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1. 发明授权

US4705620A Mercaptan extraction process 失效
标题翻译：硫醇提取过程
公开(公告)号：US4705620A
公开(公告)日：1987-11-10
申请号：US942147
申请日：1986-12-16
申请人： Jeffery C. Bricker , Bruce E. Staehle
发明人： Jeffery C. Bricker , Bruce E. Staehle
IPC分类号： C10G11/00 , B01D53/48 , B01D53/86 , B01J23/44 , B01J31/22 , C07B61/00 , C07C67/00 , C07C313/00 , C07C319/06 , C07C321/02 , C10G19/02 , C10G19/08 , C10G53/02 , C10G19/00 , C10G45/00
CPC分类号： C10G19/02 , C10G19/08
摘要： A process is disclosed for treating a sour hydrocarbon stream comprising extracting the mercaptans contained in said hydrocarbon stream with an alkaline solution in an extraction zone, oxidizing the mercaptans to disulfides in the presence of an oxidation catalyst, separating said disulfide from said alkaline solution, reducing the residual disulfides in said alkaline solution to mercaptans and recycling said alkaline solution to the extraction zone. Two ways are disclosed to effect the reduction of the disulfides to mercaptans: (1) hydrogenation with a supported metal catalyst and (2) electrochemical reduction.

2. 发明授权

US08931646B2 Polybenzoxazole membranes 有权
标题翻译：聚苯并恶唑膜
公开(公告)号：US08931646B2
公开(公告)日：2015-01-13
申请号：US12879208
申请日：2010-09-10
申请人： Chunqing Liu , Raisa Minkov , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
发明人： Chunqing Liu , Raisa Minkov , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
IPC分类号： B01D71/64 , B01D71/28 , B01D53/22 , B01D67/00 , B01D71/62 , B01D71/82 , B01D69/00 , B01D61/36
CPC分类号： B01D53/228 , B01D61/362 , B01D67/0011 , B01D71/62 , B01D71/82 , B01D2323/08
摘要： The present invention discloses a blends of an aromatic polyimide polymer and a polymer containing aromatic sulfonic acid groups that can be converted into polybenzoxazole (PBO) membranes for gas, vapor, and liquid separations. The PBO membranes that were prepared by thermal treating aromatic polyimide membranes containing between 0.05 and 20 wt-% of a poly(styrene sulfonic acid) polymer. These polymers showed up to 95% improvement in selectivity for CO2/CH4 and H2/CH4 separations compared to PBO membranes prepared from corresponding aromatic polyimide membranes without a poly(styrene sulfonic acid) polymer.
摘要翻译：本发明公开了芳族聚酰亚胺聚合物和含有芳族磺酸基团的聚合物的混合物，其可以转化成用于气体，蒸气和液体分离的聚苯并恶唑（PBO）膜。通过热处理含有0.05至20重量％聚（苯乙烯磺酸）聚合物的芳族聚酰亚胺膜制备的PBO膜。与没有聚（苯乙烯磺酸）聚合物的相应芳族聚酰亚胺膜制备的PBO膜相比，这些聚合物显示出对CO 2 / CH 4和H 2 / CH 4分离的选择性提高高达95％。

3. 发明申请

US20130253239A1 Heavy Alkylbenzene Production Through Oligomerization 审中-公开
标题翻译：通过低聚产生重质烷基苯
公开(公告)号：US20130253239A1
公开(公告)日：2013-09-26
申请号：US13428559
申请日：2012-03-23
申请人： Andrea G. Bozzano , Jeffery C. Bricker , Bryan K. Glover
发明人： Andrea G. Bozzano , Jeffery C. Bricker , Bryan K. Glover
IPC分类号： C07C7/00 , C07C7/10
CPC分类号： C07C7/167 , C07C2/06 , C07C2/64 , C07C5/327 , C07C7/163 , C10G9/00 , C10G29/205 , C10G45/32 , C10G50/00 , C10G57/005 , C10G57/02 , C10G69/00 , C10G2300/1011 , C10G2300/1022 , C10G2300/4081 , C10G2400/22 , C10G2400/30 , C07C11/02 , C07C15/107
摘要： A process for producing heavy alkyl aromatics is presented. The process utilizes low molecular weight hydrocarbons for generating larger alkyl groups. The hydrocarbons can be generated from a variety of sources including Fischer-Tropsch liquids. The process includes oligomerization of low molecular weight olefins to larger olefins. The larger olefins are passed to an alkylation reactor to alkylate aromatic compounds.
摘要翻译：提出了一种生产重质烷基芳烃的方法。该方法利用低分子量烃来产生较大的烷基。烃可以从各种来源产生，包括费 - 托液体。该方法包括将低分子量烯烃低聚成较大的烯烃。较大的烯烃通入烷基化反应器以烷基化芳族化合物。

