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1. 发明授权

US06339131B1 Synthesis of poly (arylene ether)-poly(organosiloxane) copolymers 失效
标题翻译：聚（亚芳基醚） - 聚（有机硅氧烷）共聚物的合成
公开(公告)号：US06339131B1
公开(公告)日：2002-01-15
申请号：US09455070
申请日：1999-12-06
申请人： James A. Cella , Juraj Liska , Victoria L. Ulery , Gary W. Yeager , Susan Adams Nye , Hua Guo , Navjot Singh
发明人： James A. Cella , Juraj Liska , Victoria L. Ulery , Gary W. Yeager , Susan Adams Nye , Hua Guo , Navjot Singh
IPC分类号： C08F28312
CPC分类号： C08G77/46 , C08G65/485 , C08L71/126 , C08L83/00
摘要： A method comprising (a) synthesis of a poly(arylene ether) having the structure (1) wherein m is an integer having an average value in the range from about 3 to about 300; (b) solution functionalization of polymer (1) to form functionalized poly(arylene ether) having the structure (2) wherein X is a reactive functional group selected from the group consisting of anhydride, hydroxyl, epoxy, carboxyl, —R1OH, R1CO2R2, —R1CH2═CH2, or vinyl, wherein R1 is a primary or secondary divalent alkyl or haloalky group having from 1 to 20 carbons, or an aryl group and R2 is a primary or secondary alkyl group having from 1 to 10 carbons; and Q4 is hydrogen, X, or a mixture thereof; (c) reaction of functionalized poly(arylene ether) (2) with a poly(organosiloxane) having structure (3): wherein x is zero or one and Y is a functional group reactive with X, selected from the group consisting of —OH, —CH2═CH2, epoxy, amino, carboxy, —C(O)CH2OH, or hydrogen, to form a poly(arylene ether)-poly(siloxane) copolymer, wherein the functionalization is in solution, and copolymer synthesis and isolation are effected by first solution and then melt copolymerization.
摘要翻译：一种方法，其包括（a）具有结构（1）的聚（亚芳基醚）的合成，其中m是平均值在约3至约300范围内的整数;（b）聚合物（1）的溶液官能化至具有结构（2）的官能化聚（亚芳基醚），其中X是选自酸酐，羟基，环氧基，羧基，-R 1 OH，R 1 CO 2 R 2，-R 1 CH 2 = CH 2或乙烯基的反应性官能团，其中R 1为碳原子数为1〜20的伯或仲二价烷基或卤代烷基，或芳基，R 2为碳原子数1〜10的伯或仲烷基。和Q 4是氢，X或它们的混合物;（c）官能化聚（亚芳基醚）（2）与具有结构（3）的聚（有机硅氧烷）的反应：其中x为0或1，Y为官能团与选自-OH，-CH 2 = CH 2，环氧基，氨基，羧基，-C（O）CH 2 OH或氢的X反应，形成聚（亚芳基醚） - 聚（硅氧烷）共聚物，其中官能化在溶液中，共聚物合成和分离通过第一溶液进行，然后进行熔融共聚。

2. 发明授权

US06780959B2 Compositions comprising functionalized polyphenylene ether resins 有权
标题翻译：包含官能化聚苯醚树脂的组合物
公开(公告)号：US06780959B2
公开(公告)日：2004-08-24
申请号：US10250096
申请日：2003-06-03
申请人： Adrianus J. F. M. Braat , Herbert Shin-I Chao , Hua Guo , Juraj Liska , Gary William Yeager
发明人： Adrianus J. F. M. Braat , Herbert Shin-I Chao , Hua Guo , Juraj Liska , Gary William Yeager
IPC分类号： C08G6500
CPC分类号： C08G65/485 , C08L71/02 , C08L2666/02
摘要： The invention relates to a polyphenylene ether resin containing residual aliphatic unsaturation as well as composites, blends, and articles made from the polyphenylene ether resin containing residual aliphatic unsaturation. Also included are reaction products between the polyphenylene ether resin containing residual aliphatic unsaturation and other resins and unsaturated resin formulations, e.g., thermosetting polyesters, acrylics, bismaleiimides, silicones, and allylics, and thermoplastics such as polyolefins, styrenics, rubbers, etc.
摘要翻译：本发明涉及含有残留的脂族不饱和基团的聚苯醚树脂以及由含有残余的脂肪族不饱和键的聚苯醚树脂制成的复合材料，共混物和制品。还包括含有残留的脂肪族不饱和基团的聚苯醚树脂和其它树脂和不饱和树脂配方如热固性聚酯，丙烯酸树脂，双马来酰亚胺，硅酮和烯丙基化物之类的反应产物，以及热塑性塑料如聚烯烃，苯乙烯，橡胶等。

