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1. 发明申请

US20100272939A1 POLYOLEFIN COMPOSITIONS HAVING IMPROVED OPTICAL AND MECHANICAL PROPERTIES 有权
标题翻译：具有改进的光学和机械性能的聚烯烃组合物
公开(公告)号：US20100272939A1
公开(公告)日：2010-10-28
申请号：US12733774
申请日：2008-08-26
申请人： Joachim Fiebig , Markus Gahleitner , Pirjo Jääskeläinen , Bo Malm , Tonja Schedenig
发明人： Joachim Fiebig , Markus Gahleitner , Pirjo Jääskeläinen , Bo Malm , Tonja Schedenig
IPC分类号： C08L23/14 , B32B1/08
CPC分类号： C08F210/06 , C08J5/18 , C08J2323/14 , C08L23/142 , C08L2205/02 , Y10T428/139 , C08F4/6546 , C08F4/651 , C08L2666/06 , C08F210/16 , C08F2500/12 , C08F2500/17 , C08F2500/11 , C08F2500/04
摘要： Novel polyolefin compositions comprising (A) a first propylene-ethylene random copolymer and (B) a second propylene-ethylene random copolymer, wherein the polyolefin composition has an ethylene content CMAB of 1-10 wt % and an MFR(AB) of 3-20 g/10 min with the proviso that CMAB>CMA and MFR(A)/MFR(AB)>1.45 and where the polyolefin composition further has a randomness R of the ethylene distribution in the polymer chain of 0.945. Articles made from the novel polyolefin compositions have excellent optical properties even after subjecting them to a heat sterilisation step.
摘要翻译：新型聚烯烃组合物，其包含（A）第一丙烯 - 乙烯无规共聚物和（B）第二丙烯 - 乙烯无规共聚物，其中所述聚烯烃组合物的乙烯含量CMAB为1-10重量％，MFR（AB）为3- 20g / 10min，条件是CMAB> CMA，MFR（A）/ MFR（AB）> 1.45，聚烯烃组合物中聚合物链中乙烯分布的随机度R为0.945。由新型聚烯烃组合物制成的制品即使经过加热灭菌步骤也具有优异的光学性能。

2. 发明授权

US08288481B2 Polyolefin compositions having improved optical and mechanical properties 有权
标题翻译：具有改善的光学和机械性能的聚烯烃组合物
公开(公告)号：US08288481B2
公开(公告)日：2012-10-16
申请号：US12733774
申请日：2008-08-26
申请人： Joachim Fiebig , Markus Gahleitner , Pirjo Jääskeläinen , Bo Malm , Tonja Schedenig
发明人： Joachim Fiebig , Markus Gahleitner , Pirjo Jääskeläinen , Bo Malm , Tonja Schedenig
IPC分类号： C08L23/04 , C08L23/10
CPC分类号： C08F210/06 , C08J5/18 , C08J2323/14 , C08L23/142 , C08L2205/02 , Y10T428/139 , C08F4/6546 , C08F4/651 , C08L2666/06 , C08F210/16 , C08F2500/12 , C08F2500/17 , C08F2500/11 , C08F2500/04
摘要： Novel polyolefin compositions comprising (A) a first propylene-ethylene random copolymer and (B) a second propylene-ethylene random copolymer, wherein the polyolefin composition has an ethylene content CMAB of 1-10 wt % and an MFR(AB) of 3-20 g/10 min with the proviso that CMAB>CMA and MFR(A)/MFR(AB)>1.45 and where the polyolefin composition further has a randomness R of the ethylene distribution in the polymer chain of ≧0.945. Articles made from the novel polyolefin compositions have excellent optical properties even after subjecting them to a heat sterilization step.
摘要翻译：新型聚烯烃组合物，其包含（A）第一丙烯 - 乙烯无规共聚物和（B）第二丙烯 - 乙烯无规共聚物，其中所述聚烯烃组合物的乙烯含量CMAB为1-10重量％，MFR（AB）为3- 20g / 10min，条件是CMAB> CMA，MFR（A）/ MFR（AB）> 1.45，聚烯烃组合物中聚合物链中乙烯分布的随机度R≥0.945。由新型聚烯烃组合物制成的制品即使经过加热灭菌步骤也具有优异的光学性能。

