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    • 4. 发明申请
    • Deposition methods using heteroleptic precursors
    • 使用杂音前体的沉积方法
    • US20060046521A1
    • 2006-03-02
    • US10932149
    • 2004-09-01
    • Brian VaartstraDonald WestmorelandEugene MarshStefan Uhlenbrock
    • Brian VaartstraDonald WestmorelandEugene MarshStefan Uhlenbrock
    • H01L21/31
    • C23C16/45553C23C16/34C23C16/405H01L21/0228H01L21/3141
    • An ALD method includes exposing a substrate to a first precursor including a plurality of different ligands, chemisorbing a precursor monolayer on the substrate, and reacting a second precursor with the precursor monolayer to yield a product monolayer. A surface reactive ligand exhibits a chemisorption affinity that exceeds the chemisorption affinity exhibited by a gas reactive ligand. Another deposition method includes exposing a substrate to a precursor containing an amino and/or imino ligand and a halide ligand and depositing a layer. The precursor exhibits a volatility that exceeds the volatility with a halide ligand taking the place of each amino and/or imino ligand. The precursor exhibits a thermal stability that exceeds the thermal stability with an amino and/or imino ligand taking the place of each halide ligand. The layer may exhibit less halogen content than with a halide ligand taking the place of each amino and/or imino ligand.
    • ALD方法包括将底物暴露于包含多个不同配体的第一前体,化学吸附底物上的前体单层,以及使第二前体与前体单层反应以产生产物单层。 表面反应性配体表现出超过气体反应性配体显示的化学吸附亲和力的化学吸附亲和力。 另一种沉积方法包括将底物暴露于含有氨基和/或亚氨基配体和卤化物配体的前体并沉积一层。 前体表现出挥发性,其挥发性用卤化物配体取代每个氨基和/或亚氨基配体。 前体表现出超过热稳定性的热稳定性,氨基和/或亚氨基配体取代每个卤化物配体。 该层可以表现出比卤化物配体更少的卤素含量,代替每个氨基和/或亚氨基配体。
    • 10. 发明授权
    • Deposition methods using heteroleptic precursors
    • 使用杂音前体的沉积方法
    • US07250367B2
    • 2007-07-31
    • US10932149
    • 2004-09-01
    • Brian A. VaartstraDonald WestmorelandEugene P. MarshStefan Uhlenbrock
    • Brian A. VaartstraDonald WestmorelandEugene P. MarshStefan Uhlenbrock
    • H01L21/44
    • C23C16/45553C23C16/34C23C16/405H01L21/0228H01L21/3141
    • An ALD method includes exposing a substrate to a first precursor including a plurality of different ligands, chemisorbing a precursor monolayer on the substrate, and reacting a second precursor with the precursor monolayer to yield a product monolayer. A surface reactive ligand exhibits a chemisorption affinity that exceeds the chemisorption affinity exhibited by a gas reactive ligand. Another deposition method includes exposing a substrate to a precursor containing an amino and/or imino ligand and a halide ligand and depositing a layer. The precursor exhibits a volatility that exceeds the volatility with a halide ligand taking the place of each amino and/or imino ligand. The precursor exhibits a thermal stability that exceeds the thermal stability with an amino and/or imino ligand taking the place of each halide ligand. The layer may exhibit less halogen content than with a halide ligand taking the place of each amino and/or imino ligand.
    • ALD方法包括将底物暴露于包含多个不同配体的第一前体,化学吸附底物上的前体单层,以及使第二前体与前体单层反应以产生产物单层。 表面反应性配体表现出超过气体反应性配体显示的化学吸附亲和力的化学吸附亲和力。 另一种沉积方法包括将底物暴露于含有氨基和/或亚氨基配体和卤化物配体的前体并沉积一层。 前体表现出挥发性,其挥发性用卤化物配体取代每个氨基和/或亚氨基配体。 前体表现出超过热稳定性的热稳定性,氨基和/或亚氨基配体取代每个卤化物配体。 该层可以表现出比卤化物配体更少的卤素含量,代替每个氨基和/或亚氨基配体。