专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US08039660B2 Method of producing nitrile compounds 失效
标题翻译：腈化合物的制备方法
公开(公告)号：US08039660B2
公开(公告)日：2011-10-18
申请号：US12244233
申请日：2008-10-02
申请人： Jean-Marie Basset , Yves Chauvin , Jean-Christophe Galland , Gerald Niccolai , Christine Valerio , Christophe Vallee
发明人： Jean-Marie Basset , Yves Chauvin , Jean-Christophe Galland , Gerald Niccolai , Christine Valerio , Christophe Vallee
IPC分类号： C07C253/10 , C07C255/03
CPC分类号： C07C253/10 , C07C255/04
摘要： The present invention relates to the manufacture of nitrile compounds from unsaturated organic compounds by reaction with hydrogen cyanide. It relates more particularly to the manufacture of nitrile compounds of use in the synthesis of adiponitrile, an important chemical intermediate in the manufacture of major chemical compounds, such as hexamethylenediamine and ε-caprolactam. The invention provides a process for the manufacture of organic compounds comprising at least one nitrile functional group by carrying out a hydrocyanation reaction between hydrogen cyanide and an organic compound comprising at least one ethylenic unsaturation. This reaction is carried out in the presence of a catalytic system comprising a metal element chosen from the group consisting of nickel, platinum and palladium and an organophosphorus ligand, the reaction medium additionally comprising an ionic liquid in the liquid state at least at the temperature at which the hydrocyanation reaction is carried out.
摘要翻译：本发明涉及通过与氰化氢反应从不饱和有机化合物制备腈化合物。更具体地涉及用于合成己二腈的腈化合物的制备，其是主要化学化合物如六亚甲基二胺和ε-己内酰胺的制造中的重要化学中间体。本发明提供一种制备包含至少一个腈官能团的有机化合物的方法，该方法是通过在氰化氢与包含至少一个烯属不饱和键的有机化合物之间进行氢氰化反应。该反应在包含选自镍，铂和钯的金属元素和有机磷配体的催化体系的存在下进行，所述反应介质另外包含处于液态的离子液体，至少在进行氢化反应。

2. 发明授权

US07915426B2 Imidazolium salts and their use of these ionic liquids as a solvent 有权
标题翻译：咪唑盐及其使用这些离子液体作为溶剂
公开(公告)号：US07915426B2
公开(公告)日：2011-03-29
申请号：US10399908
申请日：2001-10-25
申请人： Yves Chauvin , Lionel Magna , Gerald Peter Niccolai , Jean-Marie Basset
发明人： Yves Chauvin , Lionel Magna , Gerald Peter Niccolai , Jean-Marie Basset
IPC分类号： C07D233/64 , C07D233/66
CPC分类号： C07F7/10 , B01J31/0239 , B01J31/0244 , B01J31/0284 , B01J31/2404 , B01J31/4038 , B01J31/4053 , B01J2231/20 , B01J2531/824 , C07C311/48 , C07D231/12 , C07D233/56 , C07D249/08 , C07F5/022 , C07F7/0814 , Y02P20/542 , Y02P20/584
摘要： New 1,2,3- or 1,2,3,4- or 1,2,3,4,5- substituted imidazolium salts and their uses as solvent in catalyzed organic reactions, as well as compositions containing them and a transition metal compound. They can be used in the following reactions: the telomerisation of conjugated dienes, dimerisation of olefins, the oligomerisation of olefins, polymerization of olefins, alkylation of olefins, hydrogenation of olefins, olefin metathesis, hydroformylation of olefins, ring-closing metathesis of olefins, ring-opening metathesis polymerisation of olefins, symetric or asymetric epoxidation of olefins (including heteroatom substituted olefins) and the cyclopropanation of olefins, condensation reaction, hydrogenation reaction, isomerization reaction, Suzuki cross-coupling reactions, amination reaction, partial oxidation of alkancs, kinetic resolution of racemic mixtures, hydrogenation of imines, hydrogenation of ketones, transfer hydrogenation and hydroxylation of aromatic organic compounds.
摘要翻译：新的1,2,3-或1,2,3,4-或1,2,3,4,5-取代咪唑鎓盐及其作为催化有机反应中的溶剂的用途，以及含有它们的组合物和过渡金属复合。它们可以用于以下反应：共轭二烯的调聚，烯烃的二聚，烯烃的低聚，烯烃的聚合，烯烃的烷基化，烯烃的氢化，烯烃的复分解，烯烃的加氢甲酰化，烯烃的闭合复分解，烯烃的开环易位聚合，烯烃（包括杂原子取代烯烃）的对称或不对称环氧化和烯烃的环丙烷化，缩合反应，氢化反应，异构化反应，Suzuki交叉偶联反应，胺化反应，烷基部分氧化，动力学外消旋混合物的拆分，亚胺的氢化，酮的氢化，转移氢化和芳族有机化合物的羟基化。