3. 发明授权

US07452953B2 Propylene random copolymer and process for the production thereof 失效
标题翻译：丙烯无规共聚物及其制备方法
公开(公告)号：US07452953B2
公开(公告)日：2008-11-18
申请号：US11836657
申请日：2007-08-09
申请人： Pirjo Jääskeläinen , Norbert Hafner , Päivi Pitkänen , Markus Gahleitner , Olli Tuominen , Wilfried Töltsch
发明人： Pirjo Jääskeläinen , Norbert Hafner , Päivi Pitkänen , Markus Gahleitner , Olli Tuominen , Wilfried Töltsch
IPC分类号： C08F210/16
CPC分类号： C08F297/083 , C08F10/00 , C08F210/06 , C08F210/16 , C08F297/08 , C08F4/6465 , C08F2/001 , C08F2500/12 , C08F2500/26 , C08F2500/17
摘要： The present invention relates to a process for preparing a propylene random copolymer comprising polymerization of propylene with a comonomer, said comonomer being ethylene or an α-olefin comprising at least four carbon atoms, in the presence of a catalyst in a multistage process comprising polymerization of propylene with a comonomer in a first reaction zone including at least one slurry reactor to give a first polymerization product, transferring said first product to a second reaction zone including at least one gas phase reactor and polymerizations of propylene with a comonomer in said gas phase reactor in the presence of said first polymerization product, wherein the temperature in the gas phase reactor is at least 10° C. higher than in the slurry reactor and to a polymer obtainable by this process. Furthermore, the invention relates to a propylene random copolymer prepared by copolymerization of propylene with a comonomer wherein the distribution of the comonomer determined according to the TREF method is multimodal, preferably bimodal, a propylene random copolymer prepared by copolymerization of propylene with a comonomer wherein the copolymer is having an elution interval determined according to the TREF method of 50° C. or more, a propylene random copolymer prepared by copolymerization of propylene with a comonomer, wherein the random copolymer is a unimodal polymer and the elution interval determined by the TREF method is given by the equation Y≦4.5·m+16 wherein Y is the elution interval in ° C. and m is the percentage of ethylene in the copolymer in wt. %, and to the use of such a copolymers for the production of a film, of an article by blow moulding or injection moulding, of a fiber or of a pipe.
摘要翻译：本发明涉及一种制备丙烯无规共聚物的方法，其包括丙烯与共聚单体的聚合，所述共聚单体是乙烯或包含至少四个碳原子的α-烯烃，在催化剂存在下以多阶段方法包括聚合丙烯与第一反应区中的共聚单体包括至少一个淤浆反应器以产生第一聚合产物，将所述第一产物转移到包含至少一个气相反应器的第二反应区，并且在所述气相反应器中聚合丙烯与共聚单体在所述第一聚合产物的存在下，其中气相反应器中的温度高于浆料反应器中的至少10℃，并且可通过该方法获得的聚合物。此外，本发明涉及通过丙烯与共聚单体共聚制备的丙烯无规共聚物，其中根据TREF法测定的共聚单体的分布是多峰的，优选双峰的，丙烯与共聚单体共聚制备的丙烯无规共聚物，其中，共聚物的洗脱间隔根据TREF法测定为50℃以上，通过丙烯与共聚单体共聚制备的丙烯无规共聚物，其中无规共聚物是单峰聚合物，并且通过TREF法测定的洗脱间隔由方程Y <= 4.5.m + 16给出，其中Y是以℃计的洗脱间隔，m是共聚物中乙烯的百分比。以及使用这种共聚物来制造纤维或管子的通过吹塑或注射成型的制品的薄膜，制品。

