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1. 发明申请

US20120289666A1 PROCESS FOR THE GAS PHASE POLYMERISATION OF OLEFINS 有权
标题翻译：气相聚合方法
公开(公告)号：US20120289666A1
公开(公告)日：2012-11-15
申请号：US13519717
申请日：2010-12-24
申请人： Jean-Louis Chamayou , Andrew David Bell
发明人： Jean-Louis Chamayou , Andrew David Bell
IPC分类号： C08F210/14 , C08F2/01
CPC分类号： C08F10/00 , B01J8/0055 , C08F210/16 , C08F2/01 , C08F2/34 , C08F210/14 , C08F2500/12 , C08F2500/08
摘要： The present invention relates to a process for the gas phase polymerisation of olefins, and, in particular, to a process for the gas phase polymerisation of olefins with recycle of fines to the reaction zone.
摘要翻译：本发明涉及一种用于烯烃气相聚合的方法，特别涉及一种将细粒再循环至反应区的烯烃的气相聚合方法。

2. 发明授权

US09394382B2 Process and apparatus for the polymerisation of olefins 有权
标题翻译：用于烯烃聚合的方法和设备
公开(公告)号：US09394382B2
公开(公告)日：2016-07-19
申请号：US13988794
申请日：2011-12-14
申请人： Andrew David Bell , Jean-Louis Chamayou , Kevin Peter Ramsay
发明人： Andrew David Bell , Jean-Louis Chamayou , Kevin Peter Ramsay
IPC分类号： C08F2/34 , B01J8/24 , B01J8/44 , C08F10/00 , C08F110/02
CPC分类号： C08F10/00 , C08F2/34 , C08F110/02 , C08F2/007
摘要： Process for gas phase polymerization of olefins in a fluidized bed reactor by (a) passing a fluidizing gas containing at least one olefin monomer through a fluidized bed of polymer particles in the presence of a polymerization catalyst to produce polymer at a polymer production rate of C Tonnes/hour, (b) withdrawing a first gaseous stream containing solid particles from the top of the reactor, (c) passing the first gaseous stream to a gas/solids separator, separating solid particles therefrom, and forming a second gaseous stream containing residual solid particles, (d) passing a portion of the second gaseous stream to at least one heat exchanger to remove heat of reaction whereby residual solid particles contact the heat exchanger, and (e) recycling a portion of the cooled stream from step (d) as the fluidizing gas in step (a). The heat exchangers have a heat exchange surface area which totals less than 120×C m2.
摘要翻译：在流化床反应器中通过（a）在聚合催化剂存在下使包含至少一种烯烃单体的流化气体通过聚合物颗粒的流化床将烯烃气相聚合的方法以聚合物生产速率C 吨/小时，（b）从反应器顶部排出含有固体颗粒的第一气态流，（c）将第一气流送至气体/固体分离器，从其中分离固体颗粒，并形成含有残留物的第二气流固体颗粒，（d）将第二气流的一部分通入至少一个热交换器以除去反应热，由此残留的固体颗粒接触热交换器，和（e）将来自步骤（d）的冷却流的一部分再循环，作为步骤（a）中的流化气体。热交换器的热交换面积总计小于120×Cm2。

