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1. 发明授权

US5288787A Emulsion polymers 失效
标题翻译：乳液聚合物
公开(公告)号：US5288787A
公开(公告)日：1994-02-22
申请号：US714317
申请日：1991-06-10
申请人： Gunter Sackmann , Wolfgang Henning , Joachim Probst , Joachim Konig , Heinz Baumgen
发明人： Gunter Sackmann , Wolfgang Henning , Joachim Probst , Joachim Konig , Heinz Baumgen
IPC分类号： C08F2/26 , C08F220/12 , D21H17/34 , C08K3/20
CPC分类号： D21H17/34 , C08F2/26 , C08F220/12
摘要： Emulsion polymers obtainable by emulsifying a mixture consisting ofA) 5 to 95 % by weight of at least one monomer from the series consisting of acrylonitrile, methacrylonitrile, optionally substituted styrene, vinyl carboxylate andB) 5 to 95 % by weight of acrylic and/or methacrylic esters,the sum of components A)+B) being 100% by weight, in the presence of an aqueous solution or dispersion of an anionically modified polyurethane, preferably containing --SO.sub.3.sup.-Me.sup.+ and/or -COO.sup.- Me.sup.+ groups (Me.sup.+ =cation, preferably H.sup.+, Na.sup.+, K.sup.+, Li.sup.+, NH.sub.4.sup.+ or a substituted ammonium ion), and subjecting the resulting emulsion to a polymerization initiated by free radicals.The emulsion polymers produced are preferably used as surface sizing agents for paper.
摘要翻译：通过乳化由A）5-95重量％的至少一种由丙烯腈，甲基丙烯腈，任选取代的苯乙烯，乙烯基羧酸酯组成的系列中的至少一种单体的混合物得到的乳液聚合物和B）5-95重量％的丙烯酸和/ 或甲基丙烯酸酯，组分A）+ B的总和）为100重量％，在阴离子改性聚氨酯的水溶液或分散体存在下，优选含有-SO 3 Me +和/或-COO-Me +基团（Me + =阳离子，优选H +，Na +，K +，Li +，NH 4 +或取代的铵离子），并将所得乳液进行由自由基引发的聚合。所生产的乳液聚合物优选用作纸的表面施胶剂。

2. 发明授权

US4904727A Emulsion polymers 失效
标题翻译：乳液聚合物
公开(公告)号：US4904727A
公开(公告)日：1990-02-27
申请号：US318045
申请日：1989-03-02
申请人： Joachim Probst , Wolfgang Henning , Heinz Baumgen , Joachim Konig
发明人： Joachim Probst , Wolfgang Henning , Heinz Baumgen , Joachim Konig
IPC分类号： B01F17/52 , C08F2/28 , D21H17/28 , D21H17/35 , D21H17/37 , D21H17/57
CPC分类号： D21H17/57 , C08F2/28 , D21H17/28 , D21H17/35 , D21H17/37
摘要： Emulsion polymers obtained by emulsifying a monomer mixture of(A) 5-95% by weight of acrylonitrile, methacrylonitrile and/or substituted or unsubstituted styrene and(B) 5-95% by weight of acrylic and/or methacrylic acid esters containing 1-12 carbon atoms in the alcohol group,the sum of components (A)+(B) amounting to 100% by weight, in the presence of an aqueous solution or dispersion of a water soluble or water dispersible, cationically modified polyurethane, and subjecting the resulting emulsion to a radically initiated polymerization. The emulsion polymers are preferably used as paper sizes or in paper sizes together with conventional additives.
摘要翻译：通过将（A）5-95重量％的丙烯腈，甲基丙烯腈和/或取代或未取代的苯乙烯和（B）5-95重量％的丙烯酸和/或甲基丙烯酸酯的单体混合物乳化而得到的乳液聚合物，醇基中的12个碳原子，在水溶液或水分散性阳离子改性聚氨酯的水溶液或分散体的存在下，组分（A）+（B）的总和为100重量％，并对所得乳液进行自由基引发的聚合。乳液聚合物优选与纸张尺寸或纸张尺寸一起用于常规添加剂。