3. 发明授权

US06525228B2 Process of telomerizing conjugated dienes 失效
公开(公告)号：US06525228B2
公开(公告)日：2003-02-25
申请号：US10036265
申请日：2001-10-22
申请人： Yves Chauvin , Lionel Magna , Gerald Peter Niccolai , Jean-Marie Basset
发明人： Yves Chauvin , Lionel Magna , Gerald Peter Niccolai , Jean-Marie Basset
IPC分类号： C07C4101
CPC分类号： B01J31/0284 , B01J31/2239 , B01J31/2404 , B01J2231/20 , B01J2531/824 , B01J2531/96 , B01J2540/32 , C07C29/36 , C07C41/06 , Y02P20/584 , C07C43/15 , C07C33/02
摘要： The present invention is related to a process for telomerizing a conjugated diene which comprises reacting said conjugated diene with a compound containing active hydrogen in the presence of a catalyst system comprising at least one transition metal compound, at least one phosphorus-containing compound, and at least one salt which forms a liquid under the conditions of the telomerization process.

4. 发明授权

US08871877B2 Hybrid organic-inorganic materials that contain stabilized carbene 有权
标题翻译：混合有机 - 无机材料，含有稳定的卡宾
公开(公告)号：US08871877B2
公开(公告)日：2014-10-28
申请号：US12812535
申请日：2009-01-23
申请人： Chloe Thieuleux , Christophe Coperet , Laurent Veyre , Robert Corriu , Catherine Reye , Ahmad Mehdi , Jean-Marie Basset , Tarun Maishal , Malika Boualleg , Iyad Karame , Jean-Michel Camus , Johan Alauzun
发明人： Chloe Thieuleux , Christophe Coperet , Laurent Veyre , Robert Corriu , Catherine Reye , Ahmad Mehdi , Jean-Marie Basset , Tarun Maishal , Malika Boualleg , Iyad Karame , Jean-Michel Camus , Johan Alauzun
IPC分类号： C07F1/10 , C07F15/00 , C07C45/68 , C08F4/58
CPC分类号： B01J31/2273 , B01J31/0295 , B01J31/181 , B01J2231/4211 , B01J2531/821 , B01J2531/827 , B01J2540/32
摘要： The present invention relates to materials and particularly “organometallic-organic-inorganic hybrid materials” that can be used as heterogeneous catalysts for selective catalytic reactions. More precisely this invention relates to organic-inorganic hybrid nanostructured materials comprising a regularly distributed stabilized carbene that binds strongly to a metal so as to form a stable organometallic-organic-inorganic hybrid material having high catalytic performances.
摘要翻译：本发明涉及可用作选择性催化反应的非均相催化剂的材料，特别是“有机金属 - 有机 - 无机杂化材料”。更确切地说，本发明涉及有机 - 无机混合纳米结构材料，其包含与金属强烈结合的规则分布稳定的卡宾，以形成具有高催化性能的稳定的有机金属 - 有机 - 无机杂化材料。

