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    • 2. 发明授权
    • Mixed emulsions of different speed properties using sulfinate and
sulfonate compounds
    • 使用亚磺酸盐和磺酸盐化合物的不同速度性质的混合乳液
    • US5840473A
    • 1998-11-24
    • US841546
    • 1997-04-23
    • Jerzy Z. MydlarzRoger L. KlausFrederick C. Derks
    • Jerzy Z. MydlarzRoger L. KlausFrederick C. Derks
    • G03C1/035G03C1/34G03C1/36G03C7/30G03C1/09
    • G03C7/3022G03C1/035G03C1/36
    • The invention relates to a photographic element comprising at least two photographic emulsions wherein the grains of said at least two emulsions are the same and wherein at least one of said at least two emulsions is treated with a speed decreasing compound of Formula I: Z.sup.1 --X.sup.1 O.sub.2 S--M.sup.1 (I) and a compound of Formula II: Z.sup.2 --X.sup.2 O.sub.x --M.sup.2 (II) wherein X.sup.1 is sulfur and X.sup.2 is selected from the group consisting of sulfur and selenium, M.sup.1 and M.sup.2 are independently selected from group consisting of a metal ion and ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently selected from the group consisting of hydrogen and an alkyl of 1-3 carbon atoms, and Z.sup.1 and Z.sup.2 are independently selected from the group consisting of an unsubstituted or substituted alkyl of 1 to 18 carbon atoms, an unsubstituted or substituted aryl group having 6 to 10 carbon atoms, an unsubstituted or substituted 5-membered or 6-membered heterocyclic group having one or two heteroatoms, and L, wherein L is a divalent linking group, provided that, if Z.sup.1 is L, the compound of Formula I is a polymer and, if Z.sup.2 is L, the compound of Formula II is a polymer.
    • 本发明涉及一种包含至少两种照相乳液的照相材料,其中所述至少两种乳液的颗粒是相同的,并且其中所述至少两种乳液中的至少一种乳液用速度下降的式I化合物:Z1-X1O2S -M1(I)和式II化合物:其中X1是硫并且X2选自硫和硒的Z2-X2Ox-M2(II),M1和M2独立地选自金属离子 和< IMAGE>其中R 1,R 2,R 3和R 4独立地选自氢和1-3个碳原子的烷基,并且Z 1和Z 2独立地选自未取代或取代的1 具有6至10个碳原子的未取代或取代的芳基,具有一个或两个杂原子的未取代或取代的5元或6元杂环基,L,其中L是二价连接基团 如果Z1是L,则式I的化合物是聚合物,如果Z 2是L,则式II的化合物是聚合物。
    • 3. 发明授权
    • High chloride emulsions with improved reciprocity
    • 高氯化物乳液具有改善的互易性
    • US5750324A
    • 1998-05-12
    • US779539
    • 1997-01-08
    • Jerzy Z. MydlarzRoger L. KlausFranklin D. Saeva
    • Jerzy Z. MydlarzRoger L. KlausFranklin D. Saeva
    • G03C1/00G03C1/035G03C1/08G03C1/10G03C1/34G03C1/09
    • G03C1/10G03C1/34
    • This invention relates to a silver halide photographic element for digital exposure comprising a cubical silver chloride emulsion precipitated and/or chemically sensitized in the presence of an aryliodonium compound represented by the formula: ##STR1## wherein R.sup.1 and R.sup.2 and R.sup.3 are independently H, or aliphatic, aromatic or heterocyclic groups, alkoxy groups, hydroxy groups, halogen atoms, aryloxy groups, alkylthio groups, arylthio groups, acyl groups, sulfonyl groups, acyloxy groups, carboxyl groups, cyano groups, nitro groups, sulfo groups, alkylsulfoxide or trifluoralkyl groups, or any two of R.sup.1, R.sup.2 and R.sup.3 together represent the atoms necessary to form a five or six-membered ring or a multiple ring system; R.sup.4 is a carboxylate salt or 0.sup.- ; w is 0 or 1; and X.sup.- is an anionic counter ion; with the proviso that when R.sup.3 is a carboxyl or sulfo group, w is 0 and R.sup.4 is 0.sup.-.