4. 发明申请

US20110152066A1 LAYERED COMPOSITION AND PROCESSES FOR PREPARING AND USING THE COMPOSITION 审中-公开
标题翻译：层状组合物和制备和使用组合物的方法
公开(公告)号：US20110152066A1
公开(公告)日：2011-06-23
申请号：US13036517
申请日：2011-02-28
申请人： Tao Wang , Dean E. Rende , James E. Rekoske , Jeffery C. Bricker , Jeffrey L. Boike , Masao Takayama , Kouji Hara , Nobuyuki Aoi
发明人： Tao Wang , Dean E. Rende , James E. Rekoske , Jeffery C. Bricker , Jeffrey L. Boike , Masao Takayama , Kouji Hara , Nobuyuki Aoi
IPC分类号： B01J37/02 , B01J29/068 , B01J37/08
CPC分类号： B01J37/0242 , B01J23/44 , B01J23/52 , B01J23/58 , B01J37/0219 , B01J37/0221 , C07C67/055 , C07C69/01 , C07C69/15
摘要： A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes including production of vinyl acetate.
摘要翻译：已经开发了可用于各种方法的分层组合物。该组合物包括内核，例如堇青石芯，外层包含耐火无机氧化物，纤维组分和无机粘合剂。难熔无机氧化物层可以是氧化铝，氧化锆，二氧化钛等，而纤维成分可以是二氧化钛纤维，二氧化硅纤维，碳纤维等。无机氧化物粘合剂可以是氧化铝，二氧化硅，氧化锆等。该层也可以含有催化金属如金和铂加其他改性剂。通过用包含耐火无机氧化物，纤维组分，无机粘合剂前体和有机粘合剂如聚乙烯醇的浆料涂覆内芯来制备层状组合物。该组合物可用于各种烃转化方法，包括生产乙酸乙烯酯。

5. 发明授权

US07897804B2 Processes for preparing alkenyl alkanoates using a layered catalyst composition 有权
标题翻译：使用层状催化剂组合物制备烯基链烷酸酯的方法
公开(公告)号：US07897804B2
公开(公告)日：2011-03-01
申请号：US12098951
申请日：2008-04-07
申请人： Tao Wang , Dean E. Rende , James E. Rekoske , Jeffery C. Bricker , Jeffrey L. Boike , Masao Takayama , Kouji Hara , Nobuyuki Aoi
发明人： Tao Wang , Dean E. Rende , James E. Rekoske , Jeffery C. Bricker , Jeffrey L. Boike , Masao Takayama , Kouji Hara , Nobuyuki Aoi
IPC分类号： C07C67/05
CPC分类号： B01J37/0242 , B01J23/44 , B01J23/52 , B01J23/58 , B01J37/0219 , B01J37/0221 , C07C67/055 , C07C69/01 , C07C69/15
摘要： A layered composition which can be used in various processes has been developed. The composition comprises an inner core such as a cordierite core and an outer layer comprising a refractory inorganic oxide, a fibrous component and an inorganic binder. The refractory inorganic oxide layer can be alumina, zirconia, titania, etc. while the fibrous component can be titania fibers, silica fibers, carbon fibers, etc. The inorganic oxide binder can be alumina, silica, zirconia, etc. The layer can also contain catalytic metals such as gold and platinum plus other modifiers. The layered composition is prepared by coating the inner core with a slurry comprising the refractory inorganic oxide, fibrous component, an inorganic binder precursor and an organic binding agent such as polyvinyl alcohol. The composition can be used in various hydrocarbon conversion processes including production of vinyl acetate.
摘要翻译：已经开发了可用于各种方法的分层组合物。该组合物包括内核，例如堇青石芯，外层包含耐火无机氧化物，纤维组分和无机粘合剂。难熔无机氧化物层可以是氧化铝，氧化锆，二氧化钛等，而纤维成分可以是二氧化钛纤维，二氧化硅纤维，碳纤维等。无机氧化物粘合剂可以是氧化铝，二氧化硅，氧化锆等。该层也可以含有催化金属如金和铂加其他改性剂。通过用包含耐火无机氧化物，纤维组分，无机粘合剂前体和有机粘合剂如聚乙烯醇的浆料涂覆内芯来制备层状组合物。该组合物可用于各种烃转化方法，包括生产乙酸乙烯酯。