5. 发明授权

US08389368B2 Method for producing a conductive nanoparticle memory device 失效
标题翻译：导电纳米颗粒存储装置的制造方法
公开(公告)号：US08389368B2
公开(公告)日：2013-03-05
申请号：US12727593
申请日：2010-03-19
申请人： Simon Deleonibus , Jean-Marie Basset , Paul Campbell , Thibaut Gutel , Paul-Henri Haumesser , Gilles Marchand , Catherine Santini
发明人： Simon Deleonibus , Jean-Marie Basset , Paul Campbell , Thibaut Gutel , Paul-Henri Haumesser , Gilles Marchand , Catherine Santini
IPC分类号： H01L21/336
CPC分类号： H01L29/66833 , B82Y10/00 , B82Y40/00 , H01L21/28273 , H01L27/11563 , H01L29/42332 , H01L29/513 , H01L29/66545 , H01L29/66825 , H01L29/7881 , Y10S977/773
摘要： A method for producing a memory device with nanoparticles, including steps of: a) forming, in a substrate based on at least one semi-conductor, source and drain regions, and at least one first dielectric on at least one zone of the substrate arranged between the source and drain regions and intended to form a channel of the memory device, b) depositing of at least one ionic liquid that is an organic salt or mixture of organic salts in a liquid state, wherein nanoparticles of at least one electrically conductive material are suspended in the ionic liquid, said ionic liquid covering at least said first dielectric, c) forming a deposition of said nanoparticles at least on said first dielectric, d) removing the ionic liquid remaining on the first dielectric, and e) forming at least one second dielectric and at least one control gate on at least one part of the nanoparticles deposited on the first dielectric.
摘要翻译：一种制备具有纳米颗粒的存储器件的方法，包括以下步骤：a）在基板中基于至少一个半导体源极和漏极区域形成基底，并且至少一个第一电介质在衬底的至少一个区域上被布置在源极和漏极区之间并且旨在形成存储器件的通道，b）沉积至少一种离子液体，其是液态的有机盐或有机盐的混合物，其中至少一种导电材料的纳米颗粒悬浮在离子液体中，所述离子液体至少覆盖所述第一电介质，c）至少在所述第一电介质上形成所述纳米颗粒的沉积，d）去除残留在第一电介质上的离子液体，和e）至少形成在沉积在第一电介质上的纳米颗粒的至少一部分上的一个第二电介质和至少一个控制栅极。

6. 发明申请

US20120316057A1 OLEFIN METATHESIS CATALYST CONTAINING TUNGSTEN FLUORINE BONDS 有权
标题翻译：含有荧光荧光素的OLEFIN METATHESIS催化剂
公开(公告)号：US20120316057A1
公开(公告)日：2012-12-13
申请号：US13156860
申请日：2011-06-09
申请人： Mostafa Taoufik , Etienne Mazoyer , Christopher P. Nicholas , Jean-Marie Basset
发明人： Mostafa Taoufik , Etienne Mazoyer , Christopher P. Nicholas , Jean-Marie Basset
IPC分类号： B01J31/12 , B01J35/10 , C07F11/00
CPC分类号： B01J31/2295 , B01J21/08 , B01J23/30 , B01J31/2208 , B01J35/1014 , B01J35/1019 , B01J37/0209 , B01J37/06 , C07C6/04 , C07C2521/08 , C07C2531/22 , C07F7/02 , C07F11/00 , Y02P20/52 , C07C11/04 , C07C11/08
摘要： A catalyst for the metathesis of olefins in general and specifically for the production of propylene from ethylene and butylene has been developed. The catalyst comprises a tungsten metal compound, which contains at least one tungsten-fluoro bond, dispersed or grafted onto a support. A specific example of the catalyst is the compound WOF(CH2CMe3)3 grafted onto a silica support.
摘要翻译：已经开发了用于烯烃易分解的催化剂，特别是用于从乙烯和丁烯生产丙烯的催化剂。催化剂包含分散或接枝到载体上的至少一种钨 - 氟键的钨金属化合物。催化剂的具体实例是接枝到二氧化硅载体上的化合物WOF（CH 2 CMe 3）3。

