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1. 发明申请

US20050032988A1 METHOD FOR PREPARATION OF COPOLYORGANOSILOXANECARBONATES OF HIGH CLARITY 有权
标题翻译：用于制备高浓度共聚丙烯酰氧基丙烯酸酯的方法
公开(公告)号：US20050032988A1
公开(公告)日：2005-02-10
申请号：US10638622
申请日：2003-08-08
申请人： James Silva , David Dardaris , Gary Davis
发明人： James Silva , David Dardaris , Gary Davis
IPC分类号： C08G64/18 , C08G64/24 , C08G77/448 , C08F283/02
CPC分类号： C08G77/448 , C08G64/186 , C08G64/24 , C08G77/24 , C08G77/80
摘要： Copolyorganosiloxanecarbonates are prepared by first preparing an oligomeric aromatic polycarbonate, such as an oligomeric bisphenol A polycarbonate, in the presence of a tertiary amine as the only catalyst species; contacting the oligomeric polycarbonate mixture with a polyorganosiloxane bis(aryl)chloroformate, such as the bischloroformate of hydroxy-terminated eugenol polydimethylsiloxane; and introducing phosgene and/or chain termination agent either continuously or in stages. A feature of the process is the presence of dihydroxyaromatic compound in only one charge, at the beginning. The products have excellent physical properties, including transparency.
摘要翻译：通过在叔胺作为唯一的催化剂种存在下首先制备低聚芳族聚碳酸酯如低聚双酚A聚碳酸酯来制备共聚有机硅氧烷，使低聚聚碳酸酯混合物与聚有机硅氧烷二（芳基）氯甲酸酯接触，例如羟基封端的丁子香酚聚二甲基硅氧烷的双氯甲酸酯; 并连续或分阶段引入光气和/或链终止剂。该方法的特征是在开始时仅在一次充电中存在二羟基芳族化合物。该产品具有优异的物理性能，包括透明度。

2. 发明申请

US20060084822A1 Method for the preparation of aliphatic chloroformates 失效
标题翻译：制备脂族氯甲酸酯的方法
公开(公告)号：US20060084822A1
公开(公告)日：2006-04-20
申请号：US10968773
申请日：2004-10-19
申请人： Gary Davis , Joshua Stone , James Silva , James Mahood , David Dardaris
发明人： Gary Davis , Joshua Stone , James Silva , James Mahood , David Dardaris
IPC分类号： C07C69/96
CPC分类号： C07D493/04 , C07C68/02 , C07J9/00 , C08G64/1608 , C08G64/24 , C08G64/28 , C07C69/96
摘要： A method for preparing an aliphatic chloroformate comprising, introducing a mixture of at least one aliphatic hydroxyl compound, phosgene, at least one solvent, and optionally at least one organic base into a flow reactor to obtain a unidirectional flowing reaction mixture. The at least one aliphatic hydroxyl compound comprises at least one aliphatic hydroxyl group. The unidirectional flowing reaction mixture is maintained at a temperature between about 0° C. and about 60° C. to produce a single product stream comprising an aliphatic chloroformate.
摘要翻译：一种制备脂族氯甲酸酯的方法，包括将至少一种脂族羟基化合物，光气，至少一种溶剂和任选的至少一种有机碱的混合物引入流动反应器中以获得单向流动的反应混合物。所述至少一种脂族羟基化合物包含至少一个脂族羟基。将单向流动反应混合物保持在约0℃至约60℃之间的温度下，以产生包含脂族氯甲酸酯的单一产物流。

