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1. 发明申请

US20110045265A1 Polyolefin composition and film thereof 审中-公开
标题翻译：聚烯烃组合物及其膜
公开(公告)号：US20110045265A1
公开(公告)日：2011-02-24
申请号：US12583547
申请日：2009-08-20
申请人： Jeffrey C. Haley , Harilaos Mavridis , Dennis M. Hudson , Ganesh Nagarajan , Stephen M. Imfeld , Giampaolo Pellegatti
发明人： Jeffrey C. Haley , Harilaos Mavridis , Dennis M. Hudson , Ganesh Nagarajan , Stephen M. Imfeld , Giampaolo Pellegatti
IPC分类号： C08L23/04 , B32B27/32
CPC分类号： C08J5/18 , C08J2323/04 , C08L23/04 , C08L23/14 , C08L2205/02 , C08L2207/02 , C08L2666/06
摘要： A polyolefin composition is disclosed. The composition comprises a single-site linear low density polyethylene (mLLDPE) and an elastoplastic polypropylene. The elastoplastic polypropylene is present in an amount sufficient to improve the processability and physical property of the mLLDPE. The composition preferably comprises from 70 wt % to 99 wt % of mLLDPE and from 1 wt % to 30 wt % of the elastoplastic polypropylene. The polyolefin composition of the invention exhibits improved bubble stability in the blown film extrusion compared to the mLLDPE and improved film properties such as tear strength and modulus compared to the traditional blend of mLLDPE and low density polyethylene.
摘要翻译：公开了一种聚烯烃组合物。组合物包含单位点线性低密度聚乙烯（mLLDPE）和弹塑性聚丙烯。弹性塑料聚丙烯以足以提高mLLDPE的加工性能和物理性能的量存在。组合物优选包含70重量％至99重量％的mLLDPE和1重量％至30重量％的弹塑性聚丙烯。与mLLDPE和低密度聚乙烯的传统共混物相比，本发明的聚烯烃组合物与mLLDPE相比，在吹塑薄膜挤出中显示出改进的气泡稳定性和改进的膜性能，例如撕裂强度和模量。

2. 发明申请

US20120028017A1 Polyethylene blends and films 有权
标题翻译：聚乙烯共混物和薄膜
公开(公告)号：US20120028017A1
公开(公告)日：2012-02-02
申请号：US12804745
申请日：2010-07-28
申请人： Anil W. Saraf , Stephen M. Imfeld
发明人： Anil W. Saraf , Stephen M. Imfeld
IPC分类号： B32B7/02 , C08L23/06
CPC分类号： C08L23/06 , B32B27/32 , B32B2250/03 , B32B2250/242 , B32B2250/40 , B32B2270/00 , B32B2307/412 , B32B2307/50 , B32B2307/518 , B32B2307/736 , C08J5/18 , C08J2323/06 , C08J2323/08 , C08J2423/06 , C08J2423/08 , C08L23/0815 , C08L2205/02 , C08L2314/06 , C08L2666/06
摘要： Disclosed are polyethylene blends and films. The blend comprises from 1 to 99%, based on the weight of the blend, of a medium density polyethylene (MDPE) and from 1 to 99% a polyolefin selected from the group consisting of high density polyethylene (HDPE), linear low density polyethylene (LLDPE), low density polyethylene (LDPE), polypropylene, polybutene, and mixtures thereof. The MDPE is made by high pressure, free radical polymerization and has a density within the range of greater than 0.928 to 0.940 g/cm3 and an MI2 within the range of 0.1 to 1 dg/min. The shrink films made from the blend have strong contraction force and low creep.
摘要翻译：公开了聚乙烯共混物和薄膜。共混物包含1至99％（以混合物的重量计）中等密度聚乙烯（MDPE）和1至99％的选自高密度聚乙烯（HDPE），线性低密度聚乙烯（LLDPE），低密度聚乙烯（LDPE），聚丙烯，聚丁烯及其混合物。 MDPE由高压自由基聚合制成，密度在大于0.928至0.940g / cm3的范围内，MI2在0.1至1dg / min的范围内。由共混物制成的收缩膜具有较强的收缩力和较低的蠕变。

