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1. 发明授权

US6096408A Heat-transfer label and method of decorating polyethylene-coated glass using same 失效
标题翻译：热转印标签和使用其的装饰聚乙烯涂层玻璃的方法
公开(公告)号：US6096408A
公开(公告)日：2000-08-01
申请号：US93151
申请日：1998-06-08
申请人： Jean Paul Laprade , James S. Nugent , Darchun Billy Yang
发明人： Jean Paul Laprade , James S. Nugent , Darchun Billy Yang
IPC分类号： B41M3/12 , B41M5/00 , B41M5/52 , B44C1/17 , B32B27/14
CPC分类号： B44C1/1712 , B41M3/12 , B41M5/5272 , Y10S428/913 , Y10S428/914 , Y10T428/31855
摘要： A heat-transfer label suitable for use in decorating polyethylene-coated glass articles. In a preferred embodiment, the label is capable of withstanding pasteurization conditions on a polyethylene-coated glass article and includes (a) a support portion in the form of a sheet of paper overcoated with a release layer of polyethylene, (b) a skim coat of wax overcoated onto the polyethylene release layer and (c) a transfer portion, the transfer portion including a cross-linked phenoxy protective lacquer layer printed onto the skim coat, a polyester ink layer printed onto the protective lacquer layer, a first adhesive layer printed onto the ink layer and onto any exposed portions of the underlying protective lacquer layer, and a second adhesive layer printed onto the first adhesive layer. The first adhesive layer preferably comprises an acrylic adhesive resin of the type present in a water-based adhesive dispersion or in a water-based adhesive emulsion and also comprises a surfactant in the form of dioctyl sodium sulfosuccinate. The second adhesive layer preferably comprises a chlorinated polyolefin of the type present in a water-based chlorinated polyolefin dispersion, such a dispersion having a pH at 25.degree. C. of 9-10 and containing 2-amino-2-methyl-1-propanol as a neutralizing amine, the water-based chlorinated polyolefin dispersion containing 20%, by weight, chlorinated polyolefin and 25%, by weight, total solids. The second adhesive layer preferably also comprises a thickener in the form of a polyurethane.
摘要翻译：适用于装饰聚乙烯涂层玻璃制品的热转印标签。在优选的实施方案中，标签能够耐受聚乙烯涂覆的玻璃制品上的巴氏灭菌条件，并且包括（a）以聚乙烯脱模层包覆的纸片形式的支撑部分，（b）的蜡涂覆在聚乙烯脱模层上，（c）转印部分，转印部分包括印刷在脱脂涂层上的交联的苯氧基保护漆层，印刷在保护漆层上的聚酯油墨层，印刷的第一粘合剂层在油墨层上和下面的保护漆层的任何暴露部分上，以及印刷在第一粘合剂层上的第二粘合剂层。第一粘合剂层优选包含存在于水基粘合剂分散体或水性粘合剂乳液中的丙烯酸类粘合剂树脂，并且还包含二辛基磺基琥珀酸钠形式的表面活性剂。第二粘合剂层优选包含存在于水基氯化聚烯烃分散体中的氯化聚烯烃，这种分散体的pH在25℃为9-10，并含有2-氨基-2-甲基-1-丙醇作为中和胺，水基氯化聚烯烃分散体含有20重量％的氯化聚烯烃和25重量％的总固体。第二粘合剂层优选还包含聚氨酯形式的增稠剂。

