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1. 发明授权

US08344197B2 Production of para-xylene by the methylation of benzene and/or toluene 有权
标题翻译：通过苯和/或甲苯的甲基化生产对二甲苯
公开(公告)号：US08344197B2
公开(公告)日：2013-01-01
申请号：US12894778
申请日：2010-09-30
申请人： James R. Lattner , Mark P. Hagemeister , Jon Edmond Randolph Stanat , John Di-Yi Ou , Xiaobo Zheng , Lu Han
发明人： James R. Lattner , Mark P. Hagemeister , Jon Edmond Randolph Stanat , John Di-Yi Ou , Xiaobo Zheng , Lu Han
IPC分类号： C07C2/66
CPC分类号： C07C2/864 , C07C2529/40 , Y02P20/52 , C07C15/08
摘要： In a process for the production of para-xylene, methanol is preheated to a first temperature, an aromatic feedstock comprising toluene and/or benzene is preheated to a second temperature and the preheated methanol and aromatic feedstocks are fed to a reactor at a first methanol to aromatic feedstock molar ratio. The preheated aromatic feedstock is contacted with the preheated methanol under alkylation conditions in the reactor in the presence of a catalyst so that the methanol reacts with the aromatic feedstock to produce an effluent comprising para-xylene. During the reaction, a temperature is measured within the reactor and is compared with a predetermined optimal temperature. The methanol to aromatic feedstock molar ratio is then adjusted in a manner to reduce any difference between the measured and predetermined optimal temperatures in the reactor.
摘要翻译：在制备对二甲苯的方法中，将甲醇预热至第一温度，将包含甲苯和/或苯的芳族原料预热至第二温度，并将预热的甲醇和芳族原料以第一个甲醇与芳烃原料摩尔比。预热的芳族原料在催化剂存在下在反应器中在烷基化条件下与预热的甲醇接触，使得甲醇与芳族原料反应以产生包含对二甲苯的流出物。在反应期间，在反应器内测量温度并与预定的最佳温度进行比较。然后以降低反应器中测量的和预定的最佳温度之间的任何差异的方式调节甲醇与芳族原料的摩尔比。

2. 发明申请

US20110092755A1 Production of Para-Xylene by the Methylation of Benzene and/or Toluene 有权
标题翻译：通过苯和/或甲苯的甲基化生产对二甲苯
公开(公告)号：US20110092755A1
公开(公告)日：2011-04-21
申请号：US12894778
申请日：2010-09-30
申请人： James R. Lattner , Mark P. Hagemeister , Jon Edmond Randolph Stanat , John Di-Yi Ou , Xiaobo Zheng , Lu Han
发明人： James R. Lattner , Mark P. Hagemeister , Jon Edmond Randolph Stanat , John Di-Yi Ou , Xiaobo Zheng , Lu Han
IPC分类号： C07C15/08
CPC分类号： C07C2/864 , C07C2529/40 , Y02P20/52 , C07C15/08
摘要： In a process for the production of para-xylene, methanol is preheated to a first temperature, an aromatic feedstock comprising toluene and/or benzene is preheated to a second temperature and the preheated methanol and aromatic feedstocks are fed to a reactor at a first methanol to aromatic feedstock molar ratio. The preheated aromatic feedstock is contacted with the preheated methanol under alkylation conditions in the reactor in the presence of a catalyst so that the methanol reacts with the aromatic feedstock to produce an effluent comprising para-xylene. During the reaction, a temperature is measured within the reactor and is compared with a predetermined optimal temperature. The methanol to aromatic feedstock molar ratio is then adjusted in a manner to reduce any difference between the measured and predetermined optimal temperatures in the reactor.
摘要翻译：在制备对二甲苯的方法中，将甲醇预热至第一温度，将包含甲苯和/或苯的芳族原料预热至第二温度，并将预热的甲醇和芳族原料以第一个甲醇与芳烃原料摩尔比。预热的芳族原料在催化剂存在下在反应器中在烷基化条件下与预热的甲醇接触，使得甲醇与芳族原料反应以产生包含对二甲苯的流出物。在反应期间，在反应器内测量温度并与预定的最佳温度进行比较。然后以降低反应器中测量的和预定的最佳温度之间的任何差异的方式调节甲醇与芳族原料的摩尔比。

