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1. 发明授权

US07939572B2 Aqueous dispersion of polymeric particles 有权
标题翻译：聚合物颗粒的水分散体
公开(公告)号：US07939572B2
公开(公告)日：2011-05-10
申请号：US11210207
申请日：2005-08-23
申请人： James Keith Bardman , Robert Mitchell Blankenship , John Michael Friel
发明人： James Keith Bardman , Robert Mitchell Blankenship , John Michael Friel
IPC分类号： C08F2/16
CPC分类号： C08F2/18 , C08F2/22
摘要： An aqueous dispersion of polymeric particles, the particles including: from 5% to 80% by weight, based on the weight of the polymeric particles, of a first polymer including at least one copolymerized ethylenically unsaturated monomer; and, substantially encapsulating the first polymer, from 20% to 95% by weight, based on the weight of the polymeric particles, of a second polymer including at least one copolymerized ethylenically unsaturated monomer, the second polymer having a Tg of from −40° C. to 30° C., wherein at least 90 weight % of the second polymer is formed by polymerization at a temperature of from 5° C. to 65° C. is provided. The invention also relates to a process for forming the aqueous dispersion of polymeric particles and an aqueous coating composition including the aqueous dispersion of polymer particles, a method for providing a coated substrate, and the coated substrate so provided.
摘要翻译：聚合物颗粒的水分散体，所述颗粒包括：基于聚合物颗粒重量的5重量％至80重量％的包含至少一种共聚烯键式不饱和单体的第一聚合物; 和基本上包封第一聚合物的基于聚合物颗粒的重量的20重量％至95重量％的包含至少一种共聚的烯属不饱和单体的第二聚合物，第二聚合物的Tg为-40℃ 至30℃，其中通过在5℃至65℃的温度下聚合形成至少90重量％的第二聚合物。本发明还涉及形成聚合物颗粒的水性分散体的方法和包含聚合物颗粒的水性分散体的水性涂料组合物，提供涂布的基材的方法和如此提供的涂布的基材。

2. 发明申请

US20100113646A1 Aqueous dispersion of polymeric particles 有权
标题翻译：聚合物颗粒的水分散体
公开(公告)号：US20100113646A1
公开(公告)日：2010-05-06
申请号：US12655662
申请日：2010-01-05
申请人： James Keith Bardman , Robert Mitchell Blankenship , John Michael Friel
发明人： James Keith Bardman , Robert Mitchell Blankenship , John Michael Friel
IPC分类号： C08L67/06
CPC分类号： C08F265/06 , C08J3/05 , C08L51/003 , C09D151/003 , Y10T428/2987 , C08L2666/02
摘要： An aqueous dispersion of polymeric particles and process for forming thereof is provided. The particles comprise a first polymer comprising, when dry, at least one void; and, substantially encapsulating the first polymer, at least one second polymer comprising, as polymerized units, at least one ethylenically unsaturated monomer.
摘要翻译：提供聚合物颗粒的水分散体及其形成方法。颗粒包含第一聚合物，当干燥时包含至少一个空隙; 和基本上包封第一聚合物的至少一种第二聚合物，其包含作为聚合单元的至少一种烯属不饱和单体。

3. 发明授权

US07691942B2 Aqueous dispersion of polymeric particles 有权
公开(公告)号：US07691942B2
公开(公告)日：2010-04-06
申请号：US11507341
申请日：2006-08-21
申请人： James Keith Bardman , Robert Mitchell Blankenship , John Michael Friel
发明人： James Keith Bardman , Robert Mitchell Blankenship , John Michael Friel
IPC分类号： C08F2/22 , C08F2/16 , C08L35/02 , C08L33/12 , C08L33/10 , C08L33/08 , C08L31/02
CPC分类号： C08F265/06 , C08J3/05 , C08L51/003 , C09D151/003 , Y10T428/2987 , C08L2666/02
摘要： An aqueous dispersion of polymeric particles and process for forming thereof is provided. The particles comprise a first polymer comprising, when dry, at least one void; and, substantially encapsulating the first polymer, at least one second polymer comprising, as polymerized units, at least one ethylenically unsaturated monomer.