3. 发明授权

US07312352B2 Method of preparing ester-substituted diaryl carbonates 有权
标题翻译：酯取代的二芳基碳酸酯的制备方法
公开(公告)号：US07312352B2
公开(公告)日：2007-12-25
申请号：US10984318
申请日：2004-11-08
申请人： Paul William Buckley , James Silva , David Dardaris
发明人： Paul William Buckley , James Silva , David Dardaris
IPC分类号： C07C69/96
CPC分类号： C07C68/02 , C07C69/96
摘要： The present invention relates to an interfacial method of preparing ester-substituted diaryl carbonates. The method includes the steps of: forming a reaction mixture comprising phosgene, an ester-substituted phenol, an organic solvent, and a catalyst selected from the group consisting of a tertiary amine catalyst and a phase transfer catalyst, said reaction mixture having an organic phase and an aqueous phase, wherein said aqueous phase has a brine strength; allowing the reaction mixture to react wherein during the reaction, (i) the aqueous phase has a pH, and the pH is adjusted, if necessary, by the addition of an alkali metal hydroxide solution in amounts such that the pH is greater than or equal to 9.0 during at least some portion of the reaction, and (ii) the brine strength of the aqueous phase is adjusted, if necessary, by varying the concentration of the alkali metal hydroxide solution being added to maintain the pH such that the brine strength is between 15% and a saturated brine solution during at least some portion of the reaction: thereby forming an ester-substituted diaryl carbonate, wherein the reaction mixture is formed with less than 15% water of formulation, and wherein the brine strength is maintained at or above 15% and the pH is maintained at or above 9 for a sufficient portion of the process that the ester-substituted diaryl carbonate is formed with a conversion of at least 90% and a selectivity of at least 98%.
摘要翻译：本发明涉及制备酯取代的二芳基碳酸酯的界面方法。该方法包括以下步骤：形成包括光气，酯取代的酚，有机溶剂和选自叔胺催化剂和相转移催化剂的催化剂的反应混合物，所述反应混合物具有有机相和水相，其中所述水相具有盐水强度; 允许反应混合物反应，其中在反应期间，（i）水相具有pH，并且如果需要，通过加入碱金属氢氧化物溶液调节pH，使得pH大于或等于在反应的至少一部分期间至9.0，和（ii）如果需要，通过改变加入的碱金属氢氧化物溶液的浓度来调节水相的盐水强度，以保持pH使得盐水强度为在反应的至少一部分期间在15％和饱和盐水溶液之间，由此形成酯取代的碳酸二芳基酯，其中反应混合物由少于15％的制剂水形成，并且其中盐水强度保持在或高于15％，并且pH保持在或大于9，足够部分的方法是形成酯取代的碳酸二芳基酯，其转化率至少为90％，选择性为至少98％。

4. 发明授权

US07518011B2 Method of preparing ester-substituted diaryl carbonates 有权
标题翻译：酯取代的二芳基碳酸酯的制备方法
公开(公告)号：US07518011B2
公开(公告)日：2009-04-14
申请号：US11858732
申请日：2007-09-20
申请人： Paul William Buckley , James Silva , David Dardaris
发明人： Paul William Buckley , James Silva , David Dardaris
IPC分类号： C07C69/96
CPC分类号： C07C68/02 , C07C69/96
摘要： The present invention relates to an interfacial method of preparing ester-substituted diaryl carbonates. The method includes the steps of: forming a reaction mixture comprising phosgene, an ester-substituted phenol, an organic solvent, and a catalyst selected from the group consisting of a tertiary amine catalyst and a phase transfer catalyst, said reaction mixture having an organic phase and an aqueous phase, wherein said aqueous phase has a brine strength; allowing the reaction mixture to react wherein during the reaction, (i) the aqueous phase has a pH, and the pH is adjusted, if necessary, by the addition of an alkali metal hydroxide solution in amounts such that the pH is greater than or equal to 9.0 during at least some portion of the reaction, and (ii) the brine strength of the aqueous phase is adjusted, if necessary, by varying the concentration of the alkali metal hydroxide solution being added to maintain the pH such that the brine strength is between 15% and a saturated brine solution during at least some portion of the reaction: thereby forming an ester-substituted diaryl carbonate, wherein the reaction mixture is formed with less than 15% water of formulation, and wherein the brine strength is maintained at or above 15% and the pH is maintained at or above 9 for a sufficient portion of the process that the ester-substituted diaryl carbonate is formed with a conversion of at least 90% and a selectivity of at least 98%.
摘要翻译：本发明涉及制备酯取代的二芳基碳酸酯的界面方法。该方法包括以下步骤：形成包括光气，酯取代的酚，有机溶剂和选自叔胺催化剂和相转移催化剂的催化剂的反应混合物，所述反应混合物具有有机相和水相，其中所述水相具有盐水强度; 允许反应混合物反应，其中在反应期间，（i）水相具有pH，并且如果需要，通过加入碱金属氢氧化物溶液调节pH，使得pH大于或等于在反应的至少一部分期间至9.0，和（ii）如果需要，通过改变加入的碱金属氢氧化物溶液的浓度来调节水相的盐水强度，以保持pH使得盐水强度为在反应的至少一部分期间在15％和饱和盐水溶液之间，由此形成酯取代的碳酸二芳基酯，其中反应混合物由少于15％的制剂水形成，并且其中盐水强度保持在或高于15％，并且pH保持在或大于9，足够部分的方法是形成酯取代的碳酸二芳基酯，其转化率至少为90％，选择性为至少98％。