3. 发明授权

US4806591A Cationic sizing agents for paper 失效
标题翻译：阳离子上胶剂纸
公开(公告)号：US4806591A
公开(公告)日：1989-02-21
申请号：US921173
申请日：1986-10-20
申请人： Joachim Probst , Heinz Baumgen , Bruno Bomer , Joachim Konig , Renke Mottweiler
发明人： Joachim Probst , Heinz Baumgen , Bruno Bomer , Joachim Konig , Renke Mottweiler
IPC分类号： C08F2/28 , C08F2/24 , C08F257/02 , D21H17/35 , D21H17/37 , D21H17/45 , C08L33/20
CPC分类号： D21H17/455 , C08F2/24 , C08F257/02 , D21H17/35 , D21H17/37
摘要： Cationic sizing agents for paper, obtainable by a process in which a water-soluble cationic terpolymer compound, built up in a chemically uniform manner, of (a) 7 to 40% by weight of N,N-dimethylaminoethyl acrylate and/or methacrylate, (b) 40 to 80% by weight of styrene and (c) 4 to 50% by weight of acrylonitrile, the sum of components (a) to (c) always being 100% by weight and at least 10% of the dimethylamino groups of the terpolymer being quaternized with monoepoxides, with the exception of epihalogenohydrins, and the remainder being protonated, is dissolved in an aqueous medium and, in the presence of 10 to 70% by weight--based on the following monomer mixture--of this emulsifier, (d) 5 to 95% by weight of acrylonitrile, meth-acrylonitrile or styrene or mixtures thereof and (e) 5 to 95% by weight of acrylic acid ester and/or methacrylic acid ester with 1 to 12 C atoms in the alcohol radical--the sum of components (d) and (e) always being 100% by weight--are emulsified and the emulsion thus obtained is subjected to emulsion polymerization, initiated by free radicals, at temperatures of 20.degree. to 150.degree. C.
摘要翻译：可通过以下方法获得的阳离子上胶剂：其中以（a）7〜40重量％的N，N-二甲基氨基乙基丙烯酸酯和/或甲基丙烯酸酯组成的以化学均匀的方式构成的水溶性阳离子三元共聚物，（b）40至80重量％的苯乙烯和（c）4至50重量％的丙烯腈，组分（a）至（c）的总和总是100重量％，并且至少10重量％的二甲基氨基的三元共聚物被单过氧化物季铵化，除了表卤代醇，其余的被质子化，溶解在水性介质中，并且在该乳化剂的基于下列单体混合物的10至70重量％的存在下，（d）5至95重量％的丙烯腈，甲基丙烯腈或苯乙烯或其混合物，和（e）5至95重量％的醇基中具有1至12个C原子的丙烯酸酯和/或甲基丙烯酸酯组分（d）和（e）总是为100重量％的总和被乳化和乳液由此获得的乳液聚合在20℃至150℃的温度下由自由基引发。

4. 发明授权

US5314721A Process for sizing paper 失效
标题翻译：纸张尺寸的过程
公开(公告)号：US5314721A
公开(公告)日：1994-05-24
申请号：US000751
申请日：1993-01-05
申请人： Michael Muller , Joachim Probst , Heinrich Alberts , Joachim Konig , Heinz Baumgen , Fritz Puchner
发明人： Michael Muller , Joachim Probst , Heinrich Alberts , Joachim Konig , Heinz Baumgen , Fritz Puchner
IPC分类号： C08F2/22 , B01F17/52 , C08F2/28 , D21H17/56 , D21H21/16 , D21H27/00 , B05D3/02
CPC分类号： C08F2/28
摘要： The new vinyl polymer dispersions are obtainable by free radical polymerisation of olefinically unsaturated monomers in the presence of a cationic polyamidoamine which has been rendered hydrophobic, and can be used as sizing agents for paper which are distinguished, in particular, by their shear, electrolyte, heat and storage stability.
摘要翻译：新的乙烯基聚合物分散体可以通过烯属不饱和单体的自由基聚合在阳离子聚酰胺胺存在下获得，该阳离子聚酰胺胺已经变得疏水，并且可以用作纸的上浆剂，特别是其剪切，电解质，储热稳定。

