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1. 发明授权

US06759493B1 Transition metal catalysts containing bidentate ligands and method of using and preparing same 失效
标题翻译：含二配位体的过渡金属催化剂及其制备方法
公开(公告)号：US06759493B1
公开(公告)日：2004-07-06
申请号：US08872659
申请日：1997-06-10
申请人： Sandor Nagy , Leonard V. Cribbs , Bradley P. Etherton , Mary Cocoman , Ramesh Krishnamurti , John A. Tyrell
发明人： Sandor Nagy , Leonard V. Cribbs , Bradley P. Etherton , Mary Cocoman , Ramesh Krishnamurti , John A. Tyrell
IPC分类号： C08F444
CPC分类号： C08F10/00 , B01J31/181 , B01J31/1815 , B01J31/1825 , B01J31/2208 , B01J31/2226 , B01J31/226 , B01J31/2295 , B01J31/2404 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/56 , B01J2531/57 , B01J2531/62 , B01J2531/66 , B01J2531/828 , C07F7/003 , C07F7/28 , C07F17/00 , C08F4/659 , C08F4/65912 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2420/04 , Y10S526/943 , C08F4/64 , C08F4/6592 , C08F2500/12 , C08F210/08 , C08F2500/07 , C08F2500/03 , C08F4/64048
摘要： Disclosed is a novel bidentate pyridine transition metal catalyst having the general formula where each R is independently hydrogen, C1-6 alkyl, or C6-14 aryl; where each R′ is independently R, C1-6 alkoxy, C7-20 alkaryl, C7-20 aralkyl, halogen, or CF3; where M is a Group 3 to 10 metal; where each X is independently halogen, C1-6 alkyl, C6-14 aryl, C7-20 alkaryl, C7-20 aralkyl, C1-6 alkoxy, or L is X, cyclopentadienyl, C1-16 alkyl-substituted cyclopentadienyl, fluorenyl, indenyl, or where n is an integer from 1 to 4; a is an integer from 1 to 3; b is an integer from 0 to 2; the sum of a+b≦3; c is an integer from 1 to 6; and the sum a+b+c equals the oxidation state of M.
摘要翻译：公开了一种新颖的二齿吡啶过渡金属催化剂，其具有通式，其中每个R独立地为氢，C 1-6烷基或C 6-14芳基;其中每个R'独立地为R，C 1-6烷氧基，C 7-20烷芳基， 20芳烷基，卤素或CF 3;其中M是第3至10族金属;其中每个X独立地是卤素，C 1-6烷基，C 6-14芳基，C 7-20烷芳基，C 7-20芳烷基，C 1-6烷氧基，或L是X，环戊二烯基，C 1-6烷基取代的环戊二烯基，芴基，茚基，或者是1至4的整数; a是1至3的整数; b是0至2的整数; a + b <= 3; c是1至6的整数; 和a + b + c之和等于M的氧化态。

2. 发明授权

US06486270B1 High molecular weight, medium density polyethylene 失效
标题翻译：高分子量，中密度聚乙烯
公开(公告)号：US06486270B1
公开(公告)日：2002-11-26
申请号：US09648303
申请日：2000-08-25
申请人： Philip J. Garrison , Lawrence R. Wallace , Danny L. Wise , James H. Meas, Jr. , Leonard V. Cribbs , Jean A. Merrick-Mack , Paula L. Nygard
发明人： Philip J. Garrison , Lawrence R. Wallace , Danny L. Wise , James H. Meas, Jr. , Leonard V. Cribbs , Jean A. Merrick-Mack , Paula L. Nygard
IPC分类号： C08F204
CPC分类号： C08F297/08 , C08F210/16 , C08F255/00 , C08L23/0815 , C08L2205/02 , C08L2308/00 , C08L2314/06 , Y10S526/905 , C08F2/001 , C08L2666/04 , C08F210/08 , C08F2500/12 , C08F2500/05 , C08F2500/26
摘要： A high molecular weight, medium density polyethylene (HMW, MDPE) is disclosed. The polyethylene comprises from about 85 to about 98 wt % of recurring units of ethylene and about 2 to about 15 wt % of a C3-C10 &agr;-olefin. It has a density from about 0.92 to about 0.944 g/cc, a melt index MI2 from about 0.01 to about 0.5 dg/min, and a melt flow ratio MFR from about 50 to about 300. It has a multimodal molecular weight distribution comprising a high molecular weight component and a low molecular weight component. The low molecular weight component has an MI2 from about 50 to about 600 dg/min and a density from about 0.94 to about 0.97 g/cc. A process for making the medium density polyethylene is also disclosed. The process uses a Ziegler catalyst and applies multiple reaction zones.
摘要翻译：公开了高分子量，中密度聚乙烯（HMW，MDPE）。聚乙烯包含约85至约98重量％的乙烯重复单元和约2至约15重量％的C 3 -C 10α-烯烃。其密度为约0.92至约0.944g / cc，熔体指数MI2为约0.01至约0.5dg / min，熔体流动比MFR为约50至约300.它具有多峰分子量分布，其包含高分子量组分和低分子量组分。低分子量组分具有约50至约600dg / min的MI2和约0.94至约0.97g / cc的密度。还公开了制备中密度聚乙烯的方法。该方法使用齐格勒催化剂并应用多个反应区。