3. 发明授权

US06384176B1 Composition and process for the manufacture of functionalized polyphenylene ether resins 有权
标题翻译：用于制造官能化聚苯醚树脂的组合物和方法
公开(公告)号：US06384176B1
公开(公告)日：2002-05-07
申请号：US09613112
申请日：2000-07-10
申请人： Adrianus J. F. M. Braat , Herbert Shin-I Chao , Hua Guo , Juraj Liska , Gary William Yeager
发明人： Adrianus J. F. M. Braat , Herbert Shin-I Chao , Hua Guo , Juraj Liska , Gary William Yeager
IPC分类号： C08G6300
CPC分类号： C08G65/485 , C08L71/02 , C08L2666/02
摘要： The invention relates to a novel process for the manufacture of polyphenylene ether resin containing residual aliphatic unsaturation. The invention also relates to the polyphenylene ether resin containing residual aliphatic unsaturation as well as composites, blends, and articles made from the polyphenylene ether resin containing residual aliphatic unsaturation. Also included are reaction products between the polyphenylene ether resin containing residual aliphatic unsaturation and other resins and unsaturated resin formulations, e.g., thermosetting polyesters, acrylics, and thermoplastics such as polyolefins.
摘要翻译：本发明涉及一种制备含有残余脂族不饱和度的聚苯醚树脂的新方法。本发明还涉及含有残留的脂肪族不饱和基团的聚苯醚树脂以及由含有残留的脂族不饱和基团的聚苯醚树脂制成的复合材料，共混物和制品。还包括含有残留的脂族不饱和基团的聚苯醚树脂和其它树脂和不饱和树脂配制剂如热固性聚酯，丙烯酸树脂和热塑性塑料如聚烯烃之间的反应产物。

4. 发明授权

US06469124B2 Functionalized polyphenylene ether resins and curable compositions comprising them 有权
公开(公告)号：US06469124B2
公开(公告)日：2002-10-22
申请号：US09683352
申请日：2001-12-18
申请人： Adrianus J.F.M. Braat , Herbert Shin-I Chao , Hua Guo , Juraj Liska , Gary William Yeager
发明人： Adrianus J.F.M. Braat , Herbert Shin-I Chao , Hua Guo , Juraj Liska , Gary William Yeager
IPC分类号： C08G6300
CPC分类号： C08G65/485 , C08L71/02 , C08L2666/02
摘要： The invention relates to a polyphenylene ether resin containing residual aliphatic unsaturation as well as composites, blends, and articles made from the polyphenylene ether resin containing residual aliphatic unsaturation. Also included are reaction products between the polyphenylene ether resin containing residual aliphatic unsaturation and other resins and unsaturated resin formulations, e.g., thermosetting polyesters, acrylics, bismaleiimides, silicones, and allylics, and thermoplastics such as polyolefins, styrenics, rubbers, etc.

5. 发明授权

US06627708B2 Compositions comprising functionalized polyphenylene ether resins 有权
公开(公告)号：US06627708B2
公开(公告)日：2003-09-30
申请号：US10063152
申请日：2002-03-26
申请人： Adrianus J. F. M. Braat , Herbert Shin-I Chao , Hua Guo , Juraj Liska , Gary William Yeager
发明人： Adrianus J. F. M. Braat , Herbert Shin-I Chao , Hua Guo , Juraj Liska , Gary William Yeager
IPC分类号： C08G6300
CPC分类号： C08G65/485 , C08L71/02 , C08L2666/02
摘要： The invention relates to a polyphenylene ether resin containing residual aliphatic unsaturation as well as composites, blends, and articles made from the polyphenylene ether resin containing residual aliphatic unsaturation. Also included are reaction products between the polyphenylene ether resin containing residual aliphatic unsaturation and other resins and unsaturated resin formulations, e.g., thermosetting polyesters, acrylics, bismaleiimides, silicones, and allylics, and thermoplastics such as polyolefins, styrenics, rubbers, etc.

