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1. 发明授权

US06867246B2 N-alkyl aziridine block copolymers and the uses thereof 有权
标题翻译： N-烷基氮丙啶嵌段共聚物及其用途
公开(公告)号：US06867246B2
公开(公告)日：2005-03-15
申请号：US10296996
申请日：2001-05-30
申请人： Reinhold Nowak , Joachim Zech , Peter Bissinger , Erich Wanek , Gunther Eckhardt , Guenther Lechner
发明人： Reinhold Nowak , Joachim Zech , Peter Bissinger , Erich Wanek , Gunther Eckhardt , Guenther Lechner
IPC分类号： A61C13/34 , A61K6/093 , A61K6/10 , C08G77/388 , C08G77/46 , C08L83/12
CPC分类号： A61K6/093 , A61K6/0017 , A61K6/0023 , A61K6/10 , C08G77/388 , C08G77/46 , C08L83/12
摘要： N-alkyl aziridine block copolymers of the general structure (1), wherein R1 represents H, C1-C12 alkyl, C2-C12 alkenyl, C2-C12 alkinyl, C7-C15 aralkyl C7-C15 aralkyl, or C3-C12 cycloalkyl and these groups can be substituted with C1 or F partially, completely or in a mixed manner and/or may contain 0 to 5 heteroatoms selected from O, N, S; R2 represents a group selected from R1 and/or R4; R3 represents SiR13 or SiR12R4, wherein R4 represents a group of the general formula (2), wherein A represents an (n+1) radical saturated, unsaturated or aromatic, linear, branched or cyclic hydrocarbon group that may contain 0 to 5 heteroatoms selected from O, N, S and that comprises 1 to 18 carbon atoms; B is selected from O, S, NR1; D is selected from C(O)O, C(O)NR1, C(O), C(S)NR1, CH2; E represents a diradical saturated or unsaturated, linear, branched or cyclic hydrocarbon group that may contain 0 to 5 heteroatoms selected from O, N, S, and that comprises 0 to 18 carbon atoms; Q represents and α, ω-radical polyether chain of the general formula (3): —[O—CgH2g]h—, wherein g is 2 to 20; h is 1 to 1000; a is 0 or 1; f is an integer from 2 to 1000; n is an integer from 1 to 10; and x, y, z each represents 0 or an integer, the sum of which should range between 1 and 10000, with the proviso that if x is larger 0, y or z is smaller or equal x. There are many uses of these copolymers.
摘要翻译：通式（1）的N-烷基氮丙啶嵌段共聚物，其中R1表示H，C1-C12烷基，C2-C12烯基，C2-C12炔基，C7-C15芳烷基C7-C15烷芳基或C3-C12环烷基，基团可以部分，完全或以混合方式被C1或F取代和/或可以含有0至5个选自O，N，S的杂原子; R2表示选自R1和/或R4的基团; R3表示SiR13或SiR12R4，其中R4表示通式（2）的基团，其中A表示可以含有0至5个选自杂原子的（n + 1）基饱和，不饱和或芳族，直链，支链或环状烃基来自O，N，S并且包含1至18个碳原子; B选自O，S，NR1; D选自C（O）O，C（O）NR1，C（O），C（S）NR1，CH2; E表示可以含有0至5个选自O，N，S的杂原子并且包含0至18个碳原子的二价饱和或不饱和的直链，支链或环状烃基; Q表示和通式（3）的α，ω-自由基聚醚链： - [O-CgH2g] h-，其中g为2至20; h为1〜1000; a是0或1; f为2〜1000的整数; n是1至10的整数; 并且x，y，z各自表示0或整数，其总和应在1和10000之间，条件是如果x大于0，则y或z小于或等于x。这些共聚物有许多用途。