3. 发明授权

US06410764B1 Method for preparation of boratabenzene derivatives 失效
标题翻译：硼代苯衍生物的制备方法
公开(公告)号：US06410764B1
公开(公告)日：2002-06-25
申请号：US09764722
申请日：2001-01-18
申请人： Leonard V. Cribbs , Bradley P. Etherton
发明人： Leonard V. Cribbs , Bradley P. Etherton
IPC分类号： C07F502
CPC分类号： C07F17/00 , C07F5/027
摘要： A process for preparing boratabenzene derivatives is provided. The process includes the hydrogenation of a compound containing a boranaphthalene functional group to form a boratabenzene-containing compound. Depending on the compound containing a boranaphthalene functional group, the resulting boratabenzene compound may be converted into a catalyst suitable for olefin polymerization. A process for forming a boratabenzene derivative from a halo-dioxaborolane is also provided. In this process, a halo-dioxaborolane is reacted with a piperylide salt for form a pentadienyl dioxaborolane. The pentadienyl-dioxaborolane is reacted with a strong base to form an intermediate boratacyclohexanediene salt. The intermediate boratacyclohexanediene salt is then reacted with a trialkylaluminum compound to form an alkylboratabenzene salt.
摘要翻译：提供了一种制备硼代苯衍生物的方法。该方法包括含有硼烷官能团的化合物的氢化以形成含硼代苯的化合物。根据含有硼烷官能团的化合物，所得的硼代苯化合物可以转化为适用于烯烃聚合的催化剂。还提供了由卤代二氧硼烷制备硼代苯衍生物的方法。在该方法中，将卤代二氧杂硼杂环戊烷与哌啶子盐反应形成戊二烯基二氧杂硼杂环戊烷。将戊二烯基二氧杂硼杂环戊烷与强碱反应形成中间体硼烷环己烷二盐。然后将中间体硼烷环己二烯盐与三烷基铝化合物反应以形成烷基硼代苯盐。

4. 发明授权

US5637660A Polymerization of .alpha.-olefins with transition metal catalysts based on bidentate ligands containing pyridine or quinoline moiety 失效
标题翻译：基于含有吡啶或喹啉部分的二齿配体的过渡金属催化剂聚合α-烯烃
公开(公告)号：US5637660A
公开(公告)日：1997-06-10
申请号：US423232
申请日：1995-04-17
申请人： Sandor Nagy , Ramesh Krishnamurti , John A. Tyrell , Leonard V. Cribbs , Mary Cocoman
发明人： Sandor Nagy , Ramesh Krishnamurti , John A. Tyrell , Leonard V. Cribbs , Mary Cocoman
IPC分类号： B01J31/12 , B01J31/18 , B01J31/22 , B01J31/24 , C07F7/00 , C07F7/28 , C07F9/58 , C07F9/60 , C07F17/00 , C08F4/64 , C08F4/642 , C08F4/659 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16
CPC分类号： C08F10/00 , B01J31/181 , B01J31/1815 , B01J31/1825 , B01J31/2208 , B01J31/2226 , B01J31/2295 , C07F17/00 , C07F7/006 , C07F7/28 , C08F10/02 , B01J2531/46 , B01J2531/48 , B01J2531/49 , B01J2531/56 , B01J2531/57 , B01J2531/62 , B01J2531/66 , B01J2531/828 , B01J31/226 , B01J31/2404 , C08F110/02 , C08F210/16 , C08F2420/04 , C08F4/659 , C08F4/65912 , Y10S526/943
摘要： Disclosed is a novel bidentate pyridine transition metal catalyst having the general formula ##STR1## where Y is O, S, NR, ##STR2## each R is independently selected from hydrogen or C.sub.1 to C.sub.6 alkyl, each R' is independently selected from C.sub.1 to C.sub.6 alkyl, C.sub.1 to C.sub.6 alkoxy, C.sub.6 to C.sub.16 aryl, halogen, or CF.sub.3, M is titanium, zirconium, or hafnium, each X is independently selected from halogen, C.sub.1 to C.sub.6 alkyl, C.sub.1 to C.sub.6 alkoxy, or ##STR3## L is X, cyclopentadienyl, C.sub.1 to C.sub.6 alkyl substituted cyclopentadienyl, indenyl, fluorenyl, or ##STR4## and "n" is 1 to 4. Also disclosed is a method of making a poly-.alpha.-olefin comprising polymerizing an .alpha.-olefin monomer using that catalyst or a catalyst that has the general formula ##STR5## where Y, M, L, X, and R' were previously defined.
摘要翻译：公开了具有通式为“IMAGE”的新型二齿吡啶过渡金属催化剂，其中Y为O，S，NR，每个R独立地选自氢或C1至C6烷基，每个R'独立地选自C1至 C6烷基，C1至C6烷氧基，C6至C16芳基，卤素或CF3，M为钛，锆或铪，每个X独立地选自卤素，C1至C6烷基，C1至C6烷氧基或“ 是X，环戊二烯基，C1至C6烷基取代的环戊二烯基，茚基，芴基或“IMAGE”，“n”为1至4.还公开了一种制备聚-α-烯烃的方法，包括使用α-烯烃单体聚合该催化剂或具有通式“IMAGE”的催化剂，其中Y，M，L，X和R'被预先定义。