4. 发明授权

US07470756B2 Propylene random copolymer and process for the production thereof 有权
标题翻译：丙烯无规共聚物及其制备方法
公开(公告)号：US07470756B2
公开(公告)日：2008-12-30
申请号：US10482271
申请日：2002-06-26
申请人： Pirjo Jääskeläinen , Norbert Hafner , Päivi Pitkänen , Markus Gahleitner , Olli Tuominen , Wilfried Töltsch
发明人： Pirjo Jääskeläinen , Norbert Hafner , Päivi Pitkänen , Markus Gahleitner , Olli Tuominen , Wilfried Töltsch
IPC分类号： C08F2/02 , C08F2/06 , C08F2/14 , C08F2/34 , C08F210/06 , C08F210/16
CPC分类号： C08F297/083 , C08F10/00 , C08F210/06 , C08F210/16 , C08F297/08 , C08F4/6465 , C08F2/001 , C08F2500/12 , C08F2500/26 , C08F2500/17
摘要： The present invention relates to a process for preparing a propylene random copolymer comprising polymerisation of propylene with a comonomer, said comonomer being ethylene or an α-olefin comprising at least four carbon atoms, in the presence of a catalyst in a muiltistage process comprising polymerisation of propylene with a comonomer in a first reaction zone including at least one slurry reactor to give a first polymerisation product, transferring said first product to a second reaction zone including at least one gas phase reactor and polymerisations of propylene with a comonomer in said gas phase reactor in the presence of said first polymerisation product, wherein the temperature in the gas phase reactor is at least 10° C. higher than in the slurry reactor and to a polymer obtainable by this process. Furthermore, the invention relates to a propylene random copolymer prepared by copolymerisation of propylene with a comonomer wherein the distribution of the comonomer determined according to the TREF method is multimodal, preferably bimodal, a peopylene radom copolymer prepared by copolymerisation of propylene with a comonomer wherein the copolymer is having an elution interval determined according to the TREF method of 50° C. or more, a propylene random copolymer prepared by copolymerisation of propylene with a comonomer, wherein the random copolymer is a unimodal polymer and the elution interval determined by the TREF method is given by the equation Y≦4.5.m+16 wherein Y is the elution interval in ° C. and m is the percentage of ethylene in the copolymer in wt. %, and to the use of such a copolymers for the production of a film, of an article by blow moulding or injection moulding, of a fibre or of a pipe.
摘要翻译：丙烯无规共聚物的制备方法技术领域本发明涉及一种制备丙烯无规共聚物的方法，其包括丙烯与共聚单体的聚合，所述共聚单体是乙烯或包含至少四个碳原子的α-烯烃，在催化剂存在下，丙烯与第一反应区中的共聚单体包括至少一个浆料反应器以产生第一聚合产物，将所述第一产物转移到包含至少一个气相反应器的第二反应区和丙烯与所述气相反应器中的共聚单体聚合在所述第一聚合产物存在下，其中气相反应器中的温度高于浆料反应器中的至少10℃，并且可通过该方法获得的聚合物。此外，本发明涉及通过丙烯与共聚单体共聚制备的丙烯无规共聚物，其中根据TREF方法测定的共聚单体的分布是多峰的，优选双峰的，通过丙烯与共聚单体共聚制备的聚二苯基共聚物共聚物，其中共聚物具有根据TREF法测定的洗脱间隔为50℃以上，通过丙烯与共聚单体共聚制备的丙烯无规共聚物，其中无规共聚物是单峰聚合物，并且通过TREF方法测定的洗脱间隔由方程Y <= 4.5.m + 16给出，其中Y是以℃计的洗脱间隔，m是共聚物中乙烯的百分比。以及使用这种共聚物来制造纤维或管子的通过吹塑或注射成型的制品的薄膜，制品。