5. 发明申请

US20080009646A1 Method of Preparing Ester-Substituted Diaryl Carbonates 有权
标题翻译：酯取代的二芳基碳酸酯的制备方法
公开(公告)号：US20080009646A1
公开(公告)日：2008-01-10
申请号：US11858732
申请日：2007-09-20
申请人： Paul Buckley , James Silva , David Dardaris
发明人： Paul Buckley , James Silva , David Dardaris
IPC分类号： C07C69/96
CPC分类号： C07C68/02 , C07C69/96
摘要： The present invention relates to an interfacial method of preparing ester-substituted diaryl carbonates. The method includes the steps of: forming a reaction mixture comprising phosgene, an ester-substituted phenol, an organic solvent, and a catalyst selected from the group consisting of a tertiary amine catalyst and a phase transfer catalyst, said reaction mixture having an organic phase and an aqueous phase, wherein said aqueous phase has a brine strength; allowing the reaction mixture to react wherein during the reaction, (i) the aqueous phase has a pH, and the pH is adjusted, if necessary, by the addition of an alkali metal hydroxide solution in amounts such that the pH is greater than or equal to 9.0 during at least some portion of the reaction, and (ii) the brine strength of the aqueous phase is adjusted, if necessary, by varying the concentration of the alkali metal hydroxide solution being added to maintain the pH such that the brine strength is between 15% and a saturated brine solution during at least some portion of the reaction: thereby forming an ester-substituted diaryl carbonate, wherein the reaction mixture is formed with less than 15% water of formulation, and wherein the brine strength is maintained at or above 15% and the pH is maintained at or above 9 for a sufficient portion of the process that the ester-substituted diaryl carbonate is formed with a conversion of at least 90% and a selectivity of at least 98%.
摘要翻译：本发明涉及制备酯取代的二芳基碳酸酯的界面方法。该方法包括以下步骤：形成包括光气，酯取代的酚，有机溶剂和选自叔胺催化剂和相转移催化剂的催化剂的反应混合物，所述反应混合物具有有机相和水相，其中所述水相具有盐水强度; 允许反应混合物反应，其中在反应期间，（i）水相具有pH，并且如果需要，通过加入碱金属氢氧化物溶液调节pH，使得pH大于或等于在反应的至少一部分期间至9.0，和（ii）如果需要，通过改变加入的碱金属氢氧化物溶液的浓度来调节水相的盐水强度，以保持pH使得盐水强度为在反应的至少一部分期间在15％和饱和盐水溶液之间，由此形成酯取代的碳酸二芳基酯，其中反应混合物由少于15％的制剂水形成，并且其中盐水强度保持在或高于15％，并且pH保持在或大于9，足够部分的方法是形成酯取代的碳酸二芳基酯，其转化率至少为90％，选择性为至少98％。

