising: introducing a reactant mixture into a tube bundle and converting at least a proportion of the reactant mixture within the tube bundle to a product. The introducing comprises: feeding the reactant mixture into an interior of a feed hood of the tube bundle reactor and passing the reactant mixture on into a feed end of the tube bundle in the form of a fluid stream. The fluid stream has a cross-sectional area on entry into the feed end, and the interior of the feed hood through which the fluid stream flows has an internal volume; where the ratio of internal volume to cross-sectional area is less than 0.35 m.
摘要翻译：本发明涉及具有扁平进料罩的管束反应器。或者，释放罩也可以具有平坦的设计。在反应类型不仅在管束（未催化的反应和具有均匀分布的催化剂的反应）的情况下，扁平设计减少了发动机罩中产生的反应热。这大大地抑制了由于积热而在罩中发生的不期望的反应，这在热敏反应的情况下实现了更高的选择性。此外，可以精确地控制罩内的热分布。管束反应器包括管束，其具有连接到管束反应器的进料罩的进料端，其中进料罩构造成平坦设计，在进料端具有横截面积，内部体积，内部体积与横截面积的比值小于0.35μm。通过用于操作管束反应器的方法进一步实现本发明，其包括：将反应物混合物引入管束并将至少一部分管束内的反应物混合物转化成产物。引入包括：将反应物混合物进料到管束反应器的进料罩的内部，并将反应物混合物以流体流的形式送入管束的进料端。流体流在进入进料端时具有横截面面积，流体流流过的进料罩的内部具有内部容积; 其中内部体积与横截面积的比值小于0.35μm。

2. 发明授权

US09174192B2 Tube bundle reactor for uncatalyzed or homogeneously catalyzed reactions 有权
标题翻译：用于未催化或均匀催化反应的管束反应器
公开(公告)号：US09174192B2
公开(公告)日：2015-11-03
申请号：US13380207
申请日：2010-01-19
申请人： Joaquim Henrique Teles , Peter Resch , Wilhelm Ruppel , Ulrike Wegerle , Wolfgang Gerlinger , Beatrice Röβler-Feigel , Anton Meier , Christian Müller
发明人： Joaquim Henrique Teles , Peter Resch , Wilhelm Ruppel , Ulrike Wegerle , Wolfgang Gerlinger , Beatrice Röβler-Feigel , Anton Meier , Christian Müller
IPC分类号： B01J19/24 , B01J19/00 , B01J4/00 , F28D7/16 , F28F9/02
CPC分类号： B01J19/2425 , B01J4/001 , B01J19/006 , B01J2219/00085 , B01J2219/00166 , F28D7/16 , F28F9/0265 , F28F9/0275 , F28F9/0278 , Y02P20/582
摘要： The invention relates to a tube bundle reactor with a flat feed hood. Alternatively, the release hood may also have a flat design. The flat design reduces the heat of reaction which arises in the hood in the case of reaction types which take place not only in the tube bundle (uncatalyzed reactions and reactions with homogeneously distributed catalyst). This greatly suppresses undesired reactions which already take place in the hood owing to accumulated heat, which achieves a higher selectivity in the case of thermally sensitive reactions. In addition, the thermal distribution within the hoods can be controlled precisely.The tube bundle reactor comprises a tube bundle which has a feed end which is connected to a feed hood of the tube bundle reactor, wherein the feed hood is configured in a flat design with a cross-sectional area at the feed end and an internal volume, and the ratio of internal volume to cross-sectional area is less than 0.35 m. The invention is further implemented by means of a process for operating a tube bundle reactor, comprising: introducing a reactant mixture into a tube bundle and converting at least a proportion of the reactant mixture within the tube bundle to a product. The introducing comprises: feeding the reactant mixture into an interior of a feed hood of the tube bundle reactor and passing the reactant mixture on into a feed end of the tube bundle in the form of a fluid stream. The fluid stream has a cross-sectional area on entry into the feed end, and the interior of the feed hood through which the fluid stream flows has an internal volume; where the ratio of internal volume to cross-sectional area is less than 0.35 m.
摘要翻译：本发明涉及具有扁平进料罩的管束反应器。或者，释放罩也可以具有平坦的设计。在反应类型不仅在管束（未催化的反应和具有均匀分布的催化剂的反应）的情况下，扁平设计减少了发动机罩中产生的反应热。这大大地抑制了由于积热而在罩中发生的不期望的反应，这在热敏反应的情况下实现了更高的选择性。此外，可以精确地控制罩内的热分布。管束反应器包括管束，其具有连接到管束反应器的进料罩的进料端，其中进料罩构造成平坦设计，在进料端具有横截面积，内部体积，内部体积与横截面积的比值小于0.35μm。通过用于操作管束反应器的方法进一步实现本发明，其包括：将反应物混合物引入管束并将至少一部分管束内的反应物混合物转化成产物。引入包括：将反应物混合物进料到管束反应器的进料罩的内部，并将反应物混合物以流体流的形式送入管束的进料端。流体流在进入进料端时具有横截面面积，流体流流过的进料罩的内部具有内部容积; 其中内部体积与横截面积的比值小于0.35μm。

