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1. 发明授权

US07476770B2 Epoxidation catalyst 失效
标题翻译：环氧催化剂
公开(公告)号：US07476770B2
公开(公告)日：2009-01-13
申请号：US11888600
申请日：2007-08-01
申请人： Jay F. Miller , Bernard Cooker , Robert N. Cochran , Peter J. Whitman
发明人： Jay F. Miller , Bernard Cooker , Robert N. Cochran , Peter J. Whitman
IPC分类号： C07C27/00 , C07D301/02 , C07D301/12
CPC分类号： C07D303/04 , B01J23/06 , B01J23/60 , B01J29/89 , B01J37/0045 , B01J2229/186 , B01J2229/20 , B01J2229/42 , C07D301/06
摘要： The invention is a catalyst comprising a titanium or vanadium zeolite, a binder, and zinc oxide, wherein the catalyst is preparing an aqueous mixture of the zeolite, a binder source, and a zinc oxide source, and subjecting the mixture to rapid drying. The catalyst is useful in olefin epoxidation.
摘要翻译：本发明是一种包含钛或钒沸石，粘合剂和氧化锌的催化剂，其中催化剂正在制备沸石，粘合剂源和氧化锌源的含水混合物，并使混合物快速干燥。该催化剂可用于烯烃环氧化。

2. 发明授权

US07273826B2 Epoxidation catalyst 失效
标题翻译：环氧催化剂
公开(公告)号：US07273826B2
公开(公告)日：2007-09-25
申请号：US11190088
申请日：2005-07-26
申请人： Jay F. Miller , Bernard Cooker , Robert N. Cochran , Peter J. Whitman
发明人： Jay F. Miller , Bernard Cooker , Robert N. Cochran , Peter J. Whitman
IPC分类号： B01J29/06 , B01J29/78
CPC分类号： C07D303/04 , B01J23/06 , B01J23/60 , B01J29/89 , B01J37/0045 , B01J2229/186 , B01J2229/20 , B01J2229/42 , C07D301/06
摘要： The invention is a catalyst comprising a titanium or vanadium zeolite, a binder, and zinc oxide, wherein the catalyst is preparing an aqueous mixture of the zeolite, a binder source, and a zinc oxide source, and subjecting the mixture to rapid drying. The catalyst is useful in olefin epoxidation.
摘要翻译：本发明是一种包含钛或钒沸石，粘合剂和氧化锌的催化剂，其中催化剂正在制备沸石，粘合剂源和氧化锌源的含水混合物，并使混合物快速干燥。该催化剂可用于烯烃环氧化。

3. 发明授权

US07138535B1 Direct epoxidation process 失效
标题翻译：直接环氧化工艺
公开(公告)号：US07138535B1
公开(公告)日：2006-11-21
申请号：US11141962
申请日：2005-06-01
申请人： Peter J. Whitman , Jay F. Miller , John H. Speidel, Jr. , Robert N. Cochran
发明人： Peter J. Whitman , Jay F. Miller , John H. Speidel, Jr. , Robert N. Cochran
IPC分类号： C07D301/06 , C07D301/12
CPC分类号： C07D301/06
摘要： The invention is a process for epoxidizing an olefin with hydrogen and oxygen in the presence of a catalyst comprising a noble metal and a titanium or vanadium zeolite in a solvent mixture comprising water, methanol, and a C3–C6 aliphatic ketone. This process surprisingly gives significantly reduced by-product glycol and glycol ethers formed by the unwanted ring-opening of epoxides.
摘要翻译：本发明是一种在包含贵金属和钛或钒沸石的催化剂存在下，用氢和氧环氧化烯烃的方法，所述催化剂包含水，甲醇和C 3 - C 6脂族酮。该方法令人惊奇地得到由环氧化物不需要的开环形成的显着减少的副产物二醇和二醇醚。

4. 发明授权

US06870060B1 Product recovery from supercritical mixtures 失效
标题翻译：从超临界混合物中回收产品
公开(公告)号：US06870060B1
公开(公告)日：2005-03-22
申请号：US10691142
申请日：2003-10-22
申请人： Robert N. Cochran , Jay F. Miller
发明人： Robert N. Cochran , Jay F. Miller
IPC分类号： C07D301/04 , C07D301/02
CPC分类号： C07D301/04 , Y02P20/544
摘要： Oxidation products are recovered from a mixture of the products in a dense phase or supercritical solvent by a liquid—liquid extraction at dense phase conditions.
摘要翻译：在密相或超临界溶剂中，通过在密相条件下的液 - 液萃取从产物的混合物中回收氧化产物。

