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1. 发明授权

US06890650B2 Glass fiber sizing compositions, sized glass fibers, and polyolefin composites 失效
标题翻译：玻璃纤维上浆组合物，尺寸玻璃纤维和聚烯烃复合材料
公开(公告)号：US06890650B2
公开(公告)日：2005-05-10
申请号：US10625405
申请日：2003-07-23
申请人： Jerry C. Hedden
发明人： Jerry C. Hedden
IPC分类号： C03C25/10 , C03C25/26 , C03C25/30 , C03C25/40 , C08J5/08 , C08K9/06 , C09J11/06 , C09J183/07 , C09J201/00 , D06M13/144 , D06M13/513 , D06M15/333 , D06M15/507 , D06M15/55 , D02G3/00 , C08K3/40
CPC分类号： C08J5/08 , C03C25/26 , C03C25/30 , C03C25/40 , C08J2365/00 , C08K9/06 , Y10T428/2933 , Y10T428/2938 , Y10T428/2962 , Y10T428/2964 , C08L23/02
摘要： A sizing composition for glass fibers comprises at least one film-former, at least one silane comprising an alkenyl group comprising a straight chain segment of at least five carbon atoms, wherein at least one carbon-carbon double bond is terminal and wherein the carbon atoms on the terminal double bond are unsubstituted, and at least one lubricant. The sizing composition can be used to coat glass fibers for use as reinforcement for cycloolefins that cure by the ring-opening metathesis polymerization (“ROMP”) reaction.
摘要翻译：用于玻璃纤维的施胶组合物包含至少一种成膜剂，至少一种含有包含至少五个碳原子的直链链段的烯基的硅烷，其中至少一个碳 - 碳双键是末端，其中碳原子在末端双键上是未取代的，和至少一种润滑剂。上胶组合物可用于涂覆玻璃纤维，用作通过开环易位聚合（“ROMP”）反应固化的环烯烃增强剂。

2. 发明授权

US4592956A Treated glass fibers and aqueous dispersion and nonwoven mat of the glass fibers 失效
标题翻译：处理玻璃纤维和玻璃纤维的水性分散体和非织造毡
公开(公告)号：US4592956A
公开(公告)日：1986-06-03
申请号：US658009
申请日：1984-10-05
申请人： Peter C. Gaa , Jerry C. Hedden , Narasimhan Raghupathi
发明人： Peter C. Gaa , Jerry C. Hedden , Narasimhan Raghupathi
IPC分类号： C03C25/26 , D02G3/00
CPC分类号： C03C25/26 , Y10T428/2907 , Y10T428/2962 , Y10T428/2964
摘要： Treated glass fibers having adequate protection for gathering into strands and when chopped being more dispersible in aqueous media. The treated glass fibers having a coating of an aqueous treating composition, wherein the solids have a cationic surfactant having one or more primary, secondary and/or tertiary amine moieties and one or more water dispersible, poly(oxyethylene-oxyalkylene) copolymer having an oxide ratio of about 78 to about 22 to about 99 to about 1 and an average molecular weight of at least 15,000, and one or more polar functional coupling agents. Optionally, the solids may also have one or more starches that are insoluble or only incompletely soluble in cold water. Glass fibers treated with the aqueous treating compositions and produced into wet or dry chopped glass fiber strands having lengths of about 1/16 of an inch (1.58 mm) to about 3 inches (76.2 mm), have good dispersibility in aqueous media with or without addition of dispersing agents. Nonwoven, sheet-like mat is produced from aqueous dispersions having the chopped treated glass fibers, where some of the water is removed and polymeric binders, commonly referred to as wet strength binders, are applied and the mat is cured. The resulting nonwoven, sheet-like mat product has very good strength properties for use as a reinforcing element for roofing products, construction products and flooring products.
摘要翻译：经处理的玻璃纤维具有足够的保护以收集成股线，并且当切碎更可分散在水性介质中时。处理过的玻璃纤维具有水性处理组合物的涂层，其中固体具有阳离子表面活性剂，其具有一个或多个伯，仲和/或叔胺部分和一种或多种具有氧化物的水分散性聚（氧化乙烯 - 氧化烯）共聚物约78至约22至约99至约1，平均分子量至少为15,000，以及一种或多种极性官能偶联剂。任选地，固体还可以具有一种或多种不溶于或仅不完全溶于冷水的淀粉。用水处理组合物处理并生产长度为约1/16英寸（1.58mm）至约3英寸（76.2mm）的湿或干的短切玻璃纤维线的玻璃纤维在含或不含有水溶液的水介质中具有良好的分散性加入分散剂。非织造的片状垫是由具有短切处理的玻璃纤维的水性分散体制成的，其中一些水被除去，并且通常称为湿强度粘合剂的聚合物粘合剂被施用并且垫被固化。所得非织造的片状垫产品具有非常好的强度性能，用作屋顶产品，建筑产品和地板产品的增强元件。