3. 发明授权

US08399727B2 Production of para-xylene by the methylation of benzene and/or toluene 有权
标题翻译：通过苯和/或甲苯的甲基化生产对二甲苯
公开(公告)号：US08399727B2
公开(公告)日：2013-03-19
申请号：US12899193
申请日：2010-10-06
申请人： James R. Lattner , Mark P. Hagemeister , Christopher Gordon Smalley , Jon Edmond Randolph Stanat , Timothy Paul Bender , Masaaki Sugita , Rathna P. Davuluri , Lu Han
发明人： James R. Lattner , Mark P. Hagemeister , Christopher Gordon Smalley , Jon Edmond Randolph Stanat , Timothy Paul Bender , Masaaki Sugita , Rathna P. Davuluri , Lu Han
IPC分类号： C07C2/66
CPC分类号： C07C2/864 , C07C2529/40 , Y02P20/52 , C07C15/08
摘要： In a process for the production of para-xylene, an aromatic feedstock comprising toluene and/or benzene is reacted with methanol under alkylation conditions in a reactor in the presence of a fluidized bed of solid catalyst particles to produce a vapor phase effluent comprising para-xylene, water, unreacted toluene and/or benzene and solid catalyst fines. The vapor phase effluent is contacted with a liquid hydrocarbon quench stream under conditions to condense a minor portion of the vapor phase effluent and produce a condensate which contains at least some of the catalyst fines and which is substantially free of an aqueous phase. The condensate containing said catalyst fines is then separated from the remainder of the vapor phase effluent.
摘要翻译：在制备对二甲苯的方法中，在固体催化剂颗粒的流化床的存在下，在反应器中，在烷基化条件下，将包含甲苯和/或苯的芳族原料与甲醇反应以产生包含对 - 二甲苯，水，未反应的甲苯和/或苯和固体催化剂细粉。气相流出物与液态烃淬火流接触，条件是冷凝少部分气相流出物并产生含有至少一些催化剂细粒并且基本上不含水相的冷凝物。然后将含有所述催化剂细粒的冷凝物与其余的气相流出物分离。

4. 发明申请

US20110092756A1 Production of Para-Xylene by the Methylation of Benzene and/or Toluene 有权
标题翻译：通过苯和/或甲苯的甲基化生产对二甲苯
公开(公告)号：US20110092756A1
公开(公告)日：2011-04-21
申请号：US12899193
申请日：2010-10-06
申请人： James R. Lattner , Mark P. Hagemeister , Christopher Gordon Smalley , Jon Edmond Randolph Stanat , Timothy Paul Bender , Masaaki Sugita , Rathna P. Davuluri , Lu Han
发明人： James R. Lattner , Mark P. Hagemeister , Christopher Gordon Smalley , Jon Edmond Randolph Stanat , Timothy Paul Bender , Masaaki Sugita , Rathna P. Davuluri , Lu Han
IPC分类号： C07C15/08
CPC分类号： C07C2/864 , C07C2529/40 , Y02P20/52 , C07C15/08
摘要： In a process for the production of para-xylene, an aromatic feedstock comprising toluene and/or benzene is reacted with methanol under alkylation conditions in a reactor in the presence of a fluidized bed of solid catalyst particles to produce a vapor phase effluent comprising para-xylene, water, unreacted toluene and/or benzene and solid catalyst fines. The vapor phase effluent is contacted with a liquid hydrocarbon quench stream under conditions to condense a minor portion of the vapor phase effluent and produce a condensate which contains at least some of the catalyst fines and which is substantially free of an aqueous phase. The condensate containing said catalyst fines is then separated from the remainder of the vapor phase effluent.
摘要翻译：在制备对二甲苯的方法中，在固体催化剂颗粒的流化床的存在下，在反应器中，在烷基化条件下，将包含甲苯和/或苯的芳族原料与甲醇反应以产生包含对 - 二甲苯，水，未反应的甲苯和/或苯和固体催化剂细粉。气相流出物与液态烃淬火流接触，条件是冷凝少部分气相流出物并产生含有至少一些催化剂细粒并且基本上不含水相的冷凝物。然后将含有所述催化剂细粒的冷凝物与其余的气相流出物分离。