5. 发明授权

US08759452B2 Propylene composition with high stiffness and impact strength 有权
标题翻译：丙烯组合物具有高刚度和冲击强度
公开(公告)号：US08759452B2
公开(公告)日：2014-06-24
申请号：US13129511
申请日：2010-02-04
申请人： Markus Gahleitner , Bo Malm , Klaus Bernreitner , Juliane Braun
发明人： Markus Gahleitner , Bo Malm , Klaus Bernreitner , Juliane Braun
IPC分类号： C08J3/22 , C08F290/14 , C08L23/00 , C08F110/02
CPC分类号： C08F10/00 , C08F10/06 , C08F110/06 , C08F4/6543 , C08F4/6492 , C08F4/651 , C08F210/16 , C08F2500/04 , C08F2500/19 , C08F2500/12 , C08F2500/11 , C08F2500/20 , C08F2500/24
摘要： The present invention is directed to a polypropylene composition comprising a propylene homo- or copolymer (A) with a polydispersity index (PI), determined according ISO 6721-1, of at least 5.8 Pa−1; and an inorganic filler (B) in an amount from 2.0 to 20 parts per weight based on 100 parts per weight of (A)+(B); The present invention is furthermore directed to a polypropylene composition comprising a propylene homo- or copolymer (A); and an inorganic filler (B); whereby the following relation is fulfilled (80F+1700)MPa≦T wherein F are the parts per weight of component (B) based on 100 parts per weight of the total amount of (A)+(B). T is the tensile modulus in MPa, determined according to ISO 527-2, of the polypropylene composition measured on a test specimen prepared by injection molding according to ISO 1873-2. The present invention is also directed to a process for the production of the polypropylene compositions according to the invention and to an article made of the polypropylene compositions according to the invention.The present invention is furthermore directed to the use of the polypropylene compositions according to the invention for the production of pipes, car components, appliance housings, transport containers.
摘要翻译：本发明涉及一种聚丙烯组合物，其包含根据ISO 6721-1测定的至少5.8Pa-1的具有多分散指数（PI）的丙烯均聚物或共聚物（A）和每100重量份（A）+（B））为2.0〜20重量份的无机填料（B）。本发明还涉及包含丙烯均聚物或共聚物（A）的聚丙烯组合物; 和无机填料（B）; 由此满足以下关系（80F + 1700）MPa＆lt; NlE; T其中F是基于（A）+（B）的总量的每100重量份的组分（B）的重量份数。 T是根据ISO 527-2测定的根据ISO 1873-2通过注射成型制备的试样上测量的聚丙烯组合物的拉伸弹性模量（MPa）。本发明还涉及一种生产根据本发明的聚丙烯组合物和由本发明的聚丙烯组合物制成的制品的方法。本发明还涉及根据本发明的聚丙烯组合物用于生产管道，汽车部件，电器外壳，运输容器的用途。

6. 发明申请

US20110229670A1 PROPYLENE COMPOSITION WITH HIGH STIFFNESS AND IMPACT STRENGTH 有权
标题翻译：丙烯组合物具有高强度和抗冲击强度
公开(公告)号：US20110229670A1
公开(公告)日：2011-09-22
申请号：US13129511
申请日：2010-02-04
申请人： Markus Gahleitner , Bo Malm , Klaus Bernreitner , Juliane Braun
发明人： Markus Gahleitner , Bo Malm , Klaus Bernreitner , Juliane Braun
IPC分类号： C08L23/14 , C08L23/12 , C08K3/34 , C08K3/40 , C08K7/14 , B32B1/02 , B32B1/08
CPC分类号： C08F10/00 , C08F10/06 , C08F110/06 , C08F4/6543 , C08F4/6492 , C08F4/651 , C08F210/16 , C08F2500/04 , C08F2500/19 , C08F2500/12 , C08F2500/11 , C08F2500/20 , C08F2500/24
摘要： The present invention is directed to a polypropylene composition comprising a propylene homo- or copolymer (A) with a polydispersity index (PI), determined according ISO 6721-1, of at least 5.8 Pa−1; and an inorganic filler (B) in an amount from 2.0 to 20 parts per weight based on 100 parts per weight of (A)+(B); The present invention is furthermore directed to a polypropylene composition comprising a propylene homo- or copolymer (A); and an inorganic filler (B); whereby the following relation is fulfilled (80F+1700) MPa≦T wherein F are the parts per weight of component (B) based on 100 parts per weight of the total amount of (A)+(B). T is the tensile modulus in MPa, determined according to ISO 527-2, of the polypropylene composition measured on a test specimen prepared by injection molding according to ISO 1873-2. The present invention is also directed to a process for the production of the polypropylene compositions according to the invention and to an article made of the polypropylene compositions according to the invention.The present invention is furthermore directed to the use of the polypropylene compositions according to the invention for the production of pipes, car components, appliance housings, transport containers.
摘要翻译：本发明涉及一种聚丙烯组合物，其包含根据ISO 6721-1测定的至少5.8Pa-1的具有多分散指数（PI）的丙烯均聚物或共聚物（A）和每100重量份（A）+（B））为2.0〜20重量份的无机填料（B）。本发明还涉及包含丙烯均聚物或共聚物（A）的聚丙烯组合物; 和无机填料（B）; 由此满足以下关系（80F + 1700）MPa＆lt; NlE; T其中F是基于（A）+（B）的总量的每100重量份的组分（B）的重量份数。 T是根据ISO 527-2测定的根据ISO 1873-2通过注射成型制备的试样上测量的聚丙烯组合物的拉伸弹性模量（MPa）。本发明还涉及一种生产根据本发明的聚丙烯组合物和由本发明的聚丙烯组合物制成的制品的方法。本发明还涉及根据本发明的聚丙烯组合物用于生产管道，汽车部件，电器外壳，运输容器的用途。