3. 发明授权

US4467916A Tubular glass fiber package and method 失效
公开(公告)号：US4467916A
公开(公告)日：1984-08-28
申请号：US371899
申请日：1982-04-26
申请人： Jerry C. Hedden , Lesley M. Allen
发明人： Jerry C. Hedden , Lesley M. Allen
IPC分类号： B65D85/00 , B65H55/00 , B65H55/02
CPC分类号： B65H55/00 , B65H2701/31
摘要： A package of wound glass fiber strand from which the glass fiber strands can be removed more efficiently for feeding into processing operations. The wound package of glass fiber strand is a package of superimposed annular layers of glass fiber strands having a central longitudinal, cylindrical cavity about which the strands are wound and having an outer cylindrical surface and a substantially flat circular top and bottom section. This package is covered with a stretchable polymeric film having a stiffness modulus of at least 1200 pounds/square inch and an elongation of about at least 5 and a thickness of about 0.75 to about 10 mils. The stretchable polymeric film is stretched around the package of glass fiber strands with a force greater than 4 pounds (18 Newtons) to stretch the film to cover the outer peripheral, cylindrical portion and to extend at least 0.5 inches (1.27 cm.) radially onto the top and bottom flat circular portions of the package. The polymeric film is stretched around the package for one or more wraps. The method of producing the wrapped package includes preparing a package of glass fiber strands wound in superimposed annular layers to have a central longitudinal, cylindrical cavity and an outer cylindrical surface and a substantially flat circular top and bottom section where at least one free end of the glass fiber strand extends into the central cavity for removal from the interior to the exterior of the package with the package prepared a stretchable polymeric material is selected having a stress modulus of at least about 1200 pounds per square inch and a percent elongation of at least about 5 and a thickness of about 0.75 to 10 mils. This stretchable polymeric film is wrapped about the package with a stretching force of greater than 4 pounds (18 Newtons) to stretch the film to cover the outer cylindrical portion of the package and to extend radially 0.5 inches onto the flat top and bottom circular portions of the package in one or more wraps.

4. 发明授权

US4681802A Treated glass fibers and aqueous dispersion and nonwoven mat of the glass fibers 失效
标题翻译：处理玻璃纤维和玻璃纤维的水性分散体和非织造毡
公开(公告)号：US4681802A
公开(公告)日：1987-07-21
申请号：US834990
申请日：1986-02-28
申请人： Peter C. Gaa , Jerry C. Hedden , Narasimhan Raghupathi
发明人： Peter C. Gaa , Jerry C. Hedden , Narasimhan Raghupathi
IPC分类号： C03C25/26 , C04B35/80 , D04H1/58
CPC分类号： C03C25/26 , Y10T428/2907 , Y10T428/2964 , Y10T442/60
摘要： Treated glass fibers having adequate protection for gathering into strands and when chopped being more dispersible in aqueous media. The treated glass fibers have a coating of an aqueous treating composition, wherein the solids have a cationic surfactant having one or more primary, secondary and/or tertiary amine moieties and one or more water dispersible, poly(oxyethylene-oxyalkylene) copolymer having an oxide ratio of about 78 to about 22 to about 99 to about 1 and an average molecular weight of at least 15,000, and one or more polar functional coupling agents. Optionally, the solids may also have one or more starches that are insoluble or only incompletely soluble in cold water. Glass fibers treated with the aqueous treating compositions and produced into wet or dry chopped glass fiber strands having lengths of about 1/16 of an inch (1.58 mm) to about 3 inches (76.2 mm), have good dispersibility in aqueous media with or without addition of dispersing agents. Nonwoven, sheet-like mat is produced from aqueous dispersions having the chopped treated glass fibers, where some of the water is removed and polymeric binders, commonly referred to as wet strength binders, are applied and the mat is cured. The resulting nonwoven, sheet-like mat product has very good strength properties for use as a reinforcing element for roofing products, construction products and flooring products.
摘要翻译：经处理的玻璃纤维具有足够的保护以收集成股线，并且当切碎更可分散在水性介质中时。经处理的玻璃纤维具有水性处理组合物的涂层，其中固体具有阳离子表面活性剂，其具有一个或多个伯，仲和/或叔胺部分和一种或多种具有氧化物的水分散性聚（氧乙烯 - 氧化烯）共聚物约78至约22至约99至约1，平均分子量至少为15,000，以及一种或多种极性官能偶联剂。任选地，固体还可以具有一种或多种不溶于或仅不完全溶于冷水的淀粉。用水处理组合物处理并生产长度为约1/16英寸（1.58mm）至约3英寸（76.2mm）的湿或干的短切玻璃纤维线的玻璃纤维在含或不含有水溶液的水介质中具有良好的分散性加入分散剂。非织造的片状垫是由具有短切处理的玻璃纤维的水性分散体制成的，其中一些水被除去，并且通常称为湿强度粘合剂的聚合物粘合剂被施用并且垫被固化。所得非织造的片状垫产品具有非常好的强度性能，用作屋顶产品，建筑产品和地板产品的增强元件。