5. 发明授权

US06770715B2 High molecular weight, medium density polyethylene 失效
标题翻译：高分子量，中密度聚乙烯
公开(公告)号：US06770715B2
公开(公告)日：2004-08-03
申请号：US10242191
申请日：2002-09-12
申请人： Philip J. Garrison , Lawrence R. Wallace , Danny L. Wise , James H. Meas , Leonard V. Cribbs , Jean A. Merrick-Mack , Paula L. Nygard
发明人： Philip J. Garrison , Lawrence R. Wallace , Danny L. Wise , James H. Meas , Leonard V. Cribbs , Jean A. Merrick-Mack , Paula L. Nygard
IPC分类号： C08F21002
CPC分类号： C08F297/08 , C08F210/16 , C08F255/00 , C08L23/0815 , C08L2205/02 , C08L2308/00 , C08L2314/06 , Y10S526/905 , C08F2/001 , C08L2666/04 , C08F210/08 , C08F2500/12 , C08F2500/05 , C08F2500/26
摘要： A high molecular weight, medium density polyethylene (HMW, MDPE) is disclosed. The polyethylene comprises from about 85 to about 98 wt % of recurring units of ethylene and about 2 to about 15 wt % of a C3-C10 &agr;-olefin. It has a density from about 0.92 to about 0.944 g/cc, a melt index MI2 from about 0.01 to about 0.5 dg/min, and a melt flow ratio MFR from about 50 to about 300. It has a multimodal molecular weight distribution comprising a high molecular weight component and a low molecular weight component. The low molecular weight component has an MI2 from about 50 to about 600 dg/min and a density from about 0.94 to about 0.97 g/cc. A process for making the medium density polyethylene is also disclosed. The process uses a Ziegler catalyst and applies multiple reaction zones.
摘要翻译：公开了高分子量，中密度聚乙烯（HMW，MDPE）。聚乙烯包含约85至约98重量％的乙烯重复单元和约2至约15重量％的C 3 -C 10α-烯烃。其密度为约0.92至约0.944g / cc，熔体指数MI2为约0.01至约0.5dg / min，熔体流动比MFR为约50至约300.它具有多峰分子量分布，其包含高分子量组分和低分子量组分。低分子量组分具有约50至约600dg / min的MI2和约0.94至约0.97g / cc的密度。还公开了制备中密度聚乙烯的方法。该方法使用齐格勒催化剂并应用多个反应区。

