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    • 3. 发明申请
    • PROCESS FOR PREPARING TRICHLOROSILANE
    • 制备三氯硅烷的方法
    • US20140017155A1
    • 2014-01-16
    • US13884326
    • 2011-10-13
    • Ekkehard MühHartwig RaulederBernd Nowitzki
    • Ekkehard MühHartwig RaulederBernd Nowitzki
    • C01B33/107
    • C01B33/10763C01B33/1071C01B33/10773
    • The present invention relates to a process for preparing trichlorosilane and optionally, if required, HCDS and OCTS, by a) in a first step, allowing silicon tetrachloride and silicon to react at a temperature of >800 to 1450° C., b) in a step two, cooling the product stream (PS) thus obtained from step one to obtain a product stream (PG2), c) optionally, in a step three, removing STC and HCDS from the product stream (PG2) to obtain, as a residue or bottom product, a product mixture (PG3), d) optionally, in a step four, removing OCTS from the product stream PG3 from step three, to obtain, as a residue or bottom product, a product mixture (PG4), e) in a step five, reacting the product stream (PG2) originating from step two or the product mixture (PG3) originating from step three or the product mixture (PG4) originating from step four, or a mixture of product streams PG2 and PG3 or a mixture of product streams PG2 and PG4 with hydrogen chloride to obtain a product stream (PHS), and f) in a subsequent step six, removing trichlorosilane from a product stream (PHS) thus obtained, and discharging the remaining STC-containing bottoms or recycling them as a reactant component into step one of the process.
    • 本发明涉及一种制备三氯硅烷的方法,以及任选地,如果需要,HCDS和OCTS,通过a)在第一步中,使四氯化硅和硅在> 800至1450℃的温度下反应,b)在 步骤二,冷却从步骤1获得的产物流(PS)以获得产物流(PG2),c)任选地,在步骤3中,从产物流(PG2)中除去STC和HCDS,以获得作为 残留物或底部产物,产物混合物(PG3),d)任选地,在步骤4中,从步骤3从产物流PG3中除去OCTS,得到作为残余物或底部产物的产物混合物(PG4),e )在步骤5中使来自步骤2的产物流(PG2)或源自步骤3的产物混合物(PG3)或源自步骤4的产物混合物(PG4)或产物流PG2和PG3的混合物或 产物流PG2和PG4与氯化氢的混合物以获得产物流(PHS),和f)in 随后的步骤6,从如此获得的产物流(PHS)中除去三氯硅烷,并排出剩余的含STC的底部物质或将其作为反应物组分再循环到该方法的第一步中。