5. 发明授权

US3946132A Tire cord containing glass fibers sized with a starch based size 失效
标题翻译：含有基于淀粉尺寸的玻璃纤维的轮胎帘线
公开(公告)号：US3946132A
公开(公告)日：1976-03-23
申请号：US528362
申请日：1974-11-29
申请人： Jerry C. Hedden
发明人： Jerry C. Hedden
IPC分类号： C03C25/32 , C08L3/00 , B32B9/00 , C08L1/00 , D02G3/00
CPC分类号： C03C25/321 , C08L3/00 , Y10T428/2938 , Y10T428/2962 , Y10T428/2964
摘要： An improved textile forming size for glass fibers utilized in the preparation of rubber coated glass fiber tire cord is described in which a starch based forming size has incorporated therein a non-inoic wetting agent, a silane coupling agent and a paraffinic or microcrystalline wax. The use of this forming size on glass fibers which are subsequently coated with elastomer for use as tire cord results in a tire cord having improved flex fatigue properties.
摘要翻译：描述了用于制备涂覆有橡胶的玻璃纤维轮胎帘线的玻璃纤维的改进的纺织物形成尺寸，其中淀粉基成型尺寸中已加入非惰性润湿剂，硅烷偶联剂和石蜡或微晶蜡。在随后涂覆有弹性体的玻璃纤维上使用这种成形尺寸用作轮胎帘线导致轮胎帘线具有改善的挠曲疲劳性能。

6. 发明授权

US4810576A Treated glass fibers and aqueous dispersion and nonwoven mat of the glass fibers 失效
标题翻译：处理玻璃纤维和玻璃纤维的水性分散体和非织造毡
公开(公告)号：US4810576A
公开(公告)日：1989-03-07
申请号：US80040
申请日：1987-07-31
申请人： Peter C. Gaa , Jerry C. Hedden , Donald L. Motsinger , H. Kenyon Watkins
发明人： Peter C. Gaa , Jerry C. Hedden , Donald L. Motsinger , H. Kenyon Watkins
IPC分类号： C03C25/26 , D06P1/64 , D21H13/40 , B32B9/00 , D02G3/00
CPC分类号： D06P1/64 , C03C25/26 , D21H13/40 , Y10T428/2933 , Y10T428/2938 , Y10T428/2962 , Y10T428/2964 , Y10T428/2967 , Y10T428/2969 , Y10T428/2975
摘要： Chemically treated glass fibers of the present invention perform well as wet chopped strands of glass fibers and are useful in producing glass fiber paper. In one aspect the chopped strands of glass fibers have an aqueous chemical treatment comprised of at least one water soluble, ungelled polymer having an effective viscosity, an effective film-forming capability and an effective molecular weight. In another aspect the chemically treated glass fibers have a chemical treating composition having a polyoxyethylene polymer as the water soluble and ungelled polymer with an effective film forming molecular weight along with water soluble, dispersible or emulsifiable aldehyde-condensate-reactable, polymeric agent, cationic lubricant or lubricating surfactant, aldehyde-condensate-reactable organo silane coupling agents and a carrier like water. The amount of the reactable polymeric agent is an effective white water compatible amount, where this agent is a polymer like either polyacrylamide or polyamide or a mixture of these. The aldehyde-condensate-reactable organo silane coupling agent can be an alkoxylated gamma aminoalkyltrialkoxy silane, a polyamino organo silane, mercapto functional organo silane or a ureido functional organo silane or a mixture thereof.
摘要翻译：本发明的化学处理的玻璃纤维作为玻璃纤维的湿切短纤维表现良好，可用于生产玻璃纤维纸。在一个方面，短切的玻璃纤维束具有由至少一种具有有效粘度，有效成膜能力和有效分子量的至少一种水溶性，非凝胶聚合物组成的水性化学处理。在另一方面，化学处理的玻璃纤维具有化学处理组合物，其具有聚氧乙烯聚合物作为水溶性和未凝胶聚合物，其具有有效的膜形成分子量以及水溶性，可分散或可乳化的醛 - 缩合物 - 可反应的聚合物，阳离子润滑剂或润滑表面活性剂，醛缩合物可反应的有机硅烷偶联剂和载体如水。可反应的聚合物的量是有效的白水相容量，其中该试剂是聚丙烯酰胺或聚酰胺或这些聚合物的混合物。醛缩合反应有机硅烷偶联剂可以是烷氧基化的氨基烷基三烷氧基硅烷，聚氨基有机硅烷，巯基官能的有机硅烷或脲基官能的有机硅烷或它们的混合物。