2. 发明授权

US06906117B2 Aziridinosilicones and the use thereof 有权
标题翻译：二氮杂环丁烷及其用途
公开(公告)号：US06906117B2
公开(公告)日：2005-06-14
申请号：US10296997
申请日：2001-05-30
申请人： Reinhold Nowak , Joachim Zech , Peter Bissinger , Erich Wanek , Gunther Eckhardt , Guenther Lechner
发明人： Reinhold Nowak , Joachim Zech , Peter Bissinger , Erich Wanek , Gunther Eckhardt , Guenther Lechner
IPC分类号： A61K6/093 , A61K6/10 , C08G77/388 , C08L83/08 , C08L83/00 , C08G77/26
CPC分类号： A61K6/093 , A61K6/0017 , A61K6/0023 , A61K6/10 , C08G77/388 , C08L83/08 , C08L83/12
摘要： Arizidinosilicones of the general formula (1), wherein R1 represents H, C1-C12 alkyl, C2-C12 alkenyl, C2-C12 alkinyl, C7-C15 alkaryl, C7-C15 aralkyl, C3-C12 cycloalkyl and these groups can be substituted with Cl or F partially, completely or in a mixed manner and/or may contain 0 to 5 heteroatoms selected from O, N, S, R2 represents a group of the selection of R1 and/or R4, and R3 represents SiRl3 or SiR12R4, and wherein R4 represents formula (2), and A represents an (n+1) radical saturated, unsaturated or aromatic, linear, branched or cyclic hydrocarbon group that may contain 0 to 5 heteroatoms selected from O, N, S and that includes 1 to 18 carbon atoms, B is selected from O, S, NR1, D is selected from C(O)O, C(O)NR1, C(O), C(O)C(O), C(O)(CH2)m(C(O), C(S)NR1, CH2, E represents a diradical saturated or unsaturated, linear, branched or cyclic hydrocarbon group that may contain 0 to 5 heteroatoms selected from O, N, S and that includes 0 to 18 carbon atoms, a is 0 or 1, f is an integer from 2 to 1000, n, m is an integer from 1 to 10, and x, y, z each represents 0 or an integer, the sum of which should range between 1 and 10000, with the proviso that, if x is larger 0, y or z is smaller or equal x, preferably smaller or equal 0.05 times x, and especially preferred 0.02 times x. The invention also relates to the use of arizidinosilicones.
摘要翻译：通式（1）的亚氮烷硅氧烷，其中R1表示H，C1-C12烷基，C2-C12烯基，C2-C12炔基，C7-C15烷芳基，C7-C15芳烷基，C3-C12环烷基，这些基团可以被 Cl或F部分，完全或以混合的方式和/或可以含有0至5个选自O，N，S的杂原子，R 2表示选自R 1和/或R 4的基团，R 3表示SiR 13或SiR 12 R 4，其中R 4表示式（2），A表示可以含有0至5个选自O，N，S的杂原子的（n + 1）基饱和，不饱和或芳族，直链，支链或环状的烃基，其包括1至 18个碳原子，B选自O，S，NR1，D选自C（O）O，C（O）NR1，C（O），C（O）C（O），C（O））m（C（O），C（S）NR1，CH2，E表示可以含有0至5个选自O，N，S的杂原子的二价饱和或不饱和的直链，支链或环状烃基， 18个碳原子，a为0或1，f为整数从2到1000，n，m是1至10的整数，x，y，z各自表示0或整数，其总和应在1和10000之间，条件是如果x大于0 ，y或z小于或等于x，优选小于或等于0.05倍×，特别优选0.02倍×。本发明还涉及三氮杂的使用。

3. 发明授权

US06677393B1 Silicon-based impression compounds with improved non-sag properties 有权
标题翻译：具有改善的非凹陷性能的硅基印模化合物
公开(公告)号：US06677393B1
公开(公告)日：2004-01-13
申请号：US09937911
申请日：2001-10-01
申请人： Joachim Zech , Erich Wanek
发明人： Joachim Zech , Erich Wanek
IPC分类号： C08K506
CPC分类号： A61K6/10
摘要： The invention relates to silicone-based addition-crosslinking impression material, containing (a) organopolysiloxanes with at least two unsaturated groups in the molecule, (b) organohydrogen polysiloxanes with at least three Si—H groups in the molecule, (c) optionally, organopolysiloxanes without reactive groups, (d) platinum catalyst, (e) optionally, hydrophilizing agent, (f) filler, (g) optionally, further customary additives, auxiliaries and dyes, characterized in that it contains, as component (h), polyalkylene oxide and/or its derivatives with an average molar mass of Mw>1000 at the rate of 0.001 to 1.0 wt.-% relative to the total mass of the cured material.
摘要翻译：本发明涉及基于硅氧烷的加成交联印模材料，其包含（a）在分子中具有至少两个不饱和基团的有机聚硅氧烷，（b）分子中具有至少三个Si-H基团的有机氢聚硅氧烷，（c）没有反应性基团的有机聚硅氧烷，（d）铂催化剂，（e）任选的亲水剂，（f）填料，（g）任选的另外的常规添加剂，助剂和染料，其特征在于，其作为组分（h）含有聚亚烷基氧化物和/或其衍生物，其平均摩尔质量Mw> 1000，相对于固化材料的总质量为0.001至1.0重量％。

