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    • 2. 发明授权
    • Gas generant manufacture
    • 气体发生器制造
    • US06224697B1
    • 2001-05-01
    • US09454041
    • 1999-12-03
    • Ivan V. MendenhallRobert G. SmithRobert D. Taylor
    • Ivan V. MendenhallRobert G. SmithRobert D. Taylor
    • D03D2300
    • C06B31/00C06B21/0066C06D5/06
    • A method of making a gas generant formulation which contains a transition metal diammine dinitrate is provided wherein a transition metal nitrate is reacted with an ammonia source to form an aqueous slurry containing a corresponding reaction mixture. A spray dryable precursor to the gas generant formulation is formed including at least a gas generating fuel and a sufficient quantity of water to render the precursor spray dryable. The precursor is subsequently spray dried to form a gas generant powder. The method may also include a relatively mild heat treatment of the dried material, either as a part of the spray drying or subsequent to such spray drying.
    • 提供了一种制备含有过渡金属二硝酸二铵的气体发生剂配方的方法,其中过渡金属硝酸盐与氨源反应形成含有相应反应混合物的含水浆料。 形成气体发生剂配方的可喷雾干燥的前体,其至少包括产生气体的燃料和足够量的水以使前体喷雾可干燥。 随后喷雾干燥前体以形成气体发生剂粉末。 该方法还可以包括干燥的材料的相对温和的热处理,作为喷雾干燥的一部分或者在这种喷雾干燥之后。
    • 4. 发明授权
    • Gas generant manufacture
    • 气体发生器制造
    • US06436211B1
    • 2002-08-20
    • US09618646
    • 2000-07-18
    • Ivan V. MendenhallRobert G. SmithRobert D. Taylor
    • Ivan V. MendenhallRobert G. SmithRobert D. Taylor
    • D03D2300
    • C06D5/06C06B31/00
    • A method of making a gas generant formulation which contains a transition metal diammine dinitrate is provided wherein a transition metal ammine carbonate is reacted with nitric acid in the presence of water to form a corresponding reaction mixture. A spray dryable precursor to the gas generant formulation is formed including at least a gas generating fuel and a sufficient quantity of water to render the precursor spray dryable. The precursor is subsequently spray dried to form a gas generant powder. The method may also include a relatively mild heat treatment of the dried material, either as a part of the spray drying or subsequent to such spray drying. A phase stabilized ammonium nitrate and a corresponding method of making the same wherein ammonium nitrate is stabilized through the presence of a stabilizing metal diammine dinitrate are also provided.
    • 提供了一种制备含有过渡金属二硝酸二铵的气体发生剂制剂的方法,其中过渡金属氨基甲酸铵与硝酸在水的存在下反应形成相应的反应混合物。 形成气体发生剂配方的可喷雾干燥的前体,其至少包括产生气体的燃料和足够量的水以使前体喷雾可干燥。 随后喷雾干燥前体以形成气体发生剂粉末。 该方法还可以包括干燥的材料的相对温和的热处理,作为喷雾干燥的一部分或者在这种喷雾干燥之后。 还提供了一种相稳定的硝酸铵及其相应的制备方法,其中硝酸铵通过稳定的二氧化钛稳定二硝酸盐的存在来稳定。
    • 7. 发明授权
    • Ammonium perchlorate-containing gas generants
    • 含高氯酸铵的气体发生剂
    • US07147733B2
    • 2006-12-12
    • US10899451
    • 2004-07-26
    • Michael W. BarnesIvan V. MendenhallRobert D. Taylor
    • Michael W. BarnesIvan V. MendenhallRobert D. Taylor
    • C06B31/00C06B29/22
    • C06B23/02C06B29/22
    • Ammonium perchlorate-containing gas generant compositions which, upon combustion, produce or result in an improved effluent and related methods for generating an inflation gas for use in an inflatable restraint system are provided. Such ammonium perchlorate-containing gas generant compositions include ammonium perchlorate present with a mean particle size in excess of 100 microns. Such ammonium perchlorate-containing gas generant compositions also include or contain a chlorine scavenger present in an amount effective to result in a gaseous effluent that is substantially free of hydrogen chloride when the gas generant is combusted, wherein at least about 98 weight percent of the chlorine scavenger is a copper-containing compound. Suitable copper-containing chlorine scavenger compounds include basic copper nitrate, cupric oxide, copper diammine dinitrate-ammonium nitrate mixture wherein ammonium nitrate is present in the mixture in a range of about 3 to about 90 weight percent, copper diammine bitetrazole, a copper-nitrate complex resulting from reaction of 5-aminotetrazole with basic copper nitrate and combinations thereof.
    • 提供了含有高氯酸铵的气体发生剂组合物,其在燃烧时产生或导致改进的流出物以及用于产生用于可充气约束系统的膨胀气体的相关方法。 这种含高氯酸铵的气体发生剂组合物包括平均粒径超过100微米的高氯酸铵。 这种含高氯酸铵的气体发生剂组合物还包含或含有氯清除剂,其量有效地导致当气体发生剂燃烧时基本上不含氯化氢的气态流出物,其中至少约98重量%的氯 清除剂是含铜化合物。 合适的含铜氯清除剂包括碱式硝酸铜,氧化铜,二硝酸铜二硝酸铵 - 硝酸铵混合物,其中硝酸铵在约3至约90重量%的范围内存在于混合物中,铜二氨基四唑,硝酸铜 由5-氨基四唑与碱式硝酸铜反应产生的络合物及其组合。