2. 发明授权

US09206338B2 Heat-transfer label assembly and method of using the same 有权
标题翻译：热转印标签组装及其使用方法
公开(公告)号：US09206338B2
公开(公告)日：2015-12-08
申请号：US13595514
申请日：2012-08-27
申请人： Jean Paul Laprade
发明人： Jean Paul Laprade
IPC分类号： B32B9/00 , B32B7/12 , C09J7/02 , B65C1/00 , B65C3/00 , B44C1/17 , B44F1/06 , C09D11/10
CPC分类号： C09J7/0203 , B44C1/1712 , B44F1/06 , B65C1/00 , B65C3/00 , C09D11/10 , C09J7/29 , C09J2201/61 , C09J2203/334 , Y10T428/24843
摘要： A heat-transfer label assembly and method of using the same. In one embodiment, the assembly is well-suited for decorating refillable glass articles and includes a support portion, a wax skim coat, and a transfer portion. The support portion may include a carrier web overcoated with a polyethylene layer. The wax skim coat may overcoat the polyethylene layer. The transfer portion may include a protective lacquer, an ink design, and a heat-activatable adhesive. The protective lacquer may be printed directly on the skim coat and may include a cross-linked phenoxy resin. The ink design may be printed onto the protective lacquer and may include a binder, a colorant, and a cross-linking system. The adhesive, which may differ from the ink design only by lacking colorant, may be printed onto the ink design, any exposed portions of the protective lacquer, and the surrounding skim coat.
摘要翻译：传热标签组件及其使用方法。在一个实施例中，该组件非常适用于装饰可再填充的玻璃制品，并且包括支撑部分，蜡脱脂涂层和转印部分。支撑部分可以包括用聚乙烯层包覆的载体网。蜡脱脂涂层可以覆盖聚乙烯层。转印部分可以包括保护漆，油墨设计和可热激活的粘合剂。保护漆可以直接印刷在脱脂涂层上，并且可以包括交联的苯氧基树脂。油墨设计可以印刷在保护漆上，并且可以包括粘合剂，着色剂和交联体系。粘合剂可能不同于仅通过缺乏着色剂的油墨设计，可以印刷到油墨设计，保护漆的任何暴露部分和周围的脱脂涂层上。

3. 发明授权

US5766731A Heat-transfer label 失效
标题翻译：热转印标签
公开(公告)号：US5766731A
公开(公告)日：1998-06-16
申请号：US625013
申请日：1996-03-29
申请人： Samuel H. Stein , Onsy Y. Makar , Jean Paul Laprade
发明人： Samuel H. Stein , Onsy Y. Makar , Jean Paul Laprade
IPC分类号： B44C1/17 , G09F3/10 , B32B3/00
CPC分类号： B44C1/1712 , G09F3/10 , Y10S428/913 , Y10T428/24802 , Y10T428/24876 , Y10T428/31504 , Y10T428/31855 , Y10T428/31935
摘要： A heat-transfer label particularly well-suited for styrene-acrylonitrile surfaces and containers. In one embodiment, the label includes a support portion, a skim coat of wax on top of the support portion, and a transfer portion on top of the skim coat of wax. The support portion includes a sheet of paper overcoated with a release layer of polyethylene. The transfer portion includes an acrylic protective lacquer layer, an ink layer over the protective lacquer layer, and a heat-activatable adhesive layer over the ink layer. The protective lacquer layer includes a methyl/n-butyl methacrylate copolymer and a methyl methacrylate copolymer. The ink layer includes a polyamide and/or acrylic ink. The adhesive layer includes an acrylic resin and a chlorinated polyolefin resin.
摘要翻译：特别适用于苯乙烯 - 丙烯腈表面和容器的热转印标签。在一个实施例中，标签包括支撑部分，在支撑部分顶部的蜡的脱脂涂层，以及蜡的脱脂涂层顶部上的转印部分。支撑部分包括用聚乙烯脱模层涂覆的一张纸。转印部分包括丙烯酸保护漆层，保护漆层上的油墨层和油墨层上的可热激活的粘合剂层。保护漆层包括甲基/甲基丙烯酸正丁酯共聚物和甲基丙烯酸甲酯共聚物。油墨层包括聚酰胺和/或丙烯酸油墨。粘合剂层包括丙烯酸树脂和氯化聚烯烃树脂。

