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1. 发明授权

US5840814A Multi-arm star polymers having a well-defined core and methods for the synthesis thereof 失效
标题翻译：具有明确核心的多臂星形聚合物及其合成方法
公开(公告)号：US5840814A
公开(公告)日：1998-11-24
申请号：US693418
申请日：1996-08-07
申请人： Istvan J. Majoros , Timea M. Marsalko , Joseph P. Kennedy
发明人： Istvan J. Majoros , Timea M. Marsalko , Joseph P. Kennedy
IPC分类号： C07C43/215 , C07C69/00 , C07C69/712 , C08F8/14 , C08G77/38 , C08G77/52 , C08G81/02 , C08G85/00
CPC分类号： C07C43/215 , C07C69/00 , C08G77/38 , C08G77/52 , C08G81/024 , C07C2103/00 , C07C2103/92
摘要： The synthesis of star polymers having well-defined arms emanating from well-defined and readily controllable calix�n!arene (n=4 to 16) cores are described. The synthesis is particularly suitable for polyisobutylene and/or polysiloxane star polymers. The synthesis has been achieved using carbocationic and/or anionic ring-opening polymerization techniques to form polymer arms of desired molecular weights, then separately preparing the calixarene derivative core, and finally, linking the arms to the core by transesterification or hydrosilation.
摘要翻译：描述了从明确定义且容易控制的杯[n]芳烃（n = 4至16）核发出具有明确定义的臂的星形聚合物的合成。该合成特别适用于聚异丁烯和/或聚硅氧烷星形聚合物。已经使用碳阳离子和/或阴离子开环聚合技术来合成以形成所需分子量的聚合物臂，然后单独制备杯芳烃衍生物核心，最后通过酯交换或硅氢化将臂与核心连接。

2. 发明授权

US5395885A Multi-arm cationic star-polymers 失效
标题翻译：多臂阳离子星形聚合物
公开(公告)号：US5395885A
公开(公告)日：1995-03-07
申请号：US169434
申请日：1993-12-17
申请人： Joseph P. Kennedy , Timea M. Marsalko , Istvan J. Majoros
发明人： Joseph P. Kennedy , Timea M. Marsalko , Istvan J. Majoros
IPC分类号： C08F293/00 , C08F297/00 , C08G81/00
CPC分类号： C08F297/00
摘要： The first synthesis of a multi-arm radial-star polyisobutylene is described. The synthesis occurred by the addition of excess divinylbenzene (DVB) linking reagent to a living polyisobutylene (PIB.sup..sym.), charge, i.e., by the "arm first" method under specific conditions. The radial structure of the star-PIB was proven by determining the molecular weight of a sample by light scattering, then selectively destroying the aromatic polydivinylbenzene core, and finally determining the molecular weight of the surviving aliphatic PIB arms. The synthesis strategy, kinetic observations during synthesis, and procedures leading to a representative star-PIB are described. This product whose M.sub.w =1,134,400 g/mole with M.sub.w /M.sub.n =2.83, contained .about.90.3 mole % (.about.78 wt. %) PIB arms and .about.9.7 mole % (.about.22 wt. %) aromatic core; thus the number of PIB arms emanating from the core was N.sub.n, arm =56 or N.sub.w, arm (weight average number of arms)=110.
摘要翻译：描述了多臂径向星形聚异丁烯的第一次合成。通过在特定条件下通过加入过量的二乙烯基苯（DVB）连接试剂与活性聚异丁烯（PIB（+））进行合成，即通过“臂第一”方法进行加料。通过用光散射确定样品的分子量，然后选择性地破坏芳族聚二乙烯基苯核心，最后确定存活的脂族PIB臂的分子量，证明了星形PIB的径向结构。描述了合成策略，合成过程中的动力学观察以及导致代表性的星形-PIB的程序。该产品的＆upbar＆Mw = 1,134,400克/摩尔＆lt;上升＆Mw /＆upbar＆Mn = 2.83，含有差异90.3摩尔％（差异78重量％）PIB臂和差异9.7摩尔％（差异22重量％）芳香核; 因此从核心发出的PIB武器的数量是＆upbar＆Nn，arm = 56或＆upbar＆Nw，手臂（重量平均臂数）= 110。