3. 发明授权

US5057372A Multilayer film and laminate for use in producing printed circuit boards 失效
标题翻译：用于生产印刷电路板的多层膜和层压板
公开(公告)号：US5057372A
公开(公告)日：1991-10-15
申请号：US326931
申请日：1989-03-22
申请人： Stephen M. Imfeld , Randall S. Shipley
发明人： Stephen M. Imfeld , Randall S. Shipley
IPC分类号： B32B15/08 , H05K1/03 , H05K3/00 , H05K3/02 , H05K3/38
CPC分类号： B32B15/08 , H05K3/025 , Y10S428/901 , Y10T428/31507 , Y10T428/31692 , Y10T428/31757 , Y10T428/31797 , Y10T428/31913
摘要： A multilayer film having as one surface layer thereof a support layer containing a thermoplastic resin able to withstand temperatures up to 200 degrees C. without softening and the other surface layer an adhesive layer containing a thermoplastic resin having a melting point ranging from about 100 to 200 degrees C. Optionally, a tie layer may be employed between the support layer and the adhesive layer. The multilayer film is useful as a protective carrier sheet for a cladding metal foil used in the production of printed circuit boards. The carrier sheet provides temporary, peelable surface protection for the cladding metal foil preventing contamination and physical damage to the foil both before and during printed circuit board formation. Adhesion of the carrier sheet to the cladding metal foil, measured using a 180 degree peel test is less than 0.4 pounds/in-width and greater than 0.005 pounds/in-width, and preferably less than 0.1 pounds/in-width and greater than 0.01 pounds/in-width.
摘要翻译：一种多层膜，其具有一层表层，该支撑层含有能够耐受高达200℃的温度而不软化的热塑性树脂，另一表面层含有熔点为约100至200的热塑性树脂的粘合剂层任选地，可以在支撑层和粘合剂层之间使用粘结层。多层膜可用作印刷电路板生产中所用的包覆金属箔的保护载体片。承载板为包覆金属箔提供临时的可剥离表面保护，防止在印刷电路板形成之前和期间对箔的污染和物理损坏。使用180度剥离试验测量的载体片材对包层金属箔的粘附力小于0.4磅/宽，并且大于0.005磅/宽，优选小于0.1磅/宽度，并且大于 0.01磅/宽。

4. 发明申请

US20130225742A1 BARRIER PROPERTIES OF SUBSTANTIALLY LINEAR HDPE FILM WITH NUCLEATING AGENTS 有权
标题翻译：主要线性高密度聚乙烯薄膜与核化剂的阻隔性能
公开(公告)号：US20130225742A1
公开(公告)日：2013-08-29
申请号：US13856097
申请日：2013-04-03
申请人： JEFFREY S. BORKE , Douglas C. McFaddin , Stephen M. Imfeld
发明人： JEFFREY S. BORKE , Douglas C. McFaddin , Stephen M. Imfeld
IPC分类号： C08K5/00 , C08F110/02
CPC分类号： C08K5/0083 , C08F110/02 , C08J5/18 , C08J2323/06 , C08K5/057 , C08K5/098 , C08K2201/008 , C08L23/06
摘要： Disclosed is a method for improving the barrier properties of polyethylene films The method comprises mixing a substantially linear, high density polyethylene with a nucleating agent and converting the mixture into a film The film made by the method of the invention has at least a 15% improvement on the water vapor barrier property and/or in the oxygen barrier property compared with the control film made from the same substantially linear, high density polyethylene but does not contain the nucleating agent.
摘要翻译：公开了一种改善聚乙烯膜的阻隔性的方法。该方法包括将基本上线性的高密度聚乙烯与成核剂混合并将混合物转化成膜。通过本发明的方法制备的膜具有至少15％的改进与由相同的基本上线性的高密度聚乙烯制成但不含有成核剂的对照膜相比，具有阻水性和/或氧阻隔性。

5. 发明授权

US06355733B1 Polyethylene blends and films 失效
标题翻译：聚乙烯共混物和薄膜
公开(公告)号：US06355733B1
公开(公告)日：2002-03-12
申请号：US09688314
申请日：2000-10-13
申请人： Kelly L. Williams , Leonard V. Cribbs , Stephen M. Imfeld , Venki Chandrashekar
发明人： Kelly L. Williams , Leonard V. Cribbs , Stephen M. Imfeld , Venki Chandrashekar
IPC分类号： C08L2300
CPC分类号： C08L23/04 , C08L23/06 , C08L23/0815 , C08L2205/02 , C08L2666/04
摘要： A blend comprising a high molecular weight, medium density polyethylene (HMW, MDPE) and a linear low density polyethylene (LLDPE) is disclosed. The blend comprises from about 20 wt % to about 80 wt % of HMW MDPE. The HMW MDPE has a density from about 0.92 to about 0.944 g/cc, a melt index MI2 from about 0.01 to about 0.5 dg/min, and a melt flow ratio MFR from about 50 to about 300. The blend also comprises about 20 wt % to about 80 wt % of LLDPE. The LLDPE has a density within the range of about 0.90 to about 0.925 g/cc and an MI2 within the range of about 0.50 to about 50 dg/min. The blend provides films with significantly improved toughness and tear strength compared to MDPE or HDPE, and high modulus compared to LLDPE.
摘要翻译：公开了包含高分子量中密度聚乙烯（HMW，MDPE）和线性低密度聚乙烯（LLDPE）的共混物。共混物包含约20重量％至约80重量％的HMW MDPE。 HMW MDPE具有约0.92至约0.944g / cc的密度，约0.01至约0.5dg / min的熔体指数MI2和约50至约300的熔体流动比MFR。共混物还包含约20重量％％至约80重量％的LLDPE。 LLDPE的密度在约0.90至约0.925g / cc的范围内，MI2在约0.50至约50dg / min的范围内。与MDPE或HDPE相比，共混物提供的膜具有显着改善的韧性和撕裂强度，并且与LLDPE相比具有高模量。