6. 发明申请

US20100331437A1 POLYBENZOXAZOLE MEMBRANES PREPARED FROM AROMATIC POLYAMIDE MEMBRANES 有权
标题翻译：从芳族聚酰胺膜制备的聚苯并噻唑膜
公开(公告)号：US20100331437A1
公开(公告)日：2010-12-30
申请号：US12879244
申请日：2010-09-10
申请人： Chunqing Liu , Raisa Minkov , Syed A. Faheem , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
发明人： Chunqing Liu , Raisa Minkov , Syed A. Faheem , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
IPC分类号： C08F24/00
CPC分类号： B01D53/228 , B01D71/62 , B01D2323/30 , B01D2323/345 , C08G69/26 , C08G69/32 , C08G73/22 , C08L79/04 , H01M8/1027 , H01M8/103
摘要： The present invention discloses high performance polybenzoxazole membranes prepared from aromatic poly(o-hydroxy amide) membranes by thermal cyclization and a method for using these membranes. The polybenzoxazole membranes were prepared by thermal treating aromatic poly(o-hydroxy amide) membranes in a temperature range of 200° to 550° C. under inert atmosphere. The aromatic poly(o-hydroxy amide) membranes used for making the polybenzoxazole membranes were prepared from aromatic poly(o-hydroxy amide) polymers comprising pendent phenolic hydroxyl groups ortho to the amide nitrogen in the polymer backbone. In some embodiments of the invention, the polybenzoxazole membranes may be subjected to an additional crosslinking step to increase the selectivity of the membranes. These polybenzoxazole membranes showed significantly improved permeability for gas separations compared to the precursor aromatic poly(o-hydroxy amide) membranes and are not only suitable for a variety of liquid, gas, and vapor separations, but also can be used in catalysis and fuel cells.
摘要翻译：本发明公开了通过热环化由芳族聚（邻羟基酰胺）膜制备的高性能聚苯并恶唑膜和使用这些膜的方法。通过在惰性气氛下在200〜550℃的温度范围内热处理芳族聚（邻羟基酰胺）膜来制备聚苯并恶唑膜。用于制备聚苯并恶唑膜的芳族聚（邻羟基酰胺）膜是由芳族聚（邻羟基酰胺）聚合物制备的，该聚合物包括聚合物骨架中酰胺氮原子邻位的酚羟基。在本发明的一些实施方案中，聚苯并恶唑膜可以进行额外的交联步骤以增加膜的选择性。与前体芳族聚（邻羟基酰胺）膜相比，这些聚苯并恶唑膜显示出显着改善气体分离的渗透性，并且不仅适用于各种液体，气体和蒸气分离，而且还可用于催化和燃料电池。

