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    • 7. 发明申请
    • High glass transition temperature copolycarbonates, methods of manufacture, and uses thereof
    • 高玻璃化转变温度共聚碳酸酯,其制造方法及其应用
    • US20070123688A1
    • 2007-05-31
    • US11291195
    • 2005-11-30
    • James MahoodJon Malinoski
    • James MahoodJon Malinoski
    • C08G64/00
    • C08G64/12C08G64/28
    • A copolycarbonate of the formula wherein 5 to 75 mole percent of the total number of R1 groups is derived from a high Tg monomer of formula (2) wherein R2 and R3 are each independently a halogen or a C1-6 alkyl group, R4 is a methyl or phenyl, and c is 0 to 4; and 25 to 95 mole percent of the R1 groups are derived from a dihydroxy compound of formula HO—R5—OH, wherein at least 60% of the R5 groups are aromatic, and the dihydroxy compound of formula (3) is not the same as the high Tg monomer of formula (2), and wherein the copolycarbonate comprises at least 10% fewer carbonate linkages of formula (4) than would be theoretically obtained in a random copolymer made from the same ratio of the high Tg monomer of formula (2) and the dihydroxy compound of formula (3).
    • 一种下式的共聚碳酸酯,其中R 1〜5个基团总数的5〜75摩尔%来自式(2)的高Tg单体,其中R 2和R 2 3个独立地为卤素或C 1-6烷基,R 4为甲基或苯基,c为0至4 ; 并且25至95摩尔%的R 1基团衍生自式HO-R 5 -OH的二羟基化合物,其中至少60%的R“ > 5个基团是芳族的,并且式(3)的二羟基化合物与式(2)的高Tg单体不同,并且其中共聚碳酸酯包含至少10%的式(4)的碳酸酯键 )比在式(2)的高Tg单体和式(3)的二羟基化合物的相同比例制备的无规共聚物中理论上获得。
    • 8. 发明授权
    • Polycarbonate blends and method of making same
    • 聚碳酸酯混合物及其制备方法
    • US06462146B2
    • 2002-10-08
    • US09681379
    • 2001-03-27
    • James Mahood
    • James Mahood
    • C08L6900
    • C08G64/24C08G64/06C08L69/00
    • Copolymers of BPA and menthane bisphenols such as BPT1 and BPT2 can be used as a compatabilizer to allow the formation of homogeneous blends of BPA with menthane bisphenol polycarbonates such as poly-BPT1 or poly-BPT2 or copolymers thereof. Thus, a compatible polycarbonate blend is made by combining a bisphenol A polycarbonate, a menthane bisphenol polycarbonate and a BPA/menthane bisphenol copolymer compatabilizer, and mixing the combined materials to form a blend. The compatabilizer may contain one or more species of menthane bisphenol. In a specific example, BPT1 and BPT2 are used in the compatabilizer in a ratio, BPT1/BPT2, in the range of 70/30 to 10/90, preferably less than or equal to 1/1, for example around 30/70. By adjusting the relative amounts and the properties of the bisphenol A polycarbonate and the menthane bisphenol polycarbonate, the glass transition temperature and the toughness of the blend can be selected.