4. 发明授权

US09757922B2 Heat transfer label having a UV layer 有权
公开(公告)号：US09757922B2
公开(公告)日：2017-09-12
申请号：US12699480
申请日：2010-02-03
申请人： Ronald L. Miracle , Alexander Craig Bushman , Jean Paul Laprade
发明人： Ronald L. Miracle , Alexander Craig Bushman , Jean Paul Laprade
IPC分类号： B32B7/12 , B32B7/06 , C09J7/02 , G09F3/10
CPC分类号： B32B7/06 , B32B7/12 , C09J7/20 , G09F3/10 , Y10T428/2817 , Y10T428/2826
摘要： A heat transfer label and method for preparing same, the heat transfer label including (a) a support portion and (b) a transfer portion over the support portion, for transfer of the transfer portion from the support portion to an article upon application of heat to the support portion while the transfer portion is placed into contact with the article. The transfer portion includes at least a protective lacquer layer, an ink layer, and an adhesive layer, wherein at least one of the protective lacquer layer, the ink layer, and the adhesive layer is UV-curable. Further, the heat transfer label may additionally include a tie-coat layer, which may be a UV-curable tie-coat layer. Further, each of the plurality of layers of the transfer portion of the heat transfer label may be UV-curable.

5. 发明授权

US08252400B2 Heat-transfer label assembly and method of using the same 有权
标题翻译：热转印标签组装及其使用方法
公开(公告)号：US08252400B2
公开(公告)日：2012-08-28
申请号：US11644803
申请日：2006-12-22
申请人： Jean Paul Laprade
发明人： Jean Paul Laprade
IPC分类号： B32B9/00 , B32B7/12
CPC分类号： B44C1/1712 , B41M5/025 , B44F1/06 , C09D11/10 , Y10T428/14 , Y10T428/28 , Y10T428/2813 , Y10T428/2839 , Y10T428/2848
摘要： A heat-transfer label assembly and method of using the same. In one embodiment, the assembly is adapted for decorating glass articles and comprises a carrier, the carrier comprising a paper substrate overcoated with a layer of polyethylene. The polyethylene layer is overcoated with a skim coat of wax. One or more heat-transfer labels are printed onto the skim coat and are spaced apart from one another. Each label consists of one or more ink design layers, each ink design layer comprising a binder resin, a pigment, a cross-linking resin and a catalyst. The catalyst is capable of causing the cross-linking resin to cross-link the binder resin within 1-2 minutes after the label has been transferred to a glass article that has been preheated to a temperature of about 250° F.-325° F.
摘要翻译：传热标签组件及其使用方法。在一个实施例中，组件适于装饰玻璃制品并且包括载体，载体包括用一层聚乙烯覆盖的纸基材。聚乙烯层用蜡的外涂层涂覆。一个或多个传热标签被印刷在脱脂涂层上并且彼此间隔开。每个标签由一个或多个油墨设计层组成，每个油墨设计层包含粘合剂树脂，颜料，交联树脂和催化剂。催化剂能够在标签转移到已经预热到约250°F-325°F的玻璃制品之后的1-2分钟内使交联树脂交联粘合剂树脂。