7. 发明授权

US07810652B2 Method to improve the selectivity of polybenzoxazole membranes 有权
标题翻译：提高聚苯并恶唑膜选择性的方法
公开(公告)号：US07810652B2
公开(公告)日：2010-10-12
申请号：US12566834
申请日：2009-09-25
申请人： Chunqing Liu , Raisa Minkov , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
发明人： Chunqing Liu , Raisa Minkov , Man-Wing Tang , Lubo Zhou , Jeffery C. Bricker
IPC分类号： B01D71/64 , B01D71/28 , B01D69/00
CPC分类号： B01D53/228 , B01D67/0093 , B01D71/62 , B01D2323/08
摘要： The present invention discloses a novel method to improve the selectivities of polybenzoxazole (PBO) membranes prepared from aromatic polyimide membranes for gas, vapor, and liquid separations. The PBO membranes that were prepared by thermal treating aromatic polyimide membranes containing between 0.05 and 20 wt-% of a poly(styrene sulfonic acid) polymer. These polymers showed up to 95% improvement in selectivity for CO2/CH4 and H2/CH4 separations compared to PBO membranes prepared from corresponding aromatic polyimide membranes without a poly(styrene sulfonic acid) polymer.
摘要翻译：本发明公开了一种提高由芳族聚酰亚胺膜制备的用于气体，蒸汽和液体分离的聚苯并恶唑（PBO）膜的选择性的新方法。通过热处理含有0.05至20重量％聚（苯乙烯磺酸）聚合物的芳族聚酰亚胺膜制备的PBO膜。与没有聚（苯乙烯磺酸）聚合物的相应芳族聚酰亚胺膜制备的PBO膜相比，这些聚合物显示出对CO 2 / CH 4和H 2 / CH 4分离的选择性提高高达95％。

8. 发明申请

US20100041929A1 Selective Hydrogenation Processes Using Functional Surface Catalyst Composition 审中-公开
标题翻译：使用功能性表面催化剂组合物的选择性氢化方法
公开(公告)号：US20100041929A1
公开(公告)日：2010-02-18
申请号：US12447115
申请日：2007-11-09
申请人： Robert L Bedard , Jeffery C. Bricker , Ally S. Chan
发明人： Robert L Bedard , Jeffery C. Bricker , Ally S. Chan
IPC分类号： C07C5/02 , C07C5/03
CPC分类号： C07C5/02 , B01J21/08 , B01J21/12 , B01J23/26 , B01J23/30 , B01J23/32 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/48 , B01J23/72 , B01J23/74 , B01J23/75 , B01J27/185 , B01J35/002 , B01J35/0066 , B01J35/008 , B01J35/06 , B01J35/10 , B01J35/1009 , B01J37/0207 , B01J37/06 , B01J37/28 , B01J37/30 , C07C2521/12 , C07C2523/44 , C07C2523/89 , C10G45/36 , C10G45/40
摘要： Selective hydrogenation processes using a catalyst composition which, preferably comprises a glass substrate, with one or more functional surface active constituents integrated on and/or in the substrate surface. A substantially nonporous substrate has (i) a total surface area between about 0.01 m2/g and 10 m2/g; and (ii) a predetermined isoelectric point (IEP) obtained in a pH range greater than 0, preferably greater than or equal to 4.5, or more preferably greater than or equal to 6.0, but less than or equal to 14. At least one catalytically-active region may be contiguous or discontiguous and has a mean thickness less than or equal to about 30 nm, preferably less than or equal to 20 nm and more preferably less than or equal to 10 nm. Preferably, the substrate is a glass composition having a SARCNa less than or equal to about 0.5.
摘要翻译：使用催化剂组合物的选择性氢化方法，该催化剂组合物优选包含玻璃基底，其中一个或多个功能性表面活性成分集成在基底表面上和/或基底表面。基本上无孔基材具有（i）约0.01m 2 / g至10m 2 / g之间的总表面积; 和（ii）在大于0，优选大于或等于4.5，或更优选大于或等于6.0，但小于或等于14的pH范围内获得的预定等电点（IEP）。至少一种催化活性区域可以是连续的或不连续的，并且具有小于或等于约30nm，优选小于或等于20nm，更优选小于或等于10nm的平均厚度。优选地，基底是具有小于或等于约0.5的SARCNa的玻璃组合物。

