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1. 发明授权

US06444734B1 Silica-filled tire tread stocks having reduced hysteresis 有权
标题翻译：二氧化硅填充轮胎胎面料具有减小的滞后
公开(公告)号：US06444734B1
公开(公告)日：2002-09-03
申请号：US09723968
申请日：2000-11-28
申请人： William L. Hergenrother , William M. Cole , James Oziomek
发明人： William L. Hergenrother , William M. Cole , James Oziomek
IPC分类号： C08K515
CPC分类号： C08K3/36 , B60C1/0016 , C08K5/151 , C08L21/00
摘要： A silica-filled, vulcanized elastomeric compound comprises 100 parts by weight of an elastomer; from about 5 to about 100 parts by weight of a reinforcing filler per 100 parts of elastomer, wherein the reinforcing fillers are selected from the group consisting of carbon black and silica filler; from 0 to about 20 percent by weight of a silane, based upon the weight of the silica filler; a cure agent; from about 0 to about 20 parts by weight of a processing aid selected from the group consisting of fatty acid esters of hydrogenated and non-hydrogenated C5 and C6 sugars; from about 0 to about 20 parts by weight of a processing aid selected from the group consisting of polyoxyethylene derivatives of fatty acid esters of hydrogenated and non-hydrogenated C5 and C6 sugars; from about 0 to about 40 parts by weight of an additional filler other than silica or carbon black, with the provisos that at least one of the processing aids or additional fillers are present; that if the processing aid is sorbitan monooleate, then at least one of the polyoxyethylene derivatives or additional fillers is also present and, that the minimal amount for each processing aid and additional filler, if present, is about one part by weight. A process for the preparation of silica filled vulcanizable elastomers is provided as well as pneumatic tires employing tread stock comprising the novel vulcanizable elastomers.
摘要翻译：二氧化硅填充的硫化弹性体混合物包含100重量份的弹性体; 每100份弹性体约5至约100重量份的增强填料，其中所述增强填料选自炭黑和二氧化硅填料; 0至约20重量％的硅烷，基于二氧化硅填料的重量; 治愈剂; 约0至约20重量份的选自氢化和非氢化C5和C6糖的脂肪酸酯的加工助剂; 约0至约20重量份的选自氢化和非氢化C5和C6糖的脂肪酸酯的聚氧乙烯衍生物的加工助剂; 约0至约40重量份的除二氧化硅或炭黑之外的另外的填料，条件是存在至少一种加工助剂或另外的填料; 如果加工助剂是脱水山梨糖醇单油酸酯，那么还存在至少一种聚氧乙烯衍生物或另外的填料，并且每种加工助剂和另外的填料（如果存在的话）的最小量为约1重量份。提供了制备二氧化硅填充的可硫化弹性体的方法，以及使用包含新型可硫化弹性体的胎面胶料的充气轮胎。