    • 本发明涉及一种用于数字曝光的卤化银照相元件,包括在下式表示的芳基碘鎓化合物存在下沉淀和/或化学增感的立方氯化银乳剂:其中R1和R2和R3独立地为H,或 脂族,芳族或杂环基,烷氧基,羟基,卤素原子,芳氧基,烷硫基,芳硫基,酰基,磺酰基,酰氧基,羧基,氰基,硝基,磺基,烷基亚砜或三氟烷基 ,或者R 1,R 2和R 3中的任何两个一起表示形成五元或六元环或多环系所必需的原子; R 4是羧酸盐或O- w为0或1; 而X-是阴离子抗衡离子; 条件是当R3为羧基或磺基时,w为0且R4为0-。
    • 4. 发明授权
    • Silver halide photographic elements containing aryliodonium compounds
    • 含有芳基碘化合物的卤化银照相元件
    • US5733717A
    • 1998-03-31
    • US779538
    • 1997-01-08
    • Franklin D. SaevaRoger L. KlausJerzy Z. Mydlarz
    • Franklin D. SaevaRoger L. KlausJerzy Z. Mydlarz
    • G03C1/34G03C1/035G03C1/08
    • G03C1/34
    • This invention relates to a silver halide photographic element comprising a silver halide emulsion precipitated and/or chemically sensitized in the presence of an aryliodonium compound represented by the formula: ##STR1## wherein R.sup.1 and R.sup.2 and R.sup.3 are independently H, or aliphatic, aromatic or heterocyclic groups, alkoxy groups, hydroxy groups, halogen atoms, aryloxy groups, alkylthio groups, arylthio groups, acyl groups, sulfonyl groups, acyloxy groups, carboxyl groups, cyano groups, nitro groups, sulfo groups, alkylsulfoxide or trifluoralkyl groups, or any two of R.sup.1, R.sup.2 and R.sup.3 together represent the atoms necessary to form a five or six-membered ring or a multiple ring system; R.sup.4 is a carboxylate salt or 0.sup.- ; w is 0 or 1; and X.sup.- is an anionic counter ion; with the proviso that when R.sup.3 is a carboxyl or sulfo group, w is 0 and R.sup.4 is 0.sup.-.
    • 本发明涉及一种卤化银照相元件,其包含在由下式表示的芳基碘鎓化合物存在下沉淀和/或化学增感的卤化银乳剂:其中R 1和R 2和R 3独立地为H,或脂族,芳族或 杂环基,烷氧基,羟基,卤原子,芳氧基,烷硫基,芳硫基,酰基,磺酰基,酰氧基,羧基,氰基,硝基,磺基,烷基亚砜或三氟烷基, 的R 1,R 2和R 3一起表示形成五元或六元环或多环体系所必需的原子; R 4是羧酸盐或O- w为0或1; X-是阴离子抗衡离子; 条件是当R3为羧基或磺基时,w为0且R4为0-。
    • 7. 发明授权
    • High intensity exposure photographic imaging method employing iridium doped high chloride emulsion
    • 使用铱掺杂高氯化物乳液的高强度曝光照相成像方法
    • US06518009B1
    • 2003-02-11
    • US09608841
    • 2000-06-30
    • Jerzy Z. MydlarzRoger L. Klaus
    • Jerzy Z. MydlarzRoger L. Klaus
    • G03C1005
    • G03C1/015G03C1/035G03C5/16G03C2001/03517G03C2001/03541Y10S430/145Y10S430/146
    • A method of imaging employing sensitized high chloride silver halide emulsions which exhibit improved speed and high intensity reciprocity performance for use with short duration, high intensity exposure optical and digital exposure systems. The method comprising providing a photographic element comprising at least one high chloride silver halide emulsion layer, exposing said element utilizing a high intensity actinic radiation exposure for an exposure time of less than {fraction (1/100)} second, and developing said element to produce a photographic image, wherein the high chloride silver halide emulsion layer is comprised of silver halide emulsion grains containing at least 90 mole percent chloride, based on silver, obtained by providing a high chloride host emulsion, bringing a Lippmann emulsion comprising primarily fine silver bromide grains doped with iridium into contact with said high chloride host emulsion, and subsequently chemically sensitizing the high chloride emulsion.
    • 使用敏化的高氯化物卤化银乳剂的成像方法,其表现出改善的速度和高强度互易性能,用于短时间,高强度曝光光学和数字曝光系统。 该方法包括提供包含至少一种高氯化物卤化银乳剂层的照相元件,利用高强度光化辐射曝光暴露所述元件,曝光时间小于1/100秒,并显影所述元件以产生照相图像, 其中所述高氯化物卤化银乳剂层由卤化银乳剂颗粒组成,所述卤化银乳剂颗粒含有基于银的至少90摩尔百分数的氯化物,通过提供高氯化物主体乳液获得,使包含主要细小的掺有铱的溴化银颗粒的Lippmann乳液进入 与所述高氯化物主体乳液接触,随后对高氯化物乳液进行化学增感。