5. 发明授权

US08815992B2 Tetracarboxylic ester plasticizers 有权
标题翻译：四羧酸酯增塑剂
公开(公告)号：US08815992B2
公开(公告)日：2014-08-26
申请号：US13085905
申请日：2011-04-13
申请人： Lisa Saunders Baugh , Enock Berluche , Karla Schall Colle , Manika Varma-Nair , Ramzi Yanni Saleh , Jon Edmond Randolph Stanat , Stephen Zushma , Victor DeFlorio
发明人： Lisa Saunders Baugh , Enock Berluche , Karla Schall Colle , Manika Varma-Nair , Ramzi Yanni Saleh , Jon Edmond Randolph Stanat , Stephen Zushma , Victor DeFlorio
IPC分类号： A61L15/62 , C08K5/12 , C07C69/34 , C07C69/74 , C08K5/11
CPC分类号： C07C69/34 , C07C69/74 , C07C2601/08 , C08K5/11 , C08K5/12
摘要： Tetraesters of a C4-C5 aliphatic tetracarboxylic acid and OXO-alcohols and plasticized compositions containing said tetraesters are provided.
摘要翻译：提供C4-C5脂族四羧酸和OXO-醇的四酯和含有所述四酯的增塑组合物。

6. 发明授权

US08568846B2 Process for making polyol neoalkylester plasticizers from neo acids 有权
标题翻译：从新酸制备多元醇新烷基酯增塑剂的方法
公开(公告)号：US08568846B2
公开(公告)日：2013-10-29
申请号：US12880586
申请日：2010-09-13
申请人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Jon Edmond Randolph Stanat , Karla Schall Colle , Francisco Manuel Benitez , Peter Stokes James , Allen David Godwin , Carl Robert Beck
发明人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Jon Edmond Randolph Stanat , Karla Schall Colle , Francisco Manuel Benitez , Peter Stokes James , Allen David Godwin , Carl Robert Beck
IPC分类号： B32B1/08 , C08K5/10
CPC分类号： C07C67/38 , C08K5/103 , Y10T428/139 , Y10T442/20 , C07C69/30
摘要： Provided are compositions, processes for making, and processes for using neoalkyl polyol esters and triglycerides as plasticizers. In one form, a neoalkylester triglyceride plasticizers can be produced by (i) drying a polyol feedstream; (ii) contacting in a reactor the dried polyol feedstream with a neoacid feedstream under effective temperature, pressure and time to form a neoalkylester plasticizer effluent stream, and (iii) purifying the neoalkylester plasticizer effluent stream to remove unreacted polyol and unreacted neoacid to form a neoalkylester plasticizer. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or pour point, glass transition temperature, low volatility, increased compatibility, increased hydrolytic stability, and excellent low temperature properties in a range of polymeric resins.
摘要翻译：提供了组合物，制备方法和使用新烷基多元醇酯和甘油三酸酯作为增塑剂的方法。在一种形式中，新烷基酯甘油三酯增塑剂可以通过（i）干燥多元醇进料流来制备; （ii）在有效温度，压力和时间下在干燥的多元醇原料流中与干燥的多元醇原料流接触以形成新的烷基酯增塑剂流出物流，和（iii）纯化新烷基酯增塑剂流出物流以除去未反应的多元醇和未反应的新酸，形成新烷基酯增塑剂。这种增塑剂可以是无邻苯二甲酸酯，并且提供突出的性能，包括合适的熔点或倾点，玻璃化转变温度，低挥发性，增加的相容性，增加的水解稳定性和在一系列聚合物树脂中的优异的低温性能。