7. 发明授权

US07619165B2 Cable with thermoplastic insulation 有权
标题翻译：电缆具有热塑性绝缘
公开(公告)号：US07619165B2
公开(公告)日：2009-11-17
申请号：US11572469
申请日：2005-06-20
申请人： Markus Gahleitner , Karl-Michael Jager , Robert Nigel Hampton , Pirjo Jaaskelainen , Magnus Palmlof , Bo Malm , Merja Poikela , John Haugen
发明人： Markus Gahleitner , Karl-Michael Jager , Robert Nigel Hampton , Pirjo Jaaskelainen , Magnus Palmlof , Bo Malm , Merja Poikela , John Haugen
IPC分类号： H01B3/00
CPC分类号： C08L23/04 , C08L23/10 , C08L23/16 , C08L2205/02 , Y10T428/268 , C08L2666/06
摘要： Insulation layer for cables comprising a heterophasic polymer composition having superior mechanical and electrical properties and being environmentally friendly. The heterophasic polymer composition comprises a polymer matrix and dispersed therein a propylene copolymer having a weight average particle size of less than 1 μm.
摘要翻译：用于电缆的绝缘层包括具有优异的机械和电学性能并且是环境友好的多相聚合物组合物。多相聚合物组合物包含聚合物基质并分散其中重均粒径小于1μm的丙烯共聚物。

8. 发明申请

US20080093104A1 Cable with Thermoplastic Insulation 有权
标题翻译：电缆与热塑性绝缘
公开(公告)号：US20080093104A1
公开(公告)日：2008-04-24
申请号：US11572469
申请日：2005-06-20
申请人： Markus Gahleitner , Karl-Michael Jager , Robert Nigel Hampton , Pirjo Jaaskelainen , Magnus Palmlof , Bo Malm , Merja Poikela , John Haugen
发明人： Markus Gahleitner , Karl-Michael Jager , Robert Nigel Hampton , Pirjo Jaaskelainen , Magnus Palmlof , Bo Malm , Merja Poikela , John Haugen
IPC分类号： H01B7/00 , B32B27/32 , C08L23/10 , C08L23/16
CPC分类号： C08L23/04 , C08L23/10 , C08L23/16 , C08L2205/02 , Y10T428/268 , C08L2666/06
摘要： Insulation layer for cables comprising a heterophasic polymer composition having superior mechanical and electrical properties and being environmentally friendly. The heterophasic polymer composition comprises a polymer matrix and dispersed therein a propylene copolymer having a weight average particle size of less than 1 μm.
摘要翻译：用于电缆的绝缘层包括具有优异的机械和电学性能并且是环境友好的多相聚合物组合物。多相聚合物组合物包含聚合物基质并分散其中重均粒径小于1μm的丙烯共聚物。