6. 发明授权

US08436085B2 Barrier properties of substantially linear HDPE film with nucleating agents 有权
标题翻译：具有成核剂的基本线性HDPE薄膜的阻隔性能
公开(公告)号：US08436085B2
公开(公告)日：2013-05-07
申请号：US11717944
申请日：2007-03-14
申请人： Jeffrey S. Borke , Douglas C. McFaddin , Stephen M. Imfeld
发明人： Jeffrey S. Borke , Douglas C. McFaddin , Stephen M. Imfeld
IPC分类号： C08K5/04 , C08K5/09 , D06M15/693 , C09D4/00 , C09D201/00 , C09J4/00 , C09J201/00
CPC分类号： C08K5/0083 , C08F110/02 , C08J5/18 , C08J2323/06 , C08K5/057 , C08K5/098 , C08K2201/008 , C08L23/06
摘要： Disclosed is a method for improving the barrier properties of polyethylene films. The method comprises mixing a substantially linear, high density polyethylene with a nucleating agent and converting the mixture into a film. The film made by the method of the invention has at least a 15% improvement on the water vapor barrier property and/or in the oxygen barrier property compared with the control film made from the same substantially linear, high density polyethylene but does not contain the nucleating agent.
摘要翻译：公开了一种提高聚乙烯膜的阻隔性的方法。该方法包括将基本线性的高密度聚乙烯与成核剂混合并将混合物转化成膜。通过本发明的方法制备的薄膜与由相同的基本线性，高密度聚乙烯制成的对照膜相比，具有至少15％的水蒸汽阻隔性和/或氧气阻隔性能的改善，但不包含成核剂。

7. 发明申请

US20100016526A1 Process for the preparation of multimodal polyethylene resins 失效
标题翻译：制备多峰聚乙烯树脂的方法
公开(公告)号：US20100016526A1
公开(公告)日：2010-01-21
申请号：US12218597
申请日：2008-07-16
申请人： Bradley P. Etherton , Stephen M. Imfeld , Philip J. Garrison
发明人： Bradley P. Etherton , Stephen M. Imfeld , Philip J. Garrison
IPC分类号： C08F110/02 , C08F2/00
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/65927 , Y02P20/52 , C08F4/65904 , C08F2/001 , C08F210/14 , C08F2500/05 , C08F2500/07 , C08F2500/12 , C08F210/08
摘要： A two-stage cascade polymerization process for the production of multimodal polyethylene film resins with improved bubble stability is provided. The process comprises polymerizing ethylene or a mixture of ethylene and a C4-8 α-olefin in two reactors arranged in series using a mixed single-site catalyst comprised of a bridged and a non-bridged indenoindolyl transition metal complex to form a multimodal polyethylene resin comprised of a lower molecular weight, higher density component and a higher molecular weight, lower density component.
摘要翻译：提供了用于生产具有改善气泡稳定性的多峰聚乙烯薄膜树脂的两级级联聚合方法。该方法包括使用由桥连和非桥连的茚并吲哚基过渡金属络合物组成的混合单中心催化剂在串联的两个反应器中聚合乙烯或乙烯和C 4-8α-烯烃的混合物以形成多峰聚乙烯树脂包括较低分子量，较高密度组分和较高分子量，较低密度组分。