6. 发明授权

US6042931A Heat-transfer label including improved acrylic adhesive layer 失效
标题翻译：热转印标签包括改进的丙烯酸粘合剂层
公开(公告)号：US6042931A
公开(公告)日：2000-03-28
申请号：US93153
申请日：1998-06-08
申请人： Jean Paul Laprade
发明人： Jean Paul Laprade
IPC分类号： B44C1/17 , G09F3/02 , B32B3/00
CPC分类号： B44C1/1712 , B44C1/1716 , B44C1/172 , B44C1/1725 , G09F3/02 , Y10S428/914 , Y10T428/2486 , Y10T428/24876 , Y10T428/31504 , Y10T428/31855
摘要： A heat-transfer label including a novel acrylic adhesive layer. In a preferred embodiment, the label is used in decorating polyethylene-coated glass articles subjected to pasteurization conditions and includes (a) a support portion in the form of a sheet of paper overcoated with a release layer of polyethylene, (b) a skim coat of wax overcoated onto the polyethylene release layer and (c) a transfer portion, the transfer portion including a cross-linked phenoxy protective lacquer layer printed onto the skim coat, a polyester ink layer printed onto the protective lacquer layer, a first adhesive layer printed onto the ink layer, any exposed portions of the underlying protective lacquer layer and a surrounding area of the skim coat, and a second adhesive layer printed onto the first adhesive layer. The first adhesive layer is made by depositing an adhesive composition comprising a water-based all-acrylic elastomeric polymer emulsion. The second adhesive layer comprises a chlorinated polyolefin of the type present in a water-based chlorinated polyolefin dispersion and also comprises a thickener in the form of a polyurethane.
摘要翻译：包含新型丙烯酸粘合剂层的热转印标签。在优选的实施方案中，标签用于装饰经过巴氏消毒条件的聚乙烯涂覆的玻璃制品，并且包括（a）以聚乙烯脱模层外涂的纸张形式的支撑部分，（b）的蜡涂覆在聚乙烯脱模层上，（c）转印部分，转印部分包括印刷在脱脂涂层上的交联的苯氧基保护漆层，印刷在保护漆层上的聚酯油墨层，印刷的第一粘合剂层在油墨层上，下面的保护漆层的任何暴露部分和脱脂涂层的周围区域，以及印刷在第一粘合剂层上的第二粘合剂层。通过沉积包含水基全丙烯酸弹性体聚合物乳液的粘合剂组合物制备第一粘合剂层。第二粘合剂层包含存在于水基氯化聚烯烃分散体中的氯化聚烯烃，并且还包含聚氨酯形式的增稠剂。

7. 发明申请

US20130071634A1 HEAT-TRANSFER LABEL ASSEMBLY AND METHOD OF USING THE SAME 有权
标题翻译：传热标签组件及其使用方法
公开(公告)号：US20130071634A1
公开(公告)日：2013-03-21
申请号：US13595514
申请日：2012-08-27
申请人： Jean Paul Laprade
发明人： Jean Paul Laprade
IPC分类号： C09J7/02 , B65C3/00 , B65C1/00
CPC分类号： C09J7/0203 , B44C1/1712 , B44F1/06 , B65C1/00 , B65C3/00 , C09D11/10 , C09J7/29 , C09J2201/61 , C09J2203/334 , Y10T428/24843
摘要： A heat-transfer label assembly and method of using the same. In one embodiment, the assembly is well-suited for decorating refillable glass articles and includes a support portion, a wax skim coat, and a transfer portion. The support portion may include a carrier web overcoated with a polyethylene layer. The wax skim coat may overcoat the polyethylene layer. The transfer portion may include a protective lacquer, an ink design, and a heat-activatable adhesive. The protective lacquer may be printed directly on the skim coat and may include a cross-linked phenoxy resin. The ink design may be printed onto the protective lacquer and may include a binder, a colorant, and a cross-linking system. The adhesive, which may differ from the ink design only by lacking colorant, may be printed onto the ink design, any exposed portions of the protective lacquer, and the surrounding skim coat.
摘要翻译：传热标签组件及其使用方法。在一个实施例中，该组件非常适用于装饰可再填充的玻璃制品，并且包括支撑部分，蜡脱脂涂层和转印部分。支撑部分可以包括用聚乙烯层包覆的载体网。蜡脱脂涂层可以覆盖聚乙烯层。转印部分可以包括保护漆，油墨设计和可热激活的粘合剂。保护漆可以直接印刷在脱脂涂层上，并且可以包括交联的苯氧基树脂。油墨设计可以印刷在保护漆上，并且可以包括粘合剂，着色剂和交联体系。粘合剂可能不同于仅通过缺乏着色剂的油墨设计，可以印刷到油墨设计，保护漆的任何暴露部分和周围的脱脂涂层上。