7. 发明申请

US20110165355A1 Process For Making Polyol Neoalkylester Plasticizers From Neo Acids 有权
标题翻译：从新酸制备多元醇新烷基酯增塑剂的方法
公开(公告)号：US20110165355A1
公开(公告)日：2011-07-07
申请号：US12880586
申请日：2010-09-13
申请人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Jon Edmond Randolph Stanat , Karla Schall Colle , Francisco Manuel Benitez , Peter Stokes James , Allen David Godwin , Carl Robert Beck
发明人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Jon Edmond Randolph Stanat , Karla Schall Colle , Francisco Manuel Benitez , Peter Stokes James , Allen David Godwin , Carl Robert Beck
IPC分类号： B32B1/08 , C08K5/04 , C08K5/10 , C07C55/22 , B32B5/02 , C07C51/10
CPC分类号： C07C67/38 , C08K5/103 , Y10T428/139 , Y10T442/20 , C07C69/30
摘要： Provided are compositions, processes for making, and processes for using neoalkyl polyol esters and triglycerides as plasticizers. In one form, a neoalkylester triglyceride plasticizers can be produced by (i) drying a polyol feedstream; (ii) contacting in a reactor the dried polyol feedstream with a neoacid feedstream under effective temperature, pressure and time to form a neoalkylester plasticizer effluent stream, and (iii) purifying the neoalkylester plasticizer effluent stream to remove unreacted polyol and unreacted neoacid to form a neoalkylester plasticizer. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or pour point, glass transition temperature, low volatility, increased compatibility, increased hydrolytic stability, and excellent low temperature properties in a range of polymeric resins.
摘要翻译：提供了组合物，制备方法和使用新烷基多元醇酯和甘油三酸酯作为增塑剂的方法。在一种形式中，新烷基酯甘油三酯增塑剂可以通过（i）干燥多元醇进料流来制备; （ii）在有效温度，压力和时间下在干燥的多元醇原料流中与干燥的多元醇原料流接触以形成新的烷基酯增塑剂流出物流，和（iii）纯化新烷基酯增塑剂流出物流以除去未反应的多元醇和未反应的新酸，形成新烷基酯增塑剂。这种增塑剂可以是无邻苯二甲酸酯，并且提供突出的性能，包括合适的熔点或倾点，玻璃化转变温度，低挥发性，增加的相容性，增加的水解稳定性和在一系列聚合物树脂中的优异的低温性能。

8. 发明申请

US20080033217A1 Process for oxidizing alkylaromatic compounds 有权
标题翻译：氧化烷基芳族化合物的方法
公开(公告)号：US20080033217A1
公开(公告)日：2008-02-07
申请号：US11827952
申请日：2007-07-13
申请人： Jihad Mohammed Dakka , Doron Levin , John Scott Buchanan , Jon Edmond Randolph Stanat
发明人： Jihad Mohammed Dakka , Doron Levin , John Scott Buchanan , Jon Edmond Randolph Stanat
IPC分类号： C07C37/08
CPC分类号： C07C409/08 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/14 , C07C2601/14 , Y02P20/52 , C07C49/10 , C07C49/04 , C07C49/403 , C07C39/04
摘要： In a process for oxidizing alkylaromatic compounds to the corresponding hydroperoxide, an alkylaromatic compound of general formula (I): in which R1 and R2 each independently represents an alkyl group having from 1 to 4 carbon atoms, provided that R1 and R2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, said cyclic group being optionally substituted, and R3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group, is contacted with oxygen in the presence of an added catalyst comprising tert-butyl hydroperoxide and in the absence of any other catalyst, to produce a hydroperoxide of general formula (II): in which R1, R2 and R3 have the same meaning as in formula (I). The hydroperoxide may then be converted into a phenol and a ketone of the general formula R1COCH2R2 (III), in which R1 and R2 have the same meaning as in formula (I).
摘要翻译：在将烷基芳族化合物氧化成相应的氢过氧化物的方法中，通式（I）的烷基芳族化合物：其中R 1和R 2各自独立地表示具有如果R 1和R 2可以连接形成具有4至10个碳原子的环状基团，则所述环状基团任选被取代，R 3表示氢，一个或多个具有1至4个碳原子的烷基或环己基与氧在含叔丁基过氧化氢的加成催化剂存在下与氧接触，不存在任何其它催化剂，以产生通式（II）的氢过氧化物：其中R 1，R 2和R 3 3具有与式（I）中相同的含义。然后将氢过氧化物转化成通式为R 1，R 2，R 2，（III）的苯酚和酮，其中R ＆lt; SUP＆gt;和＆lt; 2＆gt;具有与式（I）中相同的含义。