8. 发明授权

US08637607B2 Polyethylene blends and films 有权
标题翻译：聚乙烯共混物和薄膜
公开(公告)号：US08637607B2
公开(公告)日：2014-01-28
申请号：US12804745
申请日：2010-07-28
申请人： Anil W. Saraf , Stephen M. Imfeld
发明人： Anil W. Saraf , Stephen M. Imfeld
IPC分类号： C08F8/00 , C08L23/00 , C08L23/04
CPC分类号： C08L23/06 , B32B27/32 , B32B2250/03 , B32B2250/242 , B32B2250/40 , B32B2270/00 , B32B2307/412 , B32B2307/50 , B32B2307/518 , B32B2307/736 , C08J5/18 , C08J2323/06 , C08J2323/08 , C08J2423/06 , C08J2423/08 , C08L23/0815 , C08L2205/02 , C08L2314/06 , C08L2666/06
摘要： Disclosed are polyethylene blends and films. The blend comprises from 1 to 99%, based on the weight of the blend, of a medium density polyethylene (MDPE) and from 1 to 99% a polyolefin selected from the group consisting of high density polyethylene (HDPE), linear low density polyethylene (LLDPE), low density polyethylene (LDPE), polypropylene, polybutene, and mixtures thereof. The MDPE is made by high pressure, free radical polymerization and has a density within the range of greater than 0.928 to 0.940 g/cm3 and an MI2 within the range of 0.1 to 1 dg/min. The shrink films made from the blend have strong contraction force and low creep.
摘要翻译：公开了聚乙烯共混物和薄膜。共混物包含1至99％（以混合物的重量计）中等密度聚乙烯（MDPE）和1至99％的选自高密度聚乙烯（HDPE），线性低密度聚乙烯（LLDPE），低密度聚乙烯（LDPE），聚丙烯，聚丁烯及其混合物。 MDPE由高压自由基聚合制成，密度在大于0.928至0.940g / cm3的范围内，MI2在0.1至1dg / min的范围内。由共混物制成的收缩膜具有较强的收缩力和较低的蠕变。

9. 发明授权

US07829641B2 Process for the preparation of multimodal polyethylene resins 失效
标题翻译：制备多峰聚乙烯树脂的方法
公开(公告)号：US07829641B2
公开(公告)日：2010-11-09
申请号：US12218597
申请日：2008-07-16
申请人： Bradley P. Etherton , Stephen M. Imfeld , Philip J. Garrison
发明人： Bradley P. Etherton , Stephen M. Imfeld , Philip J. Garrison
IPC分类号： C08F4/64 , C08F4/76 , C08F4/52 , C08F2/00
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/65927 , Y02P20/52 , C08F4/65904 , C08F2/001 , C08F210/14 , C08F2500/05 , C08F2500/07 , C08F2500/12 , C08F210/08
摘要： A two-stage cascade polymerization process for the production of multimodal polyethylene film resins with improved bubble stability is provided. The process comprises polymerizing ethylene or a mixture of ethylene and a C4-8 α-olefin in two reactors arranged in series using a mixed single-site catalyst comprised of a bridged and a non-bridged indenoindolyl transition metal complex to form a multimodal polyethylene resin comprised of a lower molecular weight, higher density component and a higher molecular weight, lower density component.
摘要翻译：提供了用于生产具有改善气泡稳定性的多峰聚乙烯薄膜树脂的两级级联聚合方法。该方法包括使用由桥连和非桥连的茚并吲哚基过渡金属络合物组成的混合单中心催化剂在串联排列的两个反应器中聚合乙烯或乙烯与C 4-8α-烯烃的混合物，以形成多峰聚乙烯树脂包括较低分子量，较高密度组分和较高分子量，较低密度组分。

10. 发明授权

US07816478B2 Polyethylene thick film and process for preparing polyethylene 失效
公开(公告)号：US07816478B2
公开(公告)日：2010-10-19
申请号：US12231458
申请日：2008-09-03
申请人： Bradley P. Etherton , Stephen M. Imfeld , Mohan Sasthav
发明人： Bradley P. Etherton , Stephen M. Imfeld , Mohan Sasthav
IPC分类号： C08F210/14 , C08F10/14 , C08F4/64 , C08F4/76
CPC分类号： C08F210/16 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F2420/05 , C08J5/18 , C08J2323/08 , C08L23/06 , C08L23/0815 , C08F4/65916 , C08F4/65904 , C08L2666/06 , C08F210/14 , C08F2500/12 , C08F2500/08 , C08F2500/05 , C08F210/08
摘要： A thick film and process to prepare polyethylene useful for the film are disclosed. Ethylene is polymerized in two reaction zones with a C6-C10 α-olefin in the presence of a catalyst system comprising an activator, a supported bridged zirconium complex, and a supported non-bridged zirconium complex. The process yields medium density to linear low density polyethylene having a melt index from 0.20 to 1.0 dg/min. Thick films from the polyethylene have a superior combination of high impact strength and high modulus.

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