3. 发明授权

US09228032B2 Process for the gas phase polymerisation of olefins 有权
标题翻译：烯烃气相聚合方法
公开(公告)号：US09228032B2
公开(公告)日：2016-01-05
申请号：US13519717
申请日：2010-12-24
申请人： Jean-Louis Chamayou , Andrew David Bell
发明人： Jean-Louis Chamayou , Andrew David Bell
IPC分类号： C08F210/14 , C08F2/01 , C08F10/00 , B01J8/00 , C08F210/16
CPC分类号： C08F10/00 , B01J8/0055 , C08F210/16 , C08F2/01 , C08F2/34 , C08F210/14 , C08F2500/12 , C08F2500/08
摘要： Process for the gas phase polymerization of olefins, in particular, with recycle of fines to the reaction zone. The process includes (a) polymerizing an olefin in a reaction zone in which a bed of polymer particles is maintained in an agitated state by passing a fluid stream through the bed, (b) withdrawing the fluid stream from the reactor after it has passed through the bed of polymer particles, (c) separating entrained solids from the withdrawn fluid stream, and (d) returning the separated entrained solids to the reaction zone. The polymer production rate of the process is at least 40 tonnes/hour, and the separated solids from step (c) are returned to the lower half of the bed of polymer particles in the reaction zone.
摘要翻译：烯烃气相聚合的方法，特别是将细粒再循环到反应区。该方法包括（a）在反应区中聚合烯烃，其中通过使流体流通过床将聚合物颗粒床保持在搅拌状态，（b）在经过反应器之后将流体物流从反应器中排出聚合物颗粒床，（c）从排出的流体流中分离夹带的固体，和（d）将分离的夹带的固体返回到反应区。该方法的聚合物生产速率为至少40吨/小时，并且来自步骤（c）的分离的固体返回到反应区中聚合物颗粒床的下半部分。

4. 发明申请

US20130253148A1 PROCESS AND APPARATUS FOR THE POLYMERISATION OF OLEFINS 有权
标题翻译：烯烃聚合的方法和装置
公开(公告)号：US20130253148A1
公开(公告)日：2013-09-26
申请号：US13988794
申请日：2011-12-14
申请人： Andrew David Bell , Jean-Louis Chamayou , Kevin Peter Ramsay
发明人： Andrew David Bell , Jean-Louis Chamayou , Kevin Peter Ramsay
IPC分类号： C08F2/34
CPC分类号： C08F10/00 , C08F2/34 , C08F110/02 , C08F2/007
摘要： The present invention relates to a process for the gas-phase polymerisation of olefins in a fluidised bed reactor, which process comprises: a) passing a fluidising gas comprising one or more olefin monomers through a fluidised bed of polymer particles in the presence of a polymerisation catalyst, b) withdrawing a first gaseous stream comprising solid particles from the top of the reactor, c) passing the first gaseous stream to a gas/solids separator, separating solid particles therefrom, and forming a second gaseous stream comprising residual solid particles, d) passing at least a portion of the second gaseous stream to one or more heat exchangers to remove the heat of reaction, and e) recycling at least a portion of the cooled stream from step (d) as the fluidising gas in step (a), characterised in that the rate of fouling of the one or more heat exchangers is such that i) the increase in pressure drop across the heat exchangers is equivalent to less than 5% per year, and/or ii) the decrease in heat transfer of the heat exchangers is equivalent to less than 5% per year.
摘要翻译：本发明涉及在流化床反应器中烯烃气相聚合的方法，该方法包括：a）在聚合反应存在下使包含一种或多种烯烃单体的流化气体通过聚合物颗粒的流化床催化剂，b）从反应器顶部排出包含固体颗粒的第一气流，c）将第一气流送至气/固分离器，从其中分离固体颗粒，形成包含残留固体颗粒的第二气流）将至少一部分第二气流引导至一个或多个热交换器以除去反应热，以及e）将步骤（d）中的冷却流的至少一部分循环为步骤（a）中的流化气体，其特征在于，所述一个或多个热交换器的结垢速率使得i）所述热交换器上的压降的增加等于每年小于5％，和/或ii）所述d 热交换器的热传递相当于每年少于5％。