4. 发明授权

US06894144B1 Two-constituent elastomer materials based on alkyl aziridine comprising a catalyst constituent that contains a boric acid complex 失效
标题翻译：基于烷基氮丙啶的双组分弹性体材料，其包含含有硼酸络合物的催化剂成分
公开(公告)号：US06894144B1
公开(公告)日：2005-05-17
申请号：US10070376
申请日：2000-09-01
申请人： Joachim Zech , Gunther Eckhardt , Cornelia Führer , Bernd Gangnus , Andreas Rombach , Oswald Gasser , Thomas Klettke , Erich Wanek
发明人： Joachim Zech , Gunther Eckhardt , Cornelia Führer , Bernd Gangnus , Andreas Rombach , Oswald Gasser , Thomas Klettke , Erich Wanek
IPC分类号： A61C11/00 , A61K6/00 , A61K6/087 , A61K6/10 , C08G73/02 , C08G73/04 , C08K5/55 , C08L71/02 , C08G79/38
CPC分类号： C08G73/0213 , A61K6/10 , C08L71/00
摘要： The invention relates to elastomer materials based on N-alkylaziridino compounds with a base component which contains the aziridino compounds and with a catalyst component which contains at least one acid-acting compound, both components being mixed before use, characterized in that, as acid-acting compound of the catalyst component, one or more boric acid complexes are used which can be obtained by reaction of boric acid and/or a boric acid derivative with at least one OH-functional compound, the OH functions being able to be present wholly or partly protected, and this reaction being carried out either as an upstream reaction between boric acid and/or a boric acid derivative and at least one such OH-functional compound or during or after the preparation of the catalyst component or by mixing the catalyst component with the base component which then contains at least one OH-functional compound. The elastomer materials are preferably used as dental impression materials, bite-registration materials and doubling materials.
摘要翻译：本发明涉及基于N-烷基氮丙啶基化合物的弹性体材料，其基质成分含有氮丙啶基化合物，以及含有至少一种酸作用化合物的催化剂组分，两种组分在使用前混合，其特征在于，使用催化剂组分的一种或多种硼酸络合物，其可以通过使硼酸和/或硼酸衍生物与至少一种OH官能化合物反应而获得，OH官能团可以全部存在部分保护，并且该反应作为硼酸和/或硼酸衍生物与至少一种这样的OH官能化合物之间的上游反应进行，或者在制备催化剂组分期间或之后进行，或者通过将催化剂组分与该基础组分然后含有至少一种OH官能化合物。弹性体材料优选用作牙科印模材料，咬合配准材料和加倍材料。

5. 发明授权

US5750589A Hydrophilated dental impression compounds 失效
标题翻译：亲水化牙印模化合物
公开(公告)号：US5750589A
公开(公告)日：1998-05-12
申请号：US646272
申请日：1996-05-16
申请人： Joachim Zech , Erich Wanek , Gunther Lechner , Peter Bissinger
发明人： Joachim Zech , Erich Wanek , Gunther Lechner , Peter Bissinger
IPC分类号： A61K6/10 , C07F7/08 , C08G65/336
CPC分类号： A61K6/10 , C08G65/336
摘要： The present invention relates to dental impression compounds which contain as hydrophilation agent 0.1 to 10 wt.-%, relative to the total weight of the compound, of a polyether carbosilane.
摘要翻译： PCT No.PCT / EP95 / 03638 Sec。 371日期：1996年5月16日 102（e）日期1996年5月16日PCT提交1995年9月15日PCT公布。公开号WO96 / 08230 PCT 日期：1996年3月21日本发明涉及作为亲水化剂的相对于化合物的总重量为0.1〜10重量％的聚醚碳硅烷的牙印模化合物。