2. 发明授权

US06228908B1 Diene polymers and copolymers incorporating partial coupling and terminals formed from hydrocarboxysilane compounds 有权
标题翻译：二烯聚合物和共聚物结合部分偶联和由烃基甲硅烷化合物形成的末端
公开(公告)号：US06228908B1
公开(公告)日：2001-05-08
申请号：US09229025
申请日：1999-01-12
申请人： Hideo Takeichi , Daniel F. Graves , Sunil B. Sarkar , David F. Lawson , William L. Hergenrother , William M. Cole , James Oziomek
发明人： Hideo Takeichi , Daniel F. Graves , Sunil B. Sarkar , David F. Lawson , William L. Hergenrother , William M. Cole , James Oziomek
IPC分类号： C08K515
CPC分类号： C08L7/00 , B60C1/0016 , C08C19/44 , C08K3/36 , C08K5/151 , C08K5/1535 , C08L9/00 , C08L9/06 , C08L15/00 , C08L19/006 , Y02T10/862 , C08L21/00 , C08L2666/08
摘要： Diene polymers or copolymers having improved balance between raw polymer viscosity and mixed compound viscosity, useful in tire tread compositions having highly balanced wet traction, rolling resistance, and traction in ice and snow, and fracture properties in the cured and white carbon reinforced states are provided. These diene polymers or copolymers comprise a mixture of diene polymer or copolymer chains containing carbon-tin bonds in the main polymer or copolymer chains and diene polymer or copolymer chains containing terminals derived from hydrocarboxysilane compounds. The diene polymer or copolymers are prepared by first coupling a portion of the living diene polymer or copolymer chains obtained by anionic polymerization using a tin polyhalide coupling agent and then terminating the remaining living diene polymer or copolymer chains using hydrocarboxysilane compounds. The resultant diene polymers or copolymers have improved balance between raw polymer viscosity and mixed compound viscosity when compounded with silica and/or carbon black and cured compositions are useful in tire tread having highly balanced wet traction, rolling resistance, and traction in ice and snow. The polymers can be utilized to form elastomer compositions for tire treads having balanced properties of reduced rolling resistance and wet traction and handling or balanced properties of wet traction and handling and traction in snow and ice.
摘要翻译：本发明提供了在具有高均衡湿牵引力，滚动阻力和冰雪牵引力的轮胎胎面组合物中有用的原始聚合物粘度和混合化合物粘度之间的改进平衡的二烯聚合物或共聚物，以及固化和白色碳增强状态下的断裂性能。这些二烯聚合物或共聚物包含在主聚合物或共聚物链中含有碳 - 锡键的二烯聚合物或共聚物链的混合物，以及含有衍生自烃基甲硅烷化合物的末端的二烯聚合物或共聚物链。二烯聚合物或共聚物通过首先将通过使用多卤化锡偶合剂的阴离子聚合得到的活性二烯聚合物或共聚物链的一部分，然后使用烃基甲硅烷化合物终止剩余的活性二烯聚合物或共聚物链。所得到的二烯聚合物或共聚物在与二氧化硅和/或炭黑混合时与原料聚合物粘度和混合化合物粘度之间具有改善的平衡，并且固化的组合物可用于具有高均衡的湿牵引力，滚动阻力和在冰雪中的牵引力的轮胎胎面。聚合物可用于形成用于轮胎胎面的弹性体组合物，其具有降低的滚动阻力和湿牵引力和处理性能的平衡性能或湿牵引和处理以及雪和冰中牵引的平衡性能。

3. 发明授权

US06180710B2 Addition of salts to improve the interaction of silica with rubber 有权
标题翻译：添加盐以改善二氧化硅与橡胶的相互作用
公开(公告)号：US06180710B2
公开(公告)日：2001-01-30
申请号：US09247375
申请日：1999-02-10
申请人： William L. Hergenrother , James Oziomek , William M. Cole
发明人： William L. Hergenrother , James Oziomek , William M. Cole
IPC分类号： C08K300
CPC分类号： B60C1/0016 , B60C1/00 , C08K3/36 , Y02T10/862 , C08L21/00
摘要： Incorporation of neutral water soluble inorganic salts into a precipitated silica improves the filler dispersion in a compounded rubber, reduces rolling resistance (hysteresis), and improves processability. These properties are achieved without loss of the expected reinforcement effect due to the substitution of inorganic salt for SiO2 in the silica. The properties are seen when a variety of silanes and processing aids are added to the silica.
摘要翻译：将中性水溶性无机盐掺入沉淀二氧化硅改善了复合橡胶中的填料分散，降低了滚动阻力（滞后），并提高了加工性能。由于在二氧化硅中用无机盐代替SiO 2，这些性能实现而不会损失预期的增强效果。当将多种硅烷和加工助剂添加到二氧化硅中时，可以看到性能。

4. 发明授权

US5872176A Addition of salts to improve the interaction of silica with rubber 失效
标题翻译：添加盐以改善二氧化硅与橡胶的相互作用
公开(公告)号：US5872176A
公开(公告)日：1999-02-16
申请号：US893867
申请日：1997-07-11
申请人： William L. Hergenrother , James Oziomek , William M. Cole
发明人： William L. Hergenrother , James Oziomek , William M. Cole
IPC分类号： B60C1/00 , C08K3/36 , C08L21/00 , C01B33/18
CPC分类号： B60C1/0016 , B60C1/00 , C08K3/36
摘要： Incorporation of neutral water soluble inorganic salts into a precipitated silica improves the filler dispersion in a compounded rubber, reduces rolling resistance (hysteresis), and improves processability. These properties are achieved without loss of the expected reinforcement effect due to the substitution of inorganic salt for SiO.sub.2 in the silica. The properties are seen when a variety of silanes and processing aids are added to the silica.
摘要翻译：将中性水溶性无机盐掺入沉淀二氧化硅改善了复合橡胶中的填料分散，降低了滚动阻力（滞后），并提高了加工性能。由于在二氧化硅中用无机盐代替SiO 2，这些性能实现而不会损失预期的增强效果。当将多种硅烷和加工助剂添加到二氧化硅中时，可以看到性能。

