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    • 6. 发明申请
    • METHOD FOR PREPARING ACROLEIN FROM GLYCEROL OR GLYCERINE
    • 从甘油或甘油制备丙烯酸的方法
    • US20110288323A1
    • 2011-11-24
    • US13140109
    • 2009-12-16
    • Virginie Belliere-BacaStephane LoridantJean-Marc MilletPascaline Lauriol-Garbey
    • Virginie Belliere-BacaStephane LoridantJean-Marc MilletPascaline Lauriol-Garbey
    • C07C45/29C07C253/00C07C51/235C07C381/00
    • The invention relates to a method for preparing acrolein from glycerol or glycerine, comprising dehydrating glycerol or glycerine in the presence of a catalyst consisting of at least a) a mixed oxide of zirconium and at least one metal, said metal being selected from niobium, tantalum and vanadium, b) a zirconium oxide and at least one metal oxide, the metal being selected from niobium, tantalum and vanadium, c) a silicon oxide and a mixed oxide of zirconium and at least one metal, the metal being selected from tungsten, cerium, manganese, niobium, tantalum, titanium, vanadium and silicon, d) a silicon oxide and a mixed oxide of zirconium and at least one metal, the metal being selected from tungsten, cerium, manganese, niobium, tantalum, vanadium and titanium, e) a titanium oxide and a mixed oxide of zirconium and at least one metal, said metal being selected from tungsten, cerium, manganese, niobium, tantalum, titanium, vanadium and silicon, f) a titanium oxide and a mixed oxide or zirconium and at least one metal, said metal being selected from tungsten, cerium, manganese, niobium, tantalum, titanium, vanadium and silicon. The method can be used for producing -3-(methylthio)propionic (MMP) aldehyde, 2-hydroxy-4-methylthiobutyronitrile (HMTBN), methionine and analogues thereof from acrolein.
    • 本发明涉及一种由甘油或甘油制备丙烯醛的方法,包括在由至少一种锆和至少一种金属的混合氧化物组成的催化剂存在下使甘油或甘油脱水,所述金属选自铌,钽 和钒,b)氧化锆和至少一种金属氧化物,所述金属选自铌,钽和钒,c)氧化硅和锆与至少一种金属的混合氧化物,所述金属选自钨, 铈,锰,铌,钽,钛,钒和硅,d)氧化锆和锆与至少一种金属的混合氧化物,所述金属选自钨,铈,锰,铌,钽,钒和钛, e)氧化钛和锆与至少一种金属的混合氧化物,所述金属选自钨,铈,锰,铌,钽,钛,钒和硅,f)氧化钛和混合氧化物或z 所述金属选自钨,铈,锰,铌,钽,钛,钒和硅。 该方法可用于由丙烯醛生产3-(甲硫基)丙酸(MMP)醛,2-羟基-4-甲基硫代丁腈(HMTBN),甲硫氨酸及其类似物。