3. 发明授权

US08461392B2 Process for preparing cyclic ketones 有权
标题翻译：制备环酮的方法
公开(公告)号：US08461392B2
公开(公告)日：2013-06-11
申请号：US13060545
申请日：2009-08-26
申请人： Joaquim Henrique Teles , Wilhelm Ruppel , Ulrike Wegerle , Anton Meier , Thomas Genger , Michael Schelper , Peter Resch
发明人： Joaquim Henrique Teles , Wilhelm Ruppel , Ulrike Wegerle , Anton Meier , Thomas Genger , Michael Schelper , Peter Resch
IPC分类号： C07C45/78
CPC分类号： C07C45/28 , C07C45/82 , C07C2601/08 , Y02P20/582 , C07C49/403 , C07C49/395 , C07C49/413
摘要： The present invention relates to a process for preparing at least one monocyclic ketone having from 4 to 20 carbon atoms by reacting a mixture G1 comprising at least one monocyclic olefin having from 4 to 20 carbon atoms with a mixture G2 comprising at least dinitrogen monoxide, wherein said reaction is performed adiabatically.
摘要翻译：本发明涉及一种制备至少一种具有4-20个碳原子的单环酮的方法，该方法是使包含至少一种具有4-20个碳原子的单环烯烃的混合物G1与至少包含一氧化二氮的混合物G2反应，其中所述反应是绝热的。

4. 发明申请

US20110152576A1 PROCESS FOR PREPARING CYCLIC KETONES 有权
标题翻译：制备循环克氏酮的方法
公开(公告)号：US20110152576A1
公开(公告)日：2011-06-23
申请号：US13060545
申请日：2009-08-26
申请人： Joaquim Henrique Teles , Wilhelm Ruppel , Ulrike Wegerle , Anton Meier , Thomas Genger , Michael Schelper , Peter Resch
发明人： Joaquim Henrique Teles , Wilhelm Ruppel , Ulrike Wegerle , Anton Meier , Thomas Genger , Michael Schelper , Peter Resch
IPC分类号： C07C45/28 , C07C45/78
CPC分类号： C07C45/28 , C07C45/82 , C07C2601/08 , Y02P20/582 , C07C49/403 , C07C49/395 , C07C49/413
摘要： The present invention relates to a process for preparing at least one monocyclic ketone having from 4 to 20 carbon atoms by reacting a mixture G1 comprising at least one monocyclic olefin having from 4 to 20 carbon atoms with a mixture G2 comprising at least dinitrogen monoxide, wherein said reaction is performed adiabatically.
摘要翻译：本发明涉及一种制备至少一种具有4-20个碳原子的单环酮的方法，该方法是使包含至少一种具有4-20个碳原子的单环烯烃的混合物G1与至少包含一氧化二氮的混合物G2反应，其中所述反应是绝热的。