6. 发明申请

US20060025622A1 Method of preparing ester-substituted diaryl carbonates 有权
公开(公告)号：US20060025622A1
公开(公告)日：2006-02-02
申请号：US10984318
申请日：2004-11-08
申请人： Paul Buckley , James Silva , David Dardaris
发明人： Paul Buckley , James Silva , David Dardaris
IPC分类号： C07C69/96
CPC分类号： C07C68/02 , C07C69/96
摘要： The present invention relates to an interfacial method of preparing ester-substituted diaryl carbonates. The method includes the steps of: forming a reaction mixture comprising phosgene, an ester-substituted phenol, an organic solvent, and a catalyst selected from the group consisting of a tertiary amine catalyst and a phase transfer catalyst, said reaction mixture having an organic phase and an aqueous phase, wherein said aqueous phase has a brine strength; allowing the reaction mixture to react wherein during the reaction, (i) the aqueous phase has a pH, and the pH is adjusted, if necessary, by the addition of an alkali metal hydroxide solution in amounts such that the pH is greater than or equal to 9.0 during at least some portion of the reaction, and (ii) the brine strength of the aqueous phase is adjusted, if necessary, by varying the concentration of the alkali metal hydroxide solution being added to maintain the pH such that the brine strength is between 15% and a saturated brine solution during at least some portion of the reaction: thereby forming an ester-substituted diaryl carbonate, wherein the reaction mixture is formed with less than 15% water of formulation, and wherein the brine strength is maintained at or above 15% and the pH is maintained at or above 9 for a sufficient portion of the process that the ester-substituted diaryl carbonate is formed with a conversion of at least 90% and a selectivity of at least 98%.

7. 发明申请

US20070238846A1 Polysiloxane-polycarbonate copolymer article 有权
标题翻译：聚硅氧烷 - 聚碳酸酯共聚物制品
公开(公告)号：US20070238846A1
公开(公告)日：2007-10-11
申请号：US11401171
申请日：2006-04-10
申请人： Gary Davis , James Mahood , Matthew Pixton , Niles Rosenquist , James Silva , Joshua Stone
发明人： Gary Davis , James Mahood , Matthew Pixton , Niles Rosenquist , James Silva , Joshua Stone
IPC分类号： C08G77/448 , C08L83/04
CPC分类号： C08G64/186 , C08G77/448 , C08L83/10
摘要： Disclosed herein are polysiloxane-polycarbonate copolymer articles. In one embodiment, a ⅛th inch thick bar formed from the thermoplastic composition has a B-Y ratio of less than or equal to about 1.75. This article, which has a dimension that is greater than or equal to 1.5 cm, comprises the thermoplastic composition which comprises a polysiloxane-polycarbonate copolymer, wherein the copolymer comprises repeating diorganosiloxane units of formula (1): wherein each R is, independently, a C1-13 monovalent organic group; and E has an average value of 20 to 35.
摘要翻译：本文公开的是聚硅氧烷 - 聚碳酸酯共聚物制品。在一个实施方案中，由热塑性组合物形成的1/8英寸厚的棒具有小于或等于约1.75的B-Y比。具有大于或等于1.5cm的尺寸的该制品包含包含聚硅氧烷 - 聚碳酸酯共聚物的热塑性组合物，其中所述共聚物包含重复式（1）的二有机硅氧烷单元：其中每个R独立地为 C 1-13 一价有机基团; E的平均值为20〜35。

