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1. 发明授权

US10690615B2 Micro-nano textured graphene-based bionic pH sensor and preparation method therefor 有权
公开(公告)号：US10690615B2
公开(公告)日：2020-06-23
申请号：US16078038
申请日：2016-05-27
申请人： JIANGSU UNIVERSITY
发明人： Kun Xu , Xiliang Zhang , Miaomiao Geng , Shoujuan Cui , Pingping Li , Shiqing Zhang
IPC分类号： B82Y15/00 , B82Y5/00 , G01N27/30 , H01L51/00 , B82Y30/00 , G01N27/414 , G01N27/44
摘要： A micro-nano textured graphene-based bionic pH sensor and a preparation method therefor. The micro-nano textured graphene-based bionic pH sensor comprises a substrate (1), a working electrode (4), a reference electrode (5), a copper contact A (6), a copper contact B (7), an inner lead A (8), and an inner lead B (9). A groove A (2) and a groove B (3) are formed in the substrate (1). The working electrode (4) is located in the groove A (2), and the reference electrode (5) is located in the groove B (3). The bottom of the working electrode (4) is connected to the inner lead A (8) by means of the copper contact A (6). The top of the reference electrode (5) is connected to the inner lead B (9) by means of the copper contact B (7). The working electrode (4) comprises a graphene group A (401) and a sensitive electrode material layer (402). The sensitive electrode material layer (402) is located on the upper layer of the graphene group A (401). The reference electrode (5) comprises a graphene group B (501) and a metal material silver layer (502). The metal material silver layer (502) is located on the lower layer of the graphene group B (501). Microgrooves or micro pits are formed in the upper surface of the sensitive electrode material layer (402) and the lower surface of the metal material silver layer (502). The pH sensor can fast adsorb water in soil and a culture medium and then adsorb hydrogen ions, and pH in-situ measurement of the soil, the culture medium and other heterogeneous systems is implemented.

2. 发明授权

US11150211B2 Method for preparing graphene modified composite planar pH sensor 有权
公开(公告)号：US11150211B2
公开(公告)日：2021-10-19
申请号：US15768185
申请日：2016-05-19
申请人： Jiangsu University
发明人： Xiliang Zhang , Kun Xu , Shoujuan Cui , Miaomiao Geng , Pingping Li , Shiqing Zhang
IPC分类号： G01N27/30 , C23C28/00 , C23C14/58 , C23C14/08 , C23C14/18 , C23C14/35
摘要： Provided is a fabrication method for a composite planar pH sensor modified by graphene film including: slotting into substrate, setting copper foil on both sides, and setting leads on the copper foil; coating graphene film on the copper foils using micro mechanical stripping method to form the first graphene film and the second graphene film; depositing Sb layer and Sb2O3 layer successively on the first graphene film by magnetron sputtering method, and coating Nafion™ perfluorinated sulfonic acid membrane on the Sb2O3 layer by spin-coating method to fabricate pH working electrode; depositing Ag layer on the second graphene film and dipping in FeCl3 solution to form AgCl layer; coating the third graphene film on the AgCl layer to fabricate reference electrode. The composite planar pH sensor modified by graphene film may be used in pH measurement for solid, semisolid, mash and solution samples.

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