7. 发明申请

US20110257006A1 METHOD FOR PREPARING A STRUCTURED POROUS MATERIAL COMPRISING NANOPARTICLES OF METAL 0 IMBEDDED IN THE WALLS THEREOF 审中-公开
标题翻译：制备包含在其中的金属0纳米颗粒的结构化多孔材料的方法
公开(公告)号：US20110257006A1
公开(公告)日：2011-10-20
申请号：US13122420
申请日：2009-09-24
申请人： Chloe Thieuleux , Malika Boualleg , Jean-Pierre Candy , Laurent Veyre , Jean-Marie Basset
发明人： Chloe Thieuleux , Malika Boualleg , Jean-Pierre Candy , Laurent Veyre , Jean-Marie Basset
IPC分类号： B01J35/10 , B01J21/08 , B82Y30/00
CPC分类号： B01J29/0308 , B01J23/42 , B01J23/462 , B01J29/041 , B01J35/0013 , B01J35/006 , B01J35/1023 , B01J35/1028 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/18 , B82Y30/00 , C01B33/02 , C01G23/00 , C01G23/002 , C01P2002/72 , C01P2004/64 , C01P2004/84 , C01P2006/12 , C01P2006/14 , C01P2006/16 , C01P2006/17 , C07C5/03 , C07C2523/745 , C07C15/073
摘要： The present invention relates to a process for producing a structured porous material comprising a structured inorganic framework made up of metal-oxide based walls in which nanoparticles of metal 0 are incorporated, which comprises the following steps: a) formation of a suspension of hydrophilic nanoparticles of metal 0 stabilized by non-exchangeable ligands that give the nanoparticles their hydrophilic character; b) growth of the inorganic framework from an inorganic precursor around the nanoparticles of metal 0 stabilized by the non-exchangeable hydrophilic ligands, in the presence of a pore-forming agent; and c) elimination of the pore-forming agent and at least partially of the non-exchangeable ligands that give the nanoparticles their hydrophilic character.
摘要翻译：本发明涉及一种生产结构化多孔材料的方法，其包括由金属氧化物基壁形成的结构化无机骨架，其中纳入金属O的纳米颗粒，其包括以下步骤：a）形成亲水性纳米颗粒的悬浮液的非可交换配体稳定的金属0，使纳米颗粒具有亲水性; b）在成孔剂存在下，通过由不可交换的亲水性配体稳定的金属0的纳米颗粒周围的无机前体生长无机骨架; 和c）消除造孔剂和至少部分不可交换的配体，使纳米颗粒具有亲水性。

8. 发明授权

US07638672B2 Method for converting ethylene into propylene 失效
标题翻译：乙烯转化成丙烯的方法
公开(公告)号：US07638672B2
公开(公告)日：2009-12-29
申请号：US11571602
申请日：2005-06-27
申请人： Christophe Coperet , Jean-Marie Basset , Jean Thivolle-Cazat , Erwan Le Roux , Mostafa Taoufik
发明人： Christophe Coperet , Jean-Marie Basset , Jean Thivolle-Cazat , Erwan Le Roux , Mostafa Taoufik
IPC分类号： C07C6/04
CPC分类号： C07C6/04 , C07C2531/12 , Y02P20/584 , C07C11/06
摘要： The invention relates to a method for converting ethylene into propylene consisting in reacting said ethylene with a supported metal compound comprising an aluminium oxide based support to which a tungsten hydride is grafted. Said reaction is carried out at a temperature ranging from 20 to 600° C., preferably between 50 and 350° C., at an absolute pressure ranging from 0.01 to 8 MPa, preferably between 0.01 and 1 MPa. A catalyst is regeneratable by introducing hydrogen at a temperature of 50-300° C.
摘要翻译：本发明涉及一种将乙烯转化成丙烯的方法，该方法是使所述乙烯与负载型金属化合物反应，该金属化合物包含接枝有氢化钨的氧化铝基载体。所述反应在20〜600℃，优选50〜350℃的温度下进行，绝对压力为0.01〜8MPa，优选为0.01〜1MPa。催化剂可以通过在50-300℃的温度下引入氢气来再生

