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    • 1. 发明授权
    • Method of minimizing transition metal ions during chemical pulping in a digester by adding chelating agent to the digester
    • 在蒸煮器中通过向蒸煮器中加入螯合剂在化学制浆过程中使过渡金属离子最小化的方法
    • US06475338B1
    • 2002-11-05
    • US08659682
    • 1996-06-05
    • Jian Er JiangKaj O. Henricson
    • Jian Er JiangKaj O. Henricson
    • D21C102
    • D21C3/22
    • The production of chemical (e.g., kraft) cellulose pulp much more suited to totally chlorine free or elemental chlorine free bleaching is produced by reducing the bleaching chemical consumability of the produced pulp. The effective alkalinity of the pulp during at least the majority of the cooking stage is maintained at about 15 g/l or above (e.g., about 18-25 g/l), expressed as sodium hydroxide, so as to reduce the charged acid groups (including hexeneuronic acids) by at least 30% (e.g., at least about 50%) compared with pulp cooked at conventional alkalinity. Instead—or in addition to—the cellulosic material which produces the pulp may be heated to a temperature (at least about 100° C., preferably at least about 130° C.) to release significant quantities of the transition metals within it, and preferably while it has this elevated temperature and a dissolved organic solids concentration of about 120 g/l or less, a chelating agent (such as EDTA) is added to combine with a significant quantity of the released transition metals to produce complexes. At least a majority of the complexes are preferably removed (e.g., using an extraction screen in a digester) before the pulp is bleached.
    • 通过减少所产生的纸浆的漂白化学品消耗能力,生产更适合于完全无氯或无元素无氯漂白的化学(例如牛皮纸)纤维素纸浆。 在烹饪阶段的至少大部分期间纸浆的有效碱度保持在约15g / l或更高(例如约18-25g / l),以氢氧化钠表示,以便减少带电的酸基团 (包括己烯醛酸)与常规碱度煮熟的纸浆相比至少30%(例如至少约50%)。 或者除了生产纸浆的纤维素材料之外,还可以加热到至少约100℃,优选至少约130℃的温度以释放大量的过渡金属,以及 优选当其具有这种升高的温度和约120g / l或更低的溶解有机固体浓度时,加入螯合剂(例如EDTA)以与大量释放的过渡金属组合以产生络合物。 在纸浆漂白之前,至少大部分复合物优选被除去(例如,在蒸煮器中使用提取筛网)。
    • 3. 发明授权
    • Pretreatment of chips before cooking
    • US06506283B2
    • 2003-01-14
    • US09770408
    • 2001-01-29
    • Kaj O. HenricsonAki Hannu VilpponenHannu Olavi RamarkAuvo Kimmo KettunenC. Bertil Stromberg
    • Kaj O. HenricsonAki Hannu VilpponenHannu Olavi RamarkAuvo Kimmo KettunenC. Bertil Stromberg
    • D21C706
    • D21C1/06
    • The strength properties of chemical cellulose pulp (particularly kraft pulp) are improved by substituting a cold impregnation soak for conventional impregnation procedures. After steaming, wood chips are soaked in an alkaline liquid at a temperature of about 80-110° C. (preferably 80-100° C., or 90-105° C.) for between one-half-72 hours (typically about 2-4 hours) at a pressure of about 0-15 bar (preferably about 1-5 bar), to dissolve at least about 8% of the wood (preferably about 10-20%) and at least about 15% of the lignin. The alkaline liquid used preferably contains sulfide (e.g. black liquor, green liquor, white liquor, or mixtures thereof), but almost any alkaline liquid having an alkali concentration of about 1.0 mole of NaOH/liter or less (typically about 0.75 m/l or less) is suitable. The wood chips are then raised to a cooking temperature of about 145-180° C. and cooked to produce the cellulose chemical pulp. There may be an intermediate step, between soaking and raising the cooking temperature, of heating the wood chips to a temperature of about 110-150° C. (preferably about 120-140° C.) for about 10-90 minutes (preferably about 10-30 minutes). Alternatively or additionally the majority of the dissolved lignin (and/or other solids) may be removed before raising the wood chips to cooking temperature. The system for treating the wood chips need only include a low pressure soaking vessel (with an associated pump or other transfer device) in addition to conventional equipment.
    • 6. 发明授权
    • Cooking cellulose material with high alkali concentrations and/or high pH
    • 烹饪具有高碱浓度和/或高pH值的纤维素材料
    • US5635026A
    • 1997-06-03
    • US558138
    • 1995-11-13
    • Auvo K. KettunenKaj O. HenricsonAki H. VilpponenJian E. JiangBruno S. Marcoccia
    • Auvo K. KettunenKaj O. HenricsonAki H. VilpponenJian E. JiangBruno S. Marcoccia
    • D21C3/02D21C3/26
    • D21C3/02D21C3/26D21C3/266
    • Chemical (typically kraft) pulp having enhanced intrinsic fiber strength and bleachability compared to pulp produced using conventional or modified kraft cooking is produced by using high alkali and/or pH cooking. After being impregnated with a first cooking liquor (e.g. white liquor) having low effective alkali, the first liquor is extracted from the pulp, and it is impregnated with a second cooking liquor having an effective alkali concentration of at least 25 g/l and cooked at cooking temperature (e.g. 140.degree.-190.degree. C.) to produce a spent second cooking liquor having a residual effective alkali concentration of at least about 15 g/l, which is then extracted from the pulp. The spent second liquor may be used to preheat incoming white liquor, and then flashed and used as the first liquor. The pH of the first liquor is typically less than about 13.0, and the residual pH of the spent second liquor is about 13.0 or more.