6. 发明授权

US07186758B2 Silicone-based dental impression compounds 有权
标题翻译：基于硅酮的印模化合物
公开(公告)号：US07186758B2
公开(公告)日：2007-03-06
申请号：US10473282
申请日：2002-03-28
申请人： Joachim Zech , Johann Fetz , Erich Wanek , Ingo Wagner
发明人： Joachim Zech , Johann Fetz , Erich Wanek , Ingo Wagner
IPC分类号： C08K5/01
CPC分类号： C08L83/04 , A61K6/0073 , C08G77/12 , C08G77/20 , C08K5/5425 , C08L2666/26 , C08L2666/54 , A61K6/10
摘要： The invention relates to a two-component addition-cured silicon impression compound, comprising the following when both components are mixed: (a) between 1 and 35 wt. % of at least one organopolysiloxane comprising at least two unsaturated groups in the molecule; (b) between 1 and 10 wt. % of at least one organohydrogenpolysiloxane comprising at least two SiH groups in the molecule; (c) between 0.00005 and 0.05 wt. % of at least one platinum catalyst, calculated as elementary platinum; (d) between 4 and 10 wt. % of at least one liquid paraffin or at least one white mineral oil, or of a mixture of at least one liquid paraffin and at least one white mineral oil; (e) between 50 and 90 wt. % of at least one filler, each respective percentage relating to the total weight of the silicon impression compound. According to the invention, one of the components before being mixed with the other component has a Brookfield viscosity ranging between 800 and 2000 Pa*s. The invention is characterized in that the silicon impression compound, when mixed, has a consistency stipulated by ISO 4823 of less then or equal to 35 mm.
摘要翻译：本发明涉及双组分加成固化硅印模化合物，当两种组分混合时，其包含以下物质：（a）1至35重量％％的至少一种在分子中包含至少两个不饱和基团的有机聚硅氧烷; （b）1〜10wt。％的至少一种在分子中包含至少两个SiH基团的有机氢聚硅氧烷; （c）0.00005至0.05wt。至少一种铂催化剂的％，按铂计算; （d）4至10wt。％的至少一种液体石蜡或至少一种白色矿物油，或至少一种液体石蜡和至少一种白色矿物油的混合物; （e）50-90wt。％的至少一种填料，各自的百分比与硅印模化合物的总重量有关。根据本发明，与其他组分混合之前的组分之一具有在800和2000Pa * s之间的布氏粘度。本发明的特征在于，硅印模化合物在混合时具有ISO 4823规定的小于或等于35mm的稠度。

7. 发明授权

US6121362A Silicone-based impression material 失效
标题翻译：硅胶印模材料
公开(公告)号：US6121362A
公开(公告)日：2000-09-19
申请号：US116255
申请日：1998-07-16
申请人： Erich Wanek , Joachim Zech
发明人： Erich Wanek , Joachim Zech
IPC分类号： A61K6/10 , C08K3/34
CPC分类号： A61K6/10
摘要： A monophase silicone impression composition which crosslinks by an addition reaction, includes the following components:(a) organopolysiloxanes with at least two unsaturated groups in the molecule,(b) organohydrogenpolysiloxanes with at least 2 SiH groups in the molecule,(c) optionally, organopolysiloxane without reactive groups,(d) a platinum catalyst,(e) a hydrophilizing agent,(f) diatomaceous earth,(g) a filler, and(h) optionally further customary additives, auxiliaries and dyestuffs, the amount of component (f) is 8 to 25 wt. %, based on the total weight of the cured composition, and the composition has a Shore hardness A to be determined in accordance with DIN 53505, of less than 45--measured after 30 minutes--, and a viscosity, determined in accordance with ISO 4823, of 31 to 39 mm. The impression composition is suitable for the production of provisional bridges and crowns. It replaces the alginate compositions used hitherto for this purpose and overcomes the disadvantages associated with these compositions.
摘要翻译：（a）分子中具有至少两个不饱和基团的有机聚硅氧烷，（b）分子中具有至少2个SiH基团的有机氢聚硅氧烷，（c）任选地，所述单分子硅氧烷印模组合物通过加成反应交联，没有反应性基团的有机聚硅氧烷，（d）铂催化剂，（e）亲水剂，（f）硅藻土，（g）填料和（h）任选的其它常规添加剂，助剂和染料，组分（f ）为8〜25重量％。％，基于固化组合物的总重量，组合物具有根据DIN 53505测定的肖氏硬度A，其在30分钟后测量小于45-，粘度根据ISO 4823测定，31至39毫米。印象组合适用于生产临时桥梁和牙冠。它代替迄今为止用于此目的的藻酸盐组合物，并克服了与这些组合物相关的缺点。

8. 发明授权

US5849812A Addition-crosslinking polyether impression material 失效
标题翻译：加成交联聚醚印模材料
公开(公告)号：US5849812A
公开(公告)日：1998-12-15
申请号：US852904
申请日：1997-05-09
申请人： Joachim Zech , Erich Wanek
发明人： Joachim Zech , Erich Wanek
IPC分类号： A61K6/10 , C08G65/336 , C08L71/02 , C08L83/05 , C08L83/07 , C08L71/00 , A61C9/00 , C08K5/24
CPC分类号： A61K6/10 , C08G65/336 , C08L71/02
摘要： An addition-crosslinking polyether impression material is described which ntains (a) at least one polyether which has at least two optionally substituted vinyl and/or allyl end-groups, (b) an SiH component, (c) at least one platinum catalyst, (d) optionally usual additives, and (e) an organopolysiloxane with at least two alkenyl groups. The impression material has in at least two-part form of administration in which the components (b) and (c) are spatially separated from each other a particularly satisfactory storage stability and has good mechanical properties in the cured state.
摘要翻译：描述了一种加成交联聚醚印模材料，其包含（a）至少一种具有至少两个任选取代的乙烯基和/或烯丙基端基的聚醚，（b）SiH组分，（c）至少一种铂催化剂，（d）任选通常的添加剂，和（e）具有至少两个烯基的有机聚硅氧烷。印模材料具有至少两部分给药形式，其中组分（b）和（c）在空间上彼此分离，具有特别令人满意的储存稳定性，并且在固化状态下具有良好的机械性能。