5. 发明申请

US20130053528A1 POLYMERIZATON PROCESS 有权
标题翻译：聚合过程
公开(公告)号：US20130053528A1
公开(公告)日：2013-02-28
申请号：US13695387
申请日：2011-04-13
申请人： Jean-Louis Chamayou , Benoit Sibourd
发明人： Jean-Louis Chamayou , Benoit Sibourd
IPC分类号： C08F10/14
CPC分类号： C08F2/001 , B01J8/1872 , B01J2208/0061 , C08F210/16 , C08F2400/02 , C08F2410/05 , C08F210/08 , C08F2500/12 , C08F2500/07 , C08F210/14
摘要： The present invention relates to a process for the continuous transition between two ethylene copolymers containing a different comonomer. In particular, the present invention relates to a process for the continuous transition between two ethylene copolymers containing a different comonomer.
摘要翻译：本发明涉及包含不同共聚单体的两种乙烯共聚物之间的连续过渡的方法。特别地，本发明涉及包含不同共聚单体的两种乙烯共聚物之间的连续转变的方法。

6. 发明授权

US08916658B2 Polymerizaton process 有权
标题翻译：聚合方法
公开(公告)号：US08916658B2
公开(公告)日：2014-12-23
申请号：US13695387
申请日：2011-04-13
申请人： Jean-Louis Chamayou , Benoit Sibourd
发明人： Jean-Louis Chamayou , Benoit Sibourd
IPC分类号： C08F2/00 , C08F210/00 , C08F210/16 , B01J8/18
CPC分类号： C08F2/001 , B01J8/1872 , B01J2208/0061 , C08F210/16 , C08F2400/02 , C08F2410/05 , C08F210/08 , C08F2500/12 , C08F2500/07 , C08F210/14
摘要： Process for the continuous transition between two ethylene copolymers containing a different comonomer. In particular, the process is for the continuous transition between two ethylene copolymers containing a different comonomer.
摘要翻译：含有不同共聚单体的两种乙烯共聚物之间的连续过渡的方法。特别地，该方法用于在含有不同共聚单体的两种乙烯共聚物之间的连续转变。

7. 发明授权

US08349975B2 Method for the production of polymers 有权
标题翻译：生产聚合物的方法
公开(公告)号：US08349975B2
公开(公告)日：2013-01-08
申请号：US12737862
申请日：2009-09-21
申请人： Jean-Louis Chamayou
发明人： Jean-Louis Chamayou
IPC分类号： C08F2/00 , C08F210/00 , C08F10/14 , C08F10/04 , C08F110/06 , C08F110/02
CPC分类号： B01J8/1809 , B01J2219/00191 , C08F6/005 , C08F210/16 , C08L23/10 , C08F2/00 , C08F210/14 , C08F210/08
摘要： Method for transitioning from a first process for producing a first polymer to a second process for producing a second polymer. The first and second processes each include contacting a principal olefin and a comonomer with a catalyst under gas phase polymerization conditions to form the first or second polymer. The first and second processes utilize the same olefin but differ in at least one of the comonomer used and the reaction temperature at which the polymer is produced. The respective first or second polymer is then contacted with a purge gas to remove unreacted monomers. The method includes changing the flow rate of purge gas from a first rate to a second rate defined relative to a flow rate and temperature used for an earlier polymer produced using the same comonomer as the second process.
摘要翻译：从用于制备第一聚合物的第一工艺转变为用于制备第二聚合物的第二工艺的方法。第一和第二方法各自包括在气相聚合条件下使主要烯烃和共聚单体与催化剂接触以形成第一或第二聚合物。第一和第二方法使用相同的烯烃，但是所用共聚单体和生产聚合物的反应温度中的至少一种不同。然后将相应的第一或第二聚合物与吹扫气体接触以除去未反应的单体。该方法包括将吹扫气体的流速从第一速率改变为相对于使用与第二过程相同的共聚单体产生的较早聚合物所使用的流速和温度所限定的第二速率。