9. 发明授权

US07326815B2 Selective oxidation of alkylbenzenes 失效
标题翻译：烷基苯的选择性氧化
公开(公告)号：US07326815B2
公开(公告)日：2008-02-05
申请号：US11318731
申请日：2005-12-27
申请人： Jihad Mohammed Dakka , Doron Levin , Jon Edmond Randolph Stanat
发明人： Jihad Mohammed Dakka , Doron Levin , Jon Edmond Randolph Stanat
IPC分类号： C07C45/53 , C07C37/08
CPC分类号： C07C409/08 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/10 , C07C49/08 , C07C49/10 , C07C39/04
摘要： The present invention relates to a process for producing phenol and a ketone of general formula R1COCH2R3 (I), in which R1 and R2 each independently represent an alkyl group having from 1 to 4 carbon atoms, said process comprising: (a) providing an alkylbenzene feedstock comprising (i) an alkylbenzene of general formula (II) in which R1 and R2 have the same meaning as in formula (I) and (ii) at least one structural isomer of said alkylbenzene of formula (II) in an amount of at least 0.7% of the weight of alkylbenzene of formula (II), (b) submitting the alkylbenzene feedstock to oxidation conditions in the presence of oxygen and in the presence of a cyclic imide of formula (III): in which X represents a carbonyl (CO) group or a sulfonyl (SO2) group, n is 0, 1, 2, 3 or 4, R3 is one or several groups selected from a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an amino group and R4 is a hydrogen atom, an alkaline metal cation or an alkaline earth metal cation, or in the presence of N,N′,N″-trihydroxyisocyanuric acid (THICA), to produce a product comprising a hydroperoxide of general formula (IV) in which R1 and R2 have the same meaning as in formula (I), and (c) converting the hydroperoxide of formula (IV) into phenol and a ketone of formula (I).
摘要翻译：本发明涉及一种制备通式为R 1，R 2，R 3，R 3（I）的苯酚和酮的方法，其中R 各个独立地表示具有1至4个碳原子的烷基，所述方法包括：（a）提供烷基苯原料，其包含（i）烷基苯，其中R 1和R 2 2的通式（II）具有与式（I）中相同的含义和（ii）所述烷基苯的至少一种结构异构体（II）的量为至少0.7％的式（II）的烷基苯的重量，（b）将烷基苯原料在氧气存在下并在式（III）的环状酰亚胺存在下，：其中X表示羰基（CO）基团或磺酰基（SO 2 H 2）基团，n为0,1,2,3或4，R 3为一个或选自氢原子，卤素原子，烷基，烷氧基，氨基的数个基团并且R 4是氢原子，碱金属阳离子或碱土金属阳离子，或在N，N'，N“ - 三羟基异氰尿酸（THICA）的存在下，产生包含通式（IV）的氢过氧化物的产物，其中R 1和R 2具有与式（I）中相同的含义，和（c）将氢过氧化物式（IV）转化成苯酚和式（I）的酮。

10. 发明授权

US6022929A Amorphous olefin polymers, copolymers, methods of preparation and derivatives thereof 失效
标题翻译：无定形烯烃聚合物，共聚物，制备方法及其衍生物
公开(公告)号：US6022929A
公开(公告)日：2000-02-08
申请号：US121631
申请日：1998-07-23
申请人： Frank Joung-Yei Chen , Jon Edmond Randolph Stanat , Cezar S. Baula
发明人： Frank Joung-Yei Chen , Jon Edmond Randolph Stanat , Cezar S. Baula
IPC分类号： C08L23/02 , C08F8/00 , C08F210/00 , C08F210/08 , C08L23/00 , C08F210/14
CPC分类号： C08F210/08 , C08F210/00
摘要： The present invention includes related methods and uses, including composition comprising the polymer derived from a monomer having the formula:H.sub.2 C.dbd.CHR; (1)and optionally at least one monomer selected from the group consisting of monomers having the formula:R.sup.1 HC.dbd.CHR.sup.2 ; and (2)H.sub.2 C.dbd.CR.sup.2 R.sup.3 (3)wherein R is a hydrocarbon or substituted hydrocarbon having from 2 to 22 carbon atoms, and R.sup.1, R.sup.2 and R.sup.3 are the same or different hydrocarbons or substituted hydrocarbons having 1 to 22 carbon atoms. R is preferably an ethyl group (--CH.sub.2 CH.sub.3) and R.sup.1, R.sup.2 and R.sup.3 are preferably methyl groups (--CH.sub.3).
摘要翻译：本发明包括相关的方法和用途，包括包含衍生自具有下列通式的单体的聚合物的组合物：H 2 C = CHR;（1）和任选的至少一种选自具有下式的单体的单体：R1HC = CHR2; 和（2）H 2 C = CR 2 R 3（3）其中R是具有2至22个碳原子的烃或取代烃，R 1，R 2和R 3是相同或不同的烃或具有1至22个碳原子的取代的烃。 R优选为乙基（-CH 2 CH 3），R 1，R 2和R 3优选为甲基（-CH 3）。

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