8. 发明申请

US20110189477A1 Heat Transfer Label Having a UV Layer 有权
标题翻译：具有UV层的热转印标签
公开(公告)号：US20110189477A1
公开(公告)日：2011-08-04
申请号：US12699480
申请日：2010-02-03
申请人： Ronald L. Miracle , Alexander Craig Bushman , Jean Paul Laprade
发明人： Ronald L. Miracle , Alexander Craig Bushman , Jean Paul Laprade
IPC分类号： G09F3/10 , B32B7/12 , B32B7/06 , C09J7/02
CPC分类号： B32B7/06 , B32B7/12 , C09J7/20 , G09F3/10 , Y10T428/2817 , Y10T428/2826
摘要： A heat transfer label and method for preparing same, the heat transfer label including (a) a support portion and (b) a transfer portion over the support portion, for transfer of the transfer portion from the support portion to an article upon application of heat to the support portion while the transfer portion is placed into contact with the article. The transfer portion includes at least a protective lacquer layer, an ink layer, and an adhesive layer, wherein at least one of the protective lacquer layer, the ink layer, and the adhesive layer is UV-curable. Further, the heat transfer label may additionally include a tie-coat layer, which may be a UV-curable tie-coat layer. Further, each of the plurality of layers of the transfer portion of the heat transfer label may be UV-curable.
摘要翻译：一种热转印标签及其制备方法，所述传热标签包括（a）支撑部分和（b）在所述支撑部分上方的转印部分，用于在施加热量时将所述转印部分从所述支撑部分转移到制品在转印部分与制品接触的同时向支撑部分提供。转印部分至少包括保护漆层，油墨层和粘合剂层，其中保护漆层，油墨层和粘合剂层中的至少一个是可UV固化的。此外，热转印标签还可以包括可以是可UV固化的粘结层的粘结层。此外，传热标签的转印部分的多层中的每一层可以是可UV固化的。

9. 发明授权

US6099944A Heat-transfer label including a frosted ink design 有权
标题翻译：传热标签包括磨砂墨水设计
公开(公告)号：US6099944A
公开(公告)日：2000-08-08
申请号：US204424
申请日：1998-12-03
申请人： Jean Paul Laprade , Friedrich H. H. Geurtsen , Mukund Patel
发明人： Jean Paul Laprade , Friedrich H. H. Geurtsen , Mukund Patel
IPC分类号： B44C1/17 , B44F1/06 , G09F3/02 , B32B3/00
CPC分类号： B44C1/1712 , B44C1/1716 , B44C1/172 , B44C1/1725 , B44F1/066 , G09F3/02 , Y10S428/914 , Y10T428/256 , Y10T428/259 , Y10T428/28 , Y10T428/2852 , Y10T428/31855
摘要： A heat-transfer label that may be used, for example, to decorate clear glass articles in such a way as to give such articles the appearance of having been frosted. In a preferred embodiment, the label includes (a) a support portion in the form of a sheet of paper overcoated with a release layer of polyethylene, (b) a skim coat of wax overcoated onto the polyethylene release layer and (c) a transfer portion, the transfer portion including a protective lacquer layer printed onto the skim coat, an ink layer printed onto the protective lacquer layer, and an adhesive layer printed onto the ink layer, as well as onto any exposed portions of the underlying protective lacquer layer and onto a surrounding area of the skim coat. The protective lacquer layer comprises a solvent-soluble phenoxy resin that has been cross-linked by a melamine resin. The ink layer comprises a design printed with a frosted ink, the frosted ink preferably comprising a solvent-soluble phenoxy resin, a silica and a colorant. The adhesive layer comprises a phenoxy resin of the type present in a water-based phenoxy resin dispersion.
摘要翻译：可以使用的热转印标签，例如用于装饰透明玻璃制品，以使得这些制品已经磨砂的外观。在一个优选实施例中，标签包括（a）以聚乙烯脱模层包覆的纸张形式的支撑部分，（b）覆盖在聚乙烯脱模层上的蜡的脱脂涂层，和（c）转印转印部分包括印刷在脱脂涂层上的保护漆层，印刷在保护漆层上的油墨层和印刷在油墨层上的粘合剂层，以及下面保护漆层的任何暴露部分，以及到外套的周围地区。保护漆层包括已经通过三聚氰胺树脂交联的溶剂可溶的苯氧基树脂。油墨层包括印刷有磨砂油墨的设计，磨砂油墨优选地包含溶剂可溶的苯氧基树脂，二氧化硅和着色剂。粘合剂层包含存在于水基苯氧基树脂分散体中的苯氧树脂。