5. 发明授权

US06252007B1 Elastomers having a reduced hysteresis via interaction of polymer with silica surfaces 失效
标题翻译：弹性体通过聚合物与二氧化硅表面的相互作用具有减小的滞后
公开(公告)号：US06252007B1
公开(公告)日：2001-06-26
申请号：US08891569
申请日：1997-07-11
申请人： James Oziomek , William L. Hergenrother
发明人： James Oziomek , William L. Hergenrother
IPC分类号： C08C1925
CPC分类号： C08F36/04 , C08C19/44 , C08K3/36 , Y02T10/862 , C08F4/48 , C08L19/006 , C08L15/00
摘要： The reduction of hysteresis in a silica-filled, vulcanized elastomeric compound is produced by mixing diene monomer and optionally monovinyl aromatic monomer with an initiator and a coordinator; effecting polymerization conditions; terminating polymerization with a terminator containing an organo-tin group to form a tin-coupled diene elastomer; compounding the tin-coupled diene elastomer with an amorphous silica filler and a vulcanization agent; and, effecting vulcanization. A pneumatic tire tread stock incorporating the vulcanized elastomer compound exhibits decreased rolling resistance in the tire.
摘要翻译：通过将二烯单体和任选的单乙烯基芳族单体与引发剂和协调剂混合来制备二氧化硅填充的硫化弹性体化合物中的滞后的降低; 影响聚合条件; 用包含有机锡基团的终止剂终止聚合以形成锡偶合的二烯弹性体; 将锡偶合二烯弹性体与无定形二氧化硅填料和硫化剂混合; 并进行硫化。包含硫化弹性体复合材料的充气轮胎胎面涂料在轮胎中表现出降低的滚动阻力。

6. 发明授权

US06384117B1 Processability of silica-filled rubber stocks 失效
公开(公告)号：US06384117B1
公开(公告)日：2002-05-07
申请号：US09203438
申请日：1998-12-01
申请人： William L. Hergenrother , Ashley S. Hilton , William M. Cole , James Oziomek
发明人： William L. Hergenrother , Ashley S. Hilton , William M. Cole , James Oziomek
IPC分类号： C08C524
CPC分类号： C08K5/5419 , B60C1/0016 , C08K3/36 , C08K5/0008 , C08K5/103 , C08K5/151 , C08K5/1535 , C08K9/12 , Y10T152/10855 , C08L21/00
摘要： The present invention provides silica-filled, vulcanized elastomeric compounds comprising an elastomer mixed with at least a silica filler, a processing aid, and a curing agent, and processes for the preparation of the same. Generally, the present invention provides processing aids which effectively reduce or replace the amount (i.e., about 10 percent by weight based upon the silica filler) of the processing aid bis[3-triethyoxysilyl)propyl]tetrasulfide (“Si69”) used in the production of silica-filled rubber stocks. These new processing aids include alkyl alkoxysilanes, fatty acid esters of hydrogenated and non-hydrogenated sugars and the polyoxyethylene derivatives thereof, and combinations thereof, with or without various non-reinforcing fillers such as mineral fillers. The processing aids do not hinder the physical properties of the compounds and have been found to be excellent substitutes for Si69. The processing aids may be supported on the silica filler or any of the other fillers employed in the composition for improved handling, safety and performance. Processes for the preparation of the silica filled vulcanizable elastomers are provided as well as pneumatic tires employing tread stock comprising the novel vulcanizable elastomers.