    • BPA和薄荷烷双酚(如BPT1和BPT2)的共聚物可以用作一种组合物,以使BPA与薄荷烷双酚聚碳酸酯如聚-BPT1或聚-BPT2或其共聚物的均匀共混物形成。 因此,通过组合双酚A聚碳酸酯,薄荷烷双酚聚碳酸酯和BPA /薄荷烷双酚共聚物混合物制备相容的聚碳酸酯共混物,并混合组合的材料以形成共混物。 化合物可以含有一种或多种薄荷烷双酚。 在具体实例中,BPT1和BPT2以比例BPT1 / BPT2在70/30至10/90,优选小于或等于1/1,例如约30/70的比例用于配制剂。 通过调节双酚A聚碳酸酯和薄荷烷双酚聚碳酸酯的相对量和性能,可以选择共混物的玻璃化转变温度和韧性。
    • 9. 发明申请
    • METHODS OF POLYMER PREPARATION USING POLYCYCLIC DIHYDROXY COMPOUNDS
    • 使用多环二羟基化合物制备聚合物的方法
    • US20070260033A1
    • 2007-11-08
    • US11693314
    • 2007-03-29
    • Jan KampsJan-Pleun LensJames MahoodArakali RadhakrishnaT. RajRavindra Singh
    • Jan KampsJan-Pleun LensJames MahoodArakali RadhakrishnaT. RajRavindra Singh
    • C08G64/04
    • C07C69/757C07C45/69C07C45/74C07C67/343C07C67/347C07C2601/14C08G64/14C07C49/223
    • Disclosed herein is a process for preparing a polymer comprising structural units derived from polycyclic dihydroxy compound having Formula (I), wherein R1 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic functionality having 1 to 10 carbons, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; R2 is selected from the group consisting of a cyano functionality, a nitro functionality, an aliphatic ester functionality having 2 to 10 carbons, a cycloaliphatic ester functionality having 4 to 10 carbons and an aromatic ester functionality having 4 to 10 carbons; and each R3 and R4, at each occurrence, can be the same or different and are independently at each occurrence an aliphatic functionality having 1 to 10 carbons or a cycloaliphatic functionality having 3 to 10 carbons, “n” is an integer having a value 0 to 4 and “m” is an integer having a value 0 to 4. The process comprises subjecting a polycyclic dihydroxy compound of Formula (I) to polymerization.
    • 本文公开了一种制备包含衍生自具有式(I)的多环二羟基化合物的结构单元的聚合物的方法,其中R 1选自氰基官能团,硝基官能团,脂族基团 具有1至10个碳的官能团,具有2至10个碳的脂族酯官能团,具有4至10个碳的脂环族酯官能团和具有4至10个碳的芳族酯官能团; R 2选自氰基官能团,硝基官能团,具有2至10个碳的脂族酯官能团,具有4至10个碳的脂环族酯官能团和具有4个碳原子的芳族酯官能团 至10个碳; 并且每次出现时,每个R 3和R 4可以相同或不同,并且在每次出现时独立地为具有1至10个碳的脂族官能团或脂环族官能团 具有3至10个碳,“n”是0至4的整数,“m”是0至4的整数。该方法包括使式(I)的多环二羟基化合物进行聚合。
    • 10. 发明申请
    • Copolycarbonates, methods of manufacture, and uses thereof
    • 共聚碳酸酯,制造方法及其用途
    • US20070213498A1
    • 2007-09-13
    • US11372804
    • 2006-03-10
    • James Mahood
    • James Mahood
    • C08G64/00
    • C08G64/04C08G64/28
    • A copolycarbonate of the formula wherein 5 to 50 mole percent of the total number of R1 groups is derived from a monomer of formula (2) wherein each Rf is independently at each occurrence a halogen atom, a hydrocarbon group having 1 to 10 carbons, or a halogen substituted hydrocarbon group having 1 to 10 carbons, and n is 0 to 4; and 50 to 95 mole percent of the R1 groups are derived from a dihydroxy compound of formula HO—R5—OH, wherein at least 60% of the R5 groups are aromatic, and the dihydroxy compound of formula (3) is not a compound of formula (2), and wherein the copolycarbonate comprises at least 10% fewer carbonate linkages of formula (4) than would be theoretically obtained in a random copolymer made from the same ratio of the monomer of formula (2) and the dihydroxy compound of formula (3).
    • 一种下式的共聚碳酸酯,其中R 1〜5个基团总数的5〜50摩尔%来自式(2)的单体,其中每个R f独立地为 每个出现卤原子,碳原子数为1〜10的烃基或碳数为1〜10的卤素取代烃基,n为0〜4。 并且50至95摩尔%的R 1基团衍生自式HO-R 5 -OH的二羟基化合物,其中至少60%的R 0 > 5个基团是芳族的,并且式(3)的二羟基化合物不是式(2)的化合物,并且其中共聚碳酸酯包括比理论上更少的式(4)的碳酸酯键的至少10% 由与式(2)的单体和式(3)的二羟基化合物的比例相同的无规共聚物获得。