8. 发明申请

US20070093629A1 Siloxane bishchloroformates 审中-公开
标题翻译：硅氧烷双氯甲酸酯
公开(公告)号：US20070093629A1
公开(公告)日：2007-04-26
申请号：US11226702
申请日：2005-09-14
申请人： James Silva , Gary Davis
发明人： James Silva , Gary Davis
IPC分类号： C08G77/48
CPC分类号： C07F7/0889
摘要： A continuous method for the preparation of bischloroformates of siloxane bisphenols, said method comprising introducing into a flow reactor and contacting therein at least one siloxane bisphenol, at least one metal hydroxide, at least one metal salt, at least one solvent and phosgene to form a flowing reaction mixture having an organic phase and an aqueous phase and forming bischloroformates of siloxane bisphenols in the flowing reaction mixture.
摘要翻译：一种用于制备硅氧烷双酚的双氯甲酸酯的连续方法，所述方法包括向流动反应器中引入至少一种硅氧烷双酚，至少一种金属氢氧化物，至少一种金属盐，至少一种溶剂和光气，以形成具有有机相和水相的流动反应混合物，并在流动的反应混合物中形成硅氧烷双酚的双氯甲酸酯。

9. 发明申请

US20070155945A1 Thermally stable polycarbonates, thermoplastic compositions thereof, and articles formed therefrom 有权
标题翻译：热稳定的聚碳酸酯，其热塑性组合物和由其形成的制品
公开(公告)号：US20070155945A1
公开(公告)日：2007-07-05
申请号：US11324949
申请日：2006-01-04
申请人： Gary Davis , James Mahood , James Silva , Joshua Stone
发明人： Gary Davis , James Mahood , James Silva , Joshua Stone
IPC分类号： C08G64/00
CPC分类号： C08G64/1608 , C08G63/64 , C08G64/186 , Y10T428/31504 , Y10T428/31507 , Y10T428/31855
摘要： A polycarbonate such as aliphatic/aromatic polycarbonate comprises repeating structural carbonate units of the formula (H-1): in which Rh is a radical having the formula (H-2): wherein each of R11, R12, R13, R14, R15, R16, R17, R18, R19, R20, R21, R22, R23, R24, R25, R26, R27, and R28 is independently a hydrogen, a C1-C6 alkyl group, or a halogen substituted C1-C6 alkyl group. The polycarbonate, and a thermoplastic composition thereof, have improved thermal stability, cost-effectiveness, and exhibit improved manufacturability such as, for example, minimum cyclic carbonate formation and minimum amine acceptor requirement.
摘要翻译：聚碳酸酯如脂族/芳族聚碳酸酯包括重复式（H-1）的结构碳酸酯单元：其中R hh是具有式（H-2）的基团：其中R' R 11，R 12，R 13，R 14，R 15，R 15， R 16，R 17，R 18，R 19，R 20，R 17， R 21，R 22，R 23，R 24，R 25，R 24， R 26，R 27和R 28独立地是氢，C 1 -C 6烷基，烷基，或卤素取代的C 1 -C 6烷基。聚碳酸酯及其热塑性组合物具有改进的热稳定性，成本效益，并且显示出改进的可制造性，例如最小的环状碳酸酯形成和最小的胺受体要求。

10. 发明申请

US20060293535A1 Method for the preparation of aromatic chloroformates 有权
标题翻译：芳香族氯甲酸酯的制备方法
公开(公告)号：US20060293535A1
公开(公告)日：2006-12-28
申请号：US11170306
申请日：2005-06-28
申请人： Gary Davis , James Silva , Joshua Stone
发明人： Gary Davis , James Silva , Joshua Stone
IPC分类号： C07C69/96
CPC分类号： C08G64/14 , C07C68/02 , C08G64/24 , C07C69/96
摘要： A method for preparing an aromatic chloroformate comprising, introducing a mixture of at least one aromatic hydroxyl compound, phosgene, at least one solvent, and at least one organic base into a flow reactor to obtain a unidirectionally flowing reaction mixture. The unidirectionally flowing reaction mixture is maintained at a temperature between about 0° C. and about 60° C. to produce a single product stream comprising an aromatic chloroformate.
摘要翻译：一种制备芳族氯甲酸酯的方法，包括将至少一种芳族羟基化合物，光气，至少一种溶剂和至少一种有机碱的混合物引入流动反应器中以获得单向流动的反应混合物。将单向流动的反应混合物保持在约0℃至约60℃之间的温度下，以产生包含芳族氯甲酸酯的单一产物流。

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