4. 发明授权

US08227542B2 Aqueous dispersion of polymeric particles 有权
标题翻译：聚合物颗粒的水分散体
公开(公告)号：US08227542B2
公开(公告)日：2012-07-24
申请号：US12655662
申请日：2010-01-05
申请人： James Keith Bardman , Robert Mitchell Blankenship , John Michael Friel
发明人： James Keith Bardman , Robert Mitchell Blankenship , John Michael Friel
IPC分类号： C08F2/16 , C08L83/00 , B32B5/16
CPC分类号： C08F265/06 , C08J3/05 , C08L51/003 , C09D151/003 , Y10T428/2987 , C08L2666/02
摘要： An aqueous dispersion of polymeric particles and process for forming thereof is provided. The particles comprise a first polymer comprising, when dry, at least one void; and, substantially encapsulating the first polymer, at least one second polymer comprising, as polymerized units, at least one ethylenically unsaturated monomer.
摘要翻译：提供聚合物颗粒的水分散体及其形成方法。颗粒包含第一聚合物，当干燥时包含至少一个空隙; 和基本上包封第一聚合物的至少一种第二聚合物，其包含作为聚合单元的至少一种烯属不饱和单体。

5. 发明授权

US07629414B2 Aqueous dispersion of polymeric particles 有权
标题翻译：聚合物颗粒的水分散体
公开(公告)号：US07629414B2
公开(公告)日：2009-12-08
申请号：US11507301
申请日：2006-08-21
申请人： James Keith Bardman , Robert Mitchell Blankenship , John Michael Friel
发明人： James Keith Bardman , Robert Mitchell Blankenship , John Michael Friel
IPC分类号： C08F2/22 , C08F2/16 , C08L35/02 , C08L33/12 , C08L33/10 , C08L33/08 , C08L31/02
CPC分类号： C09B67/009 , C08F2/22 , C08F265/00 , C08F265/04 , C08F265/06 , C08F291/00 , C08L51/003 , C09D151/003 , C08L2666/02
摘要： An aqueous dispersion of polymeric particles and process for forming thereof is provided. The particles comprise a first polymer comprising, as polymerized units, at least one monoethylenically unsaturated monomer and at least one multi-ethylenically unsaturated monomer and when dry, at least one void; and at least one second polymer, substantially encapsulating the first polymer, comprising, as polymerized units, at least one ethylenically unsaturated monomer.
摘要翻译：提供聚合物颗粒的水分散体及其形成方法。颗粒包含第一聚合物，其包含作为聚合单元的至少一种单烯属不饱和单体和至少一种多烯属不饱和单体，当干燥时，至少一个空隙; 和至少一种基本上包封第一聚合物的第二聚合物，其包含作为聚合单元的至少一种烯属不饱和单体。

6. 发明授权

US06921432B2 Stable mixtures containing extender pigments 有权
标题翻译：含有增量颜料的稳定混合物
公开(公告)号：US06921432B2
公开(公告)日：2005-07-26
申请号：US10214509
申请日：2002-08-08
申请人： Edwin Hugh Nungesser , Jerry William Washel , John Michael Friel
发明人： Edwin Hugh Nungesser , Jerry William Washel , John Michael Friel
IPC分类号： C09D7/12 , C09D17/00 , C09D201/00 , C09D5/00 , C09C1/00 , C09C3/00 , C09D7/00
CPC分类号： C09D17/004
摘要： A number of stable mixtures are disclosed containing specific combinations and levels of extender pigments and thickeners. These stable mixtures may be employed, inter alia, as a mixture in a method of making paints using prepaints or as a conventional component in a coating, such as a paint, or other end-use where opacifying pigments are employed.
摘要翻译：公开了许多稳定的混合物，其包含特定组合和增量剂颜料和增稠剂的含量。这些稳定的混合物尤其可以在使用前涂料或作为涂料中的常规组分的涂料或使用不透明颜料的其它最终用途的方法中作为混合物使用。

7. 发明授权

US06812278B2 Method of improving viscosity stability upon addition of an aqueous tinting composition 失效
标题翻译：添加水性着色组合物时提高粘度稳定性的方法
公开(公告)号：US06812278B2
公开(公告)日：2004-11-02
申请号：US10025707
申请日：2001-12-26
申请人： Jerome Michael Harris , Henry Jude Eichman , Homayoun Jamasbi , Dennis Paul Lorah , John Michael Friel
发明人： Jerome Michael Harris , Henry Jude Eichman , Homayoun Jamasbi , Dennis Paul Lorah , John Michael Friel
IPC分类号： C08J300
CPC分类号： C09B67/0066 , C09B67/0063 , C09D7/43 , C09D7/45 , C09D7/80 , C09D17/001
摘要： An aqueous tinting composition containing a pigment and a select dispersing resin is disclosed. In addition, a method of improving the viscosity stability of an aqueous coating composition upon the addition of the aqueous tinting composition containing a pigment and a select dispersing resin is disclosed.
摘要翻译：公开了含有颜料和选择性分散树脂的水性着色组合物。此外，公开了在添加含有颜料和选择分散树脂的水性着色组合物时改善水性涂料组合物的粘度稳定性的方法。