7. 发明授权

US5866650A Composition of cyclic amine-initiated elastomers and amorphous silica and process for the production thereof 失效
标题翻译：环胺引发的弹性体和无定形二氧化硅的组成及其制备方法
公开(公告)号：US5866650A
公开(公告)日：1999-02-02
申请号：US893868
申请日：1997-07-11
申请人： David F. Lawson , Hideo Takeichi , William L. Hergenrother , Thomas J. Lynch , James Oziomek
发明人： David F. Lawson , Hideo Takeichi , William L. Hergenrother , Thomas J. Lynch , James Oziomek
IPC分类号： B60C1/00 , C08C19/44 , C08F4/48 , C08F36/04 , C08K3/36 , C08L21/00 , C08C19/22
CPC分类号： C08F36/04 , C08C19/44 , C08K3/36 , Y10S152/905
摘要： The reduction of hysteresis in a silica-filled, vulcanized elastomeric compound is produced by mixing diene monomer and optionally monovinyl aromatic monomer with a lithium amine initiator and, optionally, a modifier; effecting polymerization conditions; terminating polymerization with an amino group producing terminator to form an amine functionalized diene elastomer; compounding the amine functionalized diene elastomer with an amorphous silica filler and a vulcanization agent; and, effecting vulcanization. A pneumatic tire tread stock incorporating the vulcanized elastomer compound exhibits improved reduced hysteresis, or highly balanced wet traction, rolling resistance, snow/ice traction, and mechanical strength when compounded with silica filler and vulcanized, in the tire.
摘要翻译：通过将二烯单体和任选的单乙烯基芳族单体与锂胺引发剂和任选的改性剂混合来制备二氧化硅填充的硫化弹性体化合物中的滞后的降低; 影响聚合条件; 用氨基产生终止剂终止聚合以形成胺官能化二烯弹性体; 将胺官能化二烯弹性体与无定形二氧化硅填料和硫化剂混合; 并进行硫化。包含硫化弹性体复合材料的充气轮胎胎面料在轮胎中与二氧化硅填料混合时，具有改善的滞后性，或者高度平衡的湿牵引力，滚动阻力，雪/冰牵引力和机械强度。

8. 发明授权

US5317057A (Halomethyl vinyl arene)-modified elastomers and compositions containing them having reduced hysteresis properties 失效
标题翻译：（卤代甲基乙烯基芳烃）改性的弹性体和含有它们的具有降低的滞后性质的组合物
公开(公告)号：US5317057A
公开(公告)日：1994-05-31
申请号：US998204
申请日：1992-12-30
申请人： James E. Hall , William L. Hergenrother , James Oziomek
发明人： James E. Hall , William L. Hergenrother , James Oziomek
IPC分类号： B60C1/00 , C08C19/44 , C08L9/06 , C08L9/00 , C08L11/00
CPC分类号： C08C19/44 , B60C1/0016
摘要： A (halomethyl arene)-modified elastomer is made by reacting a lithium terminated elastomer intermediate with the halogen atoms of a halomethyl vinyl arene compound. A road-contacting tread component for a pneumatic tire is fabricated from vulcanized elastomer made by vulcanizing an elastomer composition of a (halomethyl arene)-modified elastomer, a carbon black reinforcing agent, and a sulfur-based vulcanizing system. A process for making a (halomethyl arene)-modified elastomer includes polymerizing at least one diene monomer with a lithium-containing initiator, capping the lithium terminated elastomer by reaction with a halomethyl arene compound, and recovering the modified elastomer.
摘要翻译：通过使锂封端的弹性体中间体与卤代甲基乙烯基芳烃化合物的卤素原子反应制备（卤代甲基芳烃） - 改性的弹性体。用于充气轮胎的道路接触胎面部件由通过硫化（卤代甲基芳烃）改性弹性体，炭黑增强剂和硫基硫化体系的弹性体组合物制成的硫化弹性体制成。制备（卤代甲基芳烃）改性弹性体的方法包括使含有锂的引发剂使至少一种二烯单体聚合，通过与卤代甲基芳烃化合物的反应来封端锂封端的弹性体，并回收改性弹性体。