6. 发明授权

US06552105B2 Poly (arylene ether) composition, method for the preparation thereof, and articles derived therefrom 失效
标题翻译：聚（亚芳基醚）组合物，其制备方法和由其衍生的制品
公开(公告)号：US06552105B2
公开(公告)日：2003-04-22
申请号：US09782584
申请日：2001-02-13
申请人： Adrianus J. F. M. Braat , Amy Rene Freshour , Hua Guo , Rene de Jongh , Juraj Liska
发明人： Adrianus J. F. M. Braat , Amy Rene Freshour , Hua Guo , Rene de Jongh , Juraj Liska
IPC分类号： C08L9500
CPC分类号： C08L71/123 , C08L95/005 , C08L71/00
摘要： A composition comprises a bitumen and a poly(arylene ether) having an intrinsic viscosity less than 0.40 deciliters per gram. The composition exhibits high softening and flow temperatures, and high hardness.
摘要翻译：组合物包含沥青和特性粘度小于0.40分升/克的聚（亚芳基醚）。该组合物显示出高的软化和流动温度，以及高的硬度。

7. 发明授权

US06448327B1 Preparation process and properties of styrene butadiene random copolymer/poly(arylene ether) compositions 失效
标题翻译：苯乙烯丁二烯无规共聚物/聚（亚芳基醚）组合物的制备方法和性能
公开(公告)号：US06448327B1
公开(公告)日：2002-09-10
申请号：US09644473
申请日：2000-08-23
申请人： Adrianus J. F. M. Braat , Benny David , Hua Guo , Juraj Liska , Herb Chao , Kenneth P. Zarnoch
发明人： Adrianus J. F. M. Braat , Benny David , Hua Guo , Juraj Liska , Herb Chao , Kenneth P. Zarnoch
IPC分类号： C08L906
CPC分类号： C08L9/06 , C08L9/00 , C08L71/12 , C08L71/123 , C08L2205/02 , C08L2666/14 , C08L2666/24 , C08L2666/04
摘要： An elastomer-thermoplastic composition comprising styrene butadiene random copolymer and poly(arylene ether) resin and methods of making the composition are disclosed.
摘要翻译：公开了包含苯乙烯丁二烯无规共聚物和聚（亚芳基醚）树脂的弹性体 - 热塑性组合物及其制备方法。

8. 发明授权

US06455663B1 Process for the manufacture of low molecular weight polyphenylene ether resins through redistribution 失效
标题翻译：通过再分配制造低分子量聚苯醚树脂的方法
公开(公告)号：US06455663B1
公开(公告)日：2002-09-24
申请号：US09943122
申请日：2001-08-30
申请人： Adrianus J. F. M. Braat , Hugo G. E. Engelbrecht , Juraj Liska
发明人： Adrianus J. F. M. Braat , Hugo G. E. Engelbrecht , Juraj Liska
IPC分类号： C08G6538
CPC分类号： C08G65/44
摘要： The invention relates to a novel process for the manufacture of functionalized polyphenylene ether resins through redistribution with a functionalized phenolic compound in the polyphenylene ether resin polymerization reaction solution without the addition of an added redistribution catalyst or promoter. The invention also relates to the functionalized polyphenylene ether resin made by the process as well as blends and articles containing the functionalized polyphenylene ether resin made by the process.
摘要翻译：本发明涉及通过在聚苯醚树脂聚合反应溶液中与官能化酚类化合物重新分配来制造官能化聚苯醚树脂的新方法，而不添加添加的再分布催化剂或助催化剂。本发明还涉及通过该方法制备的官能化聚苯醚树脂以及含有通过该方法制备的官能化聚苯醚树脂的共混物和制品。