8. 发明授权

US06930141B2 Aqueous polymer blend composition 失效
标题翻译：水性聚合物共混组合物
公开(公告)号：US06930141B2
公开(公告)日：2005-08-16
申请号：US10410068
申请日：2003-04-09
申请人： Matthew Stewart Gebhart , Deborah Gay Fradkin , Bonnie Elizabeth Baker , John Michael Friel , Steven Scott Edwards , Caren Ann Puschak , Cindy Eckert , Ralph Craig Even
发明人： Matthew Stewart Gebhart , Deborah Gay Fradkin , Bonnie Elizabeth Baker , John Michael Friel , Steven Scott Edwards , Caren Ann Puschak , Cindy Eckert , Ralph Craig Even
IPC分类号： C08L27/04 , C08L33/02 , C08L33/06 , C08L53/02 , C09D133/04 , C09D133/06 , C08L33/04
CPC分类号： C08L33/06 , C08L27/04 , C08L33/02 , C08L53/02 , C09D133/04 , C09D133/06 , C08L33/00 , C08L2666/06 , C08L2666/04
摘要： An aqueous polymer blend composition including a predominant amount of soft polymer particles and a minor amount of hard polymer particles is provided. The soft polymer particles contain, as copolymerized units, 70 to 99.7% by weight monoethylenically unsaturated (meth)acrylic monomer and from 0.3 to 10% by weight monoethylenically unsaturated acid monomer, based on weight of soft polymer particles. The soft polymer particles are made by a select process including redox polymerization or polymerization in the presence of excess unreacted monomer. The aqueous polymer blend composition is useful for preparing dry coatings having improved dirt pickup resistance and acceptable scrub resistance. A method is provided for preparing a dry coating from the aqueous polymer blend composition.
摘要翻译：提供了包含主要量的软聚合物颗粒和少量硬聚合物颗粒的含水聚合物共混物组合物。作为共聚单元，软质聚合物颗粒含有基于软聚合物颗粒重量的70-99.7重量％单烯属不饱和（甲基）丙烯酸单体和0.3-10重量％单烯属不饱和酸单体。软聚合物颗粒通过选择的方法制备，包括在过量未反应单体的存在下进行氧化还原聚合或聚合。水性聚合物共混物组合物可用于制备具有改进的耐污垢吸附性和可接受的耐擦洗性的干燥涂层。提供了一种从聚合物共混混合物组合物制备干燥涂层的方法。

9. 发明授权

US06689824B2 Prepaints and method of preparing road-marking paints from prepaints 失效
标题翻译：制备涂料前处理剂和制备路标油漆的方法
公开(公告)号：US06689824B2
公开(公告)日：2004-02-10
申请号：US09785637
申请日：2001-02-16
申请人： John Michael Friel , John William Hook, III , Bernhard Helmut Lieser , Jerry William Washel , Dennis Paul Lorah , Donald Craig Schall , Ann Robertson Hermes
发明人： John Michael Friel , John William Hook, III , Bernhard Helmut Lieser , Jerry William Washel , Dennis Paul Lorah , Donald Craig Schall , Ann Robertson Hermes
IPC分类号： F21V722
CPC分类号： B01F13/1055 , B01F13/1063 , B01F15/00123 , B01F15/00305 , B44D2/002 , B44D3/003 , B44D3/08 , C09D5/004 , C09D7/40 , C09D7/80 , C09D17/008
摘要： Sets of prepaints useful for forming a road-marking paint line are provided. Also provided are methods which permit the person applying the road-marking paint to vary the properties of the road-marking paint at the application point to suit the ambient conditions, including temperature, humidity, traffic flow and the like.
摘要翻译：提供了一些用于形成道路标线漆线的预涂料。还提供了允许使用道路标线漆的人改变应用点处的道路标线漆的特性以适应包括温度，湿度，交通流量等在内的环境条件的方法。

10. 发明授权

US06613832B2 Premixes and method of preparing adhesives and caulks from premixes 失效
公开(公告)号：US06613832B2
公开(公告)日：2003-09-02
申请号：US09785389
申请日：2001-02-16
申请人： John Michael Friel , John William Hook, III , Jerry William Washel , Dennis Paul Lorah , James Alexander Costanzo
发明人： John Michael Friel , John William Hook, III , Jerry William Washel , Dennis Paul Lorah , James Alexander Costanzo
IPC分类号： C09C136
CPC分类号： C09J201/00 , B01F13/1055 , B01F13/1063 , B01F15/00123 , B01F15/00305 , B01F2215/005 , B44D2/002 , B44D3/003 , B44D3/08 , C09D7/40 , C09D7/80 , C09D17/008
摘要： Sets of fluid premixes useful for adhesives and caulks are provided. Also provided are methods of providing adhesive lines and a caulk lines using the sets of premixes. Further provided are ranges of adhesives and caulks based on the adhesive and caulk lines. Utilizing these methods the manufacturer, seller, or user can to adjust the adhesive or caulk at the point of manufacture, sale, or use to suit the processing and end-use conditions, in addition to the other benefits offered by delayed product differentiation.

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