3. 发明授权

US5844056A Star polymers having multiple polyisobutylene arms emanating from a calixarene core, initiators therefor, and method for the synthesis thereof 失效
标题翻译：具有从杯芳烃核发出的多个聚异丁烯臂的星形聚合物，其引发剂及其合成方法
公开(公告)号：US5844056A
公开(公告)日：1998-12-01
申请号：US693433
申请日：1996-08-07
申请人： Joseph P. Kennedy , Istvan J. Majoros , Sunny Jacob
发明人： Joseph P. Kennedy , Istvan J. Majoros , Sunny Jacob
IPC分类号： C08F4/14 , C08F10/10 , C08F297/06 , C07C43/225 , C07C43/23
CPC分类号： C08F297/06 , C08F10/10 , Y10S525/918 , Y10S526/941
摘要： The synthesis and characterization of novel linear polymers and multi-arm star polymers comprising polyisobutylene arms connected to a well-defined calixarene core are described. The polymers are directly telechelic. They synthesis has been achieved using the "core first" method wherein multifunctional calix�n!arene (where n=4 to 16) derivatives or their monofunctional analogues are used as initiators which, in conjunction with certain Freidel-Crafts acids as co-initiators, induce the living polymerization of isobutylene or a similar carbocationic polymerizable monomer. Novel initiators suitable for inducing the polymerization are also described.
摘要翻译：描述了包含连接到明确定义的杯芳烃核心的聚异丁烯臂的新型线性聚合物和多臂星形聚合物的合成和表征。聚合物是直接遥爪的。使用其中多功能杯[n]芳烃（其中n = 4至16）衍生物或其单官能类似物用作引发剂的“核心优先”方法已经实现了它们的合成，这些引发剂与某些Freidel-Crafts酸作为共引发剂诱导异丁烯或类似的碳阳离子聚合性单体的活性聚合。还描述了适合于引发聚合的新型引发剂。

4. 发明授权

US5804664A Star polymers having multiple arms emanating from a calixarene core, initiators therefor, and method for the synthesis thereof 失效
标题翻译：具有从杯芳烃核心发出的多臂的星形聚合物，其引发剂及其合成方法
公开(公告)号：US5804664A
公开(公告)日：1998-09-08
申请号：US862581
申请日：1997-05-23
申请人： Joseph P. Kennedy , Istvan J. Majoros , Sunny Jacob
发明人： Joseph P. Kennedy , Istvan J. Majoros , Sunny Jacob
IPC分类号： C08F4/14 , C08F10/10 , C08F297/06 , C08L53/02
CPC分类号： C08F297/06 , C08F10/10
摘要： The synthesis and characterization of novel linear polymers and multi-arm star polymers comprising polyisobutylene arms connected to a well-defined calixarene core are described. The synthesis has been achieved using the "core first" method wherein multifunctional calix�n!arene (where n=4 to 16) derivatives or their monofunctional analogues are used as initiators which, in conjunction with certain Freidel-Crafts acids as co-initiators, induce the living polymerization of isobutylene or a similar carbocationic polymerizable monomer to form star polymers or block copolymers. Novel initiators suitable for inducing the polymerization are also described.
摘要翻译：描述了包含连接到明确定义的杯芳烃核心的聚异丁烯臂的新型线性聚合物和多臂星形聚合物的合成和表征。使用其中多功能杯[n]芳烃（其中n = 4至16）衍生物或其单官能类似物用作引发剂的“核心优先”方法已经实现了合成，其结合某些Freidel-Crafts酸作为共引发剂诱导异丁烯或类似的碳阳离子聚合单体的活性聚合形成星形聚合物或嵌段共聚物。还描述了适合于引发聚合的新型引发剂。