9. 发明授权

US5244966A 1,3,2-dioxastannolane-modified elastomers and compositions containing them having reduced hysteresis properties 失效
标题翻译： 1,3,2-二氧杂环丁烷醇改性的弹性体和含有它们的具有降低的滞后性质的组合物
公开(公告)号：US5244966A
公开(公告)日：1993-09-14
申请号：US814550
申请日：1991-12-30
申请人： William L. Hergenrother , James Oziomek
发明人： William L. Hergenrother , James Oziomek
IPC分类号： C08C19/44 , C08F8/42
CPC分类号： C08C19/44 , C08F8/42
摘要： Modification of lithium-terminated elastomer intermediates by reaction under anionic conditions with 1,3,2-dioxastannolanes provides tin-containing elastomers with improved hysteresis properties. In specific examples, modification of a lithium-terminated styrene-butadiene rubber with a dioxastannolane derived from reaction of dibutyl tin(IV)oxide with an alkyl-substituted 1,3-pentane provides tin-modified SBRs with lowered tan delta properties. Such modified elastomers are useful in making tread portions of pneumatic tires.
摘要翻译：通过在阴离子条件下与1,3,2-二恶烷烷醇反应来改性锂封端的弹性体中间体提供具有改进的磁滞特性的含锡弹性体。在具体实例中，由二丁基锡（IV）氧化物与烷基取代的1,3-戊烷的反应衍生的具有二恶烷烷醇的锂封端苯乙烯 - 丁二烯橡胶的改性提供具有降低的tanδ特性的锡改性SBR。这种改性弹性体可用于制造充气轮胎的胎面部分。

10. 发明授权

US06790889B2 Processability of silica-filled rubber stocks 失效
标题翻译：二氧化硅填充橡胶原料的加工性能
公开(公告)号：US06790889B2
公开(公告)日：2004-09-14
申请号：US10095604
申请日：2002-03-11
申请人： William L. Hergenrother , Ashley S. Hilton , William M. Cole , James Oziomek
发明人： William L. Hergenrother , Ashley S. Hilton , William M. Cole , James Oziomek
IPC分类号： C08C524
CPC分类号： C08K5/5419 , B60C1/0016 , C08K3/36 , C08K5/0008 , C08K5/103 , C08K5/151 , C08K5/1535 , C08K9/12 , Y10T152/10855 , C08L21/00
摘要： The present invention provides silica-filled, vulcanized elastomeric compounds comprising an elastomer mixed with at least a silica filler, a processing aid, and a curing agent, and processes for the preparation of the same. Generally, the present invention provides processing aids which effectively reduce or replace the amount (i.e., about 10 percent by weight based upon the silica filler) of the processing aid bis[3-triethyoxysilyl)propyl]tetrasulfide (“Si69”) used in the production of silica-filled rubber stocks. These new processing aids include alkyl alkoxysilanes, fatty acid esters of hydrogenated and non-hydrogenated sugars and the polyoxyethylene derivatives thereof, and combinations thereof, with or without various non-reinforcing fillers such as mineral fillers. The processing aids do not hinder the physical properties of the compounds and have been found to be excellent substitutes for Si69. The processing aids may be supported on the silica filler or any of the other fillers employed in the composition for improved handling, safety and performance. Processes for the preparation of the silica filled vulcanizable elastomers are provided as well as pneumatic tires employing tread stock comprising the novel vulcanizable elastomers.
摘要翻译：本发明提供二氧化硅填充的硫化弹性体化合物，其包含与至少二氧化硅填料混合的弹性体，加工助剂和固化剂，及其制备方法。通常，本发明提供加工助剂，其有效地减少或替代加工助剂双[3-三乙氧基甲硅烷基]丙基]四硫化物（“Si69”）的量（即，基于二氧化硅填料的约10重量％）生产二氧化硅填充橡胶原料。这些新的加工助剂包括烷基烷氧基硅烷，氢化和非氢化的糖的脂肪酸酯及其聚氧乙烯衍生物，以及它们的组合，与或不同的各种非增强填料如矿物填料。加工助剂不妨碍化合物的物理性能，并且已被发现是Si69的优良替代物。加工助剂可以负载在二氧化硅填料或用于组合物中的任何其它填料以提高处理，安全性和性能。提供用于制备二氧化硅填充的可硫化弹性体的方法以及使用包含新型可硫化弹性体的胎面胶料的充气轮胎。

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