5. 发明申请

US20110130607A1 REACTOR FOR CARRYING OUT AUTOTHERMAL GAS-PHASE DEHYDROGENATIONS 有权
标题翻译：用于实施自动气相脱氢反应的反应器
公开(公告)号：US20110130607A1
公开(公告)日：2011-06-02
申请号：US12957618
申请日：2010-12-01
申请人： Grigorios Kolios , Wilhelm Ruppel , Ulrike Wegerle , Jasmina Kessel , Wolfgang Gerlinger , Godwind Tafara Peter Mabande , Goetz-Peter Schindler , Albena Kostova , Gerhard Olbert , Peter Pfab
发明人： Grigorios Kolios , Wilhelm Ruppel , Ulrike Wegerle , Jasmina Kessel , Wolfgang Gerlinger , Godwind Tafara Peter Mabande , Goetz-Peter Schindler , Albena Kostova , Gerhard Olbert , Peter Pfab
IPC分类号： C07C5/333 , B01J8/02
CPC分类号： B01J19/2485 , B01J2219/182
摘要： A reactor (1) in the form of an essentially horizontal cylinder for carrying out an autothermal gas-phase dehydrogenation of a hydrocarbon-comprising gas stream (2) by means of an oxygen-comprising gas stream (3) to give a reaction gas mixture over a heterogeneous catalyst configured as monolith (4), wherein the interior of the reactor (1) is divided by a detachable, cylindrical or prismatic housing G which is arranged in the longitudinal direction of the reactor (1) and is gastight in the circumferential direction and open at two end faces of the housing into an inner region A having one or more catalytically active zones (5), in which in each case a packing composed of monoliths (4) stacked on top of one another, next to one another and above one another and before each catalytically active zone (5) in each case a mixing zone (6) having solid internals are provided, and an outer region B arranged coaxially to the inner region A, is proposed.
摘要翻译：一种基本上水平的圆筒形式的反应器（1），用于通过含氧气流（3）进行含烃气流（2）的自热气相脱氢，得到反应气体混合物在构造为整料（4）的非均相催化剂上，其中反应器（1）的内部被沿着反应器（1）的纵向布置的可拆卸的圆柱形或棱柱形的壳体G分开，并且在圆周方向并且在壳体的两个端面处打开到具有一个或多个催化活性区域（5）的内部区域A中，其中在每个情况下由堆叠在彼此顶部的整料（4）彼此相邻的填料构成并且在每种情况下，在每个催化活性区（5）之前和之前提供具有固体内部的混合区（6），并且提供与内部区域A同轴布置的外部区域B.

6. 发明授权

US5821390A Catalytic gas-phase oxidation of propene to acrolein 失效
标题翻译：丙烯催化气相氧化成丙烯醛
公开(公告)号：US5821390A
公开(公告)日：1998-10-13
申请号：US525011
申请日：1995-09-08
申请人： Wilhelm Ruppel , Ulrike Wegerle , Andreas Tenten , Ulrich Hammon
发明人： Wilhelm Ruppel , Ulrike Wegerle , Andreas Tenten , Ulrich Hammon
IPC分类号： B01J23/88 , B01J8/06 , B01J21/02 , B01J23/16 , B01J23/887 , B01J27/132 , B01J27/192 , C07B61/00 , C07C45/35 , C07C47/22
CPC分类号： B01J27/192 , B01J23/8876 , B01J8/067 , C07C45/35 , B01J2208/00212 , B01J2208/00221 , B01J2219/00777
摘要： A gas-phase mixture of propene and oxygen is catalytically oxidized by passing a reactant gas mixture comprising propene and oxygen through a plurality of catalyst containing contact tubes in a fixed bed reactor and simultaneously passing only one heat-exchange medium at elevated temperature over the exterior surfaces of the contact tubes in a longitudinal flow pattern which is cocurrent with the direction of flow of the reactants through said tube; simultaneously superposing a transverse flow on said longitudinal flow of heat exchange medium by means of an arrangement of successive baffles along the contact tubes which leave passage cross-sections free, thereby resulting in a meandrous flow of the heat-exchange medium through the reactor and setting the flow rate of said heat-exchange medium so that its temperature between the point of entry of the medium into the reactor and its point of exit increases by 2.degree. to 10.degree. C.; and obtaining product acrolein at a selectivity .gtoreq.85 mol % from the reactor at a single pass propene conversion .gtoreq.90 mol %.
摘要翻译：丙烯和氧气的气相混合物通过在固定床反应器中通过包含丙烯和氧气的反应气体混合物通过多个含有接触管的催化剂催化氧化，同时仅使一个热交换介质在高温下通过外部接触管的表面以与通过所述管的反应物的流动方向并流的纵向流动图案; 同时通过沿着接触管的连续挡板的布置使横向流在所述纵向流动的热交换介质上，使得通道横截面自由，从而导致热交换介质通过反应器的蜿蜒流动和设定所述热交换介质的流速使得其进入反应器的入口点和其出口点之间的温度升高2℃至10℃; 并且在单次丙烯转化率为90摩尔％时，以反应器的选择性> 85％摩尔得到产物丙烯醛。