9. 发明申请

US20110196095A1 Flexible Polypropylene With High Impact Strength 有权
标题翻译：具有高冲击强度的柔性聚丙烯
公开(公告)号：US20110196095A1
公开(公告)日：2011-08-11
申请号：US12937282
申请日：2009-01-13
申请人： Markus Gahleitner , Doris Machl , Katja Klimke , Tung Pham
发明人： Markus Gahleitner , Doris Machl , Katja Klimke , Tung Pham
IPC分类号： C08L53/00 , C08L43/04
CPC分类号： C08L23/142 , C08L23/0892 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/16 , C08L2666/06
摘要： The present invention is directed to a first polypropylene composition comprising a propylene copolymer as matrix phase (A) comprising a homo/random/block copolymer consisting of a) a propylene homopolymer (A1); b) a propylene random copolymer (A2); and c) an ethylene-propylene rubber (EPR) (A3) and a polyolefin (B) dispersed in the matrix phase (A), which comprises hydrolysable silicon-containing groups. The present invention is furthermore directed to a second polypropylene composition comprising a matrix phase (A) comprising a propylene homo- or copolymer with an impact strength at +23° C. of at least 40.0 kJ/m2 in a Charpy notched test according to ISO 179-1eA:2000 and a polyolefin (B) dispersed in the matrix phase (A), which comprises hydrolysable silicon-containing groups. The invention is furthermore directed to a production process for the polypropylene compositions and an article made thereof.
摘要翻译：本发明涉及包含丙烯共聚物作为基质相（A）的第一聚丙烯组合物，其包含由a）丙烯均聚物（A1）组成的均相/无规/嵌段共聚物; b）丙烯无规共聚物（A2）; 和c）分散在基质相（A）中的乙丙橡胶（EPR）（A3）和聚烯烃（B），其包含可水解的含硅基团。本发明还涉及一种第二聚丙烯组合物，其包含在根据ISO的Charpy缺口试验中包含至少40.0kJ / m 2的冲击强度在+ 23℃下的丙烯均聚物或共聚物的基体相（A） 179-1eA：2000和分散在基质相（A）中的聚烯烃（B），其包含可水解的含硅基团。本发明还涉及聚丙烯组合物的制备方法及其制成的制品。

10. 发明申请

US20100267900A1 POLYPROPYLENE COMPOSITION COMPRISING A CROSS-LINKABLE DISPERSED PHASE COMPRISING SILANOL GROUPS CONTAINING NANOFILLERS 审中-公开
标题翻译：包含包含纳米纤维素的硅烷醇组的可交联分散相的聚丙烯组合物
公开(公告)号：US20100267900A1
公开(公告)日：2010-10-21
申请号：US12809914
申请日：2008-12-09
申请人： Markus Gahleitner , Tung Pham , Doris Machl , Urban Andreassonn , Roger Carlsson
发明人： Markus Gahleitner , Tung Pham , Doris Machl , Urban Andreassonn , Roger Carlsson
IPC分类号： C08L23/12 , C08L23/14
CPC分类号： C08L51/00 , C08L23/04 , C08L23/0815 , C08L23/10 , C08L51/06 , C08L2207/02 , C08L2666/06 , C08L2666/08 , C08L2666/02
摘要： The present invention relates to a polypropylene composition comprising: a matrix phase comprising a polypropylene homo- or copolymer (A); and a phase dispersed in said matrix phase comprising an olefin homo- or copolymer (B) having hydrolysable silicon-containing groups, and an inorganic filler material (C) containing on its surface silanol groups or precursors thereof, and having a specific surface BET of 30 to 300 m2/g, determined according to ISO 9277:1995, to an article comprising such a composition, and to the use of such a composition for the production of an article.
摘要翻译：本发明涉及一种聚丙烯组合物，其包含：包含聚丙烯均聚物或共聚物（A）的基体相; 以及分散在所述基质相中的相，其包含具有可水解的含硅基团的烯烃均聚物或共聚物（B）和在其表面上含有硅烷醇基团或其前体的无机填料（C），并且具有比表面积BET 30至300m2 / g，根据ISO 9277：1995确定，涉及包含这种组合物的制品，以及使用这种组合物来制造制品。

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