5. 发明授权

US4670100A Aqueous solutions or dispersions of polyisocyanate addition products, a process for their preparation, and their use as coating compounds or as sizing agents for paper 失效
标题翻译：多异氰酸酯加成产物的水溶液或分散体，它们的制备方法以及它们作为涂料化合物或作为纸张施胶剂的用途
公开(公告)号：US4670100A
公开(公告)日：1987-06-02
申请号：US876526
申请日：1986-06-19
申请人： Wolfgang Henning , Walter Meckel , Ulrich Beck , Heinz Baumgen , Joachim Konig
发明人： Wolfgang Henning , Walter Meckel , Ulrich Beck , Heinz Baumgen , Joachim Konig
IPC分类号： C08G18/00 , C08G18/08 , C08G18/38 , C08G18/50 , C08G18/78 , C09D175/08 , D06M15/564 , D21H17/46 , D21H17/57 , C08L75/00 , D21H3/48
CPC分类号： C08G18/7818 , C08G18/0814 , C08G18/3823 , C08G18/5042 , D21H17/57
摘要： The present invention relates to aqueous solutions or dispersions of polyisocyanate addition products which contain about 2 to 300 milliequivalents per 100 g of solids of chemically incorporated ternary or quaternary ammonium groups and up to about 25% by weight, based on solids, of chemically incorporated ethylene oxide units, --CH.sub.2 --CH.sub.2 --O--, present within a polyether chain, the ternary or quaternary ammonium groups and the ethylene oxide units being present in an amount sufficient to guarantee the solubility or dispersibility of the polyisocyanate addition products in water, characterized in that the polyisocyanate addition products have segments incorporated in the polymer chain which correspond to the following general formula ##STR1## in an amount of about 0.1 to 20% by weight based on the above formula, but excluding the weight of R.The present invention also relates to a process for the production of polyisocyanate addition products and to their use as coating agents for flexible or inflexible substrates and as sizing agents for paper or for the production sizing agents for paper.
摘要翻译：本发明涉及多异氰酸酯加成产物的水溶液或分散体，其含有约2至300毫当量/ 100g化学掺入的三元或季铵基团的固体，至多约25重量％，基于固体，化学结合的乙烯存在于聚醚链内的氧化单元，-CH 2 -CH 2 -O-，三元或季铵基团和环氧乙烷单元的存在量足以保证多异氰酸酯加成产物在水中的溶解度或分散性，其特征在于多异氰酸酯加成产物具有引入聚合物链中的链段，其对应于下列通式（IMAGE），其量为约0.1至20重量％，基于上式，但不包括R的重量。本发明还涉及用于制备多异氰酸酯加成产物的方法及其作为柔性涂料的用途或不灵活的基材和作为纸张的上浆剂或用于纸的生产施胶剂。

6. 发明授权

US4931510A Polymers from ethylenic monomers 失效
标题翻译：乙烯单体的聚合物
公开(公告)号：US4931510A
公开(公告)日：1990-06-05
申请号：US312089
申请日：1989-02-17
申请人： Gunter Sackmann , Joachim Konig , Heinz Baumgen
发明人： Gunter Sackmann , Joachim Konig , Heinz Baumgen
IPC分类号： C08F210/10 , B01F17/52 , C08F2/24 , C08F8/00 , C08F267/10 , D21H17/34 , D21H19/20 , D21H21/16
CPC分类号： D21H21/16 , C08F267/10 , D21H17/34
摘要： Polymers obtainable by subjecting at least one monomer, polymerizable by free radicals, to a free-radical emulsion polymerization in the presence of a polymer of the formulae I and/or II ##STR1## in which M, n, R, R.sup.1, R.sup.2, x and y have the meanings mentioned in the description, the use of the polymers obtained for surface-sizing of paper or paper-like materials and also novel polymers of the formulae I and/or II.
摘要翻译：聚合物可以通过使至少一种可自由基聚合的单体在式I和/或II的聚合物存在下进行自由基乳液聚合，其中M，n，R R1，R2，x和y具有说明书中提到的含义，用于纸或纸状材料表面施胶的聚合物的用途，以及式I和/或II的新型聚合物。

7. 发明授权

US4418175A Cationic sizing agents for paper 失效
标题翻译：阳离子上胶剂纸
公开(公告)号：US4418175A
公开(公告)日：1983-11-29
申请号：US329721
申请日：1981-12-11
申请人： Joachim Probst , Gunter Kolb , Friedhelm Muller , Heinz Baumgen
发明人： Joachim Probst , Gunter Kolb , Friedhelm Muller , Heinz Baumgen
IPC分类号： D21H19/20 , C08F8/44 , D21H17/35 , D21H17/37 , D21H17/45 , C08F220/46
CPC分类号： D21H17/455 , C08F8/44 , D21H17/35 , D21H17/37
摘要： The aqueous solution of a statistical terpolymer containing quaternized amino groups and having a regular chemical structure of(a) from 8 to 20%, by weight, of N,N-dimethylaminoethyl acrylate and/or N,N-dimethylaminoethyl methacrylate;(b) from 45 to 80%, by weight, of styrene; and(c) from 8 to 35%, by weight, of acrylonitrile;the sum of (a) to (c) being 100%, by weight, and at least 10% of the dimethylamino groups of the terpolymer being quaternized and the remainder protonated is suitable as cationic paper sizing agent.
摘要翻译：具有季铵化氨基的统计三元共聚物的水溶液，其具有规则的化学结构（a）8至20重量％的丙烯酸N，N-二甲基氨基乙酯和/或甲基丙烯酸N，N-二甲基氨基乙酯; （b）45〜80重量％的苯乙烯; 和（c）8至35重量％的丙烯腈; （a）至（c）的总和为100重量％，并且至少10％的三元共聚物的二甲基氨基被季铵化，其余被质子化适合作为阳离子纸上胶剂。