9. 发明授权

US07473814B2 Process for converting methane into ethane 失效
标题翻译：将甲烷转化为乙烷的方法
公开(公告)号：US07473814B2
公开(公告)日：2009-01-06
申请号：US10517212
申请日：2003-06-04
申请人： Jean-Marie Basset , Philippe Bres , Christophe Coperet , Barry Martin Maunders , Daravong Soulivong , Mostafa Taoufik , Jean Thivolle-Cazat
发明人： Jean-Marie Basset , Philippe Bres , Christophe Coperet , Barry Martin Maunders , Daravong Soulivong , Mostafa Taoufik , Jean Thivolle-Cazat
IPC分类号： C07C2/00
CPC分类号： C07C2/76 , C07C2531/12 , Y10S585/943 , C07C9/06
摘要： The invention relates to a process for producing ethane comprising contacting methane with a metal catalyst selected from metal hydrides, metal organic compounds and mixtures thereof. It also relates to a process for the conversion of methane to carbon-containing products comprising contacting methane with a metal catalyst comprising at least one metal, Me, chosen from the lanthanides, the actinides and the metals from Groups 2 to 12 of the Periodic Table of the Elements, so as to produce ethane in a proportion of at least 65%, especially at least 98% or 99% by weight with respect to carbon-containing products formed in the process. The process can be a single-step process, preferably carried out under conditions involving a non-oxidative catalytic coupling of methane, in particular under operating conditions maintained substantially constant, preferably continuously, during the ethane production, e.g. at a temperature ranging from −30° C. to +80° C., preferably from 20° C. to 500° C., under a total absolute pressure ranging from 10−3 to 100 MPa, preferably from 0.1 to 50 MPa. The metal catalyst may be chosen from metal catalysts supported on and preferably grafted to a solid support. One of the main advantages of the present invention is to produce ethane with a very high selectivity.
摘要翻译：本发明涉及一种生产乙烷的方法，包括使甲烷与选自金属氢化物，金属有机化合物及其混合物的金属催化剂接触。它还涉及将甲烷转化为含碳产物的方法，包括使甲烷与包含至少一种金属的金属催化剂接触，所述金属催化剂选自镧系元素，锕系元素和元素周期表第2至12族中的金属的元素，以便相对于在该方法中形成的含碳产品，以至少65重量％，特别是至少98重量％或99重量％的比例制备乙烷。该方法可以是单步骤方法，优选在涉及甲烷的非氧化催化偶合的条件下进行，特别是在乙烷生产期间，优选连续保持基本上恒定的操作条件下，例如乙烷生产。在-30℃至+ 80℃，优选20℃至500℃的温度下，在绝对压力范围为10-3-100MPa，优选0.1-50MPa的温度下进行。金属催化剂可以选自负载在并优选接枝到固体载体上的金属催化剂。本发明的主要优点之一是以非常高的选择性生产乙烷。

10. 发明申请

US20080255328A1 Method For Metathesis of Compounds Comprising an Olefinic Double Bond, in Particular Olefins 失效
标题翻译：包含烯烃双键，特别是烯烃的化合物的复分解方法
公开(公告)号：US20080255328A1
公开(公告)日：2008-10-16
申请号：US11571395
申请日：2005-07-01
申请人： Jean-Marie Basset , Jean Thivolle-Cazat , Mostafa Taoufik , Erwan Le Roux , Christophe Coperet
发明人： Jean-Marie Basset , Jean Thivolle-Cazat , Mostafa Taoufik , Erwan Le Roux , Christophe Coperet
IPC分类号： C08F2/00 , C08F4/52
CPC分类号： C07C6/04 , C07C2521/04 , C07C2531/12 , C07C11/06
摘要： The invention relates to a method for metathesis of one or several reagents comprising a linear or branched hydrocarbon chain containing a double olefinic bond Csp2═Csp2 consisting in reacting said reagent or reagents with a supported metal compound comprising an aluminium oxide-based support to which a tungsten hydride is grafted. Typically, each said reagent or reagents comprises from 2 to 30 carbon atoms. The reagent can be embodied in the form of olefin. The inventive method can be used, for example for producing propylene from ethylene and butane.
摘要翻译：本发明涉及一种或多种试剂的复分解方法，所述试剂包括含有双重烯键Csp 2 -Csp 2的直链或支链烃链，所述双链烯键用于将所述试剂或具有负载金属化合物的试剂，其包含接枝氢化钨的基于氧化铝的载体。通常，每个所述试剂或试剂包含2至30个碳原子。试剂可以以烯烃的形式实施。本发明的方法可用于例如从乙烯和丁烷生产丙烯。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式