    • 通过使用高碱和/或pH蒸煮来生产与使用常规或改性硫酸盐蒸煮生产的纸浆相比具有增强的本征纤维强度和可漂白性的化学(通常是牛皮纸)纸浆。 在用有效碱性低的第一蒸煮液(例如白液)浸渍之后,将第一液体从纸浆中提取出来,并用第二种有效碱浓度至少为25g / l的蒸煮液浸渍,并煮熟 在烹饪温度(例如140°-19℃)下,产生具有至少约15g / l的残留有效碱浓度的废第二蒸煮液,然后从纸浆中提取。 用过的第二种酒可以用于预热白液,然后闪蒸并用作第一种液体。 第一液体的pH通常小于约13.0,并且废第二液体的残留pH为约13.0或更高。
    • 9. 发明授权
    • Apparatus for washing fiber stock
    • 洗涤纤维原料的设备
    • US4485646A
    • 1984-12-04
    • US461176
    • 1983-01-26
    • Kaj O. Henricson
    • Kaj O. Henricson
    • D06B3/02D21C9/02
    • D06B3/02
    • Apparatus for washing fiber stock, comprising a substantially horizontally disposed rotating screen drum, means for supplying fiber stock to one end of said screen drum for passage along the screen surface through said screen drum, means for removing fiber stock from the other end of said screen drum, and a longitudinally extending liquid supply member fixedly mounted beneath the center axis of the screen drum, immersed in the fiber stock. The apparatus is provided with suction chambers and it acts as a screen with self-suction.
    • 用于清洗纤维原料的设备,包括基本上水平设置的旋转筛筒,用于将纤维原料供给到所述筛筒的一端以便沿筛网表面通过所述筛筒的装置,用于从所述筛网的另一端除去纤维原料的装置 滚筒和固定地安装在筛筒的中心轴线下方的纵向延伸的液体供应部件,浸入纤维原料中。 该设备设置有抽吸室,并且其用作具有自吸的筛网。
    • 10. 发明授权
    • Pretreatment of chips before cooking
    • 烹饪前预处理薯片
    • US06248208B1
    • 2001-06-19
    • US08460723
    • 1995-06-02
    • Kaj O. HenricsonAki Hannu VilpponenHannu Olavi RamarkAuvo Kimmo KettunenC. Bertil Stromberg
    • Kaj O. HenricsonAki Hannu VilpponenHannu Olavi RamarkAuvo Kimmo KettunenC. Bertil Stromberg
    • D21C102
    • D21C1/06
    • The strength properties of chemical cellulose pulp (particularly kraft pulp) are improved by substituting a cold impregnation soak for conventional impregnation procedures. After steaming, wood chips are soaked in an alkaline liquid at a temperature of about 80-110° C. (preferably 80-100° C., or alternatively 90-105° C.) for between one-half-72 hours (typically about 2-4 hours) at a pressure of about 0-15 bar (preferably about 1-5 bar), to dissolve at least about 8% of the wood (preferably about 10-20%) and at least about 15% of the lignin. The alkaline liquid used preferably contains sulfide (e.g. black liquor, green liquor, white liquor, or mixtures thereof), but almost any alkaline liquid having an alkali concentration of about 1.0 mole of NaOH/liter or less (typically about 0.75 m/l or less) is suitable. The wood chips are then raised to a cooking temperature of about 145-180° C. and cooked to produce the cellulose chemical pulp. There may be an intermediate step, between soaking and raising the cooking temperature, of heating the wood chips to a temperature of about 110-150° C. (preferably about 120-140° C.) for about 10-90 minutes (preferably about 10-30 minutes). Alternatively or additionally the majority of the dissolved lignin (and/or other solids) may be removed before raising the wood chips to cooking temperature. The system for treating the wood chips need only include a low pressure soaking vessel (with an associated pump or other transfer device) in addition to conventional equipment.
    • 化学纤维素纸浆(特别是牛皮纸浆)的强度性能通过用常规浸渍方法的冷浸渍浸渍来改善。 蒸汽之后,将木屑浸入碱性液体中,温度约为80-110℃(优选80-100℃,或90-105℃)浸渍半个小时之间(通常为 约2-4小时),在约0-15巴(优选约1-5巴)的压力下溶解至少约8%的木材(优选约10-20%)和至少约15% 木质素。 使用的碱性液体优选含有硫化物(例如黑液,绿液,白液或其混合物),但几乎任何碱性浓度为约1.0摩尔NaOH /升或更低(通常约0.75米2 /升)或 少)适合。 然后将木屑升至约145-180℃的烹饪温度,并煮熟以生产纤维素化学纸浆。 在浸泡和提高烹饪温度之间可以有一个中间步骤,将木片加热至约110-150℃(优选约120-140℃)的温度约10-90分钟(优选约为 10-30分钟)。 或者或另外,在将木屑升高至烹饪温度之前,可以除去大部分溶解的木质素(和/或其它固体)。 用于处理木片的系统除了常规设备之外仅需要包括低压均热容器(具有相关联的泵或其它转移装置)。