8. 发明授权

US08314197B2 Process for the degassing of polymer power 有权
标题翻译：聚合物动力脱气的方法
公开(公告)号：US08314197B2
公开(公告)日：2012-11-20
申请号：US12737910
申请日：2009-09-21
申请人： Jean-Louis Chamayou , Daniel Marissal
发明人： Jean-Louis Chamayou , Daniel Marissal
IPC分类号： C08F210/00 , C08F10/14 , C08F110/14 , C08F10/04
CPC分类号： C08F6/001
摘要： Process for producing a degassed polymer powder, by a) feeding i) a principal monomer, and ii) one or more comonomers in an amount of at least 5000 ppmw relative to the principal monomer feed rate, and iii) optionally an added alkane having 2 to 10 carbon atoms, fed in an amount of at least 1000 ppmw relative to the principal monomer feed rate; into a polymerization reactor. The monomer and comonomers react to form a polymer including residual hydrocarbons having one or more hydrocarbons with 3 to 10 carbon atoms, and b) passing the polymer to a degassing step where it is contacted with a purge gas to remove some of the residual hydrocarbons.
摘要翻译：通过以下方法制备脱气的聚合物粉末的方法：a）相对于主要单体进料速率喂入i）主要单体和ii）一种或多种相对于主要单体进料速率至少5000ppmw的共聚单体，和iii）任选加入的具有2 至10个碳原子，相对于主要单体进料速率进料至少1000ppmw; 进入聚合反应器。单体和共聚单体反应形成聚合物，包括具有一个或多个具有3-10个碳原子的烃的残余烃，和b）将聚合物通入脱气步骤，在该步骤中，其与吹扫气体接触以除去一些残留的烃。

9. 发明申请

US20110009576A1 POLYMERISATION PROCESS 审中-公开
标题翻译：聚合过程
公开(公告)号：US20110009576A1
公开(公告)日：2011-01-13
申请号：US12736148
申请日：2009-02-24
申请人： Jean-Louis Chamayou , Claudine Viviane Lalanne-Magne , Melanie Muron
发明人： Jean-Louis Chamayou , Claudine Viviane Lalanne-Magne , Melanie Muron
IPC分类号： C08F10/14 , C08F4/00
CPC分类号： C08F210/16 , C08F4/6565 , C08F4/6495 , C08F2/34 , C08F210/14 , C08F2500/12 , C08F2500/24 , C08F2500/18
摘要： The present invention relates to a polymerisation process and in particular to a process for the copolymerisation of ethylene and an α-olefin comonomer having 7 to 10 carbon atoms in a fluidised bed gas phase reactor in the presence of a multi-site Ziegler-Natta polymerisation catalyst characterised in that (i) said process is operated in condensed mode, (ii) the amount of said α-olefin is maintained below that at which substantial condensation in the reactor occurs and (iii) at least one of the following apply:a) the catalyst has an uptake rate of 1-octene of at least 700;b) the polymerisation is performed in the presence of an activity promoter.
摘要翻译：本发明涉及一种聚合方法，特别涉及一种在多位点齐格勒 - 纳塔聚合存在下，在流化床气相反应器中共聚乙烯和具有7至10个碳原子的α-烯烃共聚单体的方法催化剂的特征在于：（i）所述方法以冷凝模式运行，（ii）所述α-烯烃的量保持低于反应器发生基本冷凝的量，以及（iii）以下至少一种适用：）催化剂具有至少700的1-辛烯的吸收速率; b）聚合在活性促进剂存在下进行。

10. 发明授权

US09394381B2 Polymerisation control process 有权
标题翻译：聚合控制过程
公开(公告)号：US09394381B2
公开(公告)日：2016-07-19
申请号：US13885375
申请日：2011-11-16
申请人： Jean-Louis Chamayou , Daniel Marissal
发明人： Jean-Louis Chamayou , Daniel Marissal
IPC分类号： C08F2/34 , C08F10/00 , B01J8/44
CPC分类号： C08F2/34 , C08F10/00 , C08F2400/02 , Y02P20/582 , C08F2/00
摘要： Process for maintaining a continuous gas-phase (co-) polymerization of olefins in a large fluidized bed reactor in a homogeneous mode while operating at high space time yield and condensation rate in the presence of a polymerization catalyst.
摘要翻译：在大型流化床反应器中以高空间时间操作，在聚合催化剂存在下产生和缩合速率的同时维持烯烃连续气相（共）聚合的方法。

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