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1. 发明授权

US4031161A Process for producing mixture containing 4-(4'-methyl-4'-hydroxyamyl)-.DELTA..sup.3 -cyclohexene carboxaldehyde 失效
标题翻译：制备含有4-（4 {40-甲基-4 {40-羟基戊基） - {66 {hu 3 {b-环己烯甲醛
公开(公告)号：US4031161A
公开(公告)日：1977-06-21
申请号：US694391
申请日：1976-06-09
申请人： James Milton Sanders , William I. Taylor , Ira D. Hill , John J. Kryschuk
发明人： James Milton Sanders , William I. Taylor , Ira D. Hill , John J. Kryschuk
IPC分类号： C07C45/69 , C07C47/46 , C11B9/00 , C07C45/00
CPC分类号： C11B9/0034 , C07C403/02 , C07C45/69 , C07C2101/16
摘要： A process is described for reacting "myrac aldehyde" having the structure: ##STR1## (which structure is representative of a mixture of two compounds, one where the carboxaldehyde is in the "4" position and the other wherein the carboxaldehyde is in the "5" position) with an acid hydrating agent at a temperature of from 0.degree. up to 120.degree. C, to produce a mixture containing a major proportion of 4-(4'-methyl-4'-hydroxyamyl)-.DELTA..sup.3 -cyclohexene carboxaldehyde and a minor proportion of 3-(4'-methyl-4'-hydroxyamyl)-.DELTA..sup.3 -cyclohexene carboxaldehyde (otherwise termed "Lyral") having the structure: ##STR2## and a minor proportion of 3-(4'-methyl-4'-hydroxyamyl)-.DELTA..sup.3 -cyclohexene carboxaldehyde having the structure: ##STR3## which mixture possesses a sweet, lilac-lily aromatic odor and isolating a mixture of the two carboxaldehydes. The products produced by the aforementioned process are useful in various aspects of perfumery.
摘要翻译：描述了具有以下结构的“烟酰醛”的反应方法：（该结构代表两种化合物的混合物，其中甲醛处于“4”位，另一种是甲醛在“ 5“位置）与酸性水合剂在0℃至120℃的温度下反应，生成含有主要比例的4-（4'-甲基-4'-羟基戊基）-Δt3 3-环己烯甲醛的混合物和较小比例的具有以下结构的3-（4'-甲基-4'-羟基戊基）-TATA-环己烯甲醛（另外称为“Lyral”）和少量的3-（4'-甲基 -4'-羟基戊基） - 具有以下结构的DELTA 3-环己烯甲醛：该混合物具有甜味的丁香芳香气味，并分离出两种羧醛的混合物。通过上述方法生产的产品在香料的各个方面都是有用的。

2. 发明授权

US4159987A Process for preparing substituted cyclic acetals of oxyacetaldehydes and said cyclic acetals 失效
标题翻译：制备取代的环氧缩醛缩醛和所述环状缩醛的方法
公开(公告)号：US4159987A
公开(公告)日：1979-07-03
申请号：US902390
申请日：1978-05-03
申请人： Mark A. Sprecker , John J. Kryschuk , John B. Hall
发明人： Mark A. Sprecker , John J. Kryschuk , John B. Hall
IPC分类号： C07C43/315 , C07C41/00 , C07C41/48 , C07C43/303 , C07C45/00 , C07C45/51 , C07C47/198 , C07C47/277 , C07C67/00 , C07D317/22 , C11B9/00 , C07D317/10
CPC分类号： C11B9/0015 , C07C45/59 , C07C47/277
摘要： A process is described for the preparation of substituted oxyacetaldehydes and cyclic acetals thereof according to the reaction sequence: ##STR1## wherein R.sub.1 and R.sub.2, taken together form a lower alkylene group; wherein R.sub.3 is alkyl, alkenyl or alkadienyl and X is halogen selected from the group consisting of chlorine and bromine, the reaction (i) being carried out (1) using a "phase transfer agent" and (2) in a two phase system.
摘要翻译：根据反应顺序描述了制备取代的氧乙醛和其环状缩醛的方法：其中R1和R2一起形成（ⅰ）+ 低级亚烷基; 其中R 3是烷基，烯基或链二烯基，X是选自氯和溴的卤素，反应（i）使用“相转移剂”和（2）在两相体系中进行（1）。