5. 发明授权

US12091489B1 Multiply-crosslinked polyisobutylene-based polyurethanes and their preparations and uses thereof 有权
公开(公告)号：US12091489B1
公开(公告)日：2024-09-17
申请号：US18602926
申请日：2024-03-12
申请人： Joseph P. Kennedy , Turgut Nugay
发明人： Joseph P. Kennedy , Turgut Nugay
IPC分类号： C08G18/62 , A61F2/24 , C08G18/12 , C08G18/24 , C08G18/32 , C08L75/04
CPC分类号： C08G18/6204 , A61F2/24 , C08G18/12 , C08G18/242 , C08G18/3206 , C08G18/3228 , C08L75/04 , C08L2312/00
摘要： A multiply-crosslinked polyisobutylene-based polyurethane includes a plurality of multi-telechelic polyisobutylene-based segments and a plurality of urethane segments having a plurality of chain extender-based segments therein. Each end of one of the plurality of urethane segments is linked either to an end of one of the plurality of multi-telechelic polyisobutylene-based segments, or to an end of one of the plurality of chain extender-based segments. Also, one or more of the plurality of urethane segments are physically crosslinked to one or more other of the plurality of urethane segments. Notably, the plurality of multi-telechelic polyisobutylene-based segments constitute at least 70 weight percent of the polyisobutylene-based polyurethane and the plurality of urethane segments, including the plurality of chain extender-based segments therein, constitute up to 30 weight percent of the polyisobutylene-based polyurethane.

6. 发明授权

US10329361B2 Quantitative preparation of allyl telechelic polyisobutylene under reflux conditions 有权
公开(公告)号：US10329361B2
公开(公告)日：2019-06-25
申请号：US15795638
申请日：2017-10-27
申请人： Joseph P. Kennedy , Tejal J. Deodhar , Balazs L. Keszler
发明人： Joseph P. Kennedy , Tejal J. Deodhar , Balazs L. Keszler
IPC分类号： C08F110/10 , C08F2/01 , C08F2/06 , C08F2/38 , C07C22/04
摘要： In one or more embodiments, the present invention provides a method for forming allyl telechelic polyisobutylene polymers having well defined molecular weights and molecular weight distributions using living cationic polymerization under ideal temperature control using a mixture of polar and nonpolar refluxing solvents. The methods according to various embodiments of the present invention provide temperature control that approaches the ideal, i.e., the heat of polymerization is instantaneously absorbed by the medium and the temperature of the system remains unchanged. The heat generated during the exothermic polymerization of isobutylene is released as an increase in the rate of reflux, rather than the temperature, since the temperature is set by the boiling point of the system and does not change.

7. 发明授权

US09588218B2 System and method for robust navigation and geolocation using measurements of opportunity 有权
标题翻译：使用机会测量的鲁棒导航和地理位置的系统和方法
公开(公告)号：US09588218B2
公开(公告)日：2017-03-07
申请号：US13250134
申请日：2011-09-30
申请人： Joseph P. Kennedy , John Carlson
发明人： Joseph P. Kennedy , John Carlson
IPC分类号： G01S19/38 , G01S5/02
CPC分类号： G01S5/0289 , G01S5/0242 , G01S5/0252 , G01S19/215 , G01S19/46
摘要： A system and method to opportunistically capture and use measurements on a priori unknown radio signals, not intended for radio navigation or geolocation, to improve navigation/geolocation position estimation yield and accuracy.
摘要翻译：一种系统和方法，用于机会地捕获和使用不适用于无线电导航或地理定位的先验未知无线电信号的测量，以改善导航/地理定位位置估计的产量和准确度。