7. 发明授权

US4305742A Method of forming and sizing glass fibers 失效
标题翻译：玻璃纤维的形成和定型方法
公开(公告)号：US4305742A
公开(公告)日：1981-12-15
申请号：US222452
申请日：1981-01-05
申请人： Herbert W. Barch , Howard J. Hudson , Jerry C. Hedden
发明人： Herbert W. Barch , Howard J. Hudson , Jerry C. Hedden
IPC分类号： C03C25/12 , C03C25/32 , C03C25/02
CPC分类号： C03C25/12 , C03C25/323 , Y10T428/2936 , Y10T428/2938
摘要： A sizing composition and process are provided for producing wound packages and particularly precision wound packages of glass fiber strand and/or roving. The sizing composition has a total solids content in the range of about 9 to about 30 weight percent and comprises a phenolic epoxy resin, the reaction product of a partial ester of a polycarboxylic acid containing one or more unesterified carboxyl groups with a compound containing more than one epoxy group; and organo silane or silanes; a non-ionic surface active agent; a protective colloid; and a cationic lubricant. The process for producing the precision wound packages of glass fibers includes forming a plurality of glass fibers from molten glass, treating the glass fibers with the sizing composition having a total solids content of about 9 to about 30 weight percent, gathering the treated glass fibers together into one or more strands and collecting the gathered strand or strands on a winder in a precision wound package to produce glass fiber strands or roving.
摘要翻译：提供了一种施胶组合物和方法，用于生产伤口包装，特别是玻璃纤维束和/或粗纱的精密伤口包装。上浆组合物的总固体含量在约9至约30重量％的范围内，并且包含酚类环氧树脂，含有一个或多个未酯化羧基的多元羧酸的部分酯与含有多于一个环氧基; 和有机硅烷或硅烷; 非离子表面活性剂; 保护胶体和阳离子润滑剂。用于生产玻璃纤维的精密卷绕包装的方法包括从熔融玻璃形成多个玻璃纤维，用总固体含量为约9至约30重量％的施胶组合物处理玻璃纤维，将处理的玻璃纤维聚集在一起在一个或多个股线中收集聚集的股线或股线在精密伤口包装上的络纱机上，以产生玻璃纤维股或粗纱。

8. 发明授权

US3997306A Glass fiber sizing composition for the reinforcement of resin matrices and method of using same 失效
标题翻译：用于增强树脂基体的玻璃纤维施胶组合物及其使用方法
公开(公告)号：US3997306A
公开(公告)日：1976-12-14
申请号：US565986
申请日：1975-03-31
申请人： Jerry C. Hedden
发明人： Jerry C. Hedden
IPC分类号： C03C25/26 , C03C25/02
CPC分类号： C03C25/26
摘要： A glass fiber size is provided which contains a phenolic epoxy resin, the reaction product of the partial ester of a polycarboxylic acid containing one or more unesterified carboxyl groups with a compound containing more than one epoxy group, an amino silane coupling agent, a methacryloxy alkyl trialkoxy silane, and a non-ionic surface active agent. A method of sizing glass fibers and glass fibers sized with the aforementioned composition are also provided.
摘要翻译：提供玻璃纤维尺寸，其包含酚醛环氧树脂，含有一个或多个未酯化羧基的多元羧酸的部分酯与含有多于一个环氧基的化合物的反应产物，氨基硅烷偶联剂，甲基丙烯酰氧基烷基三烷氧基硅烷和非离子表面活性剂。还提供了用上述组合物调整玻璃纤维和玻璃纤维尺寸的方法。

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