7. 发明授权

US5739391A Catalytic gas-phase oxidation of acrolein to acrylic acid 失效
标题翻译：丙烯醛催化气相氧化成丙烯酸
公开(公告)号：US5739391A
公开(公告)日：1998-04-14
申请号：US525118
申请日：1995-09-08
申请人： Wilhelm Ruppel , Ulrike Wegerle , Andreas Tenten , Ulrich Hammon
发明人： Wilhelm Ruppel , Ulrike Wegerle , Andreas Tenten , Ulrich Hammon
IPC分类号： B01J23/28 , B01J8/06 , B01J21/02 , B01J23/16 , C07B61/00 , C07C51/25 , C07C57/055 , C07C51/16
CPC分类号： B01J8/067 , C07C51/252 , B01J2208/00212
摘要： A process for the catalytic gas-phase oxidation of acrolein to acrylic acid in a multiple contact tube fixed-bed reactor through whose space surrounding the contact tubes only one heat-exchange medium circuit is passed, at elevated temperature on catalytically active multimetal oxides with an acrolein conversion for a single pass of .gtoreq.95 mol % and an acrylic acid formation selectivity of .gtoreq.90 mol %, which comprises firstly passing the heat-exchange medium through the multiple contact tube fixed-bed reactor longitudinally, considered over the reaction container as a whole, to the contact tubes in cocurrent to the reaction-gas mixture and secondly superposing a transverse flow within the reaction container by means of an arrangement of successive baffles along the contact tubes which leaves passage cross sections free, so as to give a meandrous flow of the heat-exchange medium, seen in longitudinal section through the contact tube bundle, and setting the flow rate of the circulated heat-exchange medium so that its temperature rises by from 2.degree. to 10.degree. C. between the point of entry into the reactor and the point of exit out of the reactor.
摘要翻译：一种在多接触管固定床反应器中将丙烯醛催化气相氧化成丙烯酸的方法，其中通过其接触管周围的空间仅使一个热交换介质回路在高温下通过催化活性多金属氧化物，其具有丙烯醛转化率为> / = 95mol％，丙烯酸形成选择性> 90wt％，其包括首先使热交换介质通过多接触管固定床反应器纵向通过反应容器作为整体，与反应气体混合物并流到接触管，并且其次通过沿接触管的连续挡板的布置叠加在反应容器内的横向流动，使得通道横截面自由，从而通过接触管束在纵剖面中看到热交换介质的蜿蜒流动，并设定循环hea的流量 t-交换介质，使其在进入反应器的点和从反应器出来的点之间的温度升高2℃至10℃。

8. 发明授权

US5144091A Preparation of acrolein or methacrolein by actalytic gas-phase oxidation of propene or isobutene 失效
标题翻译：丙烯酸或甲基纤维素通过丙烯酸或丙烯酸的活性气相氧化法制备
公开(公告)号：US5144091A
公开(公告)日：1992-09-01
申请号：US732910
申请日：1991-07-19
申请人： Hans Martan , Ulrike Wegerle , Wilhelm Ruppel , Lothar Riekert , Dieter Becker , Michael Kotter
发明人： Hans Martan , Ulrike Wegerle , Wilhelm Ruppel , Lothar Riekert , Dieter Becker , Michael Kotter
IPC分类号： B01J23/88 , B01J23/887 , B01J27/19 , B01J27/192 , C07B61/00 , C07C45/35 , C07C47/22
CPC分类号： B01J27/192 , B01J23/002 , B01J23/8876 , C07C45/35 , B01J2523/00
摘要： A process for the catalytic gas-phase oxidation of propene or isobutene to acrolein or methacrolein in a tubular fixed bed reactor or catalytically active oxides with a .gtoreq.90% conversion of the initial olefin on a single passage, wherein the temperature of the gases containing the reactants in the direction of flow along the tubes from their entrance until the conversion of the initial olefin is from 30 to 70% is from 360.degree. to 420.degree. C. and is then adjusted to from 360.degree. to 300.degree. C. until the conversion of the initial olefin is from 80 to 90% and is thereafter maintained at from 330.degree. to 390.degree. C. until the gases emerge from the tubes, is described.
摘要翻译：在管式固定床反应器中催化气相氧化丙烯或异丁烯至丙烯醛或甲基丙烯醛的方法或在单一通道上具有初始烯烃转化率> 90％的催化活性氧化物的方法，其中气体的温度在反应物的入口方向沿着管的流动方向含有反应物，直到初始烯烃的转化率为30-70％为360℃至420℃，然后调节至360℃至300℃直至描述了初始烯烃的转化率为80-90％，然后保持在330℃至390℃，直到气体从管中出来。