8. 发明申请

US20120157603A1 THERMOPLASTIC ELASTOMERIC MULTIBLOCK COPOLYMERS OF ISOBUTYLENE AND NORBORNENE 审中-公开
标题翻译：异丁烯和异丁烯的热塑性弹性体多元共聚物
公开(公告)号：US20120157603A1
公开(公告)日：2012-06-21
申请号：US13329870
申请日：2011-12-19
申请人： Joseph P. Kennedy , Ralf M. Peetz
发明人： Joseph P. Kennedy , Ralf M. Peetz
IPC分类号： C08F279/00 , C09D145/00 , C09J145/00
CPC分类号： C09J153/00 , C08F210/10 , C08F297/00 , C08L53/00 , C08L2666/02 , C08L2666/24 , C09D153/00 , C08F4/06
摘要： A composition of matter including a polyisobutylene segment and a polycycloolefin segment. The polyisobutylene segment and the polycycloolefin segment form a repeating unit multiblock copolymer. A method of forming a composition of matter that includes a polyisobutylene segment and a polycycloolefin segment.
摘要翻译：包括聚异丁烯链段和聚环烯烃链段的物质组合物。聚异丁烯链段和聚环烯烃链段形成重复单元多嵌段共聚物。一种形成包含聚异丁烯链段和聚环烯烃链段的物质组合物的方法。

9. 发明授权

US07974633B2 System and method for single sensor geolocation 失效
标题翻译：单传感器地理位置的系统和方法
公开(公告)号：US07974633B2
公开(公告)日：2011-07-05
申请号：US11505950
申请日：2006-08-18
申请人： Joseph P. Kennedy , John P. Carlson
发明人： Joseph P. Kennedy , John P. Carlson
IPC分类号： H04W24/00
CPC分类号： H04W64/00 , G01S5/0252 , G01S5/14
摘要： A system and method for determining a position of a wireless mobile device. The method comprising the steps of providing one base station in communication with the mobile device, providing a sensor spaced apart a known distance from the base station, and determining the range between the mobile device and the base station. The time of arrival of a signal transmitted from the mobile device is measured at the sensor and a set of coordinates is calculated for the mobile device relative to the sensor as a function of the known distance from the sensor to the base station, the range between the mobile device and the base station, an estimate of base station transmission timing relative to a time source, and the time of arrival. One of the set of coordinates may then be chosen to thereby determine a position of the mobile device relative to the sensor.
摘要翻译：一种用于确定无线移动设备的位置的系统和方法。该方法包括以下步骤：提供与移动设备通信的一个基站，提供与基站间隔开已知距离的传感器，以及确定移动设备与基站之间的距离。在传感器处测量从移动设备发送的信号的到达时间，并且针对移动设备相对于传感器计算一组坐标作为从传感器到基站的已知距离的函数，移动设备和基站，相对于时间源的基站传输定时的估计以及到达时间。然后可以选择坐标系中的一个，从而确定移动设备相对于传感器的位置。

10. 发明申请

US20100209468A1 IMPLANTABLE DEVICES FOR PRODUCING INSULIN 有权
标题翻译：用于生产胰岛素的可植入装置
公开(公告)号：US20100209468A1
公开(公告)日：2010-08-19
申请号：US12439057
申请日：2007-08-29
申请人： Joseph P. Kennedy , Gabor Erdodi
发明人： Joseph P. Kennedy , Gabor Erdodi
IPC分类号： A61K35/12 , A61K9/00 , A61K38/28 , A61P3/10
CPC分类号： A61L27/3804 , A61F2/022 , A61K9/0024 , A61L27/3839
摘要： The present invention generally relates to implantable devices for producing insulin in diabetic animals. Some embodiments include amphiphilic biomembranes for use in biological applications (e.g., as an alternative and/or supplemental insulin source). Some embodiments also include live insulin-producing cells contained within one or more amphiphilic membranes so as to prevent or diminish an immuno-response and/or rejection by the host.
摘要翻译：本发明一般涉及用于在糖尿病动物中产生胰岛素的可植入装置。一些实施方案包括用于生物应用的两亲生物膜（例如，作为替代和/或补充胰岛素源）。一些实施方案还包括含在一个或多个两亲膜内的活的产生胰岛素的细胞，以便防止或减少宿主的免疫应答和/或排斥。

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