10. 发明授权

US06033763A Heat-transfer label including cross-linked phenoxy lacquer layer 失效
标题翻译：热转印标签包括交联苯氧漆层
公开(公告)号：US06033763A
公开(公告)日：2000-03-07
申请号：US93150
申请日：1998-06-08
申请人： Jean Paul Laprade , James S. Nugent , Darchun Billy Yang
发明人： Jean Paul Laprade , James S. Nugent , Darchun Billy Yang
IPC分类号： B44C1/17 , B32B3/00
CPC分类号： B44C1/1716 , Y10T428/2486 , Y10T428/2822 , Y10T428/2826 , Y10T428/2839
摘要： A heat-transfer label suitable for use in decorating polyethylene-coated glass articles. In a preferred embodiment, the label is capable of withstanding pasteurization conditions on a polyethylene-coated glass article and includes (a) a support portion in the form of a sheet of paper overcoated with a release layer of polyethylene, (b) a skim coat of wax overcoated onto the polyethylene release layer and (c) a transfer portion, the transfer portion including a cross-linked phenoxy protective lacquer layer printed onto the skim coat, a polyester ink layer printed onto the protective lacquer layer, a first adhesive layer printed onto the ink layer and onto any exposed portions of the underlying protective lacquer layer, and a second adhesive layer printed onto the first adhesive layer. The cross-linked phenoxy resin comprises a phenoxy resin of the formula ##STR1## wherein phenoxy resin is cross-linked by a melamine formaldehyde resin. The first adhesive layer preferably comprises an acrylic adhesive resin of the type present in a water-based adhesive dispersion or in a water-based adhesive emulsion and also comprises a surfactant in the form of dioctyl sodium sulfosuccinate. The second adhesive layer preferably comprises a chlorinated polyolefin of the type present in a water-based chlorinated polyolefin dispersion and also comprises a thickener in the form of a polyurethane.
摘要翻译：适用于装饰聚乙烯涂层玻璃制品的热转印标签。在优选的实施方案中，标签能够耐受聚乙烯涂覆的玻璃制品上的巴氏灭菌条件，并且包括（a）以聚乙烯脱模层包覆的纸片形式的支撑部分，（b）的蜡涂覆在聚乙烯脱模层上，（c）转印部分，转印部分包括印刷在脱脂涂层上的交联的苯氧基保护漆层，印刷在保护漆层上的聚酯油墨层，印刷的第一粘合剂层在油墨层上和下面的保护漆层的任何暴露部分上，以及印刷在第一粘合剂层上的第二粘合剂层。交联的苯氧基树脂包括下式的苯氧基树脂，其中苯氧基树脂通过三聚氰胺甲醛树脂交联。第一粘合剂层优选包含存在于水基粘合剂分散体或水性粘合剂乳液中的丙烯酸类粘合剂树脂，并且还包含二辛基磺基琥珀酸钠形式的表面活性剂。第二粘合剂层优选包含存在于水基氯化聚烯烃分散体中的氯化聚烯烃，并且还包含聚氨酯形式的增稠剂。

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