6. 发明授权

US5298579A Olefin polymerization process 失效
标题翻译：烯烃聚合工艺
公开(公告)号：US5298579A
公开(公告)日：1994-03-29
申请号：US976194
申请日：1992-11-13
申请人： Raymond E. Hoff , Leonard V. Cribbs
发明人： Raymond E. Hoff , Leonard V. Cribbs
IPC分类号： C08F4/609 , C08F10/00 , C08J9/00
CPC分类号： C08F10/00 , Y10S526/904 , Y10S526/943
摘要： A method of using a catalyst with a suitable cocatalyst in the polymerization or copolymerization of 1-olefins are disclosed. The catalyst is prepared by: a) contacting a Group IIA organometallic compound, like 2-methylpentanoxymagnesium chloride, or a Group III organometallic compound, like triethylaluminum, or a combination thereof, with a porous or nonporous biodegradable substrate having active surface hydroxyl groups, like cellulose, to provide a modified biodegradable substrate; then b) contacting the modified biodegradable substrate with a transition metal compound, such as a transition metal halide or alkoxide, like titanium tetrachloride or vanadium (V) trichloride oxide, to form discrete catalyst particles. The catalyst particles are used in conjunction with a suitable cocatalyst, like triethylaluminum, in the homopolymerization or copolymerization of 1-olefins. During polymerization, porous biodegradable catalyst particles are fragmented into small solid particles that are trapped within polymer. The fragmented catalyst particles are allowed to remain within the polymer; do not adversely affect the physical or esthetic properties of the polymer or articles made therefrom; and serve as biodegradable sites that facilitate environmental degradation of the polymer.
摘要翻译：公开了在1-烯烃的聚合或共聚中使用具有合适助催化剂的催化剂的方法。该催化剂通过以下方法制备：a）使IIA族有机金属化合物如2-甲基戊氧基氯化镁或III族有机金属化合物如三乙基铝或其组合与具有活性表面羟基的多孔或无孔可生物降解底物接触，如纤维素，以提供改性的可生物降解底物; 然后b）使改性的可生物降解底物与过渡金属化合物如过渡金属卤化物或醇盐如四氯化钛或钒（V）三氯化氧接触，以形成离散的催化剂颗粒。催化剂颗粒与合适的助催化剂如三乙基铝一起用于1-烯烃的均聚或共聚。在聚合过程中，多孔可生物降解的催化剂颗粒被分散在被聚集在聚合物内的小固体颗粒中。使碎裂的催化剂颗粒保留在聚合物内; 不会对聚合物或由其制成的制品的物理或美学性质产生不利影响; 并且用作促进聚合物环境降解的可生物降解位点。

7. 发明授权

US07423098B2 Polyethylene process 有权
标题翻译：聚乙烯工艺
公开(公告)号：US07423098B2
公开(公告)日：2008-09-09
申请号：US11333576
申请日：2006-01-17
申请人： Philip J. Garrison , Charles S. Holland , Mark P. Mack , Linda N. Winslow , Everett O. Lewis , James R. Clark , Leonard V. Cribbs , Bradley P. Etherton , Jean A. Merrick-Mack , Paula L. Nygard
发明人： Philip J. Garrison , Charles S. Holland , Mark P. Mack , Linda N. Winslow , Everett O. Lewis , James R. Clark , Leonard V. Cribbs , Bradley P. Etherton , Jean A. Merrick-Mack , Paula L. Nygard
IPC分类号： C08F4/6192 , C08F4/6592 , C08F210/14 , C08F210/16
CPC分类号： C08F210/16 , Y10S526/905 , C08F2/001 , C08F2/14 , C08F210/08 , C08F2500/12 , C08F2500/26 , C08F210/14
摘要： An ethylene polymerization process is disclosed. Ethylene is polymerized in two slurry reaction zones with a C6-C10 alpha-olefin in the presence of a single-site catalyst capable of making a high molecular weight polyolefin. The process yields medium density and linear low density polyethylene having a bimodal molecular weight distribution and a melt index from about 0.10 to about 0.80. Films from the polyethylene have superior impact properties.
摘要翻译：公开了一种乙烯聚合方法。在能够制备高分子量聚烯烃的单中心催化剂的存在下，乙烯在两个浆料反应区中与C 6 -C 10α-烯烃聚合。该方法产生具有双峰分子量分布和约0.10至约0.80的熔体指数的中密度和线性低密度聚乙烯。聚乙烯薄膜具有优异的冲击性能。

8. 发明授权

US06211311B1 Supported olefin polymerization catalysts 有权
标题翻译：负载型烯烃聚合催化剂
公开(公告)号：US06211311B1
公开(公告)日：2001-04-03
申请号：US09318008
申请日：1999-05-25
申请人： Shaotian Wang , Bradley P. Etherton , Karen E. Meyer , Michael W. Lynch , Linda N. Winslow , Leonard V. Cribbs , Jia-Chu X. Liu
发明人： Shaotian Wang , Bradley P. Etherton , Karen E. Meyer , Michael W. Lynch , Linda N. Winslow , Leonard V. Cribbs , Jia-Chu X. Liu
IPC分类号： C08F442
CPC分类号： B01J31/165 , B01J31/0231 , B01J31/0272 , B01J31/0274 , B01J31/0275 , B01J31/14 , B01J31/1616 , B01J31/2295 , B01J2531/0225 , B01J2531/0233 , B01J2531/0236 , B01J2531/46 , B01J2531/48 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/65916 , C08F210/08 , C08F210/14
摘要： A supported olefin polymerization catalyst system and a method of making it are disclosed. The catalyst system comprises: (a) a support chemically treated with an organoaluminum, organosilicon, organomagnesium, or organoboron compound; (b) a single-site catalyst that contains a polymerization-stable, heteroatomic ligand; and (c) an activator. Chemical treatment is a key to making supported heterometallocenes that have high activity and long shelf-lives, and can effectively incorporate comonomers.
摘要翻译：公开了一种负载型烯烃聚合催化剂体系及其制备方法。催化剂体系包括：（a）用有机铝，有机硅，有机镁或有机硼化合物化学处理的载体; （b）含有聚合稳定的杂原子配体的单中心催化剂; 和（c）活化剂。化学处理是制备具有高活性和长保质期的负载型异金属茂并能有效掺入共聚单体的关键。