9. 发明授权

US08889936B2 Method of regenerating ruthenium catalysts for the hydrogenation of benzene 有权
标题翻译：再生用于氢化苯的钌催化剂的方法
公开(公告)号：US08889936B2
公开(公告)日：2014-11-18
申请号：US12375759
申请日：2007-07-27
申请人： Jochem Henkelmann , Michael Becker , Michael Schönherr , Wilhelm Ruppel , Ulrike Wegerle , Bianca Stäck
发明人： Jochem Henkelmann , Michael Becker , Michael Schönherr , Wilhelm Ruppel , Ulrike Wegerle , Bianca Stäck
IPC分类号： C07C5/10 , B01J23/46 , B01J23/96 , B01J38/04 , B01J23/75 , B01J23/40 , B01J23/755
CPC分类号： B01J38/04 , B01J23/40 , B01J23/462 , B01J23/75 , B01J23/755 , B01J23/96 , C07C5/10 , C07C2523/46 , Y02P20/584 , Y10S585/906 , C07C13/18
摘要： The present patent application describes a method of regenerating a ruthenium catalyst for the hydrogenation of benzene, which comprises flushing the catalyst with inert gas in a regeneration step until the original activity or part of the original activity has been attained.
摘要翻译：本专利申请描述了一种再生用于苯氢化的钌催化剂的方法，其包括在再生步骤中用惰性气体冲洗催化剂直到达到原始活性或部分原始活性。

10. 发明授权

US08697016B2 Reactor for carrying out autothermal gas-phase dehydrogenations 有权
标题翻译：用于进行自热气相脱氢反应器
公开(公告)号：US08697016B2
公开(公告)日：2014-04-15
申请号：US12957618
申请日：2010-12-01
申请人： Grigorios Kolios , Wilhelm Ruppel , Ulrike Wegerle , Jasmina Kessel , Wolfgang Gerlinger , Godwind Tafara Peter Mabande , Goetz-Peter Schindler , Albena Kostova , Gerhard Olbert , Peter Pfab
发明人： Grigorios Kolios , Wilhelm Ruppel , Ulrike Wegerle , Jasmina Kessel , Wolfgang Gerlinger , Godwind Tafara Peter Mabande , Goetz-Peter Schindler , Albena Kostova , Gerhard Olbert , Peter Pfab
IPC分类号： B01J8/04 , C07C5/333
CPC分类号： B01J19/2485 , B01J2219/182
摘要： A reactor in the form of an essentially horizontal cylinder for carrying out an autothermal gas-phase dehydrogenation of a hydrocarbon-comprising gas stream by means of an oxygen-comprising gas stream to give a reaction gas mixture over a heterogeneous catalyst configured as monolith is disclosed herein. The interior of the reactor is divided by a detachable, cylindrical or prismatic housing which is arranged in the longitudinal direction of the reactor, gastight in the circumferential direction and open at two end faces of the housing into an inner region, having one or more catalytically active zones. In each case, a packing composed of monoliths may be stacked on top of one another, next to one another, and above one another and before each catalytically active zone. Also in each case, a mixing zone having solid internals and an outer region arranged coaxially to the inner region are provided.
摘要翻译：公开了一种基本上水平的圆筒形式的反应器，用于通过含氧气流进行含烃气流的自热气相脱氢，得到构成为整料的多相催化剂上的反应气体混合物这里。反应器的内部被可拆卸的圆柱形或棱柱形壳体分隔开，该壳体沿反应器的纵向方向布置，在圆周方向上气密并且在壳体的两个端面处开放到具有一个或多个催化剂的内部区域活动区。在每种情况下，由整料组成的包装可以彼此重叠，彼此重叠，并且在每个催化活性区之前堆叠。在每种情况下，还提供了具有固体内部和与内部区域同轴配置的外部区域的混合区域。

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