3. 发明授权

US4248787A Process for preparing substituted cyclic acetals of oxyacetaldehydes and said cyclic acetals 失效
标题翻译：制备取代的环氧缩醛缩醛和所述环状缩醛的方法
公开(公告)号：US4248787A
公开(公告)日：1981-02-03
申请号：US968009
申请日：1978-12-08
申请人： Mark A. Sprecker , John J. Kryschuk , John B. Hall
发明人： Mark A. Sprecker , John J. Kryschuk , John B. Hall
IPC分类号： C07C41/48 , C07C43/303 , C11B9/00 , C07D317/10 , C07D319/06 , C07D321/06
CPC分类号： C11B9/0015 , C07C41/48 , C07C43/303 , C07C45/59
摘要： A process is described for the preparation of substituted oxyacetaldehydes and cyclic acetals thereof according to the reaction sequence: ##STR1## wherein R.sub.1 and R.sub.2, taken together form a lower alkylene group; wherein R.sub.3 is alkyl, alkenyl or alkadienyl and X is halogen selected from the group consisting of chlorine and bromine, the reaction (i) being carried out (1) using a "phase transfer agent" and (2) in a two phase system.
摘要翻译：描述了根据反应顺序制备取代的氧乙醛及其缩醛的方法：其中R 1和R 2一起形成低级亚烷基（ⅰ）其中R 1和R 2一起形成低级亚烷基 ; 其中R 3是烷基，烯基或链二烯基，X是选自氯和溴的卤素，反应（i）使用“相转移剂”和（2）在两相体系中进行（1）。

4. 发明授权

US4205186A Process for preparing substituted oxyacetaldehydes and acetals thereof 失效
标题翻译：制备取代的氧乙醛及其缩醛的方法
公开(公告)号：US4205186A
公开(公告)日：1980-05-27
申请号：US3883
申请日：1979-01-16
申请人： Mark A. Sprecker , John J. Kryschuk , John B. Hall
发明人： Mark A. Sprecker , John J. Kryschuk , John B. Hall
IPC分类号： C07C41/48 , C07C43/315 , C07C45/51 , C07C47/277 , C11B9/00 , C07C43/30
CPC分类号： C11B9/0015 , C07C41/48 , C07C43/315 , C07C45/515 , C07C47/277
摘要： A process is described for the preparation of substituted oxyacetaldehydes and acetals thereof according to the reaction sequence: ##STR1## wherein R.sub.1 and R.sub.2 are each lower alkyl or R.sub.1 and R.sub.2, taken together form a lower alkylene group; wherein R.sub.3 is alkyl, alkenyl or alkadienyl and X is halogen selected from the group consisting of chlorine and bromine, the reaction (i) being carried out (1) using a "phase transfer agent" and (2) in a two phase system.
摘要翻译：描述根据反应顺序制备取代的氧乙醛及其缩醛的方法：其中R 1和R 2各自为低级烷基或R 1和R 2，取代一起形成低级亚烷基; 其中R 3是烷基，烯基或链二烯基，X是选自氯和溴的卤素，反应（i）使用“相转移剂”和（2）在两相体系中进行（1）。

5. 发明授权

US4124644A Process for preparing substituted oxyacetaldehydes and acetals thereof 失效
标题翻译：制备取代的氧乙醛及其缩醛的方法
公开(公告)号：US4124644A
公开(公告)日：1978-11-07
申请号：US868726
申请日：1978-01-11
申请人： Mark A. Sprecker , John J. Kryschuk , John B. Hall
发明人： Mark A. Sprecker , John J. Kryschuk , John B. Hall
IPC分类号： C07C43/315 , C07C41/00 , C07C41/48 , C07C43/303 , C07C45/00 , C07C45/51 , C07C47/198 , C07C47/277 , C07C67/00 , C07D317/22 , C11B9/00 , C07C47/06
CPC分类号： C11B9/0015 , C07C45/59 , C07C47/277
摘要： A process is described for the preparation of substituted oxyacetaldehydes and acetals thereof according to the reaction sequence: ##STR1## WHEREIN R.sub.1 and R.sub.2 are each lower alkyl or R.sub.1 and R.sub.2, taken together form a lower alkylene group; wherein R.sub.3 is alkyl, alkenyl or alkadienyl and X is halogen selected from the group consisting of chlorine and bromine, the reaction (i) being carried out (1) using a "phase transfer agent" and (2) in a two phase system.
摘要翻译：描述根据反应顺序制备取代的氧乙醛及其缩醛的方法：其中R1和R2分别为低级烷基或R1和R2，取代为（ⅰ）+ 一起形成低级亚烷基; 其中R 3是烷基，烯基或链二烯基，X是选自氯和溴的卤素，反应（i）使用“相转移剂”和（2）在两相体系中进行（1）。

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