9. 发明授权

US6121183A Modified polysiloxane catalysts and a method of using the same 失效
标题翻译：改性聚硅氧烷催化剂及其使用方法
公开(公告)号：US6121183A
公开(公告)日：2000-09-19
申请号：US859319
申请日：1997-05-20
申请人： Leonard V. Cribbs , John A. Tyrell , Sandor Nagy
发明人： Leonard V. Cribbs , John A. Tyrell , Sandor Nagy
IPC分类号： C08F4/605 , C08F4/02 , C08F4/52 , C08F4/60 , C08F4/616 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/642 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/42 , C08F4/58
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , C08F4/61912 , C08F4/61916 , C08F4/6192 , Y10S526/943
摘要： Catalysts for the polymerization of olefins contain units of the formula: wherein ##STR1## each R is independently selected from a C.sub.1 to C.sub.10 aliphatic or cycloaliphatic group or a C.sub.6 to C.sub.18 aryl, aralkyl, or alkaryl;each R.sup.2 is independently selected from hydride, R, and Q radicals wherein at least one R.sup.2 is Q;Q has the general formulaLM.sup.p L'.sub.r X.sub.p-r-1whereinL is a monoanionic aromatic ancillary ligand pi-bonded to M and covalently bonded to Si;L' is a monoanionic aromatic ancillary ligand pi-bonded to M and optionally bonded to L through a covalent bridging group;M is a metal selected from Groups 3-10 of the Periodic Table or lanthanides;X is independently selected from a hydride radical, halide radical, hydrocarbyl radical, halocarbyl radical, silahydrocarbyl, alkoxy radical, aryloxy radical, alkylsulfonate radical, arylsulfonate radical or (R).sub.2 N-- radical; or two X groups are joined with M to form a metallacycle, silametallacycle or pi-diene metallacycle moiety;p is the valence of M;r is 0 or 1; andn is an integer between about 10 and about 500.
摘要翻译：用于烯烃聚合的催化剂含有下式的单元：其中每个R独立地选自C1至C10脂族或脂环族基团或C6至C18芳基，芳烷基或烷芳基; 每个R 2独立地选自氢化物，R和Q基团，其中至少一个R 2是Q; Q具有通式LMpL'rXp-r-1，其中L是与M键合并与Si共价结合的单阴离子芳族辅助配体; L'是与M键合的单阴离子芳族辅助配体，并且任选地通过共价桥连基团与L键合; M是选自元素周期表第3-10族或镧系元素的金属; X独立地选自氢化物基，卤化物基，烃基，卤代烃基，硅烷烃基，烷氧基，芳氧基，烷基磺酸根，芳基磺酸根或（R）或两个X基团与M连接以形成金属环，硅烷环或者偕二烯金属环部分; p是M的化合价; r为0或1; n为约10至约500的整数。

10. 发明授权

US5202397A Olefin polymerization method 失效
公开(公告)号：US5202397A
公开(公告)日：1993-04-13
申请号：US923147
申请日：1992-07-31
申请人： Leonard V. Cribbs , Michael W. Lynch
发明人： Leonard V. Cribbs , Michael W. Lynch
摘要： A multiple site solid catalyst component capable of producing polyolefins having a broad or multimodal molecular weight distribution, such as a bimodal molecular weight distribution, is prepared by contacting a particulate solid support with a zirconium compound or complex to bind the zirconium compound or complex to the support, optionally followed by contacting the supported zirconium compound or complex with a Lewis acid to produce an intermediate product, optionally isolating and washing the supported zirconium compound or complex or resulting intermediate product to remove soluble by-products therefrom, and reacting the washed or unwashed supported zirconium compound or complex or intermediate product with a titanium or vanadium compound to produce a solid catalyst component.

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