5. 发明授权

US06936740B1 Dense phase oxidation of benzene 失效
标题翻译：苯的强相氧化
公开(公告)号：US06936740B1
公开(公告)日：2005-08-30
申请号：US10921686
申请日：2004-08-19
申请人： Robert N. Cochran , Jay F. Miller , Eric John Beckman , Sarah Emma Jones
发明人： Robert N. Cochran , Jay F. Miller , Eric John Beckman , Sarah Emma Jones
IPC分类号： C07C37/58 , C07C37/60 , C07C39/04
CPC分类号： C07C37/58 , C07C37/60 , C07C39/04
摘要： Phenol is formed by reaction of oxidant and benzene over a solid catalyst such as Pd on TS-1, the reaction being carried out in carbon dioxide solvent at conditions effective to provide a dense phase reaction mixture.
摘要翻译：苯酚通过氧化剂和苯在固体催化剂如Pd在TS-1上的反应形成，反应在有效提供致密相反应混合物的条件下在二氧化碳溶剂中进行。

6. 发明申请

US20080103319A1 Alkylene oxide process 失效
标题翻译：环氧丙烷工艺
公开(公告)号：US20080103319A1
公开(公告)日：2008-05-01
申请号：US11588453
申请日：2006-10-27
申请人： Jay F. Miller
发明人： Jay F. Miller
IPC分类号： C07D301/06
CPC分类号： C07D301/06
摘要： A process is provided for the production of alkylene oxide by catalytic reaction of olefin, hydrogen and oxygen in the presence of promoting buffer salts, the improvement wherein the buffer salts are recovered by electrodialysis and/or crystallization and recycled to the catalytic reaction.
摘要翻译：提供了一种在促进缓冲盐存在下通过烯烃，氢和氧的催化反应生产烯化氧的方法，其中缓冲盐通过电渗析和/或结晶回收并再循环到催化反应中。

7. 发明申请

US20100331556A1 Epoxidation process 有权
标题翻译：环氧化工艺
公开(公告)号：US20100331556A1
公开(公告)日：2010-12-30
申请号：US12459065
申请日：2009-06-26
申请人： Jay F. Miller , John H. Speidel, JR.
发明人： Jay F. Miller , John H. Speidel, JR.
IPC分类号： C07D301/12
CPC分类号： C07D301/12 , C07D301/32
摘要： This invention is a process for producing propylene oxide. The process comprises first contacting a titanium zeolite with a reaction feed comprising propylene, hydrogen peroxide, tertiary butyl alcohol, and water to produce a product stream comprising propylene, propylene oxide, propylene glycol, tertiary butyl alcohol, and water. The product stream is distilled to produce a first overhead stream comprising propylene and a first bottoms stream comprising propylene oxide, propylene glycol, tertiary butyl alcohol, and water. The first bottoms stream is distilled to produce a second overhead stream comprising propylene oxide and a second bottoms product stream comprising propylene glycol, tertiary butyl alcohol, and water. The second bottoms stream is distilled to produce a third overhead stream comprising an azeotrope of tertiary butyl alcohol and water and a third bottoms stream comprising propylene glycol and water.
摘要翻译：本发明是一种生产环氧丙烷的方法。该方法包括首先使钛沸石与包含丙烯，过氧化氢，叔丁醇和水的反应进料接触，以产生包含丙烯，环氧丙烷，丙二醇，叔丁醇和水的产物流。将产物流蒸馏以产生包含丙烯的第一塔顶物流和包含环氧丙烷，丙二醇，叔丁醇和水的第一塔底物流。将第一塔底物流蒸馏以产生包含环氧丙烷的第二塔顶物流和包含丙二醇，叔丁醇和水的第二塔底物产物流。蒸馏第二塔底物流以产生包含叔丁醇和水的共沸物的第三塔顶物流和包含丙二醇和水的第三塔底物流。