9. 发明授权

US06306978B1 Capping of polyphenylene ether resin 失效
标题翻译：聚苯醚树脂封端
公开(公告)号：US06306978B1
公开(公告)日：2001-10-23
申请号：US09245255
申请日：1999-02-05
申请人： Adrianus J. F. M. Braat , Adrie Landa , Juraj Liska
发明人： Adrianus J. F. M. Braat , Adrie Landa , Juraj Liska
IPC分类号： C08G6548
CPC分类号： C08G65/485
摘要： The invention relates to methods of capping poly(phenylene ether) resin having an intrinsic viscosity between 0.05 and 0.35 dl/g. More particularly, the methods comprise capping a poly(phenylene ether) resin having an intrinsic viscosity between 0.05 and 0.35 dl/g in a solvent to produce a capped poly(phenylene ether) resin having an intrinsic viscosity between 0.05 and 0.35 dl/g and isolating the capped poly(phenylene ether) resin by removal of the solvent, preferably in a process other than precipitation. The invention also relates to the capped poly(phenylene ether) resin having an intrinsic viscosity between 0.05 and 0.35 dl/g.
摘要翻译：本发明涉及特征粘度在0.05和0.35dl / g之间的聚（苯醚）树脂的封端方法。更具体地说，该方法包括在特性粘度为0.05至0.35dl / g之间的特性粘度为0.05至0.35dl / g的聚苯醚树脂中，在特性粘度为0.05至0.35dl / g的范围内制备封端的聚苯醚树脂，通过除去溶剂来分离封端的聚（苯醚）树脂，优选以除沉淀之外的方法。本发明还涉及特性粘度在0.05和0.35dl / g之间的封端聚（苯醚）树脂。

10. 发明授权

US5880221A Redistribution of polyphenylene ethers and polyphenylene ethers with novel structure 失效
标题翻译：具有新颖结构的聚苯醚和聚苯醚的再分布
公开(公告)号：US5880221A
公开(公告)日：1999-03-09
申请号：US800694
申请日：1997-02-14
申请人： Juraj Liska , Hubertus Adrianus Maria van Aert , Gert De Wit
发明人： Juraj Liska , Hubertus Adrianus Maria van Aert , Gert De Wit
IPC分类号： C08G65/48 , C08G65/38
CPC分类号： C08G65/485
摘要： The present invention deals with the distribution of polyphenylene ethers 1. by reacting the polyphenylene ether in solution with a phenolic compound, wherein special phenolic compounds are used. The redistribution reaction can be performed in toluene or in toluene/alcohol blends. The reaction can be run in the presence or the absence of a catalyst. By using a process for the redistribution of polyphenylene ethers by reacting the polyphenylene ether in solution with a phenolic compound, wherein the polyphenylene ether is reacted with a phenolic compound with formula 3 wherein the phenolic rings are disubstituted with methyl groups or ethyl groups in the ortho positions and the group X is separated from the phenolic ring through at least two carbon atoms and the phenolic compound has a molecular weight of not more than 400 g/mol, preferably not more than 300 g/mol and the redistribution is performed in a mixture of toluene and methanol with 1-30 volume % of methanol or in toluene in the presence of a phase transfer catalyst such as tri (C8-C1O alkyl) methyl ammonium chloride as a promoter; and a diphenoquinone, preferably of 3,3',5,5'-tetramethyl-4,4'-diphenoquinone is used as a catalyst and the molar concentration of the phenolic compound is chosen between 0.9 to 1.1 times the molar quantity of monomeric units in the polyphenylene ether in the reaction solution, more than 90% of the phenolic compound can be incorporated in the polyphenylene.
摘要翻译：本发明涉及聚苯醚1.通过溶液中的聚苯醚与酚类化合物的反应，其中使用了特殊的酚类化合物。再分布反应可在甲苯或甲苯/醇混合物中进行。反应可以在催化剂存在或不存在下进行。通过使用溶液中的聚苯醚与酚类化合物反应来重新分配聚苯醚的方法，其中聚苯醚与式3的酚类化合物反应，其中酚环在邻位上被甲基或乙基二取代位置，并且基团X通过至少两个碳原子与酚环分离，酚类化合物的分子量不超过400g / mol，优选不大于300g / mol，并且重新分布在混合物中进行的甲苯和甲醇与1-30体积％的甲醇或在甲苯中，在相转移催化剂如三（C 8 -C 10烷基）甲基氯化铵作为助催化剂的存在下反应; 并且使用优选3,3'，5,5'-四甲基-4,4'-联苯醌的联苯醌作为催化剂，并且酚类化合物的摩尔浓度选自单体单元的摩尔量的0.9至1.1倍在反应溶液中的聚苯醚中，可以将多于90％的酚类化合物加入到聚亚苯基中。

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