8. 发明授权

US4771097A Tub sizes for paper 失效
标题翻译：纸的尺寸
公开(公告)号：US4771097A
公开(公告)日：1988-09-13
申请号：US26340
申请日：1987-03-16
申请人： Gunter Sackmann , Ulrich Beck , Joachim Konig , Heinz Baumgen , Klaus-Dieter Albrecht
发明人： Gunter Sackmann , Ulrich Beck , Joachim Konig , Heinz Baumgen , Klaus-Dieter Albrecht
IPC分类号： C08F8/44 , C08F8/14 , C08L35/00 , D21H17/43 , D21H19/20 , D21H21/16 , C08L35/02
CPC分类号： C08F8/14 , D21H17/43 , D21H21/16
摘要： Tub sizes for paper, containing aqueous or aqueous-alcoholic alkali metal, amine or ammonium salt solutions of copolymers of maleic anhydride and diisobutylene and, if appropriate, a vinyl monomer of the formula ##STR1## in which R designates H, --CH.sub.3, --C.sub.2 H.sub.5, --OR.sub.2, --OCOCH.sub.3, ##STR2## --CH.sub.2 OH or --CH.sub.2 --O--COCH.sub.3, R.sub.1 designates H or --CH.sub.3 andR.sub.2 designates alkyl,the anhydride groups of the copolymers being bis-esterified to the extent of about 3 to about 20 mol %, relative to the anhydride groups, with aliphatic monoalcohols having 1 to 12 C atoms.
摘要翻译：用于含有水性或含水醇碱金属的纸的桶尺寸，马来酸酐和二异丁烯的共聚物的胺或铵盐溶液，以及如果合适的话，其中R表示H，-CH 3， C 2 H 5，-OR 2，-OCOCH 3，-CH 2 OH或-CH 2 -O-COCH 3，R 1表示H或-CH 3，R 2表示烷基，所述共聚物的酸酐基团被双酯化至约3至约相对于酸酐基团为20摩尔％，具有1至12个碳原子的脂肪族一元醇。

9. 发明授权

US5258466A Paper size 失效
标题翻译：纸张尺寸
公开(公告)号：US5258466A
公开(公告)日：1993-11-02
申请号：US713923
申请日：1991-06-12
申请人： Gunter Sackmann , Joachim Konig , Fritz Puchner , Heinz Baumgen
发明人： Gunter Sackmann , Joachim Konig , Fritz Puchner , Heinz Baumgen
IPC分类号： C08F2/24 , C08F2/26 , C08F267/10 , D21H17/42 , C08F20/10 , C08F22/06
CPC分类号： D21H17/42 , C08F267/10
摘要： Emulsion polymers which are prepared by free-radical polymerisation of monomers in the presence ofa) polymers of the formulae ##STR1## wherein the radicals have the meanings given in the description, and b) low-molecular anionic emulsifiers,are outstandingly suitable as surface sizes for paper. They are distinguished by a low tendency to foaming and by a wide application spectrum.
摘要翻译：通过在a）式（I）的聚合物（II）的存在下，通过单体的自由基聚合制备的乳液聚合物，其中基团具有在说明书中给出的含义，和b）分子阴离子乳化剂，非常适合作为纸张的表面尺寸。它们的特征在于低发泡趋势和广泛的应用范围。

10. 发明授权

US5013794A Polymers of diisobutylene-sulfonate alkane maleic acid derivatives 失效
标题翻译：二异丁烯磺酸烷烃马来酸衍生物的聚合物
公开(公告)号：US5013794A
公开(公告)日：1991-05-07
申请号：US475623
申请日：1990-02-06
申请人： Gunter Sackmann , Joachim Konig , Heinz Baumgen
发明人： Gunter Sackmann , Joachim Konig , Heinz Baumgen
IPC分类号： C08F267/10 , D21H17/34 , D21H21/16
CPC分类号： C08F267/10 , D21H17/34 , D21H21/16
摘要： Polymers obtainable by subjecting at least one monomer, polymerizable by free radicals, to a free-radical emulsion polymerization in the presence of a polymer of the formulae I and/or II ##STR1## in which M, n, R, R.sup.1, R.sup.2, x and y have the meanings mentioned in the description, the use of the polymers obtained for surface-sizing of paper or paper-like materials and also novel polymers of the formulae I and/or II.
摘要翻译：聚合物可以通过使至少一种可自由基聚合的单体在式I和/或II的聚合物存在下进行自由基乳液聚合，其中M，n，R R1，R2，x和y具有说明书中提到的含义，用于纸或纸状材料表面施胶的聚合物的用途，以及式I和/或II的新型聚合物。

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