8. 发明授权

US06289568B1 Method for making a balloon catheter stent deployment system 有权
标题翻译：球囊导管支架展开系统的制作方法
公开(公告)号：US06289568B1
公开(公告)日：2001-09-18
申请号：US09192899
申请日：1998-11-16
申请人： Jay F. Miller , Edward J. Play
发明人： Jay F. Miller , Edward J. Play
IPC分类号： B23D1700
CPC分类号： A61M25/0014 , A61F2/958 , Y10T29/4981 , Y10T29/49927
摘要： A balloon catheter and stent delivery system for medical treatment of a patient includes a balloon inflatable to an inflated shape having a cylindrical working portion, and a deflated shape that is temporarily reformed to enhance longitudinal retention of the stent while the catheter system is advanced or withdrawn. The balloon catheter provides for uniform expansion of the stent when the balloon is inflated. In addition, the balloon catheter system can be modified to initiate partial inflation of the proximal and distal ends of the stent, to further resist longitudinal motion of the stent during inflation, and to facilitate more effective tacking of the stent. One possible feature of the catheter system is that the balloon is pleated in a particular pattern when deflated, whereby the central balloon portion carrying the stent has a greater number of pleats than the shoulder portions proximal and distal of the stent. Another possible feature is the formation of small channels that facilitate fluid communication from the proximal end of the balloon to the distal end, even when the balloon is deflated. The balloon may be formed to protrude partially outward among the stent interstices while in its deflated state, further enhancing stent position retention. The present invention also protects the leading or distal end of the stent during advancement, and protects the proximal end of the stent during any withdrawal of the catheter system.
摘要翻译：用于患者医疗处理的球囊导管和支架输送系统包括可膨胀至具有圆柱形工作部分的膨胀形状的球囊，以及当导管系统前进或撤回时暂时重新形成以增强支架纵向保持力的放气形状。当气囊膨胀时，气囊导管提供支架的均匀膨胀。此外，气囊导管系统可以被修改以引起支架的近端和远端的部分充气，以进一步阻止支架在充胀期间的纵向运动，并且有助于更有效地固定支架。导管系统的一个可能的特征是当放气时气囊以特定的图案打褶，由此承载支架的中心球囊部分具有比支架近端和远端的肩部更大数量的褶皱。另一个可能的特征是形成小通道，其促进从球囊的近端到远端的流体连通，即使当气囊被放气时。气囊可以被形成为在其放气状态下部分地向外伸出支架间隙，进一步增强支架位置保持力。本发明还在前进期间保护支架的前端或远端，并且在任何取出导管系统期间保护支架的近端。

9. 发明授权

US08124555B2 Process for making titanium-MWW zeolite 有权
标题翻译：制备钛-WWW沸石的方法
公开(公告)号：US08124555B2
公开(公告)日：2012-02-28
申请号：US12658029
申请日：2010-02-01
申请人： Beaven S. Mandimutsira , Jay F. Miller
发明人： Beaven S. Mandimutsira , Jay F. Miller
IPC分类号： B01J29/06 , B01J29/89 , B01J21/00 , C07D301/12 , C07D301/06
CPC分类号： C01B37/005 , B01J29/89 , C07C29/03 , C07D301/12
摘要： Titanium-MWW zeolite is prepared by heating a gel formed from a titanium compound, a silicon source, a boron source, an MWW-templating agent, and water at a temperature in the range of 35° C. to 75° C. for a period of 8 to 30 hours to form a pre-crystallized gel, and heating the pre-crystallized gel to a temperature in the range of 160° C. to 190° C. for a period of 5 or more days to form the titanium-MWW zeolite. The zeolite, after it is contacted with an acid, is useful in olefin epoxidation with hydrogen peroxide.
摘要翻译：通过在35℃至75℃的温度范围内加热由钛化合物，硅源，硼源，MWW模板剂和水形成的凝胶来制备钛-WWW沸石，用于时间为8至30小时以形成预结晶凝胶，并将预结晶凝胶加热至160℃至190℃的温度，持续5天或更长时间，以形成钛 - MWW沸石。沸石与酸接触后，可用于与过氧化氢进行烯烃环氧化反应。

10. 发明授权

US07387981B1 Direct epoxidation catalyst and process 失效
标题翻译：直接环氧化催化剂和工艺
公开(公告)号：US07387981B1
公开(公告)日：2008-06-17
申请号：US11823651
申请日：2007-06-28
申请人： Mark P. Kaminsky , Roger A. Grey , Jay F. Miller
发明人： Mark P. Kaminsky , Roger A. Grey , Jay F. Miller
IPC分类号： B01J23/44
CPC分类号： B01J29/89 , B01J21/063 , B01J23/38 , B01J23/44 , B01J23/52 , B01J23/66 , B01J35/0006 , B01J35/023 , B01J35/1019 , B01J37/0009 , B01J2229/20 , C07D301/10
摘要： A catalyst comprising a transition metal zeolite and a supported noble metal is disclosed. The mean mass diameter of the catalyst is greater than 0.5 mm. The catalyst is formed from transition metal zeolite particles and the supported noble metal particles each having a mean mass diameter of less than 0.1 mm. An epoxidation process by reacting an olefin, hydrogen, and oxygen in the presence of the catalyst is disclosed.
摘要翻译：公开了一种包含过渡金属沸石和负载的贵金属的催化剂。催化剂的平均质量直径大于0.5mm。催化剂由平均质量直径小于0.1mm的过渡金属沸石颗粒和负载的贵金属颗粒形成。公开了在催化剂存在下使烯烃，氢气和氧气反应的环氧化方法。

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