9. 发明申请

US20100025628A1 Oxidation Processes Using Functional Surface Catalyst Composition 审中-公开
标题翻译：使用功能性表面催化剂组合物的氧化工艺
公开(公告)号：US20100025628A1
公开(公告)日：2010-02-04
申请号：US12447108
申请日：2007-11-09
申请人： Robert L. Bedard , Jeffery C. Bricker , Dean E. Rende , Ally S. Chan
发明人： Robert L. Bedard , Jeffery C. Bricker , Dean E. Rende , Ally S. Chan
IPC分类号： C09K3/00
CPC分类号： B01J35/06 , B01J21/08 , B01J21/12 , B01J23/26 , B01J23/30 , B01J23/32 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/48 , B01J23/72 , B01J23/74 , B01J23/75 , B01J27/185 , B01J35/002 , B01J35/0066 , B01J35/008 , B01J35/10 , B01J35/1009 , B01J37/0207 , B01J37/06 , B01J37/28 , B01J37/30 , C01B15/029 , C07D301/06 , C07D301/12 , C07D301/19 , C10G27/04 , C10G27/12
摘要： Oxidation processes using a catalyst composition which, preferably comprises a glass substrate, with one or more functional surface active constituents integrated on and/or in the substrate surface. A substantially nonporous substrate has (i) a total surface area between about 0.01 m2/g and 10 m2/g; and (ii) a predetermined isoelectric point (IEP) obtained in a pH range greater than 0, preferably greater than or equal to 4.5, or more preferably greater than or equal to 6.0, but less than or equal to 14. At least one catalytically-active region may be contiguous or discontiguous and has a mean thickness less than or equal to about 30 nm, preferably less than or equal to 20 nm and more preferably less than or equal to 10 nm. Preferably, the substrate is a glass composition having a SARCNa less than or equal to about 0.5.
摘要翻译：使用催化剂组合物的氧化方法，该催化剂组合物优选包含玻璃基底，其中一个或多个功能性表面活性成分集成在基底表面上和/或基底表面。基本上无孔基材具有（i）约0.01m 2 / g至10m 2 / g之间的总表面积; 和（ii）在大于0，优选大于或等于4.5，或更优选大于或等于6.0，但小于或等于14的pH范围内获得的预定等电点（IEP）。至少一种催化活性区域可以是连续的或不连续的，并且具有小于或等于约30nm，优选小于或等于20nm，更优选小于或等于10nm的平均厚度。优选地，基底是具有小于或等于约0.5的SARCNa的玻璃组合物。

10. 发明授权

US07422676B2 Apparatus and process for the synthesis of hydrogen peroxide directly from hydrogen and oxygen 失效
标题翻译：用于直接从氢和氧合成过氧化氢的装置和方法
公开(公告)号：US07422676B2
公开(公告)日：2008-09-09
申请号：US11313201
申请日：2005-12-20
申请人： Kurt M. Vanden Bussche , Anil R. Oroskar , Jeffery C. Bricker , Laszlo T. Nemeth , Gavin P. Towler
发明人： Kurt M. Vanden Bussche , Anil R. Oroskar , Jeffery C. Bricker , Laszlo T. Nemeth , Gavin P. Towler
IPC分类号： C25B1/30 , C25B1/04 , C01B15/029
CPC分类号： B01J8/025 , B01F5/0057 , B01F15/0201 , B01J10/007 , B01J19/002 , B01J2219/00013 , B01J2219/00263 , B01J2219/00889 , C01B15/029 , C07D223/10 , C07D301/12 , C07D313/04
摘要： A device is disclosed for the generation of hydrogen peroxide. The device produces hydrogen peroxide on an as-needed basis through the use of electrolysis of water, remixing hydrogen and oxygen in an appropriate ratio, and reacting the hydrogen and oxygen in water in a reactor.
摘要翻译：公开了用于产生过氧化氢的装置。该设备通过使用水的电解，以适当的比例重新混合氢气和氧气，并在反应器中使氢气和氧气在水中反应，根据需要生产过氧化氢。

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