9. 发明授权

US5147904A Open-pored moldings, a process for their production and use thereof 失效
标题翻译：开放式模具，其生产和使用过程
公开(公告)号：US5147904A
公开(公告)日：1992-09-15
申请号：US570808
申请日：1990-08-22
申请人： Peter Jochum , Oswald Gasser , Manfred Holupirek , Erich Wanek , Rainer Guggenberger , Klaus-Peter Stefan , Klaus Ellrich
发明人： Peter Jochum , Oswald Gasser , Manfred Holupirek , Erich Wanek , Rainer Guggenberger , Klaus-Peter Stefan , Klaus Ellrich
IPC分类号： A61L26/00 , A61L27/00 , A61L27/44 , C04B28/28 , C04B38/02 , C08J3/24 , C08J9/00 , C08K3/34 , C08K3/40 , C08L33/02
CPC分类号： C04B28/28 , A61L27/446 , C04B2111/00836
摘要： Open-pored moldings containing the product of the foaming and setting of (a) an aluminum fluorosilicate glass, (b) at least one polycarboxylic acid with an average molecular weight of >500, (c) a foaming agent, other than carbonates and/or hydrogen-carbonates, (d) optionally a chelating agent and (e) water, are suitable in particular as bone substitute material.Production is carried out by homogeneously mixing (a), (b), (c), optionally (d), and (e), then foaming, shaping and setting.
摘要翻译：含有（a）氟硅酸铝玻璃，（b）至少一种平均分子量> 500的多元羧酸的发泡和固化产物的开孔模制品，（c）不同于碳酸酯和/ 或碳酸氢盐，（d）任选的螯合剂和（e）水，特别适合作为骨代用材料。通过均匀混合（a），（b），（c），任选（d）和（e））进行生产，然后进行发泡，成型和固化。

10. 发明授权

US08415266B2 Catalyst constituent 有权
标题翻译：催化剂成分
公开(公告)号：US08415266B2
公开(公告)日：2013-04-09
申请号：US10257760
申请日：2001-04-12
申请人： Gunther Eckhardt , Erich Wanek , Bernd Kuppermann
发明人： Gunther Eckhardt , Erich Wanek , Bernd Kuppermann
IPC分类号： B01J31/00 , C08G18/48
CPC分类号： A61K6/10 , C08G65/333
摘要： The invention relates to catalyst components, containing: (A) at least one Brönsted acid, (B) water, (C) at least one antacid-acting compound from the group consisting of the oxides, hydroxides, carbonates and/or carboxylates of the elements aluminum, chromium, copper, germanium, manganese, lead, antimony, tin, tellurium, titanium and/or zinc, (D) optionally at least one inert diluent, (E) optionally at least one modifier, the mixture of one part by weight of the catalyst component with three parts by weight bisaziridino polyether with an average imino equivalent mass of 3100, preparable from a polyetherdiol which comprises ethylene oxide and tetrahydrofuran units in the molar ratio 1:3.5 solidifying within 0.5 to 20 minutes to a solid elastomer material which has a shore A hardness of at least 20 according to DIN 53505 after 24 hours' storage time at room temperature.
摘要翻译：本发明涉及催化剂组分，其包含：（A）至少一种布朗斯台德酸，（B）水，（C）至少一种抗酸作用化合物，其来自所述氧化物，氢氧化物，碳酸酯和/或羧酸盐元素铝，铬，铜，锗，锰，铅，锑，锡，碲，钛和/或锌，（D）任选地至少一种惰性稀释剂，（E）任选的至少一种改性剂，催化剂组分的重量为3重量份平均亚氨基当量为3100的双氮茚地基聚醚，其可由包含环氧乙烷和四氢呋喃单元的聚醚二醇制备，摩尔比为1:3.5，在0.5至20分钟内固化成固体弹性体材料其在室温下24小时储存时间后根据DIN 53505具有至少20的肖氏硬度。

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